| 研究課題/領域番号 |
14J12396
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| 研究種目 |
特別研究員奨励費
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| 配分区分 | 補助金 |
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| 応募区分 | 国内 |
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| 研究分野 |
触媒・資源化学プロセス
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| 研究機関 | 北陸先端科学技術大学院大学 |
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研究代表者 |
CHOUDHARY HEMANT (2015) 北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 特別研究員(DC2)
CHOUDHARY Hemant (2014) 北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 特別研究員(DC2)
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| 研究期間 (年度) |
2014-04-25 – 2016-03-31
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| 研究課題ステータス |
完了 (2015年度)
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| 配分額 *注記 |
1,900千円 (直接経費: 1,900千円)
2015年度: 900千円 (直接経費: 900千円)
2014年度: 1,000千円 (直接経費: 1,000千円)
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| キーワード | Biomass / Metal Organic Framework / Heterogeneous Catalyst / Organic transformation / Acid Catalyst / Proton Conductivity / Organic Transformation |
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| 研究実績の概要 |
In the event of engineering greener methodologies for converting inedible-biomass into commodity chemicals over heterogeneous catalysts, various heterogeneous catalysts were developed. The preparation of metal-organic framework (MOF) based acid catalyst were successfully achieved through post-synthetic modification methodology. The prepared catalyst possessed acidic properties and catalytic activity for esterification and hydrolysis reaction comparable to the commercially known acid catalysts such as Amberlyst-15 and Nafions. In addition to the catalysis, the prepared acidic materials had potential for applications in fuel cells with high proton conductivity.
The research also proposed the functionalization of MOFs to afford not only acid catalysts but also to immobilize metals like palladium (Pd) through amine functionalization. The successful incorporation of amine functionality was achieved through ligand design methodology and Pd was grafted on such material to afford a potent heterogeneous catalyst. Such catalyst demonstrated remarkable stability and catalytic performances for Mizoroki-Heck reaction. Surfactant-treated and/or stabilized monometallic and bimetallic nanoparticle based catalysts were also developed for various selective transformations including hydrogenation of olefins, oxidation of diols and cross-coupling reaction of aryl chloride.
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| 現在までの達成度 (段落) |
27年度が最終年度であるため、記入しない。
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| 今後の研究の推進方策 |
27年度が最終年度であるため、記入しない。
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