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Investigation of reaction mechanism of electrochemical oxygen reactions by thin-film oxide electrodes

Research Project

Project/Area Number 26810128
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Device related chemistry
Research InstitutionKyoto University

Principal Investigator

Miyazaki Kohei  京都大学, 工学(系)研究科(研究院), 助教 (10512783)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords酸化物触媒 / 酸素還元 / 酸素発生 / 金属-空気二次電池 / 電気化学反応 / 電極触媒
Outline of Final Research Achievements

Metal-air secondary batteries have attracted much attention since they have some advantages of high energy density. While electrocatalysts are usually used for accelerating oxygen reduction and evolution reactions, the detailed reaction mechanism of these reactions cannot be fully understood. In this research, we used thin film electrodes of perovskite oxides to clarify the reaction mechanism of oxygen reduction and evolution. Electrochemical results clearly showed that carbon materials, which is widely added as an electron-conductive additive, are active for the initial reaction of oxygen reduction and perovskite oxides work at the following chemical reactions.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (7 results)

All 2016 2015 2014

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (6 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Influence of Surface Orientation on Catalytic Activities of La0.8Sr0.2CoO3 for Oxygen Reduction and Evolution Reactions2016

    • Author(s)
      Y. Miyahara, K. Miyazaki, T. Fukutsuka, T. Abe
    • Journal Title

      ChemElectroChem

      Volume: 3 Issue: 2 Pages: 214-217

    • DOI

      10.1002/celc.201500439

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] ペロブスカイト型酸化物の酸素電極反応活性における酸素不定性比の影響2016

    • Author(s)
      宮原雄人, 宮崎晃平, 福塚友和, 安部武志
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-03-31
    • Related Report
      2015 Annual Research Report
  • [Presentation] Catalytic Activities of Perovskite-type Oxide Thin Films and Single Crystals as Oxygen Electrodes in Alkaline Media2015

    • Author(s)
      Y. Miyahara, K. Miyazaki, T. Fukutsuka, T. Abe
    • Organizer
      ISE 66th Meeting
    • Place of Presentation
      台湾
    • Year and Date
      2015-10-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ロブスカイト型酸化物単結晶電極を用いた酸素電極反応活性評価(2)2015

    • Author(s)
      宮原 雄人,宮崎 晃平,福塚 友和,安部 武志
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      埼玉
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Catalytic Activities of Perovskite Oxide Electrodes for Oxygen Reduction in Alkaline Solutions2015

    • Author(s)
      K. Miyazaki, Y. Miyahara, T. Fukutsuka, T. Abe
    • Organizer
      ECS Conference with SOFC-XIV
    • Place of Presentation
      イギリス
    • Year and Date
      2015-07-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ペロブスカイト型酸化物単結晶電極を用いた酸素電極反応活性評価2015

    • Author(s)
      宮原雄人, 宮崎晃平, 福塚友和, 安部武志
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜
    • Year and Date
      2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] ペロブスカイト型酸化物の酸素電極反応活性評価2014

    • Author(s)
      宮原雄人, 宮崎晃平, 福塚友和, 安部武志
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      札幌
    • Year and Date
      2014-09-28
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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