1990 年度実績報告書

ミクロ場における高感度分光計測

研究課題

研究課題/領域番号	02353008
研究機関	九州大学
研究代表者	小川禎一郎九州大学, 大学院・総合理工学研究科, 教授 (50028156)
研究分担者	横山友大阪大学, 理学部, 教授原口紘煕名古屋大学, 工学部, 教授沢田嗣郎東京大学, 工学部, 教授合志陽一東京大学, 工学部, 教授石橋信彦九州大学, 工学部, 教授
キーワード	ミクロ領域 / 分光計測 / 気相 / 液相 / 表面 / 超高感度
研究概要	現代化学の基礎は分子にあり、分子レベルのミクロな場における計測が構造・反応・物性・機能の各化学分野における発展の基礎となる。ミクロの極限状態での計測手法の飛躍的革新を図るため、分光学的な手法を柱に据え、衆知を集めて討論し、この分野の発展に努めることを研究目的とした。具体的にはミクロ場における高感度分光計測手法の発展を、(1)気相におけるミクロ計測(分担者:小川、今坂、河口、谷本)、(2)液相におけるミクロ計測(分担者:石橋、澤田、寺前、藤原、山田)、(3)表面におけるミクロ計測(分担者:合志、二瓶、肥後、横山)、(4)ミクロ計測手法のシステム化(分担者:原口、前田、南)の4つの観点から捉え研究討議を進めた。この目的を達成するため、研究会を2回開催し、また研究成果報告書を発行した。 1.第1回研究会平成2年8月10,11日福岡市東区福岡リ-セントホテルにて総合研究開代者・分担者(計16名)の他、この分野の研究者多数の参加を得た。この分野における研究状況と発展の方向について24件の講演と熱心な討論が行われた。 2.第2回研究会平成3年1月22日東京都文京区学士会館分館にて総合研究の成果報告会をかねて開催し、総合研究代表者・分担者の他、各大学・産業界より多くの聴衆があった。ミクロ場における高感度分光計測について4つの特別講演があり、活発な討論が行われた。 3.研究成果報告書 150ペ-ジ研究討論の結果と総合研究の成果をまとめて編集した。

研究成果

(30件)

すべてその他

すべて文献書誌 (30件)

[文献書誌] T.Ogawa,T.Yoshidome,H.Kawazumi: "Excited triplet states of dimethylether studied by electron energyーloss spectroscopy." Bulletin of the Chemical Society of Japan. 63. 2707-2709 (1990)
[文献書誌] T.Yoshidome,H.Kawazumi,T.Ogawa: "Electron energy loss spectra of methanol and assignments of its triplet states." Journal of the electron spectroscopy and related phenomenon. 53. 185-192 (1990)
[文献書誌] T.Tsuboi,K.Nakashima,T.Ogawa: "Translational energy distributions and emission cross sections of the excited hydrogen atom produced in eーSiH_4 collisions." Bulletin of the Chemical Society of Japan. 64. 1-4 (1990)
[文献書誌] T.Imasaka,H.Nakagawa,N.Ishibashi: "Determination of surfactant by visible semiconducotor laser fluorometry after solvent extraction with Rhodamine 800" Analytical Sciences. 6. 775 (1990)
[文献書誌] T.Imasaka,H.Nakagawa,T.Okazaki,N.Ishibashi: "Enzyme immunoassay of insulin by Semiconductor laser fluorometry" Analytical Chemistry. 62. 2404 (1990)
[文献書誌] T.Imasaka,K.Kasaki,N.Ishibashi: "Detemination of Fe(II) with 2ーnitrosoー5ーdiethylaminophenol by thermal lens spectrophotometry using semiconductor laser as light source." Analytica Chimica Acta. (1991)
[文献書誌] C.H.Lin,H.Fukii,T.Imasaka,N.Ishibashi: "Normal and reverse synchronous scan luminescence techniques in supersonic jet spectroscopy.I.principle and analytical procedure"
[文献書誌] C.H.Lin,T.Imasaka,N.Ishibashi: "Normal and Reverse synchronous scan luminescence techniques in supersonic jet spectrometry .II.Application to anthracene derivatices."
[文献書誌] T.Imasaka,N.Ishibashi: "Analytical techniques using lasers" Progree in Quantum Electronics. 14. 131 (1990)
[文献書誌] K.Sasaki,K.Itoh,A.Fujishima,Y.Goshi: Journal vacuum Science and Technology. 8. 525-529 (1990)
[文献書誌] K.Sakamaki,K.Itoh,A.Fujishima,Y.Goshi: Journal of vacuum Science and Technology. 8. 614-617 (1990)
[文献書誌] A.Okumura,K.Miyamura,Y.Goshi: "A canning tunneling microscopy/current imaging tunneling spectroscopy investigation of an organic molecule:4ーCyanoー4ーnーheptylbiphenyl." Journal of vacuum Science and Technology. 8. 625-627 (1990)
[文献書誌] S.Kohiki,T.Satoh,S.Hatta,K.Setsune,K.Wasa,Y.Goshi: Materials Letters. 9. 185-188 (1990)
[文献書誌] K.Miyamura,H.Morooka,K.Hirai,Y.Goshi: Chemistry Letters. 1990. 1833-1836 (1990)
[文献書誌] M.Tanimoto,S.Saito,S.Yamamoto,K.Kawaguchi: "Microwave spectrum of CCS radical in vibrationally excited states." Proceeding PACIFICHEM symmposium on Chemistry and spectroscopy of Interstellar Molecules.
[文献書誌] X.Z.Wu,N.Teramae,T.Kitamori,T.Sawada: "Surface analysis of films by laser induced fluorescence spectroscopy under normal reflectance conditions." Bulletin of the Chemical Society of Japan. 64. (1991)
[文献書誌] M.Higo,S.Kamata,: "Surface reaction of dialkyl phosphite on alumina and magnesia studied by inelastic electron tunneling spectroscopy." Journal of Physical Chemistry. 94. 8709 (1990)
[文献書誌] M.Higo,K.Nishino,S.Kamata: "Characterization of evaporated silicon film by inelastic electron tunneling spectroscopy." Applied Surface Science. (1991)
[文献書誌] K.Fujiwara,R.Kojyo,H.Tsubota,K.Seki: "Spectrometric behavior of magnetite colloid in waveーguide long capillary cell." Analytical Sciences. 6. 207-209 (1990)
[文献書誌] K.Fujiwara,T.Nakamura,T.Kashima,H.Tsubota,T.Slin: "Mirrorーcoated longーpath cells for colorimetry with use of a bifurcated optical guide." Applied Spectroscopy. 44. 1084-1088 (1990)
[文献書誌] K.Fujiwara,T.Kashima,H.Tsubota,Y.Toyoshima,M.Aihara,M.Kiboku: "Oscillation found in reaction between permanganate and oxalic acid." Chemistry Letters. 1990. 1385-1386 (1990)
[文献書誌] Y.Oki,U.Uda,C.Honda,M.Maeda,J.Izumi,T.Morimoto,M.Tanoura: "Laserーinducedーfluorescence detection of sodium atomized by a microwaveーinduced plasma with Tungsten filament vaporization" Analytical Chemistry. 62. 680-683 (1990)
[文献書誌] 興,出羽,田代,本田,前田,長谷川,二見,泉,前田: "色素セル瞬時交換機能を有する自動波長可変色素レ-ザ-システム" レ-ザ-研究. (1991)
[文献書誌] X.F.Wang S.Kitajima,T.Uchida,D.M.Coleman,S.Minami: "Timeーresolved fluorescence microscopy using multichannel photon cunting." Applied Spectroscopy. 44. 25 (1990)
[文献書誌] X.F.Wang,T.Uchida,S.Minami: "Timeーresolved fluorescnce image spectroscopy techniques." Applied Fluorescence Technology. 2. 10 (1990)
[文献書誌] X.F.Wang,T.Uchida,D.M.Coleman,S.Minami: "A twoーdimensional fluorescence lifetime imaging system using a gated image intensifier." Applied Spectroscopy. 45. (1991)
[文献書誌] X.F.Wang,T.Uchida,M.Maeshima,S.Minami: "Fluorescence pattern analysis based on timeーresolved ration method" Applied Spectroscopy. 45. (1991)
[文献書誌] S.Yamada: "Twoーcolor multiphoton ionization with ultraviolet and visible laser excitation for the determination of polycyclic aromatic molecules in solution." Analytical Sciences. 7. (1991)
[文献書誌] H.Hinoue,M.Kawabe,S.Doi,Y.Yokoyama: Hyomen Kagaku. 10. 129 (1990)
[文献書誌] H.satoh,M.Owari,Y.Nihei: "Relative sensitivity factors for gallium primary ion beam in“Secondary Ion Mass Spectrometry SIMS VII" eds.Benninghoven et al." John Wiley & Sons, (1990)

1990 年度 実績報告書

ミクロ場における高感度分光計測

研究代表者

小川 禎一郎 九州大学, 大学院・総合理工学研究科, 教授 (50028156)

研究成果

[文献書誌] T.Ogawa,T.Yoshidome,H.Kawazumi: "Excited triplet states of dimethylether studied by electron energyーloss spectroscopy." Bulletin of the Chemical Society of Japan. 63. 2707-2709 (1990)

[文献書誌] T.Yoshidome,H.Kawazumi,T.Ogawa: "Electron energy loss spectra of methanol and assignments of its triplet states." Journal of the electron spectroscopy and related phenomenon. 53. 185-192 (1990)

[文献書誌] T.Tsuboi,K.Nakashima,T.Ogawa: "Translational energy distributions and emission cross sections of the excited hydrogen atom produced in eーSiH_4 collisions." Bulletin of the Chemical Society of Japan. 64. 1-4 (1990)

[文献書誌] T.Imasaka,H.Nakagawa,N.Ishibashi: "Determination of surfactant by visible semiconducotor laser fluorometry after solvent extraction with Rhodamine 800" Analytical Sciences. 6. 775 (1990)

[文献書誌] T.Imasaka,H.Nakagawa,T.Okazaki,N.Ishibashi: "Enzyme immunoassay of insulin by Semiconductor laser fluorometry" Analytical Chemistry. 62. 2404 (1990)

[文献書誌] T.Imasaka,K.Kasaki,N.Ishibashi: "Detemination of Fe(II) with 2ーnitrosoー5ーdiethylaminophenol by thermal lens spectrophotometry using semiconductor laser as light source." Analytica Chimica Acta. (1991)

[文献書誌] C.H.Lin,H.Fukii,T.Imasaka,N.Ishibashi: "Normal and reverse synchronous scan luminescence techniques in supersonic jet spectroscopy.I.principle and analytical procedure"

[文献書誌] C.H.Lin,T.Imasaka,N.Ishibashi: "Normal and Reverse synchronous scan luminescence techniques in supersonic jet spectrometry .II.Application to anthracene derivatices."

[文献書誌] T.Imasaka,N.Ishibashi: "Analytical techniques using lasers" Progree in Quantum Electronics. 14. 131 (1990)

[文献書誌] K.Sasaki,K.Itoh,A.Fujishima,Y.Goshi: Journal vacuum Science and Technology. 8. 525-529 (1990)

[文献書誌] K.Sakamaki,K.Itoh,A.Fujishima,Y.Goshi: Journal of vacuum Science and Technology. 8. 614-617 (1990)

[文献書誌] A.Okumura,K.Miyamura,Y.Goshi: "A canning tunneling microscopy/current imaging tunneling spectroscopy investigation of an organic molecule:4ーCyanoー4ーnーheptylbiphenyl." Journal of vacuum Science and Technology. 8. 625-627 (1990)

[文献書誌] S.Kohiki,T.Satoh,S.Hatta,K.Setsune,K.Wasa,Y.Goshi: Materials Letters. 9. 185-188 (1990)

[文献書誌] K.Miyamura,H.Morooka,K.Hirai,Y.Goshi: Chemistry Letters. 1990. 1833-1836 (1990)

[文献書誌] M.Tanimoto,S.Saito,S.Yamamoto,K.Kawaguchi: "Microwave spectrum of CCS radical in vibrationally excited states." Proceeding PACIFICHEM symmposium on Chemistry and spectroscopy of Interstellar Molecules.

[文献書誌] X.Z.Wu,N.Teramae,T.Kitamori,T.Sawada: "Surface analysis of films by laser induced fluorescence spectroscopy under normal reflectance conditions." Bulletin of the Chemical Society of Japan. 64. (1991)

[文献書誌] M.Higo,S.Kamata,: "Surface reaction of dialkyl phosphite on alumina and magnesia studied by inelastic electron tunneling spectroscopy." Journal of Physical Chemistry. 94. 8709 (1990)

[文献書誌] M.Higo,K.Nishino,S.Kamata: "Characterization of evaporated silicon film by inelastic electron tunneling spectroscopy." Applied Surface Science. (1991)

[文献書誌] K.Fujiwara,R.Kojyo,H.Tsubota,K.Seki: "Spectrometric behavior of magnetite colloid in waveーguide long capillary cell." Analytical Sciences. 6. 207-209 (1990)

[文献書誌] K.Fujiwara,T.Nakamura,T.Kashima,H.Tsubota,T.Slin: "Mirrorーcoated longーpath cells for colorimetry with use of a bifurcated optical guide." Applied Spectroscopy. 44. 1084-1088 (1990)

[文献書誌] K.Fujiwara,T.Kashima,H.Tsubota,Y.Toyoshima,M.Aihara,M.Kiboku: "Oscillation found in reaction between permanganate and oxalic acid." Chemistry Letters. 1990. 1385-1386 (1990)

[文献書誌] Y.Oki,U.Uda,C.Honda,M.Maeda,J.Izumi,T.Morimoto,M.Tanoura: "Laserーinducedーfluorescence detection of sodium atomized by a microwaveーinduced plasma with Tungsten filament vaporization" Analytical Chemistry. 62. 680-683 (1990)

[文献書誌] 興,出羽,田代,本田,前田,長谷川,二見,泉,前田: "色素セル瞬時交換機能を有する自動波長可変色素レ-ザ-システム" レ-ザ-研究. (1991)

[文献書誌] X.F.Wang S.Kitajima,T.Uchida,D.M.Coleman,S.Minami: "Timeーresolved fluorescence microscopy using multichannel photon cunting." Applied Spectroscopy. 44. 25 (1990)

[文献書誌] X.F.Wang,T.Uchida,S.Minami: "Timeーresolved fluorescnce image spectroscopy techniques." Applied Fluorescence Technology. 2. 10 (1990)

[文献書誌] X.F.Wang,T.Uchida,D.M.Coleman,S.Minami: "A twoーdimensional fluorescence lifetime imaging system using a gated image intensifier." Applied Spectroscopy. 45. (1991)

[文献書誌] X.F.Wang,T.Uchida,M.Maeshima,S.Minami: "Fluorescence pattern analysis based on timeーresolved ration method" Applied Spectroscopy. 45. (1991)

[文献書誌] S.Yamada: "Twoーcolor multiphoton ionization with ultraviolet and visible laser excitation for the determination of polycyclic aromatic molecules in solution." Analytical Sciences. 7. (1991)

[文献書誌] H.Hinoue,M.Kawabe,S.Doi,Y.Yokoyama: Hyomen Kagaku. 10. 129 (1990)

[文献書誌] H.satoh,M.Owari,Y.Nihei: "Relative sensitivity factors for gallium primary ion beam in“Secondary Ion Mass Spectrometry SIMS VII" eds.Benninghoven et al." John Wiley & Sons, (1990)

1990 年度実績報告書

小川禎一郎九州大学, 大学院・総合理工学研究科, 教授 (50028156)