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Carbene-Type Reactive Intermediates: Novel Physical Properties and Synthetic Applications

Research Project

Project/Area Number 62300014
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 広領域
Research InstitutionKyoto Institute of Technology

Principal Investigator

OKU Akira  Faculty Engineering and Design, Professor, Kyoto Inst. Tech., 工芸学部, 教授 (50027885)

Co-Investigator(Kenkyū-buntansha) 原田 俊郎  京都工芸繊維大学, 工芸学部, 助教授 (30135628)
FUJIMOTO Hiroshi  Faculty of Engineering, Professor, Kyoto Univ., 工学部, 助教授 (40026068)
NAGAO Yoshimitsu  Inst. for Chem. Research, Assoc. Professor, Kyoto Univ., 化学研究所, 助教授 (40027074)
村橋 俊一  大阪大学, 基礎工学部, 教授 (60029436)
TOMIOKA Hideo  Faculty of Engineering, Professor, Mie Univ., 工学部, 教授 (20024599)
IWAMURA Hiizu  Faculty of Science, Professor, Univ. Tokyo (10011496)
ISHIKAWA Mitsuo  Faculty of Engineering, Professor, Hiroshima Univ. (20025985)
Project Period (FY) 1987 – 1988
Project Status Completed (Fiscal Year 1988)
Budget Amount *help
¥10,000,000 (Direct Cost: ¥10,000,000)
Fiscal Year 1988: ¥4,000,000 (Direct Cost: ¥4,000,000)
Fiscal Year 1987: ¥6,000,000 (Direct Cost: ¥6,000,000)
KeywordsCarbene / Nitrene / Silylene / Carbenoid / C-H Insertion / Spectroscopy / Organic Magnetism / 有機合成 / スピン多重度 / 有機合成反応 / 二原子価欠損型反応性中間体
Research Abstract

Divalent reactive intermediate carbene and its analog nitrene, silylene have been widely investigated with regard to their physical properties and synthetic potentiality. These one-centered biradical intermediates are now attracting research interest in organic synthesis because their ambiphilic character, both nucleophilicity and electrophilicity, can be effectively controlled and utilized to form two bonds at one time on a single carbon atom. Moreover, electronic specificity, particularly the spin multiplicity, is also gathering research interest in terms of organic magnetism and new materials.
The objective of this Co-Operative research, thus, is to promote co-operative net-work researches among diversed research fields of carbene-related chemistry.

Report

(3 results)
  • 1988 Annual Research Report   Final Research Report Summary
  • 1987 Annual Research Report
  • Research Products

    (26 results)

All Other

All Publications (26 results)

  • [Publications] Akira OKU: Journal of Organic Chemistry. 53. 3089-3098 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Akira OKU: Journal of the Chemical Society, Chem.Commun.1988. 1490-1491 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Toshiiro HARADA: Tetrahedron Lett. 29. 3821-3824 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] H.Fujimoto: J.Mol.Struc.(Theochem),. 163. 249-258 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Mitsuo Ishikawa: Chem.Phys.Lett.143. 225 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Hideo TOMIOKA: J.Chem.Soc., Chem.Commun.,. 1988. 1090-1091 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] H.Iwamura: ""High-Spin Polycarbenes.In Pursuit of Organic Ferromagents"Reviews of Heteroatom Chemistry, S.Oae, Ed., Vol.1" MYU, 9 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] A. Oku.: "Stereochemical Aspects in the Insertion by Alkylidenemethylee Carbenoids into the -C-H Bond of Alkoxides" J. Org. Chem.53. 3089-3098 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] H. Iwamura.: "Design of Organic Molecules and Molecular Assembles with Electron Spin Alignment" Pure & Appl. Chem.59. 1595-1604 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Y. Nagao.: "Hypervalent Alkenyliodonium Tetrafluoroborates. Evidence for Generation of Alkylidenecarbenes via Base-Induced -Eliminaton." J. Am. Chem. Soc.110. 6565-6566 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] H. Tomioka.: "Absence of "p-Nitro-Effect" in the Photochemical Reactions of 3-Chloro-3-aryldiazirines in the Presebce of Amines" J.Chem. Soc., Chem. Commun.1988. 1090-1091 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] H, Fujimoto.: "A study on the Active Region of molecules and Chemical Reactivity" J. Mol. Struc.163. 249-258 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] H. IWamura.: High Spin Polycarbenes. In Pursuit of Organic Ferromagnets. MYU, 22-30 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Akira OKU,: J.Org.Chem.53. 3089-3098 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Toshiro HARADA,: Tetrahedron Lett.29. 3821-3824 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Hiroshi FUJIMOTO,: J.Mol.Struc.(Theochem). 163. 249-258 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Mitsuo ISHIKAWA,: Chem.Phys.Lett.143. 225 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Hideo TOMIOKA,: J.Chem.Soc.,Chem.Commun.1988. 1090-1091 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] Yoshimitsu NAGAO,: J.Am.Chem.Soc.110. 6565-6566 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] H.Iwamura,: "High Spin Polycarbenes.In Pursuit of Organic Ferromagnets.Reviews of Heteroatom Chemistry,S.,Oae.,Ed.,Vol.1" MYU, 9 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] A.Oku: J.Org.Chem.51. 3730-3732 (1986)

    • Related Report
      1987 Annual Research Report
  • [Publications] A.Oku: Rep.Asahi Glass Dound.Ind.Technol.,. 49. 65-75 (1986)

    • Related Report
      1987 Annual Research Report
  • [Publications] T.Harada: Bull.Chem.Soc.Jpn. 60. 1715-1719 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] A.Oku: Bull.Chem.Soc.Jpn.,. 60. 1915-1916 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] J.Nishimura: J.Aa.Chem.Soc.109. 5293-5295 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] T.Harada: J.Am.Chem.Soc.109. 527-532 (1987)

    • Related Report
      1987 Annual Research Report

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Published: 1987-04-01   Modified: 2016-04-21  

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