Fabrication of high-performance ternary carbon nitride ceramics using ubiquitous elements

• Project/Area Number: 26630372
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Material processing/Microstructural control engineering
• Research Institution: National Institute for Materials Science
• Principal Investigator: Sakka Yoshio 国立研究開発法人物質・材料研究機構, 機能材料研究拠点, 特命研究員 (00354217)
• Project Period (FY): 2014-04-01 – 2016-03-31
• Project Status: Completed (Fiscal Year 2015)
• Budget Amount: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000); Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
• Keywords: 非酸化物セラミックス / 配向 / 焼結 / 力学特性 / コロイド成形 / 粉体 / 配向体 / MAX相セラミックス / 高強度 / 高靱性 / 非酸化物

Outline of Final Research Achievements

The purpose of this research is to fabricate high-performance ternary carbon nitride ceramics using ubiquitous elements by texturing.
Texture Ti3SiC2 and alumina dispersed Ti3SiC2 were successfully prepared by slip casting under a strong magnetic field followed by pulsed current sintering. Both bending strength and fracture toughness of Ti3SiC2 have been improved by texturing and alumina addition. In addition textured Ti2AlN shows higher bending strength, fracture toughness and wear resistance than those of non-textured Ti2AlN.New types of stable phase of MAX phase ceramics with X=B and two-dimensional transition metal carbides, Mxenes, were demonstrated to show unique properties by calculations.

Research Products

• [Journal Article] 微粉体プロセスの高度化による高次構造制御セラミックスの創製 (2015)
  • Author(s): 目義雄
  • Journal Title: 粉砕 Volume: 58 Pages: 3-10
  • NAID: 130007495425
  • Peer Reviewed
• [Journal Article] Mo2Ga2C: A new ternary nanolaminated carbide (2015)
  • Author(s): HU Chunfeng, C. C., Tao Q, Lu J, Halim J, Sun L, Zhan J, Wang J, Yang J, Anasori B, Y. Sakka, L. Hultman, Rosen J, Ekulund P, Barsoum MW
  • Journal Title: Chem.Comm.. Volume: 51 Issue: 30 Pages: 6560-6563
  • DOI: 10.1039/c5cc00980d
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Deflocculation and stabilization of Ti₃SiC₂ ceramic powder in gelcasting process (2015)
  • Author(s): A. Idzkowska, K. Sato, Y. Sakka, Warsaw UT
  • Journal Title: Journal of the Ceramic Society of Japan Volume: 123 Issue: 1443 Pages: 1010-1017
  • DOI: 10.2109/jcersj2.123.1010
  • NAID: 130005106918
  • ISSN: 1348-6535, 1882-0743
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Tailoring Ti3AlC2 ceramic with high anisotropic physical and mechanical properties (2015)
  • Author(s): H.B.Zhang, C.F.Hu, K. Sato, S. Grasso, M. Estili, S.Q. Guo, K. Morita, H. Yoshida, T. Nishimura, T. S. Suzuki, M. W. Barsoum, B. N. Kim, Y. Sakka
  • Journal Title: J. Europ. Ceram. Soc. Volume: 35 Pages: 393-397
  • Peer Reviewed
• [Journal Article] 磁場中スリップキャストとパルス通電焼結によるTi2AlN配向体の創製 (2014)
  • Author(s): 武舍翔太郎, 佐藤仁俊, 鈴木達, 藤本憲次郎, 目義雄
  • Journal Title: 粉体および粉末冶金 Volume: 61 Pages: 538-543
  • NAID: 130004705370
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Fabrication of textured Ti₃SiC₂ ceramic by slip casting in a strong magnetic field and pressureless sintering (2014)
  • Author(s): K. Sato, M. Mishra, H. Hirano, T. Suzuki, Y. Sakka
  • Journal Title: Journal of the Ceramic Society of Japan Volume: 122 Issue: 1429 Pages: 817-821
  • DOI: 10.2109/jcersj2.122.817
  • NAID: 130004951027
  • ISSN: 1348-6535, 1882-0743
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Pressureless Sintering and Reaction Mechanisms of Ti3SiC2 Ceramics (2014)
  • Author(s): K. Sato, M. Mishra, H. Hirano, C. Hu and Y. Sakka
  • Journal Title: J. Am. Ceram. Soc. Volume: 97 Issue: 5 Pages: 1407-1412
  • DOI: 10.1111/jace.12903
  • Peer Reviewed
• [Presentation] Preparation and some properties of textured Ti2AlN ceramics (2016)
  • Author(s): S. Musha, K. Sato, T. Suzuki, Y. Sakka
  • Organizer: European Ceramic Society 2015
  • Place of Presentation: Toredo, Spain
  • Year and Date: 2016-06-21
  • Int'l Joint Research
• [Presentation] Ti3SiC2系MAX相セラミックス配向体の作製とその力学特性 (2016)
  • Author(s): 打田 雄一、武舎翔太郎、 森田孝治、 鈴木達、 西村聡之、 藤本憲次郎、目義雄
  • Organizer: 日本セラミックス協会 2016年年会
  • Place of Presentation: 早稲田大学、東京
  • Year and Date: 2016-03-14
• [Presentation] 磁場中スリップキャストによるTi2AlN配向体の作製とその特性評価 (2016)
  • Author(s): 武舍 翔太郎, 笠原 章, 土佐 正弘, 鈴木 達, 西村 聡之, 藤本 憲次郎, 目 義雄
  • Organizer: 日本セラミックス協会 2016年年会
  • Place of Presentation: 早稲田大学、東京
  • Year and Date: 2016-03-14
• [Presentation] 強磁場を利用したセラミック配向体の作製とその特性 (2016)
  • Author(s): 目義雄
  • Organizer: 第16回バルクセラミックス研究会
  • Place of Presentation: 早稲田大学、東京
  • Year and Date: 2016-03-14
  • Invited
• [Presentation] 強磁場中コロイド成形による配向セラミックスの作製とその特性 (2016)
  • Author(s): 目義雄
  • Organizer: 2015年度第3回 多次元拘束磁場の発生と物質応答に関する調査研究会
  • Place of Presentation: 早稲田大学、東京
  • Year and Date: 2016-03-10
  • Invited
• [Presentation] Texture developing and some properties of feeble magnetic ceramics (2016)
  • Author(s): Y. Sakka
  • Organizer: EMN Meeting/Ceramics
  • Place of Presentation: 香港
  • Year and Date: 2016-01-25
  • Int'l Joint Research / Invited
• [Presentation] Development of Electric current activated/assisted sintering (ECAS) (2015)
  • Author(s): Y. Sakka
  • Organizer: 32nd International Japan-Korea Seminar on Ceramics
  • Place of Presentation: 長岡市
  • Year and Date: 2015-11-18
  • Int'l Joint Research / Invited
• [Presentation] Fabrication and some properties of Textured MAX phase Ceramics (2015)
  • Author(s): Y. Sakka, S. Musha, T. Suzuki
  • Organizer: 3rd International Conference on Powder Metallurgy in Asia
  • Place of Presentation: 京都大学
  • Year and Date: 2015-11-08
  • Int'l Joint Research
• [Presentation] Texture developing and some properties of feeble magnetic ceramics (2015)
  • Author(s): Y. Sakka, C. Hu, T. Suzuki, T. Uchikoshi
  • Organizer: PACRIM 11
  • Place of Presentation: 済州島、韓国
  • Year and Date: 2015-08-30
  • Int'l Joint Research / Invited
• [Presentation] Fabrication and some properties of Textured MAX phase Ceramics (2015)
  • Author(s): Y. Sakka, S. Musha, K. Sato, C. Hu, T. Suzuki
  • Organizer: ICCC
  • Place of Presentation: 倉敷
  • Year and Date: 2015-07-07
  • Int'l Joint Research
• [Presentation] 磁場中スリップキャストによるTi2AlN配向体と特性評価 (2015)
  • Author(s): 武舍翔太郎, 鈴木達, 藤本憲次郎, 目義雄
  • Organizer: 材料科学会年会
  • Place of Presentation: 工学院大学、東京
  • Year and Date: 2015-06-05
• [Presentation] Fabrication of advanced ceramics by electric current activated/assisted sintering (2015)
  • Author(s): Y. Sakka, M. Estili, C. Hu, K. Sato, G. Salvatore
  • Organizer: Engineering Ceramics 2015
  • Place of Presentation: The Castle of Smolence, Slovakia
  • Year and Date: 2015-05-10
  • Int'l Joint Research / Invited
• [Presentation] 微粒子プロセスの高度化による多機能材料の創製 (2015)
  • Author(s): 目 義雄
  • Organizer: 応用物理学会春期大会
  • Place of Presentation: 東海大学
  • Year and Date: 2015-03-12
  • Invited
• [Presentation] Texture developing and some properties of feeble magnetic ceramics by colloidal processing in a strong magnetic field (2014)
  • Author(s): Y. Sakka, T. Suzuki, T. Uchikoshi
  • Organizer: Materiaux2014
  • Place of Presentation: フランス、モンペリエ
  • Year and Date: 2014-11-24 – 2014-11-28
  • Invited
• [Presentation] MAX相セラミックスのコロイド成形（スリップキャスト、ゲルキャスト、電気泳動堆積）と配向体の作製 (2014)
  • Author(s): 目 義雄
  • Organizer: 日本学術振興会先進セラミックス第124委員会第146回会議
  • Place of Presentation: 東工大
  • Year and Date: 2014-09-30
• [Presentation] Fabrication of textured MAX phase ceramics through colloidal processing in strong magnetic field and subsequent sintering (2014)
  • Author(s): Y. Sakka, K. Sato, C. Hu, T. Suzuki
  • Organizer: Sintering 2014
  • Place of Presentation: ドイツ、ドレスデン
  • Year and Date: 2014-08-24 – 2014-08-28
• [Presentation] Fabrication of textured MAX phase ceramics through colloidal processing in strong magnetic field and subsequent sintering (2014)
  • Author(s): Y. Sakka, K. Sato, S. Musha, C. Hu, T. Suzuki
  • Organizer: The 5th International Congress on Ceramics (ICC5)
  • Place of Presentation: イタリア、モンテカティーニ
  • Year and Date: 2014-08-17 – 2014-08-21
  • Invited
• [Presentation] Texture developing and some properties of feeble magnetic ceramics (2014)
  • Author(s): Y. Sakka, K. Sato, C. Hu, T. Suzuki, T. Uchikoshi
  • Organizer: MAP6
  • Place of Presentation: 沖縄
  • Year and Date: 2014-07-08 – 2014-07-10
  • Invited
• [Presentation] Fabrication and some properties of textured Ti2AlN ceramic by slip casting in a strong magnetic field and spark plasma sintering (2014)
  • Author(s): S. Musha, K. Sato, C. Hu, T. Suzuki, Y. Sakka
  • Organizer: MAP6
  • Place of Presentation: 沖縄
  • Year and Date: 2014-07-08 – 2014-07-10
• [Remarks] SAMURAI
  • URL: http://samurai.nims.go.jp/SAKKA_Yoshio-j.html
• [Remarks] NIMS Researcher Database SAMURAI
  • URL: http://samurai.nims.go.jp/SAKKA_Yoshio-j.html