| 研究課題/領域番号 |
20K22554
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| 研究種目 |
研究活動スタート支援
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| 配分区分 | 基金 |
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| 審査区分 |
0502:無機・錯体化学、分析化学、無機材料化学、エネルギー関連化学およびその関連分野
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| 研究機関 | 九州大学 |
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研究代表者 |
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| 研究期間 (年度) |
2020-09-11 – 2022-03-31
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| 研究課題ステータス |
完了 (2021年度)
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| 配分額 *注記 |
2,860千円 (直接経費: 2,200千円、間接経費: 660千円)
2021年度: 1,430千円 (直接経費: 1,100千円、間接経費: 330千円)
2020年度: 1,430千円 (直接経費: 1,100千円、間接経費: 330千円)
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| キーワード | Metal-organic polyhedra / Porous material / Composite material / Polyoxometalate / Enzyme immobilization / Metal-organic polyhedron / Supra-molecular assembly / porous materials / ionic solids / Metal-Organic Polyhedra / Porous materials / self-assembly |
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| 研究開始時の研究の概要 |
In this project, I will use metal-organic polyhedra (MOPs) as elementary porous bricks, in order to build extended structures through their modular assembly. Focus will be given on the surface chemistry of MOPs, as-well-as on the driving forces toward supra-MOP assembly. MOPs’ outer surface can be easily functionalized by coordination of ligands, allowing for instance their compatibilization in host matrices such as silica. In addition, other interactions such as hydrophobic/hydrophilic or coulombic interactions will be investigated as a way to reach organized porous structures.
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| 研究成果の概要 |
Metal-organic polyhedra where assembled with either polyoxometalates or enzymes, to prepare functional porous composites.
Both types of systems lead to very efficient composites, with performances enhanced due to MOPs' porosity.
See English section for detailed outline.
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| 研究成果の学術的意義や社会的意義 |
At a fundamental level, this project helped understanding the modes of assembly between MOPs and diverse nanometer-sized object. Focusing on applicability, it also lead to the preparation of highly active composites, benefitting from improved performances thanks to MOPs' porosity.
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