| 研究課題/領域番号 |
20K15229
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| 研究種目 |
若手研究
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| 配分区分 | 基金 |
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| 審査区分 |
小区分32010:基礎物理化学関連
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| 研究機関 | 京都大学 |
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研究代表者 |
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| 研究期間 (年度) |
2020-04-01 – 2024-03-31
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| 研究課題ステータス |
交付 (2022年度)
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| 配分額 *注記 |
4,160千円 (直接経費: 3,200千円、間接経費: 960千円)
2022年度: 1,170千円 (直接経費: 900千円、間接経費: 270千円)
2021年度: 1,690千円 (直接経費: 1,300千円、間接経費: 390千円)
2020年度: 1,300千円 (直接経費: 1,000千円、間接経費: 300千円)
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| キーワード | electron spectroscopy / electron scattering / liquid water / photoelectron anisotropy / aqueous solution / synchrotron radiation |
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| 研究開始時の研究の概要 |
Important for many chemical and biological processes is a solute’s propensity vs. depth and its orientation at the surface, which is measured with photoelectron spectroscopy by exploiting electron scattering. We quantify how electrons scatter and loose energy in aqueous solutions for this purpose.
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| 研究実績の概要 |
The project gives new insights into electron scattering mechanisms in liquid water and aqueous solutions and its impact on photoelectron angular distributions using photoelectron spectroscopy in international collaboration. Electron scattering is crucial for understanding energy deposition, radical formation, and biological damage by slow and fast electrons, and a correct interpretation of spectra from liquid water and aqueous solutions.
In the past year, it was demonstrated that surface-active molecules (here: perfluoropentanoate) in aqueous solution can be precisely mapped using photoelectron angular distributions (PADs). Electron scattering alters the PAD signature in a way that is uniquely linked to the probing depth down to an Angstrom resolution. Combined with the chemical specificity of photoemission, this novel technique paves the way to study the detailed surface composition of solutions relevant for, e.g., atmospheric chemistry.
Recent results reveal that electron scattering affects surface-active species differently than bulk species. Photoelectrons from the surface do not suffer from scattering in the bulk liquid, and are thus detectable down to much lower kinetic energies. This distinction is crucial to understand photoelectron spectra from low-energy sources such as lasers, which might be misinterpreted if the surface-propensity and concentration is not considered. These results are currently prepared for publication.
Furthermore, a method for accessing the work function (surface potential) of aqueous solutions has been developed and is currently under review.
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| 現在までの達成度 (区分) |
現在までの達成度 (区分)
1: 当初の計画以上に進展している
理由
The project has already revealed many new insights into electron scattering, such as a largely enhanced scattering behavior in bulk liquid water at low kinetic energies, which is however not observed at the interface. Furthermore, a novel energy-referencing scheme was developed which will become the new standard in photoemission from liquids. Now in its final stage, the project concentrates more on the behavior of solutes, both in terms of electron scattering and angular anisotropy. Thanks to the end of the pandemic, on-site experiments in Europe are possible again, which is ideal to wrap up the project.
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| 今後の研究の推進方策 |
The final stage of the project will further explore electron scattering in the low kinetic-energy regime in liquid water and aqueous solution. Here, also the role of the solute (bulk and surface-active ones) will become a larger focus. This will culminate in a modernized description of the photoelectron spectra of liquid water and aqueous solution alike with the proper inclusion of all relevant scattering processes.
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