1990 年度実績報告書

新規機能材料の合成と応用開発

研究課題

研究課題/領域番号	01430016
研究機関	広島大学
研究代表者	小倉文夫広島大学, 工学部, 教授 (90028150)
研究分担者	大下浄治広島大学, 工学部, 助手 (90201376) 塩谷優広島大学, 工学部, 助教授 (80002137) 木谷晧広島大学, 工学部, 助教授 (70034395) 藤原祐三広島大学, 工学部, 教授 (10029481) 服部信広島大学, 工学部, 教授 (30034416)
キーワード	低次元有機電導体の合成 / 新規有機電子供与体と受容体 / 電導性高分子 / 無機層状化合物とインタ-カレ-ション / 放射線化学反応の初期過程 / 新規有機ケイ素ポリマ- / フォトレジスト材料 / 希土類金属を用いる有機合成
研究概要	低次元有機電導体合成に関して,アントラセン,テトラセンのperiー位ジカルコゲン架橋体,TTF,BTP両ドナ-の部分構造を含むTPDT誘導体,周辺ベンゼン環をチオフェンに置換したペリレンと等電子構造のヘテロアレ-ン等のドナ-を詳細に検討した。また拡張共役係と異なるカルコゲン原子を持つヘテロキノイド電子受容体についても検討した。これらの研究から多くの高電性錯体を得て,X線解析により構造を明らかにし物性との相関と評価を行った。特にアントラセンセレン架橋体のBF_4塩の450Scm^<-1>の室温電導度と150K付近までの金属的挙動は均一の積層カラム構造による事を証明した。電導性高分子に関してポリアニリンの欠点の一つである機械的強度の改善を目ざし重合条件,後処理を検討し以下の結果を得た。1)HC10_4,HBF_4を用い高モノマ-濃度で電解重合を行い可撓性のある試料を得た。2)Nーメチルピロリドン処理によりゴム状或はフィルム状への加工が可能となり,更に後処理により機械的強度,電導度共に高い試料を得た。無機層状化合物の合成と応用開発に関連しLi二次電池の開発を目的としてβーZrNC1層へのアルカリ金属のインタ-カレ-ションを調べた。金属と共に非水系有機電解液の溶媒がコインタ-カレ-ションすることを見い出し,その機構と電池特性への影響を調べた。チオ尿素等をホストとするブタジエン等の放射性重合の基礎過程を引続き研究し多くの新知見を得た。さらにシクロヘキサン/ハロゲン化炭化水素系を用いて放射線化学反応の初期過程をESR法で研究した。SiーSi結合と芳香族,ヘテロ芳香族π電子系を主鎖に交互に持つ新規有機ケイ素ポリマ-を合成し,これらがフォトレジスト或は導電性材料として利用可能である事を示した。希土類金属Ybを用い各種イミンとCO_2から重要なポリマ-原料,αーアミノ酸,脂肪族カルボン酸を,またPdを用いてアルカンとCOからカルボン酸を一段階で合成する反応を開発した。

研究成果
(42件)

すべてその他

すべて文献書誌 (42件)

[文献書誌] TAKIMIYA Kazuo(滝宮和男): "2,3ーDimethyl and 2,3,6,7ーTetramethyl Derivatives of Anthra[1,9ーcd:4,10ーc'd']bis[1,2]dichalcogenoles as New Electron Donors" Chemistry Letters. 567-570 (1990)
[文献書誌] MIYAMOTO Hisakazu(宮本久一): "Naphthaceno[1,2ーcd:4,5ーc'd']bis[1,2]diselenole as a New Electron Donor" Bulletin of the Chemical Society of Japan. 63. 2441-2443 (1990)
[文献書誌] ABE Taro(安部太郎): "OxygenーInduced Transmetallation of Organoboranes with Diphenyl Ditelluride" Chemistry Letters. 1671-1674 (1990)
[文献書誌] ISHIDA Hideki(石田英樹): "Novel Electron Acceptors Bearing a Heteroquinonoid System III:2,5ーBis(dicyanomethylene)ー2,5ーdihydrofuran and Its Conjugated Homologues as Novel OxygenーContaining Electron Acceptors" Bulletin of the Chemical Society of Japan. 63. 2828-2835 (1990)
[文献書誌] FUKUMOTO Takahiro(福本貴啓): "Benzenetellurinic Mixed Anhydrides as Mild Oxidizing Agents" Chemistry Letters. 2269-2272 (1990)
[文献書誌] OTSUBO Tetsuo(大坪徹夫): "ベンゼンテルリン酸混合酸無水物を利用した有機合成反応" 旭硝子財団研究報告. 56. 89-94 (1990)
[文献書誌] SASAKI Kazuaki(佐々木和明): "Nucleophilic Reactions of Acetals,Alkyl Sulfonates,and Oxiranes with Diisobutylaluminum Benzenetellurolate" Chemistry Letters. (1991)
[文献書誌] MIYAMOTO Hisakazu(宮本久一): "Dimethyl and Tetramethyl Derivatives of Anthra[1,9ーcd:4,10ーc'd']ーand Naphtaceno[5,6ーcd:11,12ーc'd']ーbis[1,2]dichalcogenoles" Synthetic Metals. (1991)
[文献書誌] ISHIDA Hideki(石田英樹): "2,5ーBis(dicyanomethylene)ー2,5ーdihydrofuran and Its Conjugated Homologues as Novel Oxygenーcontaining Electron Acceptors" Synthetic Metals. (1991)
[文献書誌] YAMANAKA Shoji(山中昭司): "Unusual Ionic Conductivies of Hydrothermally Prepared MZr_2(PO_4)_3 (M=Na,K)" Solid State Ionic. 40/41. 43-47 (1990)
[文献書誌] OHASHI Masao(大橋正夫): "Coーintercalation of Tetrahydrofuran with Lithium in βーZrNCl Layered Crystal" Chem.Lett.93-96 (1990)
[文献書誌] TAKAKI Ken(高木謙): "A Novel Cyclodimerization of α,βーUnsaturated Carbnyl Compounds Promoted by Ytterbium Metal" J.Chem.Soc.,Chem.Commun.516-517 (1990)
[文献書誌] TAKAKI Ken(高木謙): "Reduction and Coupling Reaction of Imines Promoted by Ytterbium Metal" Chem.Lett.203-204 (1990)
[文献書誌] TAKAKI Ken(高木謙): "Synthesis of Chiral 1,3ーDiols from the Reaction of Yb Metal Umpoled Diaryl Ketones with Chiral Epoxides" Chem.Lett.1427-1430 (1990)
[文献書誌] TAKAKI Ken(高木謙): "Reaction of Benzophenone with Alkylー,Acylー,and SilylーHalides Promoted by Ytterbium Metal" Chem.Express. 6. 57-60 (1990)
[文献書誌] TAKAKI Ken(高木謙): "The Exploitation of New Synthetic Reactios by Means of Rare Earth Metals" Appl.Organomet.Chem.4297-4310 (1990)
[文献書誌] TAKAKI Ken(高木謙): "PalladiumーCatalyzed Synthesis of Aromatic Acids from Carbon Monoxide and Aromatic Compounds via the Aromatic CarbonーHydrogen Bond Activation" J.Organomet.Chem.385. 297-306 (1990)
[文献書誌] JINTOKU Tetsuro(神徳哲郎): "PalladiumーCatalyzed Direct Oxidation of Benzene with Molecular Oxygen to Phenol" Bull.Chem.Soc.Jpn.63. 438-441 (1990)
[文献書誌] JINTOKU Tetsuro(神徳哲郎): "Palladium Catalyzed Transformation of Benzene to Phenol with Molecular Oxygen" Chem.Lett.1687-1688 (1990)
[文献書誌] FUJIWARA Yuzo(藤原祐三): "Look What Pd Catalyzes" Chemtech. 636-640 (1990)
[文献書誌] 高木謙: "アルカンのCーH結合活性化(総説)" 化学. 46. 80-81 (1991)
[文献書誌] 木谷晧: "電解重合ポリアニリンの伝導度および機械的性質の向上" 電子情報通信学会技術研究報告. 90. 13-16 (1990)
[文献書誌] SHIOTANI Masaru(塩谷優): "The JahnーTeller Split HOMO of the Cyclohexane Cation in Selectively Substituted Cyclohexanes:An ESR and MNDO/INDO MO Study" J.Am.Chem.Soc.112. 967-973 (1990)
[文献書誌] SHIOTANI Masaru(塩谷優): "An ESR and Theoretical ab Initio Study of the Structure and Dynamics of the Pyrrolidine Radical Cation and the Neutral 1ーPyrrolidinyl Radical" J.Phys.Chem.94. 8081-8089 (1990)
[文献書誌] SHIOTANI Masaru(塩谷優): "On the Alkyl Radical Formation from Alkane Cations in Halocarbons:Results for Various AlkylーSubstituted Cyclohexanes" Chem.Phys.Lett.170. 201-205 (1990)
[文献書誌] L.Sjoqvist: "The Structure of Transーand Cisー3ーhexene Cations Stabilized in Halocarbon Matrices at Low Temperatures:An ESR MNDO/AM1 Study" Chem.Phys.141. 417-430 (1990)
[文献書誌] L.Sjoqvist: "Mirror Inversion of the Lowーsymmetry Groundーstate Structures of the Methylcyclohexane and 1,1ーDimethylcyclohexane Radical Cations:An Electron Paramagnetic Resonance Study" J.Chem.Soc.Faraday Trans.86. 3377-3382 (1990)
[文献書誌] SOHMA Junkichi(相馬純吉): "Solid State HighーResolution ^<13>CーNMR Study of Crosslinks in Heavily γーirradiated Polyethylene" Radiat.Phys.Chem.37. 47-51 (1991)
[文献書誌] SHIOTANI Masaru(塩谷優): "Radical Cations of Cyclohexanes Alkylsubstituted on One Carbon:An ESR Study of the JahnーTeller Distorted HOMO of Cyclohexane" J.Chem.Soc.Perkin Trans.2. 86. (1991)
[文献書誌] L.Sjoqvist: "The Structure of the Azetidine Radial Cation and the Neutral 1ーAzetidinyl Radical:An Theoretical Ab Initio and ESR Study" J.Chem.Soc.Faraday Trans.(1991)
[文献書誌] OHSHITA Joji(大下浄治): "POLYMERIC ORGANOSILICON SYSTEMS.PART9.SYNTHESIS AND CONDUCTING PROPERTY OF POLY[(DISILANYLENE)FURYLENE]" Chem.Express. 5. 489-492 (1990)
[文献書誌] OHSHITA Joji(大下浄治): "SiliconーCarbon Unsaturated Compounds.26.Photochemical Behavior of 1,4ーand 1,5ーBis(pentamethyldisilanyl)naphthalene]" Organometallics.
[文献書誌] OHSHITA Joji(大下浄治): "Polymeric Organosilicon Systems.10.Synthesis and Conducting Properties Properties of Poly[2,5ー(disilanylene)ーthienylenes]" Macromolecules.
[文献書誌] TAKIMIYA Kazuo(滝宮和男): "Syntheses and Properties of Dimethyl and Tetramethyl Anthra[1,9ーcd:4,10ーc'd']bis[1,2]dichalcogenoles and their ChargeーTransfer Complexes" Bulletin of the Chemical Society of Japan.
[文献書誌] OHASHI Masao(大橋正夫): "Coーintercalations of Tetrahydrofuran and Propylene Carbonate with Alkali Metals in βーZrNCl Layered Crystal" Bull.Chem.Soc.Jpn.
[文献書誌] OTSUBO Tetsuo(大坪徹夫): "The Physics and Chemistry of Organic Superconductors (The Proceedings of the 1st ISSP International Symposium on the Physics and Chemistry of Organic Superconductors),Proceedings in Physics 51" SpringerーVerlag, 4 (1990)
[文献書誌] OGURA Fumio(小倉文夫): "The Physics and Chemistry of Organic Superconductors (The Proceedings of the 1st ISSP International Symposium on the Physics and Chemistry of Organic Superconductors),Proceedings in Physics 51" SpringerーVerlag, 5 (1990)
[文献書誌] 中村晃(編集): "実験化学講座18" 丸善, 557 (1991)
[文献書誌] 木谷晧: "電池便覧(ポリアニリン電池の項を分担執筆)" 丸善, 535 (1990)
[文献書誌] A.Lund and M.Shiotani (Editors): "Radical Ionic Systems" Kluwer Academic Publishers, 496 (1991)
[文献書誌] M.Lindgren and M.Shiotani(Eds:Lund and M.Shiotani): "Radical Ionic Systems,Chap.1:5 ESR Studies of Radical Cations of Cycloalkanes and Saturated Heterocycles" Kluwer Academic Publishers, 26 (1991)
[文献書誌] M.Shiotani and A.Lund(Eds:Lund and M.Shiotani): "Radical Ionic Systems,Chap.1:6 Deuterium Labelling Studies of Cation Radicals" Kluwer Academic Publishers, 26 (1991)

1990 年度 実績報告書

新規機能材料の合成と応用開発

研究代表者

小倉 文夫 広島大学, 工学部, 教授 (90028150)

研究成果

[文献書誌] TAKIMIYA Kazuo(滝宮 和男): "2,3ーDimethyl and 2,3,6,7ーTetramethyl Derivatives of Anthra[1,9ーcd:4,10ーc'd']bis[1,2]dichalcogenoles as New Electron Donors" Chemistry Letters. 567-570 (1990)

[文献書誌] MIYAMOTO Hisakazu(宮本 久一): "Naphthaceno[1,2ーcd:4,5ーc'd']bis[1,2]diselenole as a New Electron Donor" Bulletin of the Chemical Society of Japan. 63. 2441-2443 (1990)

[文献書誌] ABE Taro(安部 太郎): "OxygenーInduced Transmetallation of Organoboranes with Diphenyl Ditelluride" Chemistry Letters. 1671-1674 (1990)

[文献書誌] ISHIDA Hideki(石田 英樹): "Novel Electron Acceptors Bearing a Heteroquinonoid System III:2,5ーBis(dicyanomethylene)ー2,5ーdihydrofuran and Its Conjugated Homologues as Novel OxygenーContaining Electron Acceptors" Bulletin of the Chemical Society of Japan. 63. 2828-2835 (1990)

[文献書誌] FUKUMOTO Takahiro(福本 貴啓): "Benzenetellurinic Mixed Anhydrides as Mild Oxidizing Agents" Chemistry Letters. 2269-2272 (1990)

[文献書誌] OTSUBO Tetsuo(大坪 徹夫): "ベンゼンテルリン酸混合酸無水物を利用した有機合成反応" 旭硝子財団研究報告. 56. 89-94 (1990)

[文献書誌] SASAKI Kazuaki(佐々木 和明): "Nucleophilic Reactions of Acetals,Alkyl Sulfonates,and Oxiranes with Diisobutylaluminum Benzenetellurolate" Chemistry Letters. (1991)

[文献書誌] MIYAMOTO Hisakazu(宮本 久一): "Dimethyl and Tetramethyl Derivatives of Anthra[1,9ーcd:4,10ーc'd']ーand Naphtaceno[5,6ーcd:11,12ーc'd']ーbis[1,2]dichalcogenoles" Synthetic Metals. (1991)

[文献書誌] ISHIDA Hideki(石田 英樹): "2,5ーBis(dicyanomethylene)ー2,5ーdihydrofuran and Its Conjugated Homologues as Novel Oxygenーcontaining Electron Acceptors" Synthetic Metals. (1991)

[文献書誌] YAMANAKA Shoji(山中 昭司): "Unusual Ionic Conductivies of Hydrothermally Prepared MZr_2(PO_4)_3 (M=Na,K)" Solid State Ionic. 40/41. 43-47 (1990)

[文献書誌] OHASHI Masao(大橋 正夫): "Coーintercalation of Tetrahydrofuran with Lithium in βーZrNCl Layered Crystal" Chem.Lett.93-96 (1990)

[文献書誌] TAKAKI Ken(高木 謙): "A Novel Cyclodimerization of α,βーUnsaturated Carbnyl Compounds Promoted by Ytterbium Metal" J.Chem.Soc.,Chem.Commun.516-517 (1990)

[文献書誌] TAKAKI Ken(高木 謙): "Reduction and Coupling Reaction of Imines Promoted by Ytterbium Metal" Chem.Lett.203-204 (1990)

[文献書誌] TAKAKI Ken(高木 謙): "Synthesis of Chiral 1,3ーDiols from the Reaction of Yb Metal Umpoled Diaryl Ketones with Chiral Epoxides" Chem.Lett.1427-1430 (1990)

[文献書誌] TAKAKI Ken(高木 謙): "Reaction of Benzophenone with Alkylー,Acylー,and SilylーHalides Promoted by Ytterbium Metal" Chem.Express. 6. 57-60 (1990)

[文献書誌] TAKAKI Ken(高木 謙): "The Exploitation of New Synthetic Reactios by Means of Rare Earth Metals" Appl.Organomet.Chem.4297-4310 (1990)

[文献書誌] TAKAKI Ken(高木 謙): "PalladiumーCatalyzed Synthesis of Aromatic Acids from Carbon Monoxide and Aromatic Compounds via the Aromatic CarbonーHydrogen Bond Activation" J.Organomet.Chem.385. 297-306 (1990)

[文献書誌] JINTOKU Tetsuro(神徳 哲郎): "PalladiumーCatalyzed Direct Oxidation of Benzene with Molecular Oxygen to Phenol" Bull.Chem.Soc.Jpn.63. 438-441 (1990)

[文献書誌] JINTOKU Tetsuro(神徳 哲郎): "Palladium Catalyzed Transformation of Benzene to Phenol with Molecular Oxygen" Chem.Lett.1687-1688 (1990)

[文献書誌] FUJIWARA Yuzo(藤原 祐三): "Look What Pd Catalyzes" Chemtech. 636-640 (1990)

[文献書誌] 高木 謙: "アルカンのCーH結合活性化(総説)" 化学. 46. 80-81 (1991)

[文献書誌] 木谷 晧: "電解重合ポリアニリンの伝導度および機械的性質の向上" 電子情報通信学会技術研究報告. 90. 13-16 (1990)

[文献書誌] SHIOTANI Masaru(塩谷 優): "The JahnーTeller Split HOMO of the Cyclohexane Cation in Selectively Substituted Cyclohexanes:An ESR and MNDO/INDO MO Study" J.Am.Chem.Soc.112. 967-973 (1990)

[文献書誌] SHIOTANI Masaru(塩谷 優): "An ESR and Theoretical ab Initio Study of the Structure and Dynamics of the Pyrrolidine Radical Cation and the Neutral 1ーPyrrolidinyl Radical" J.Phys.Chem.94. 8081-8089 (1990)

[文献書誌] SHIOTANI Masaru(塩谷 優): "On the Alkyl Radical Formation from Alkane Cations in Halocarbons:Results for Various AlkylーSubstituted Cyclohexanes" Chem.Phys.Lett.170. 201-205 (1990)

[文献書誌] L.Sjoqvist: "The Structure of Transーand Cisー3ーhexene Cations Stabilized in Halocarbon Matrices at Low Temperatures:An ESR MNDO/AM1 Study" Chem.Phys.141. 417-430 (1990)

[文献書誌] L.Sjoqvist: "Mirror Inversion of the Lowーsymmetry Groundーstate Structures of the Methylcyclohexane and 1,1ーDimethylcyclohexane Radical Cations:An Electron Paramagnetic Resonance Study" J.Chem.Soc.Faraday Trans.86. 3377-3382 (1990)

[文献書誌] SOHMA Junkichi(相馬 純吉): "Solid State HighーResolution ^<13>CーNMR Study of Crosslinks in Heavily γーirradiated Polyethylene" Radiat.Phys.Chem.37. 47-51 (1991)

[文献書誌] SHIOTANI Masaru(塩谷 優): "Radical Cations of Cyclohexanes Alkylsubstituted on One Carbon:An ESR Study of the JahnーTeller Distorted HOMO of Cyclohexane" J.Chem.Soc.Perkin Trans.2. 86. (1991)

[文献書誌] L.Sjoqvist: "The Structure of the Azetidine Radial Cation and the Neutral 1ーAzetidinyl Radical:An Theoretical Ab Initio and ESR Study" J.Chem.Soc.Faraday Trans.(1991)

[文献書誌] OHSHITA Joji(大下 浄治): "POLYMERIC ORGANOSILICON SYSTEMS.PART9.SYNTHESIS AND CONDUCTING PROPERTY OF POLY[(DISILANYLENE)FURYLENE]" Chem.Express. 5. 489-492 (1990)

[文献書誌] OHSHITA Joji(大下 浄治): "SiliconーCarbon Unsaturated Compounds.26.Photochemical Behavior of 1,4ーand 1,5ーBis(pentamethyldisilanyl)naphthalene]" Organometallics.

[文献書誌] OHSHITA Joji(大下 浄治): "Polymeric Organosilicon Systems.10.Synthesis and Conducting Properties Properties of Poly[2,5ー(disilanylene)ーthienylenes]" Macromolecules.

[文献書誌] TAKIMIYA Kazuo(滝宮 和男): "Syntheses and Properties of Dimethyl and Tetramethyl Anthra[1,9ーcd:4,10ーc'd']bis[1,2]dichalcogenoles and their ChargeーTransfer Complexes" Bulletin of the Chemical Society of Japan.

[文献書誌] OHASHI Masao(大橋 正夫): "Coーintercalations of Tetrahydrofuran and Propylene Carbonate with Alkali Metals in βーZrNCl Layered Crystal" Bull.Chem.Soc.Jpn.

[文献書誌] OTSUBO Tetsuo(大坪 徹夫): "The Physics and Chemistry of Organic Superconductors (The Proceedings of the 1st ISSP International Symposium on the Physics and Chemistry of Organic Superconductors),Proceedings in Physics 51" SpringerーVerlag, 4 (1990)

[文献書誌] OGURA Fumio(小倉 文夫): "The Physics and Chemistry of Organic Superconductors (The Proceedings of the 1st ISSP International Symposium on the Physics and Chemistry of Organic Superconductors),Proceedings in Physics 51" SpringerーVerlag, 5 (1990)

[文献書誌] 中村 晃(編集): "実験化学講座18" 丸善, 557 (1991)

[文献書誌] 木谷 晧: "電池便覧(ポリアニリン電池の項を分担執筆)" 丸善, 535 (1990)

[文献書誌] A.Lund and M.Shiotani (Editors): "Radical Ionic Systems" Kluwer Academic Publishers, 496 (1991)

[文献書誌] M.Lindgren and M.Shiotani(Eds:Lund and M.Shiotani): "Radical Ionic Systems,Chap.1:5 ESR Studies of Radical Cations of Cycloalkanes and Saturated Heterocycles" Kluwer Academic Publishers, 26 (1991)

[文献書誌] M.Shiotani and A.Lund(Eds:Lund and M.Shiotani): "Radical Ionic Systems,Chap.1:6 Deuterium Labelling Studies of Cation Radicals" Kluwer Academic Publishers, 26 (1991)

1990 年度実績報告書

小倉文夫広島大学, 工学部, 教授 (90028150)

[文献書誌] TAKIMIYA Kazuo(滝宮和男): "2,3ーDimethyl and 2,3,6,7ーTetramethyl Derivatives of Anthra[1,9ーcd:4,10ーc'd']bis[1,2]dichalcogenoles as New Electron Donors" Chemistry Letters. 567-570 (1990)

[文献書誌] MIYAMOTO Hisakazu(宮本久一): "Naphthaceno[1,2ーcd:4,5ーc'd']bis[1,2]diselenole as a New Electron Donor" Bulletin of the Chemical Society of Japan. 63. 2441-2443 (1990)

[文献書誌] ABE Taro(安部太郎): "OxygenーInduced Transmetallation of Organoboranes with Diphenyl Ditelluride" Chemistry Letters. 1671-1674 (1990)

[文献書誌] ISHIDA Hideki(石田英樹): "Novel Electron Acceptors Bearing a Heteroquinonoid System III:2,5ーBis(dicyanomethylene)ー2,5ーdihydrofuran and Its Conjugated Homologues as Novel OxygenーContaining Electron Acceptors" Bulletin of the Chemical Society of Japan. 63. 2828-2835 (1990)

[文献書誌] FUKUMOTO Takahiro(福本貴啓): "Benzenetellurinic Mixed Anhydrides as Mild Oxidizing Agents" Chemistry Letters. 2269-2272 (1990)

[文献書誌] OTSUBO Tetsuo(大坪徹夫): "ベンゼンテルリン酸混合酸無水物を利用した有機合成反応" 旭硝子財団研究報告. 56. 89-94 (1990)

[文献書誌] SASAKI Kazuaki(佐々木和明): "Nucleophilic Reactions of Acetals,Alkyl Sulfonates,and Oxiranes with Diisobutylaluminum Benzenetellurolate" Chemistry Letters. (1991)

[文献書誌] MIYAMOTO Hisakazu(宮本久一): "Dimethyl and Tetramethyl Derivatives of Anthra[1,9ーcd:4,10ーc'd']ーand Naphtaceno[5,6ーcd:11,12ーc'd']ーbis[1,2]dichalcogenoles" Synthetic Metals. (1991)

[文献書誌] ISHIDA Hideki(石田英樹): "2,5ーBis(dicyanomethylene)ー2,5ーdihydrofuran and Its Conjugated Homologues as Novel Oxygenーcontaining Electron Acceptors" Synthetic Metals. (1991)

[文献書誌] YAMANAKA Shoji(山中昭司): "Unusual Ionic Conductivies of Hydrothermally Prepared MZr_2(PO_4)_3 (M=Na,K)" Solid State Ionic. 40/41. 43-47 (1990)

[文献書誌] OHASHI Masao(大橋正夫): "Coーintercalation of Tetrahydrofuran with Lithium in βーZrNCl Layered Crystal" Chem.Lett.93-96 (1990)

[文献書誌] TAKAKI Ken(高木謙): "A Novel Cyclodimerization of α,βーUnsaturated Carbnyl Compounds Promoted by Ytterbium Metal" J.Chem.Soc.,Chem.Commun.516-517 (1990)

[文献書誌] TAKAKI Ken(高木謙): "Reduction and Coupling Reaction of Imines Promoted by Ytterbium Metal" Chem.Lett.203-204 (1990)

[文献書誌] TAKAKI Ken(高木謙): "Synthesis of Chiral 1,3ーDiols from the Reaction of Yb Metal Umpoled Diaryl Ketones with Chiral Epoxides" Chem.Lett.1427-1430 (1990)

[文献書誌] TAKAKI Ken(高木謙): "Reaction of Benzophenone with Alkylー,Acylー,and SilylーHalides Promoted by Ytterbium Metal" Chem.Express. 6. 57-60 (1990)

[文献書誌] TAKAKI Ken(高木謙): "The Exploitation of New Synthetic Reactios by Means of Rare Earth Metals" Appl.Organomet.Chem.4297-4310 (1990)

[文献書誌] TAKAKI Ken(高木謙): "PalladiumーCatalyzed Synthesis of Aromatic Acids from Carbon Monoxide and Aromatic Compounds via the Aromatic CarbonーHydrogen Bond Activation" J.Organomet.Chem.385. 297-306 (1990)

[文献書誌] JINTOKU Tetsuro(神徳哲郎): "PalladiumーCatalyzed Direct Oxidation of Benzene with Molecular Oxygen to Phenol" Bull.Chem.Soc.Jpn.63. 438-441 (1990)

[文献書誌] JINTOKU Tetsuro(神徳哲郎): "Palladium Catalyzed Transformation of Benzene to Phenol with Molecular Oxygen" Chem.Lett.1687-1688 (1990)

[文献書誌] FUJIWARA Yuzo(藤原祐三): "Look What Pd Catalyzes" Chemtech. 636-640 (1990)

[文献書誌] 高木謙: "アルカンのCーH結合活性化(総説)" 化学. 46. 80-81 (1991)

[文献書誌] 木谷晧: "電解重合ポリアニリンの伝導度および機械的性質の向上" 電子情報通信学会技術研究報告. 90. 13-16 (1990)

[文献書誌] SHIOTANI Masaru(塩谷優): "The JahnーTeller Split HOMO of the Cyclohexane Cation in Selectively Substituted Cyclohexanes:An ESR and MNDO/INDO MO Study" J.Am.Chem.Soc.112. 967-973 (1990)

[文献書誌] SHIOTANI Masaru(塩谷優): "An ESR and Theoretical ab Initio Study of the Structure and Dynamics of the Pyrrolidine Radical Cation and the Neutral 1ーPyrrolidinyl Radical" J.Phys.Chem.94. 8081-8089 (1990)

[文献書誌] SHIOTANI Masaru(塩谷優): "On the Alkyl Radical Formation from Alkane Cations in Halocarbons:Results for Various AlkylーSubstituted Cyclohexanes" Chem.Phys.Lett.170. 201-205 (1990)

[文献書誌] SOHMA Junkichi(相馬純吉): "Solid State HighーResolution ^<13>CーNMR Study of Crosslinks in Heavily γーirradiated Polyethylene" Radiat.Phys.Chem.37. 47-51 (1991)

[文献書誌] SHIOTANI Masaru(塩谷優): "Radical Cations of Cyclohexanes Alkylsubstituted on One Carbon:An ESR Study of the JahnーTeller Distorted HOMO of Cyclohexane" J.Chem.Soc.Perkin Trans.2. 86. (1991)

[文献書誌] OHSHITA Joji(大下浄治): "POLYMERIC ORGANOSILICON SYSTEMS.PART9.SYNTHESIS AND CONDUCTING PROPERTY OF POLY[(DISILANYLENE)FURYLENE]" Chem.Express. 5. 489-492 (1990)

[文献書誌] OHSHITA Joji(大下浄治): "SiliconーCarbon Unsaturated Compounds.26.Photochemical Behavior of 1,4ーand 1,5ーBis(pentamethyldisilanyl)naphthalene]" Organometallics.

[文献書誌] OHSHITA Joji(大下浄治): "Polymeric Organosilicon Systems.10.Synthesis and Conducting Properties Properties of Poly[2,5ー(disilanylene)ーthienylenes]" Macromolecules.

[文献書誌] TAKIMIYA Kazuo(滝宮和男): "Syntheses and Properties of Dimethyl and Tetramethyl Anthra[1,9ーcd:4,10ーc'd']bis[1,2]dichalcogenoles and their ChargeーTransfer Complexes" Bulletin of the Chemical Society of Japan.

[文献書誌] OHASHI Masao(大橋正夫): "Coーintercalations of Tetrahydrofuran and Propylene Carbonate with Alkali Metals in βーZrNCl Layered Crystal" Bull.Chem.Soc.Jpn.

[文献書誌] OTSUBO Tetsuo(大坪徹夫): "The Physics and Chemistry of Organic Superconductors (The Proceedings of the 1st ISSP International Symposium on the Physics and Chemistry of Organic Superconductors),Proceedings in Physics 51" SpringerーVerlag, 4 (1990)

[文献書誌] OGURA Fumio(小倉文夫): "The Physics and Chemistry of Organic Superconductors (The Proceedings of the 1st ISSP International Symposium on the Physics and Chemistry of Organic Superconductors),Proceedings in Physics 51" SpringerーVerlag, 5 (1990)

[文献書誌] 中村晃(編集): "実験化学講座18" 丸善, 557 (1991)

[文献書誌] 木谷晧: "電池便覧(ポリアニリン電池の項を分担執筆)" 丸善, 535 (1990)