| 研究課題/領域番号 |
22K20478
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| 研究種目 |
研究活動スタート支援
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| 配分区分 | 基金 |
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| 審査区分 |
0401:材料工学、化学工学およびその関連分野
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| 研究機関 | 横浜国立大学 |
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研究代表者 |
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| 研究期間 (年度) |
2022-08-31 – 2024-03-31
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| 研究課題ステータス |
交付 (2022年度)
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| 配分額 *注記 |
2,730千円 (直接経費: 2,100千円、間接経費: 630千円)
2023年度: 1,300千円 (直接経費: 1,000千円、間接経費: 300千円)
2022年度: 1,430千円 (直接経費: 1,100千円、間接経費: 330千円)
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| キーワード | High entropy alloys / Microstructure / Neutron diffraction / Heat treatment / Plastic deformation / Mechanical properties / high entropy alloys / Dislocation density |
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| 研究開始時の研究の概要 |
To enhance strength-ductility trade-off, the dislocation characteristics should be studied with microstructure design. In this study, microstructure of C-doped FeNiCoCr HEA i.e., grain size and carbide content is tuned for optimizing dislocation activities in order to balance strength-ductility.
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| 研究実績の概要 |
The 1%C-doped CoCrFeNi HEA performed high deformability by larger 60% thickness reduction of cold-rolling without macroscopic crack. As-rolled sample obtained high dislocation density resulting in the microhardness of 398 HV. The microstructure evolution of as-rolled samples was studied during isochronal annealing (1 hour) at 978, 1078 and 1178 K in terms of grain morphology, dislocation density and carbide precipitation. The solute drag effect and carbide precipitations due to carbon addition delayed the recrystallization process. In the fully recrystallized microstructure after 1178 K heat-treatment, the average grain size is about 4 microns and the microhardness is about 228 HV. The fine recrystallized grains were resulted by large dislocation density of as-rolled sample.
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| 現在までの達成度 (区分) |
現在までの達成度 (区分)
2: おおむね順調に進展している
理由
After obtaining the relationship between microstructure and annealing temperature, the larger size samples have been fabricated by 70% thickness reduction of cold rolling for further study on the effect of annealing temperature and plastic deformation. The samples were completely conducted in the in-situ neutron diffraction study during heat-treatment and tensile deformation. Currently, the neutron diffraction data are being analyzed for the fraction of carbide precipitation, dislocation density and texture. The analysis result will be correlated to tensile properties. The recent result showed that, in a microstructure after 1178K, 1h annealing, the yield strength reached 481 MPa larger than that of C-undoped CoCrFeNi HEA (~200 MPa). The tensile ductility was also as large as ~45%.
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| 今後の研究の推進方策 |
The result indicated that an addition of interstitial C atoms and multiple-component solid solution led to large number of recrystallized grains and an inhibition of grain growth. Therefore, on the next research plan, the fabrication of nano-scaled structure for 1%C-doped CoCrFeNi HEA will be conducted by conventional thermo-mechanical process. Furthermore, the different type of carbide precipitation will be studied on the microstructure control of (CoCrFeNi)96Mo3C1 (at%). The addition of Mo is expected to increase a solid solution hardening and precipitation hardening with different carbide type.
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