1992 年度実績報告書

多核錯体,低次元錯体など集合構造をもつ新しい錯体の合成,および集合の化学的効果

研究課題

研究課題/領域番号	02303006
研究機関	東北大学
研究代表者	伊藤翼東北大学, 理学部, 教授 (90007328)
研究分担者	藤田純之佑名古屋大学, 理学部, 教授 (80004266) 中村晃大阪大学, 理学部, 教授 (80029404) 齋藤太郎東京大学, 理学部, 教授 (90011006) 海崎純男大阪大学, 理学部, 教授 (20089874) 大滝仁志岡崎国立共同研究機構, 分子科学研究所, 教授 (80022549)
キーワード	多核金属錯体 / 金属クラスター錯体 / 低次錯体 / 錯体集合体
研究概要	1.本年度は,3年間にわたって研究活動を進めてきた当総合研究(A)班の研究最終年度あたる。3年間の研究成果の報告会を,公開シンポジウムの形で平成4年11月12-13日の二日間,岡崎国立共同研究機構・分子科学研究所において開催した。全国から50名の参加者があり,19名の班員全員が研究成果について講演を行い活発な討論がなされた。講演要旨集を500部作成し参会者に配布したほか、関係する全国の研究者に配布した。 2.研究成果の具体的内容については,冊子体の研究成果報告書に詳しく述べたのでここでは省略するが、多核錯体の化学に加え錯体集合体の化学について著しい研究の進展がみられた。また,分子研大瀧班員から,ポルフィリン錯体の溶液内反応における反応中間体をstopped-flowEXAFS法により直接検出できたというきわめて興味深い最新の研究結果が上記の公開シンポジウムで報告された。 3.班会議においてこの研究分野の基礎化学における重要性が議論され,″重点領域研究″への申請や国際会議の開催などについて意見交換が行なわれた。

研究成果

(39件)

すべてその他

すべて文献書誌 (39件)

[文献書誌] H.Sato,Yamagishi,and S.Kato: "Monte Carlo Simulations for rhe Interactions of Metal Complexes with the silicate sheets of a clay:Compareson of binding states between tris(1,10-phenanthroline)metal(II)and tres(2,2'-bipyridyl)metal(II)chelates" J.Am.Chem.Soc.,. 114. 10933-10940 (1992)
[文献書誌] H.Sato,A.Yamagishi,and S.Kato: "Theorerical studies on racemic adsorption of tris(1,10-phenanthroline)metal(II)by a clay:Monte Carlo simulations" J.Am.Chem.Soc.,. 114. 10933-10940 (1992)
[文献書誌] H.Sato,A.Yamagishi,ahd S.Kato: "Theoretical studies on racemic adsorption of tres(1,10-phenanthrolin)metal(II)by a clay:Monte Carlo simulations" J.Phys.Chem.,. 96. 9382-9387 (1992)
[文献書誌] M.Nakahanaka,T.Fuhihara, and,S.Kaizaki: "Sythesis and Z-Ray Structure of Novel Phenoxo Bridged Binuclear Complexes:Bis(μ-phenoxo)bis[bis(acetylacetonato)chromium(III)]Complex and Para-Substituted Phenoxo Analogues" Inorg.Chem.,. 31. 1315-1316 (1992)
[文献書誌] M.Nakafanada,T.Fujihara,N.Koine,andS.Kaizaki: "Synthesis and Characterization of L-tartrato Chromate(III)Complexes with Acetylactonate Ions" J.Chem.Soc.,Dalton Trans.,. 3423-3426 (1992)
[文献書誌] H.Ohtaki and Fukushima: "A Structural Study of Sarutared AQueors Solution of Some Alkail Halides by X-Ray Diffraction" J.Solution Chem.,. 21. 23-38 (1992)
[文献書誌] K.Ozutsumi,T.Takamuku,S.Ishiguro,and H.Ohtaki: "EXAFS and X-Ray Diffraction Studies on the Structure of the Tetrathiocyanatocadmate(II)Complex Ion Dimethyl Sulfoxide" Bull.Chem.Soc.Jpn.,. 65. 2104-2113 (1992)
[文献書誌] A.Miyamoto,H.Kobayashi,R.Kato,A.Kobayashi Y.Nishio,K Kajita,and W.Sesaki: "Metal Instability of(DMe-DCNQI)2Cu Induced by Uniaxial Stress and Enhancement of Electron Mass" Chem.Lett.,. 115-118 (1992)
[文献書誌] H.Tajima,S.Ikeda,A.Kobayashi,H.Kuroda,R.Kato and H.Kobayashi.: "Magnetoresistance of α-Et_2Me_2[Ni(dmit)_2]_2 Salt" Said State Commun.,. 82. 157-160 (1992)
[文献書誌] G.Saito,T.Komatsu,T.Nakamura,and H.Yamochi: "Design of Organic Superconductors Basec on BEDT-TTF" Mat.Res.Soc.,. 247. 483-494 (1992)
[文献書誌] G.Saito: "Organic Srperconductors Based on Sulfur and SElenium Compounds" Phosphrus,Sulfur,and Silecon.,. 67. 345-360 (1992)
[文献書誌] H.Kobayashi,N.Uryu,A.Tokiwa,T.Yamaguchi,Y.Sasaki,and T.Ito: "Magnctec Properties of Oxygen Centered Trinucear Ru(III)and Ph(III)" Bull.Chem.Soc.Jpn.,. 65. 198-202 (1992)
[文献書誌] D.Akashi,H.Kido,Y.Sasaki and T.Ito: "Preparation and Electrochemical Response of Poly(4-vinyl-pyrdine)-CoordinatedOxo-Acetato Triruthenium Cluster Film." Chem.Lett.,. 143-146 (1992)
[文献書誌] H.Takei,M.Koike,K.Imai,H.Sawa,and Y.Iye: "Growth and Properties of Li-deficient Lithium vanadium oxide singli ctystals" Materials Res.Bull.,. 27. 555-562 (1992)
[文献書誌] K.Imai,M.Koiki,H.sawa,and H.Takei: "Structural change in rhombohedral single ctystals Li_<1-x>VO_2(x=0.2)" J.Solid State Chem.,.
[文献書誌] M.Suzuku,Y.Hayashi,K.Munezawa,M.Suinaga,H.Senda,and A.Uehara: "Synthesid and Characterization of a Novel Dimer ofDi(μ-oxo)manganese Dimers with Two Coordinated Water Molecules in(III,IV,III,IV)Oxidation State" Chem.Lett.,. 1229-1932 (1991)
[文献書誌] Y.Hayashi,M.Suzuki,and A.Uehara: "(μ-Aikoxo)-diiron(II,II)Complexes of N,N,N,N'N'-Tetra-Kis(2-6-nethylpyridyl)nethyl)-1,3-diaminopropane-2-olate and Reversible Formation of the O_2-adduct" Chem.Lett.,. 91-94 (1992)
[文献書誌] K.Umakishi,A.Ichmura,I.Kinoshita,and S.Ooi: "The Dinuclear Palladium(II)Complex of Pyridine-2-thiol.synthesis,Structure and Electrochemistry" Inorg.Chem.,. 29. 4005-4010 (1990)
[文献書誌] T.Nishioka,I.Kinoshita,K.Kitano,and S.Ooi: "Synthesis of Lantern-type Dinucclear Mixed Metal Complex of Platinum(II)and Mickel(II)" Chem.Lett.,. 883-886 (1992)
[文献書誌] T.Shimada,M.Kodera,H.Okowa,and S.Kida: "Synthesis of 1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-pctaaza-cyclohexatriacontane(L)and its Complex[Cu_4L(OH)_4](CIO_4)_4" J.Chem.Soc.DaltonTrans.,. 1121-1125 (1992)
[文献書誌] M.Tadakoro,H.Sakiyama,N.Matsumoto,M.kodera,H.Okawa,and S.Kida: "Tenplate Synthesis of Copper(II)-Lead(II)Complexes of New Binuceating Macrocycoes with Dissimilea Coordination Sites" J.Chem.Soc.Dalton Trans.,. 313-317 (1992)
[文献書誌] T.Kawamoto and Y.Kushi: "Ctystal and Moleculea structure of Tetra-palladium Cluster with a C,N,S-Tredentate Ligand" Chem.Lett.,. 1057-1059 (1992)
[文献書誌] T.Kawamoto and Y.Kushi: "Helical Bis[2-(ferrocanylethleneamino)benzenethiolato]Metal(II)Complexes(M=Ni,Zn or Pd)and a Related Mercury(II)Complex" J.Chem.Soc.Dalton Trans.,. 3137-3143 (1992)
[文献書誌] N.Sato and Y.Fukuda: "Anion Sensing Electrodes Based on Nicke(II)Mixed Ligand Complexes" Chem.Lett.,. 399-402 (1992)
[文献書誌] K.Yamada,K.Hore,and Y.Fukuda: "The Structure of(μ-Carbonato)bis[(acetylacetonato)(N,N,N'N'-Tetra-methylethylenedianine)nckel(II)][aqua(methanol)(acethlacetonato)(N,N,N',N'-tetramethylethylethylenediamine(mickel(II)]tetraphaphentlborate" Acta Cryst.,. (1993)
[文献書誌] K.Tsuge,S.Yajima,H.Imoto,T.Saito: "Synthesis of an Equilateral Trinagular Moltbdenum Cluster Complex[Mo_3(μ_3-S)_2(μ-S)_3(PMe_3)_6]with Elght Cluster Valence Electrons" J.Am.Chem.Soc.,. 114. 7910-7912 (1992)
[文献書誌] K.Tsuge.H.Imoto,T.Saito: "Synthesis of[Mo_4S_6(SH)_2(PME_3)_6]and [Mo_6S_<10>(SH)_2(PEt_3)_6]_6]Consisting of Fused Mo_3(μ_3-S)Cluster Units" Inorg.Chem.,. 23. 4715-4716 (1992)
[文献書誌] T.Yamaguchi,N.Nishimura,and T.Ito: "Triangular Platinum(II)ClusterComplexes[Pt_3(CH_3COO)_4(cdoh)_2(cdoh_2)]and [Pt_3(CH_3COO)_4(dmgh)_2(dmgH)_2(dmgH_2)](cdoH_2=cycohexanedionedioXime and dmgH_2=dimethyglyoXime)" J.Am.Chem.Soc.,. 115. (1993)
[文献書誌] Y.Sasaki,Y.Yoshida,A.Ohto,A.Tokiwa,T.Ito,H,Kobayashi,N.Uryu,andI.Mogi: "Mixed Chromium(III)-Ruthenuum(3)Trinuclear CompleX,[CrRu_2(μ_3-O)(μ-CH_3COO)_6(pyridine)_3]^+" Chem.Lett.,. 69-72 (1993)
[文献書誌] Y.Ozawa,A.Vazquez de Migiel,and K. Isobe: "μ-Methtlene Rhodium Complexes with SH Ligand:Synthesis and Structures of[Rh_2Cp^*_2(μ-CH_2)_2(μ-SH)Bph_4 and trans[Rh_2Cp^*=η^5-C_5ME_5)" J. Organomet.Chem.,. 433. 183-188 (1992)
[文献書誌] H.Akashi,K. Isobe,Y.Ozawa,and A. Yagasaki.,: "β-Methally6rhodium(III)Supported on a Vanadium Oxide Cluster:Synthesis,Structure,and Reaction" J.Cluster Sci.,. 2. 291-296 (1992)
[文献書誌] N.Ueyama: "Synthesis,Crysral Structure and Electronic properties of a 2Fe-2S Complex with a Buiky Yhiolato Ligand" J.Chem.Soc.,. 2723-2727 (1991)
[文献書誌] K.Mashima: "Rational Preparation and Characterization of a Tandem Tetrametal Clusters. Crystal Structure of Tetrakis(6-di-phenyphosphino-2-pyridonato)dimolybdenum" Chem.Lett.185-188 (1992)
[文献書誌] K.Nakagima,K.Kojima,M.Kojima,and J.Fuiita: "Preparation and Characterization of Optically Active Schiff Base-Oxo-vanadium(IV)and-Oxovanadium(IV)Coplexes and Catalytic Properteisa These Complexes on Asymmeteic Oxidation of Sulfed into Sulfoxides with Organic Hydroperoxides" Bull.Chem.Soc.jpn.,. 63. 2620-2630 (1992)
[文献書誌] C.Sasaki,K.Nakajina,M.Kojima,and J.Fujita: "Preparation and Characterization of Optically Active Quadridentate Schiff Base-Titanium(IV)Complexes and the Catalytic Properties of These Complexes on Asymmeteic Oxidation of Methyly Phenyl Sulfides with Organic HydroperoXides" Bull.Chem.Soc.Jph.64. 1318-1324 (1991)
[文献書誌] M.Kawano,C.Hoshimo,and K.Matsumoto: "Synthesis,Properties and Crystal Structure of a Novel μ-Hydragine-Bridged Mixed-Valonice Rutenium(II,III)Complex Stabilized by Hydrazine Hydrogen Bonds,[RuCI(TMP)_2]_2(μ-CI)(μ-CI)(μ-N_2H_4)(μ-S_2)(TMP=P(OM_e)_3" Inorg.Chem.,. 31. 5158-5159 (1992)
[文献書誌] H.Uemura,M.Kawano,T.Watenabe,T.matsumoto,and K.matsumoto: "Synyhesis and Crystal Structure of a Binuclear Rutenium Compound Comtaining[Ru^2(μ-S^5)(μ-S^<22>CNMe^2)(s^2CNMe^2\(CO)^2(PPh^3)^2]and[Ru2(μ-S6)(μ-S2CNMe2)(siCNMe2)(CO)2(PPh3)2]:The First RutheniumCom&3unds with Bridging S5 and S6 Ligands" Inorg.Chei.,. 31. 5137-5139 (1992)
[文献書誌] M.Munakata,S.Kitagawa,and K.Kawada: "Synthesis,Structures Formation Constants of Copper(I)Complexes with Alkynes and 1.10-Phenanthroline." J.Chem.Soc.,Dalton.Trans.,. 2225-2230 (1992)
[文献書誌] S.Kitagawa,M.Munakata,and T.Tanimura: "Synthesis of the Novel Infinete-Sheet and-Chain Copper(I)Complex Polymers,{[Cu(C^44H^4N^2)_<3/2>(CH_3CN)](PF_6)・0.5C_3H_6O}_∞and{[Cu(C_8H_<12>N_2)_3](ClO_4)_2}∞and Their X-ray Crystal Structures" Inorg.Chem.,. 31. 1714-1717 (1992)

1992 年度 実績報告書

多核錯体,低次元錯体など集合構造をもつ新しい錯体の合成,および集合の化学的効果

研究代表者

伊藤 翼 東北大学, 理学部, 教授 (90007328)

研究成果

[文献書誌] H.Sato,Yamagishi,and S.Kato: "Monte Carlo Simulations for rhe Interactions of Metal Complexes with the silicate sheets of a clay:Compareson of binding states between tris(1,10-phenanthroline)metal(II)and tres(2,2'-bipyridyl)metal(II)chelates" J.Am.Chem.Soc.,. 114. 10933-10940 (1992)

[文献書誌] H.Sato,A.Yamagishi,and S.Kato: "Theorerical studies on racemic adsorption of tris(1,10-phenanthroline)metal(II)by a clay:Monte Carlo simulations" J.Am.Chem.Soc.,. 114. 10933-10940 (1992)

[文献書誌] H.Sato,A.Yamagishi,ahd S.Kato: "Theoretical studies on racemic adsorption of tres(1,10-phenanthrolin)metal(II)by a clay:Monte Carlo simulations" J.Phys.Chem.,. 96. 9382-9387 (1992)

[文献書誌] M.Nakahanaka,T.Fuhihara, and,S.Kaizaki: "Sythesis and Z-Ray Structure of Novel Phenoxo Bridged Binuclear Complexes:Bis(μ-phenoxo)bis[bis(acetylacetonato)chromium(III)]Complex and Para-Substituted Phenoxo Analogues" Inorg.Chem.,. 31. 1315-1316 (1992)

[文献書誌] M.Nakafanada,T.Fujihara,N.Koine,andS.Kaizaki: "Synthesis and Characterization of L-tartrato Chromate(III)Complexes with Acetylactonate Ions" J.Chem.Soc.,Dalton Trans.,. 3423-3426 (1992)

[文献書誌] H.Ohtaki and Fukushima: "A Structural Study of Sarutared AQueors Solution of Some Alkail Halides by X-Ray Diffraction" J.Solution Chem.,. 21. 23-38 (1992)

[文献書誌] K.Ozutsumi,T.Takamuku,S.Ishiguro,and H.Ohtaki: "EXAFS and X-Ray Diffraction Studies on the Structure of the Tetrathiocyanatocadmate(II)Complex Ion Dimethyl Sulfoxide" Bull.Chem.Soc.Jpn.,. 65. 2104-2113 (1992)

[文献書誌] A.Miyamoto,H.Kobayashi,R.Kato,A.Kobayashi Y.Nishio,K Kajita,and W.Sesaki: "Metal Instability of(DMe-DCNQI)2Cu Induced by Uniaxial Stress and Enhancement of Electron Mass" Chem.Lett.,. 115-118 (1992)

[文献書誌] H.Tajima,S.Ikeda,A.Kobayashi,H.Kuroda,R.Kato and H.Kobayashi.: "Magnetoresistance of α-Et_2Me_2[Ni(dmit)_2]_2 Salt" Said State Commun.,. 82. 157-160 (1992)

[文献書誌] G.Saito,T.Komatsu,T.Nakamura,and H.Yamochi: "Design of Organic Superconductors Basec on BEDT-TTF" Mat.Res.Soc.,. 247. 483-494 (1992)

[文献書誌] G.Saito: "Organic Srperconductors Based on Sulfur and SElenium Compounds" Phosphrus,Sulfur,and Silecon.,. 67. 345-360 (1992)

[文献書誌] H.Kobayashi,N.Uryu,A.Tokiwa,T.Yamaguchi,Y.Sasaki,and T.Ito: "Magnctec Properties of Oxygen Centered Trinucear Ru(III)and Ph(III)" Bull.Chem.Soc.Jpn.,. 65. 198-202 (1992)

[文献書誌] D.Akashi,H.Kido,Y.Sasaki and T.Ito: "Preparation and Electrochemical Response of Poly(4-vinyl-pyrdine)-CoordinatedOxo-Acetato Triruthenium Cluster Film." Chem.Lett.,. 143-146 (1992)

[文献書誌] H.Takei,M.Koike,K.Imai,H.Sawa,and Y.Iye: "Growth and Properties of Li-deficient Lithium vanadium oxide singli ctystals" Materials Res.Bull.,. 27. 555-562 (1992)

[文献書誌] K.Imai,M.Koiki,H.sawa,and H.Takei: "Structural change in rhombohedral single ctystals Li_<1-x>VO_2(x=0.2)" J.Solid State Chem.,.

[文献書誌] M.Suzuku,Y.Hayashi,K.Munezawa,M.Suinaga,H.Senda,and A.Uehara: "Synthesid and Characterization of a Novel Dimer ofDi(μ-oxo)manganese Dimers with Two Coordinated Water Molecules in(III,IV,III,IV)Oxidation State" Chem.Lett.,. 1229-1932 (1991)

[文献書誌] Y.Hayashi,M.Suzuki,and A.Uehara: "(μ-Aikoxo)-diiron(II,II)Complexes of N,N,N,N'N'-Tetra-Kis(2-6-nethylpyridyl)nethyl)-1,3-diaminopropane-2-olate and Reversible Formation of the O_2-adduct" Chem.Lett.,. 91-94 (1992)

[文献書誌] K.Umakishi,A.Ichmura,I.Kinoshita,and S.Ooi: "The Dinuclear Palladium(II)Complex of Pyridine-2-thiol.synthesis,Structure and Electrochemistry" Inorg.Chem.,. 29. 4005-4010 (1990)

[文献書誌] T.Nishioka,I.Kinoshita,K.Kitano,and S.Ooi: "Synthesis of Lantern-type Dinucclear Mixed Metal Complex of Platinum(II)and Mickel(II)" Chem.Lett.,. 883-886 (1992)

[文献書誌] T.Shimada,M.Kodera,H.Okowa,and S.Kida: "Synthesis of 1,10,19,28-Tetraoxa-4,7,13,16,22,25,31,34-pctaaza-cyclohexatriacontane(L)and its Complex[Cu_4L(OH)_4](CIO_4)_4" J.Chem.Soc.DaltonTrans.,. 1121-1125 (1992)

[文献書誌] M.Tadakoro,H.Sakiyama,N.Matsumoto,M.kodera,H.Okawa,and S.Kida: "Tenplate Synthesis of Copper(II)-Lead(II)Complexes of New Binuceating Macrocycoes with Dissimilea Coordination Sites" J.Chem.Soc.Dalton Trans.,. 313-317 (1992)

[文献書誌] T.Kawamoto and Y.Kushi: "Ctystal and Moleculea structure of Tetra-palladium Cluster with a C,N,S-Tredentate Ligand" Chem.Lett.,. 1057-1059 (1992)

[文献書誌] T.Kawamoto and Y.Kushi: "Helical Bis[2-(ferrocanylethleneamino)benzenethiolato]Metal(II)Complexes(M=Ni,Zn or Pd)and a Related Mercury(II)Complex" J.Chem.Soc.Dalton Trans.,. 3137-3143 (1992)

[文献書誌] N.Sato and Y.Fukuda: "Anion Sensing Electrodes Based on Nicke(II)Mixed Ligand Complexes" Chem.Lett.,. 399-402 (1992)

[文献書誌] K.Yamada,K.Hore,and Y.Fukuda: "The Structure of(μ-Carbonato)bis[(acetylacetonato)(N,N,N'N'-Tetra-methylethylenedianine)nckel(II)][aqua(methanol)(acethlacetonato)(N,N,N',N'-tetramethylethylethylenediamine(mickel(II)]tetraphaphentlborate" Acta Cryst.,. (1993)

[文献書誌] K.Tsuge,S.Yajima,H.Imoto,T.Saito: "Synthesis of an Equilateral Trinagular Moltbdenum Cluster Complex[Mo_3(μ_3-S)_2(μ-S)_3(PMe_3)_6]with Elght Cluster Valence Electrons" J.Am.Chem.Soc.,. 114. 7910-7912 (1992)

[文献書誌] K.Tsuge.H.Imoto,T.Saito: "Synthesis of[Mo_4S_6(SH)_2(PME_3)_6]and [Mo_6S_<10>(SH)_2(PEt_3)_6]_6]Consisting of Fused Mo_3(μ_3-S)Cluster Units" Inorg.Chem.,. 23. 4715-4716 (1992)

[文献書誌] T.Yamaguchi,N.Nishimura,and T.Ito: "Triangular Platinum(II)ClusterComplexes[Pt_3(CH_3COO)_4(cdoh)_2(cdoh_2)]and [Pt_3(CH_3COO)_4(dmgh)_2(dmgH)_2(dmgH_2)](cdoH_2=cycohexanedionedioXime and dmgH_2=dimethyglyoXime)" J.Am.Chem.Soc.,. 115. (1993)

[文献書誌] Y.Sasaki,Y.Yoshida,A.Ohto,A.Tokiwa,T.Ito,H,Kobayashi,N.Uryu,andI.Mogi: "Mixed Chromium(III)-Ruthenuum(3)Trinuclear CompleX,[CrRu_2(μ_3-O)(μ-CH_3COO)_6(pyridine)_3]^+" Chem.Lett.,. 69-72 (1993)

[文献書誌] Y.Ozawa,A.Vazquez de Migiel,and K. Isobe: "μ-Methtlene Rhodium Complexes with SH Ligand:Synthesis and Structures of[Rh_2Cp^*_2(μ-CH_2)_2(μ-SH)Bph_4 and trans[Rh_2Cp^*=η^5-C_5ME_5)" J. Organomet.Chem.,. 433. 183-188 (1992)

[文献書誌] H.Akashi,K. Isobe,Y.Ozawa,and A. Yagasaki.,: "β-Methally6rhodium(III)Supported on a Vanadium Oxide Cluster:Synthesis,Structure,and Reaction" J.Cluster Sci.,. 2. 291-296 (1992)

[文献書誌] N.Ueyama: "Synthesis,Crysral Structure and Electronic properties of a 2Fe-2S Complex with a Buiky Yhiolato Ligand" J.Chem.Soc.,. 2723-2727 (1991)

[文献書誌] K.Mashima: "Rational Preparation and Characterization of a Tandem Tetrametal Clusters. Crystal Structure of Tetrakis(6-di-phenyphosphino-2-pyridonato)dimolybdenum" Chem.Lett.185-188 (1992)

[文献書誌] M.Munakata,S.Kitagawa,and K.Kawada: "Synthesis,Structures Formation Constants of Copper(I)Complexes with Alkynes and 1.10-Phenanthroline." J.Chem.Soc.,Dalton.Trans.,. 2225-2230 (1992)

[文献書誌] S.Kitagawa,M.Munakata,and T.Tanimura: "Synthesis of the Novel Infinete-Sheet and-Chain Copper(I)Complex Polymers,{[Cu(C^44H^4N^2)_<3/2>(CH_3CN)](PF_6)・0.5C_3H_6O}_∞and{[Cu(C_8H_<12>N_2)_3](ClO_4)_2}∞and Their X-ray Crystal Structures" Inorg.Chem.,. 31. 1714-1717 (1992)

1992 年度実績報告書

伊藤翼東北大学, 理学部, 教授 (90007328)

[文献書誌] Y.Ozawa,A.Vazquez de Migiel,and K. Isobe: "μ-Methtlene Rhodium Complexes with SH Ligand:Synthesis and Structures of[Rh_2Cp^_2(μ-CH_2)_2(μ-SH)Bph_4 and trans[Rh_2Cp^=η^5-C_5ME_5)" J. Organomet.Chem.,. 433. 183-188 (1992)