| 配分額 *注記 |
8,060千円 (直接経費: 6,200千円、間接経費: 1,860千円)
2025年度: 4,030千円 (直接経費: 3,100千円、間接経費: 930千円)
2024年度: 4,030千円 (直接経費: 3,100千円、間接経費: 930千円)
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| 研究開始時の研究の概要 |
Abundant arenes and chloroarenes are of interest as starting materials in organic synthesis, but the strong C-H or C-Cl bond is difficult to cleave. The reactions to date either use specialized substrates, or require a highly active metal catalyst. The strategy proposed here aims at the activation of simple arenes and chloroarenes via transient pi-coordination to a catalytic amount of a metal fragment. The new strategy will enable the use of arenes and chloroarenes as substrates in organic synthesis, such as C-H functionalization, cross coupling, and radical reactions.
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