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Study of coordination polymer showing crystal melting

Research Project

Project/Area Number 26708006
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Inorganic chemistry
Research InstitutionKyoto University

Principal Investigator

HORIKE SATOSHI  京都大学, 物質-細胞統合システム拠点, 准教授 (70552652)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥24,700,000 (Direct Cost: ¥19,000,000、Indirect Cost: ¥5,700,000)
Fiscal Year 2015: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Fiscal Year 2014: ¥13,000,000 (Direct Cost: ¥10,000,000、Indirect Cost: ¥3,000,000)
Keywords配位高分子 / 固液相転移 / イオン伝導 / ガラス / 錯体 / 相転移 / イオン液体 / ガス吸着
Outline of Final Research Achievements

Coordination polymer (CP) is a crystalline material composed of metal ions and bridging ligands. Most of the research of CP are for crystalline phase, and this research focused on the phase transition of CP such as cyrstal melt, crystal-to-glass transformation. In the first research period, we investigated the appropriate composition of CP which show crystal melt/vitrification. We then moved to design the unique functionality based on the melting CP crystal. We found high ion conductive CP glass, switching of ion current in CP glass, and porous CP glass for example. Some has also the property of transparency and it is promising to design multifunctional CP such as optics/conductivity.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (38 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (1 results) Journal Article (17 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 17 results,  Acknowledgement Compliant: 12 results,  Open Access: 2 results) Presentation (19 results) (of which Int'l Joint Research: 7 results,  Invited: 18 results) Book (1 results)

  • [Int'l Joint Research] University of Milano Bicocca/Department of Materials Science(イタリア)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Mechanical Alloying of Metal-Organic Frameworks2017

    • Author(s)
      Tamas Panda, Satoshi Horike, Keisuke Hagi, Naoki Ogiwara, Kentaro Kadota, Tomoya Itakura, Masahiko Tsujimoto, Susumu Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 56 Issue: 9 Pages: 2413-2417

    • DOI

      10.1002/anie.201612587

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fast Conduction of Organic Cations in Metal Sulfate Frameworks2016

    • Author(s)
      Naoki Ogiwara, Munehiro Inukai, Tomoya Itakura, Satoshi Horike, Susumu Kitagawa
    • Journal Title

      Chem. Mater.

      Volume: 28 Issue: 11 Pages: 3968-3975

    • DOI

      10.1021/acs.chemmater.6b01284

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Encapsulating Mobile Proton Carriers into Structural Defects in Coordination Polymer Crystals: High Anhydrous Proton Conduction and Fuel Cell Application2016

    • Author(s)
      Munehiro Inukai, Satoshi Horike, Tomoya Itakura, Ryota Shinozaki, Naoki Ogiwara, Daiki Umeyama, Sanjog Nagarkar, Yusuke Nishiyama, Michal Malon, Akari Hayashi, Takashi Ohhara, Ryoji Kiyanagi, Susumu Kitagawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 27 Pages: 8505-8511

    • DOI

      10.1021/jacs.6b03625

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recognition of 1,3-Butadiene by a Porous Coordination Polymer2016

    • Author(s)
      Keisuke Kishida, Yoshikuni Okumura, Yoshihiro Watanabe, Megumi Mukoyoshi, Silvia Bracco, Angiolina Comotti, Piero Sozzani, Satoshi Horike, Susumu Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 44 Pages: 13784-13788

    • DOI

      10.1002/anie.201607676

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Freeze-drying synthesis of an amorphous Zn(2+) complex and its transformation to a 2-D coordination framework in the solid state2016

    • Author(s)
      Itakura, T.; Horike, S.; Inukai, M.; Kitagawa, S.
    • Journal Title

      Dalton Trans.

      Volume: 45 Issue: 10 Pages: 4127-4131

    • DOI

      10.1039/c5dt03286e

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Glass Formation of a Coordination Polymer Crystal for Enhanced Proton Conductivity and Material Flexibility2016

    • Author(s)
      Chen, W.; Horike, S.; Umeyama, D.; Ogiwara, N.; Itakura, T.; Tassel, C.; Goto, Y.; Kageyama, H.; Kitagawa, S.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 17 Pages: 5195-5200

    • DOI

      10.1002/anie.201600123

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Glass formation via structural fragmentation of a 2D coordination network2015

    • Author(s)
      Umeyama, D.; Funnell, N. P.; Cliffe, M. J.; Hill, J. A.; Goodwin, A. L.; Hijikata, Y.; Itakura, T.; Okubo, T.; Horike, S.; Kitagawa, S.
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 64 Pages: 12728-12731

    • DOI

      10.1039/c5cc04626b

    • NAID

      120005672584

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation of Foam-like Microstructural Carbon Material by Carbonization of Porous Coordination Polymers through a Ligand-Assisted Foaming Process2015

    • Author(s)
      Kongpatpanich, K.; Horike, S.; Fujiwara, Y.; Ogiwara, N.; Nishihara, H.; Kitagawa, S.
    • Journal Title

      Chem. Eur. J.

      Volume: 21 Issue: 38 Pages: 13278-13283

    • DOI

      10.1002/chem.201501988

    • NAID

      120005672583

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Control of Molecular Rotor Rotational Frequencies in Porous Coordination Polymers Using a Solid-Solution Approach2015

    • Author(s)
      Inukai, M.; Fukushima, T.; Hijikata, Y.; Ogiwara, N.; Horike, S.; Kitagawa, S.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 137 Issue: 38 Pages: 12183-12186

    • DOI

      10.1021/jacs.5b05413

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 1.Reversible Solid-to-Liquid Phase Transition of Coordination Polymer Crystals2015

    • Author(s)
      Daiki Umeyama, Satoshi Horike, Munehiro Inukai, Tomoya Itakura, Susumu Kitagawa
    • Journal Title

      Journal of the American Chemical Society

      Volume: 137 Issue: 2 Pages: 864-870

    • DOI

      10.1021/ja511019u

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of magnesium ZIF-8 from Mg(BH)22015

    • Author(s)
      S. Horike, K. Kadota, T. Itakura, M. Inukai, S. Kitagawa
    • Journal Title

      Dalton Trans.

      Volume: 44 Issue: 34 Pages: 15107-15110

    • DOI

      10.1039/c5dt01183c

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Control of Pore Distribution of Porous Carbons Derive From Mg2+ Porous Coordination Polymers2015

    • Author(s)
      Yuichi Fujiwara, Satoshi Horike, Kanokwan Kongpatpanich, Takashi Sugiyama, Norio Tobori, Hirotomo Nishihara, Susumu Kitagawa
    • Journal Title

      Inorg. Chem. Front.

      Volume: 2 Issue: 5 Pages: 473-476

    • DOI

      10.1039/c5qi00019j

    • NAID

      120005712916

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Study on a 2D layer coordination framework showing order-to-disorder phase transition by ionothermal synthesis.2015

    • Author(s)
      Wenqian Chen, Satoshi Horike, Munehiro Inukai, Susumu Kitagawa
    • Journal Title

      Polymer Journal

      Volume: 47 Issue: 2 Pages: 141-145

    • DOI

      10.1038/pj.2014.100

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressure-induced Amorphization of a Dense Coordination Polymer and Its Impact on Proton Conductivity2014

    • Author(s)
      Daiki Umeyama, Satoshi Horike, Cedric Tassel, Hiroshi Kageyama, Yuji Higo, Keisuke Hagi, Naoki Ogiwara, Susumu Kitagawa
    • Journal Title

      APL Materials

      Volume: 2 Issue: 12 Pages: 124401-124401

    • DOI

      10.1063/1.4898806

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and Porous Properties of Chromium Azolate Porous Coordination Polymers2014

    • Author(s)
      Kanokwan Kongpatpanich, Satoshi Horike, Masayuki Sugimoto, Tomohiro Fukushima, Daiki Umeyama, Yosuke Tsutsumi, Susumu Kitagawa
    • Journal Title

      Inorg. Chem.

      Volume: 53 Issue: 18 Pages: 9870-9875

    • DOI

      10.1021/ic501459m

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Template-Directed Proton Conduction Pathways in a Coordination Framework2014

    • Author(s)
      Munehiro Inukai, Satoshi Horike, Wenqian Chen, Daiki Umeyama, Tomoya Itakura, Susumu Kitagawa
    • Journal Title

      J. Mater. Chem. A

      Volume: 2 Issue: 27 Pages: 10404-10409

    • DOI

      10.1039/c4ta01261e

    • NAID

      120005651931

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction2014

    • Author(s)
      Satoshi Horike, Wenqian Chen, Tomoya Itakura, Munehiro Inukai, Daiki Umeyama, Hiroyuki Asakura, Susumu Kitagawa
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 71 Pages: 10241-10243

    • DOI

      10.1039/c4cc04370g

    • NAID

      120005657898

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Design and Synthesis of Ion Conducting Materials for Energy Applications2017

    • Author(s)
      Satoshi Horike
    • Organizer
      iCeMS-VISTEC Joint Symposium
    • Place of Presentation
      VISTEC, Wangchan, Rayong, Thailand
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属ー有機構造体(MOF)結晶の相変化と機能2017

    • Author(s)
      堀毛悟史
    • Organizer
      Workshop on Materials Science under Ultra-high pressure
    • Place of Presentation
      愛媛大学
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ガラス化された金属—有機構造体(MOF)の構造と機能2016

    • Author(s)
      堀毛悟史
    • Organizer
      7.第8回東北大学研究会「金属錯体の固体物性化学最前線ー金属錯体と固体物性物理と生物物性の連携新領域をめざして―」
    • Place of Presentation
      東北大学理学部
    • Year and Date
      2016-02-21
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Design of Liquid/Glass States of Metal Organic Framework (MOF) for Ion Conductivity2016

    • Author(s)
      Satoshi Horike
    • Organizer
      The 3rd CMS International Symposium
    • Place of Presentation
      九州大学伊都キャンパス
    • Year and Date
      2016-01-22
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Molecular Motions in Metal Organic Framework for Solid State Ionics and Glass Chemistry2016

    • Author(s)
      Satoshi Horike
    • Organizer
      JSPS二国間交流事業オープンパートナーシップセミナー「日本ー台湾若手化学者のための環境・エネルギーセミナー」
    • Place of Presentation
      台湾高雄 国立中山大学
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Porous inorganic-organic hybrid solids for gas separation and fuel cell technologies2016

    • Author(s)
      Satoshi Horike
    • Organizer
      ISCA-Japan Workshop “Design and characterization of advanced materials”
    • Place of Presentation
      アイルランド大使館
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Glass Formation of Coordination Framework for Anhydrous Proton Conductivity2016

    • Author(s)
      Satoshi Horike
    • Organizer
      Solid State Protonic Conductors-18
    • Place of Presentation
      Soria Moria conference venue, Oslo, Norway
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Porous Coordination Polymers and Their Applications in Energy2016

    • Author(s)
      Satoshi Horike
    • Organizer
      1st International Conference of Molecular Engineering of Polymers (MEP-2016)
    • Place of Presentation
      Fudan University, China
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Solid State Ionics and Glass Science of Molecular-based Framework Materials2016

    • Author(s)
      Satoshi Horike
    • Organizer
      東北大学WPI-AIMR Joint Seminar
    • Place of Presentation
      東北大学原子分子材料科学高等研究機構
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Disorder and Phase Control of MOFs for Anhydrous Proton Conductivity and Fuel Cell Application2016

    • Author(s)
      Satoshi Horike
    • Organizer
      5th International Conference on MetalOrganic Frameworks & Open Framework Compounds
    • Place of Presentation
      Long Beach, California
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Melting, and glassy MOFs with porosity and ion conductivity2015

    • Author(s)
      Satoshi Horike
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ハワイ、ワイキキ
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 錯体化学、MOFから見たアモルファス―結晶相転移:バイオミネラル形成との関連2015

    • Author(s)
      堀毛悟史
    • Organizer
      日本セラミックス協会 第28回秋季シンポジウム
    • Place of Presentation
      富山大学
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Control of Disorder in Coordination Framework Crystals for Solid State Ionics2015

    • Author(s)
      Satoshi Horike
    • Organizer
      8th International Conference on Materials for Advanced Technologies
    • Place of Presentation
      シンガポール、SINTEC
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ion Conductive Coordination Frameworks: Their Ion Transport Mechanism and Application2015

    • Author(s)
      Satoshi Horike
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Gas Separation and Ion Transport of Porous Coordination Polymers2015

    • Author(s)
      Satoshi Horike
    • Organizer
      249th ACS National Meeting & Exposition
    • Place of Presentation
      アメリカ、デンバー
    • Year and Date
      2015-03-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Melting MOFs: Their Dynamics and Ionic Transport2014

    • Author(s)
      Satoshi Horike
    • Organizer
      4th International Conference on Metal-Organic Frameworks and Open Framework Compounds
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2014-09-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Movable Ions in Coordination Frameworks - Crystal and Amorphous Views2014

    • Author(s)
      Satoshi Horike
    • Organizer
      錯体化学第64回討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Protonic Molecular Motions in Coordination Frameworks2014

    • Author(s)
      Satoshi Horike
    • Organizer
      Solid State Protonic Conductors - 17
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2014-09-15
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Design of Soft Coordination Frameworks for Ion Conducting Material2014

    • Author(s)
      Satoshi Horike
    • Organizer
      International Union of Materials Research Societies- The IUMRS International Conference in Asia 2014
    • Place of Presentation
      福岡大学
    • Year and Date
      2014-08-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Book] ナノ空間材料2015

    • Author(s)
      堀毛悟史
    • Total Pages
      13
    • Publisher
      株式会社エヌ・ティー・エス
    • Related Report
      2015 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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