| 研究課題/領域番号 |
19K21135
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| 補助金の研究課題番号 |
18H05989 (2018)
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| 研究種目 |
研究活動スタート支援
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| 配分区分 | 基金 (2019)
補助金 (2018) |
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| 審査区分 |
0502:無機・錯体化学、分析化学、無機材料化学、エネルギー関連化学およびその関連分野
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| 研究機関 | 新潟大学 |
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研究代表者 |
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| 研究期間 (年度) |
2018-08-24 – 2020-03-31
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| 研究課題ステータス |
完了 (2019年度)
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| 配分額 *注記 |
2,990千円 (直接経費: 2,300千円、間接経費: 690千円)
2019年度: 1,430千円 (直接経費: 1,100千円、間接経費: 330千円)
2018年度: 1,560千円 (直接経費: 1,200千円、間接経費: 360千円)
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| キーワード | Carbon dioxide reduction / Iron non heme complexes / Homogeneous catalysis / Heterogeneous Catalysis / Nitrogen doped graphene / iron catalysts / CO2 reduction / photosynthesis / Electrocatalysis / Photocatalysis / iron complexes / nonporphyrin ligands / bifunctional / catalysts / carbon dioxide / electroreduction / water oxidation / aqueous nonaqueous / Fuels |
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| 研究開始時の研究の概要 |
1. designing iron non-porphyrin complexes with efficient CO2 to CO reduction ability.
2. Investigation the activity of complexes in homogeneous and heterogeneous catalysis.
3. Modification of complexes on the electrode surface for electro and photocatalytic CO2 to CO conversion.
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| 研究成果の概要 |
Here we developed several cheap iron non-porphyrin complexes, an Fe(bpb) that showed high activity for CO2 reduction with 93% CO faradaic efficiency at a moderate overpotential η = 0.41 V in homogeneous and heterogeneous media.
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| 研究成果の学術的意義や社会的意義 |
This work is expected to develop the academic and social society in terms of developing systems for the production of renewable fuel based on storage of solar energy in the form of renewable fuels and is expected to reduce the carbon dioxide atmospheric level to reduce its global warming effect.
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