新規な液液界面反応計測法の開発と界面分析反応の開拓

• 研究課題/領域番号: 16105002
• 研究種目: 基盤研究(S)
• 配分区分: 補助金
• 研究分野: 分析化学
• 研究機関: 大阪大学
• 研究代表者: 渡會 仁 大阪大学, 大学院・理学研究科, 教授 (30091771)
• 研究分担者: 文珠四郎 秀昭 大阪大学, 大学院・理学研究科, 准教授 (80191071) ; 諏訪 雅頼 大阪大学, 大学院・理学研究科, 助教 (90403097)
• 研究期間 (年度): 2004 – 2008
• 研究課題ステータス: 完了 (2008年度)
• 配分額: 112,710千円 (直接経費: 86,700千円、間接経費: 26,010千円); 2008年度: 9,360千円 (直接経費: 7,200千円、間接経費: 2,160千円); 2007年度: 9,360千円 (直接経費: 7,200千円、間接経費: 2,160千円); 2006年度: 30,290千円 (直接経費: 23,300千円、間接経費: 6,990千円); 2005年度: 40,950千円 (直接経費: 31,500千円、間接経費: 9,450千円); 2004年度: 22,750千円 (直接経費: 17,500千円、間接経費: 5,250千円)
• キーワード: 液液界面吸着 / 界面集合体生成 / 界面キラル測定 / 界面SHG-CD / 界面磁気効果 / 界面単一分子反応 / 界面高速反応 / レーザー光泳動 / 液液界面磁化率 / 顕微円二色性 / 微粒子磁化率 / 界面分子集合体 / 共鳴ラマン散乱 / 全内部反射法 / 界面質量分析法 / 界面キラリティー / 界面キラル集合体生成 / 液液界面SHG / 界面キラル分子認識 / 遠心液膜円二色法 / 液液界面酵素触媒 / 界面タンパク機能診断 / 界面高速化学反応 / 遠心液膜法 / マイクロシースフロー法 / 界面電気泳動法 / 液液界面SHG-CD / 磁気泳動法

研究概要

液液界面における分子集合反応について、以下の成果を得た。
1)界面単一分子反応と高速界面反応の計測法、液液界面SERS法、遠心液膜円二色性(CD)法、液液界面SHG-CD法等の新手法を開発した。
2)界面単一分子ラクトン化反応、10^7-10^8M^<-1>s^<-1>の液液界面高速反応解析、液液界面におけるポルフィリンおよびフタロシアニンのキラル集合体の生成反応機構および界面吸着反応における磁場効果を明らかにした。

研究成果

• [雑誌論文] OHDE, Takahiro Microscopic Measurement of Second Harmonic Generation from Chiral Surfaces (2009)
  • 著者名/発表者名: TOKUNAGA, Daisuke; TAKECHI, Hideaki; YIN, Jian-Hua; WATARAI, Hitoshi
  • 雑誌名: Anal. Sci. 25 ページ: 311-314
• [雑誌論文] Magnetic susceptibility measurement of a microdroplet interface using a magnetic circuit. (2009)
  • 著者名/発表者名: EGAMI, Shigeki; WATARAI, Hitoshi
  • 雑誌名: The Analyst 134(2) ページ: 278-282
• [雑誌論文] Effect of chloroform on complexation and chiral aggregation of bilirubin-bovine serum albumin at heptane/water interface. (2009)
  • 著者名/発表者名: YIN, Jian-Hua; WATARAI, Hitoshi
  • 雑誌名: J. Colloid Interface Sci. 329 ページ: 325-330
• [雑誌論文] OYAMA, Hiroko In Situ Measurements of Aggregation and Disaggregation of Cu(II) Complex at Liquid/Liquid Interface. (2008)
  • 著者名/発表者名: WATARAI, Hitoshi
  • 雑誌名: Anal. Chem. 80(21) ページ: 8348-8353
• [雑誌論文] Counterion-Dependent Morphology of Porphyrin Aggregates Formed at the Liquid/Liquid Interface Studied by Total Internal Reflection Resonant Rayleigh and Raman Scattering Microscopy. (2008)
  • 著者名/発表者名: YAMAMOTO, Shigeki; WATARAI, Hitoshi
  • 雑誌名: J. Phys. Chem. C 122 ページ: 12417-12424
• [雑誌論文] Linear Dichroism of Zn(II)-TetrapyridylpoAggregates Formed at the Toluene/Water Interface. (2008)
  • 著者名/発表者名: TAKECHI, Hideaki; ADACHI, Kenta; MONJUSHIRO, Hideaki; WATARAI, Hitoshi
  • 雑誌名: Langmuir 24(9) ページ: 4722-4728
• [雑誌論文] Microscopic Measurement of Circular Dichroism Spectra. (2008)
  • 著者名/発表者名: MATSUGAKI, Aira; TAKECHI, Hideaki; MONJUSHIRO, Hideaki; WATARAI Hitoshi
  • 雑誌名: Anal. Sci. 24 ページ: 297-300
  • NAID: 10021098731
• [雑誌論文] Magnetophoretic Evaluation of Interfacial Adsorption of Dysprosium(III) on a Single Microdroplet. (2008)
  • 著者名/発表者名: SUWA, Masayori; WATARAI, Hitoshi
  • 雑誌名: Anal. Sci. 24(1) ページ: 133-137
  • NAID: 10020143704
• [雑誌論文] Chiral complexation and aggregation of biliubin with serum albumin at a liquid/liquid interface. (2007)
  • 著者名/発表者名: YIN, Jian-Hua; WATARAI, Hitoshi
  • 雑誌名: Anal. Bioanal. Chem. 389(3) ページ: 895-902
• [雑誌論文] Optical chirality of protonted tetraphenylporphyrin J-aggregate formed at the liquid/liquid interface in a certrifugal liquid membrane cell. (2007)
  • 著者名/発表者名: WADA, Sayaka; FUJIWARA, Kazuhiko; MONJUSHIRO, Hideaki; WATARAI Hitoshi
  • 雑誌名: J. Phys. Condens. Matter 19 ページ: 375105-375105
• [雑誌論文] Effect of pulsed and static magnetic fields on surface tension measurement by drop volume method (2007)
  • 著者名/発表者名: ISAI, Kento; SUWA, Masayori; WATARA Hitoshi
  • 雑誌名: Bunseki Kagaku 56 ページ: 505-509
  • NAID: 110006291371
• [雑誌論文] Resonance Raman spectroscopic study on chiral aggregation of bilirubin-bovine serum albumin complex formed at liquid/liquid interface. (2007)
  • 著者名/発表者名: Yin, Jian-Hua; WATARAI Hitoshi
  • 雑誌名: Anal. Sci. 23 ページ: 841-846
  • NAID: 10019526335
• [雑誌論文] Role of Zn(II) and Pyridyl Groups in the Adsorption and Self-Aggregation of Zinc Tetrapyridylporphine at the liquid/liquid Interface. (2007)
  • 著者名/発表者名: AKECHI, Hideaki; WATARAI, Hitoshi
  • 雑誌名: Solvent Extraction Research and Development, Japan 14 ページ: 133-144
• [雑誌論文] In situ measurement of undividual W/O microemulsions of aerosol OT in dodecane/wextraction system by total internal reflection lalight scattering microscopy (2007)
  • 著者名/発表者名: TSUKAHARA, Satoshi; KITAGUCHI, Haruyasu; WATARAI, Hitoshi
  • 雑誌名: chem. lett. 36(1) ページ: 148-149
• [雑誌論文] Chiral complexation and aggregation of bilirubin with serum albumin at a liquid/liquid interface (2007)
  • 著者名/発表者名: YIN, Jian-Hua, WATARAI, Hitoshi
  • 雑誌名: Anal. Bioanal. Chem. 389(3) ページ: 895-902
  • 査読あり
• [雑誌論文] Optical chirality of protonated tetraphenylporphyrin J-aggregate for med at the liquid/liquid interface in a centrifugal liquid membrane cell (2007)
  • 著者名/発表者名: WADA, Sayaka, FUJIWARA, Kazuhiko, MONJUSHIRO, Hideaki, WATARAI, Hitoshi
  • 雑誌名: J. Phys. Condens. Matter 19 ページ: 375105-375105
  • 査読あり
• [雑誌論文] Resonance Raman spectroscopic study on chiral aggregation of bilirubin-bovine serum albumin complex formed at liquid/liquid interface (2007)
  • 著者名/発表者名: Yin, Jian-Hua, WATARAI, Hitoshi
  • 雑誌名: Anal. Sci. 23 ページ: 841-846
  • NAID: 10019526335
  • 査読あり
• [雑誌論文] (2007)
  • 著者名/発表者名: WATARAI, Hitoshi edited by IMAE Toyoko
  • 雑誌名: Measurement of complex formation and aggregation at the liquid-liquid interface. In "Advanced Chemistry of Monolayers at interfaces, 14"(Elsevier) ページ: 277-308
• [雑誌論文] Optical chirality of protonated tetraphenylporphyrin J-aggregate formed at theliquid/liquid interface in a centrifugal liquid membrane cell (2007)
  • 著者名/発表者名: WADA, Sayaka
  • 雑誌名: J. Phys.: Condens Matter 19 ページ: 1-12
• [雑誌論文] Measurement of hydrolysis kinetics galactose-substituted fluorescein by b-galactosidase at the toluene-water interface by spinning microtube fluorometry. (2006)
  • 著者名/発表者名: OKAMOTO, Yusuke; MONJUSHIRO Hideaki; FUKUMOTO, Takao; WATARAI, Hitoshi
  • 雑誌名: Anal. BioChem. 385(8) ページ: 1430-1438
• [雑誌論文] Magnetic susceptibility measurements of solutions by surface nanodisplacement detection (2006)
  • 著者名/発表者名: EGAMI, Shigeki; MONJUSHIRO, Hideaki; WATARAI, Hitoshi
  • 雑誌名: Anal. Sci. 22(9) ページ: 1157-1162
  • NAID: 10018063956
• [雑誌論文] Binding Behavior of Subphthalocyanine-Tagged Testosterone with Human Serum Albumin at the n-Hexane/Water Interface (2006)
  • 著者名/発表者名: ADACHI, Kenta; WATARAI Hitoshi
  • 雑誌名: Anal. Chem. 78(19) ページ: 6840-6846
• [雑誌論文] Raman Microprobe Spectrometer Installed iSuper-Conducting Magnet (2006)
  • 著者名/発表者名: GOTO, Takeyoshi; SUWA, Masayori; WATARAI Hitoshi
  • 雑誌名: Anal. Sci. 22(7) ページ: 1043-1046
• [雑誌論文] Spectroscopic Detection of Chiral Aggregation at Liquid-Liquid Interfaces (2006)
  • 著者名/発表者名: WATARAI, Hitoshi; WADA, Sayaka;FUJIWARA, Kazuhiko
  • 雑誌名: Tisinghua. Sci. Tech. 11 ページ: 228-232
• [雑誌論文] Control of Optically Active Structure of Thioether-Phthalocyanine Aggregates by Chiral Pd(II)-BINAP Complexes in Toluene and at the Toluene/Water Interface. (2006)
  • 著者名/発表者名: ADACHI, Kenta; CHAYAMA, Kenji; WATARAI, Hitoshi
  • 雑誌名: Chirality 18(8) ページ: 599-608
• [雑誌論文] Ion-Association Aggregation of an Anionic Porphyrin at the Liquid/Liquid Interface Studied by Second Harmonic Generation Spectroscopy (2006)
  • 著者名/発表者名: FUJIWARA, Kazuhiko; WADA, Sayaka; MONJUSHIRO, Hideaki;WATARAI Hitoshi
  • 雑誌名: Langmuir 22(6) ページ: 2482-2486
• [雑誌論文] Electromagnetophoretic Measurements of Adsorption Forces of Polystyrene Microparticles on Silica Surfaces in Surfactant Solutions. (2006)
  • 著者名/発表者名: IIGUNI, Yoshinori; WATARAI, Hitoshi
  • 雑誌名: Bull Chem. Soc. Jpn. 79 ページ: 47-52
  • NAID: 40007080503
• [雑誌論文] Formation of Helical J-Aggregate of Chiral Thioether-Derivatised Phthalocyanine Bound by Palladium(II) at the Toluene/Water Interface. (2006)
  • 著者名/発表者名: ADACHI, Kenta; CHAYAMA, Kenji; WATARAI, Hitoshi
  • 雑誌名: Langmuir 22(4) ページ: 1630-1639
• [雑誌論文] Circular dichrodism measurement of (5, 10, 15, 20-tetrapyridylporphyrinato)zinc(II) at the toluene-water interface. (2006)
  • 著者名/発表者名: MATSUMOTO, Yusuke; WATARAI, Hitoshi
  • 雑誌名: Solvent Extraction Research and Development Japan 13 ページ: 207-211
• [雑誌論文] Site-Selective Formation of Optically Active Inclusion Complexes of Alkoxo-Subphthalocyanines with beta-Cyclodextrin at the Toluene/Water Interface. (2006)
  • 著者名/発表者名: ADACHI, Kenta; WATARAI, Hitoshi
  • 雑誌名: Chem. Eur. J. 12(16) ページ: 4249-4260
• [雑誌論文] Surface-Enhanced Raman Spectroscopy of Dodecanethiol-Bound Silver Nanoparticles at the Liquid/Liquid Interface (2006)
  • 著者名/発表者名: YAMAMOTO, Shigeki;WATARAI Hitoshi
  • 雑誌名: Langmuir 22(15) ページ: 6562-6569
• [雑誌論文] WADA, Sayaka FUJIWARA, Kazuhiko Spectroscopic detection of chiral aggregation at liquid-liquid interfaces. (2006)
  • 著者名/発表者名: WATARAI, Hitoshi
  • 雑誌名: Tsinghua Science and Technology 11(2) ページ: 228-232
• [雑誌論文] wo-phase Couette flow liner dichroism measurement of the shear-forced orientation of a palladium(II)-induced aggregate of thiother-derivatized subphthalocyanines at the toluene/glycerol interface (2006)
  • 著者名/発表者名: ADACHI, Kenta; WATARAI, Hitoshi
  • 雑誌名: New. J. Chem. 30(3) ページ: 343-348
• [雑誌論文] Measurement of hydrolysis kinetics of galactose-substituted fluorescein by b-galactosidase at the toluene-water interface by spinning microtube fluorometry (2006)
  • 著者名/発表者名: OKAMOTO, Yusuke
  • 雑誌名: Anal. Bioanal. Chem. 385(8) ページ: 1430-1438
• [雑誌論文] Binding Behavior of Subphthalocyanine-Tagged Testosterone with Human Serum Albumin at the n-Hexane/Water Interface (2006)
  • 著者名/発表者名: ADACHI, Kenta
  • 雑誌名: Anal. Chem. 78(19) ページ: 6840-6846
• [雑誌論文] Control of Optically Active Structure of Thioether-Phthalocyanine Aggregates by Chiral Pd (II)-BINAP Complexes in Toluene and at the Toluene/Water Interface (2006)
  • 著者名/発表者名: ADACHI, Kenta
  • 雑誌名: Chirality 18(8) ページ: 599-608
• [雑誌論文] Ion-Association Aggregation of an Anionic Porphyrin at the Liquid/Liquid Interface Studied by Second Harmonic Generation Spectroscopy (2006)
  • 著者名/発表者名: FUJIWARA, Kazuhiko
  • 雑誌名: Langmuir 22(6) ページ: 2482-2486
• [雑誌論文] Site-Selective Formation of Optically Active Inclusion Complexes of Alkoxo-Subphthalocyanines with beta-Cyclodextrin at the Toluene/Water Interfaee (2006)
  • 著者名/発表者名: ADACHI, Kenta
  • 雑誌名: Chem. Eur. J. 12(16) ページ: 4249-4260
• [雑誌論文] Surface-Enhanced Raman Spectroscopy of Dodecanethiol-Bound Silver Nanoparticles at the Liquid/Liquid Interface (2006)
  • 著者名/発表者名: YAMAMOTO, Shigeki
  • 雑誌名: Langmuir 22(15) ページ: 6562-6569
• [雑誌論文] Magnetic susceptibility measurements of solutions by surface nanodisplacement detection (2006)
  • 著者名/発表者名: EGAMI, Shigeki
  • 雑誌名: Anal. Sci 22(9) ページ: 1157-1162
• [雑誌論文] Raman Microprobe Spectrometer Installed in a Super-Conducting Magnet (2006)
  • 著者名/発表者名: GOTO, Takeyoshi
  • 雑誌名: Anal. Sci 22(7) ページ: 1043-1046
• [雑誌論文] Electromagnetophoretic Measurements of Adsorption Forces of Polystyrene Microparticles on Silica Surfaces in Surfactant Solutions (2006)
  • 著者名/発表者名: IIGUNI, Yoshinori
  • 雑誌名: Bull. Chem. Soc. Jpn 79 ページ: 47-52
• [雑誌論文] Formation of Helical J-Aggregate of Chiral Thioether-Derivatised Phthalocyanine Bound by Palladium (II) at the Toluene/Water Interface (2006)
  • 著者名/発表者名: ADACHI, Kenta
  • 雑誌名: Langmuir 22(4) ページ: 1630-1639
• [雑誌論文] Circular dichroism measurement of (5,10,15,20-tetrapyridylporphyrinato) zinc (II) at the toluene-water interface (2006)
  • 著者名/発表者名: MATSUMOTO, Yusuke
  • 雑誌名: Solv. Extr. Research & Development, Japan 13 ページ: 207-211
• [雑誌論文] Spectroscopic detection of chiral aggregation at liquid-liquid interfaces (2006)
  • 著者名/発表者名: WATARAI, Hitoshi
  • 雑誌名: Tsinghua Science and Technology 11(2) ページ: 228-232
• [雑誌論文] Two-phase Couette flow linear dichroism measurement of the shear-forced orientation of a palladium(II)-induced aggregate of thioether-derivatized subphth alocyanines at the toluene/glycerol interface (2006)
  • 著者名/発表者名: ADACHI, Kenta
  • 雑誌名: New J. Chem 30(3) ページ: 343-348
• [雑誌論文] Electromagnetophoretic Measurements of Adsorption Forces of Polystyrene Microparticles on Silica Surfaces in surfactant Solutions (2006)
  • 著者名/発表者名: IIGUNI, Yoshinori
  • 雑誌名: Bull.Chem.Soc.Jpn. 79巻1号 ページ: 47-52
• [雑誌論文] Interfacial aggregation of thioether-substituted phthalocyaninatomagnesium(II)-Palladium(II) complexes in the toluene/water system (2005)
  • 著者名/発表者名: ADACHI, Kenta
  • 雑誌名: J.Mater.Chem., 15巻 ページ: 4701-4710
• [雑誌論文] Aggregation of thioether-substituted subphthalocyanines with palladium(II) at the toluene-water interface (2005)
  • 著者名/発表者名: ADACHI, Kenta
  • 雑誌名: Soft Matter, 1巻(4号) ページ: 292-302
• [雑誌論文] Measurement of dielectrophoretic mobility of single micro-particles in a flow channel. (2005)
  • 著者名/発表者名: IKEDA, Ikuhiro
  • 雑誌名: The Analyst 130巻(10号) ページ: 1340-1342
• [雑誌論文] Lactone Cleavage Reaction Kinetics of Rhodamine Dye at Liquid/Liquid Interfaces Studied by Micro-Two-Phase Sheath Flow/Two-Photon Excitation Fluorescence Microscopy (2005)
  • 著者名/発表者名: TOKIMTO, Takahira
  • 雑誌名: Langmuir 21巻(4号) ページ: 1299-1304
• [雑誌論文] Total Internal Reflection Second-Harmonic Generation Spectrometer System Optimized for the Liquid/Liquid Interface (2005)
  • 著者名/発表者名: FUJIWARA, Kazuhiko
  • 雑誌名: Rev.Sci.Instrum. 76巻(2号)
• [雑誌論文] Interfacial hydrolysis in the μ-oxo dimer formation of tetraphenylpor phinatomanganese(III)in the toluene/water system (2004)
  • 著者名/発表者名: K.Fujiwara, H.Watarai
  • 雑誌名: Anal.Sci 20 ページ: 369-372
  • NAID: 10012047154
• [雑誌論文] Interfacial aggregate growth process of Fe(II) and Fe(III) complexes with pyridylazophenol in solvent extraction system (2004)
  • 著者名/発表者名: Y.Yulizar, H.Monjushiro, H.Watarai
  • 雑誌名: J.Colloid Interface Sci 275 ページ: 560-569
• [雑誌論文] Non-linear optical activity of porphyrin aggregate at the liquid/liquid interface (2004)
  • 著者名/発表者名: K.Fujiwara, H.Monjushiro, H.Watarai
  • 雑誌名: Chem.Phys.Lett 394 ページ: 349-353
• [雑誌論文] Surface-enhanced Raman scattering from oleate-stabilized silver colloids at a liquid/liquid interface (2004)
  • 著者名/発表者名: S.Yamamoto, K.Fujiwara, H.Watarai
  • 雑誌名: Anal.Sci 20 ページ: 1347-1347
  • NAID: 10013524712
• [雑誌論文] Dynamic microscopic extraction of europium(III) with 2-thenoyltrifluoroacetone observed as random fluorescence flashes at dodecane-water interface (2004)
  • 著者名/発表者名: A.Takata, S.Tsukahara, H.Watarai
  • 雑誌名: Chem.Lett 33(5) ページ: 518-519
  • NAID: 10012943301
• [雑誌論文] Adsorption Equilibria of Novel phthalocyaninatomagnesium(III) Derivatives with Thioethers at the Toluene/Water Interface (2004)
  • 著者名/発表者名: K.Adachi, H.Watarai
  • 雑誌名: Bull.Chem.Soc.Jpn 77(11) ページ: 2011-2020
• [学会発表] Dynamic Force Analysis of Chemical Bonding with Electromagneto-Buoyancy (2009)
  • 著者名/発表者名: H. Watarai, T. Kato
  • 発表場所: Nijmegen, Netherlands
• [学会発表] Chiral recognition by molecaggregation at liquid-liquid interface (2008)
  • 著者名/発表者名: H. Watarai
  • 学会等名: International Solvent Extraction Conference (ISEC2008)
  • 発表場所: Tucson, Arizona, USA
  • 年月日: 2008-09-16
• [学会発表] Measurement of Optical Chirality at Liquid-Liquid Interface (2007)
  • 著者名/発表者名: H. Watarai
  • 学会等名: CSIXXXV
  • 発表場所: Xiamen
  • 年月日: 2007-09-26
• [学会発表] Optical chirality analysis at liquid/liquid interface (2007)
  • 著者名/発表者名: H. Watarai
  • 学会等名: IUPAC Congress, Trino
  • 年月日: 2007-08-10
• [学会発表] Optical chirality of molecular aggregates at liquid/liquid interface (2007)
  • 著者名/発表者名: H. Watarai
  • 学会等名: 233rd ACS National Meeting
  • 発表場所: Chicago
  • 年月日: 2007-03-29
• [図書] Fundamentals in Solvent Extraction Processes Thermodynamic, Kinetic, and Interfacial Aspects. In "SOLVENT EXTRACTION and LIQUID MEMBRANES" (2008)
  • 著者名/発表者名: H. Watarai.
  • 出版者: CRC press
• [図書] 分析化学 (2007)
  • 著者名/発表者名: 渡會仁
  • 出版者: 丸善
• [図書] ナノテクのための化学・材料入門(ナノテクノロジー入門シリーズ2)日本表面科学会編集、Chapter 3局所構造:液液ナノ界面,固体界面,ナノ粒子 (2007)
  • 著者名/発表者名: 山本茂樹, 飯国良規, 渡會仁, 本間芳和, 北森武彦
  • 出版者: 共立出版
• [図書] Measurement of complex formation and aggregation at the Liquid-Liquid interface. In“Advanced Chemistry of Monolayers at interfaces, 14" (2007)
  • 著者名/発表者名: H. Watarai
  • 出版者: Elsevier
• [図書] 表面 (2006)
  • 著者名/発表者名: ADACHI, Kenta
  • 総ページ数: 20
  • 出版者: 広信社
• [図書] ぶんせき (2006)
  • 著者名/発表者名: 渡會 仁
  • 総ページ数: 7
  • 出版者: 日本分析化学会
• [図書] Interfacial Nanochmistry Molecular Science and Engineering at Liquid-Liquid Interfaces Series:Naostrucure Science and Technology (2005)
  • 著者名/発表者名: Watarai, Hitoshi, Teramae, Norio, Sawada, Tsuguo (Eds.)
  • 出版者: Springer
• [図書] Interfacial Nanochemiatry Molecular Science and Engineering at Liquid-Liquid Interfaces (2005)
  • 著者名/発表者名: H.Watarai, N.Teramae, T.Sawada
  • 総ページ数: 321
  • 出版者: Kluwer Academic/Plenum Publishers
• [備考]
  • URL: http://www.chem.sci.osaka-u.ac.jp/lab/watarai/index.html
• [備考]
  • URL: http://www.chem.sci.osaka-u.ac.jp/lab/watarai/paper2.hte#2008