1991 年度実績報告書

分子設計の基礎と展開

研究課題

研究課題/領域番号	03214104
研究機関	大阪大学
研究代表者	村田一郎大阪大学, 理学部, 教授 (90028077)
研究分担者	竹内賢一京都大学, 工学部, 教授 (50026358) 新海征治九州大学, 工学部, 教授 (20038045) 大木道則岡山理科大学, 理学部, 教授 (40011407) 今村詮広島大学, 理学部, 教授 (70076991) 安藤亘筑波大学, 化学系, 教授 (30008429)
キーワード	分子設計理論 / 分子の動的性質 / 分子認識場 / 不安定分子種 / 電子授受 / ヘテロ原子
研究概要	1.平成3年6月21日(金)、22日(土)の二日間、仙台市商工会議所ホ-ルにおいて平成3年度第一回公開シンポジウムを行った。こゝでは計画研究班員会員の他、評価班から桜井、吉田、三角、長倉の四教授、一般より66名の出席を得て、13名の班員の研究発表が行われた。発表会終了後、長倉教授より全体に亘っての講評を頂いた。 2.上記シンポジウム初日の昼食時に総括班会議を開き、評価班の吉田、三角教授の出席を得て主として予算、今年度の活動方針並びに最終年度の成果報告および本領域の成果取り纏めについて協議した。また、A04班岩村秀班長の特別推進研究採択内定に伴い、同班の班長候補者として京大・工・竹内賢一教授を内定した。また二日目昼食時に各班会議を行ない各種亊務連絡の他、第二回シンポジウム発表者を決定した。 3.各研究班では次のように研究連絡会議を開き、研究進行状況および問題点について討論を行った。A01(北大・理)、A02(東大・理)、A03(東京ガ-デンパレス)、A04(名大・理)、A05(富山高志会館)、A06(作並)。これらの会議には理論班から1〜2名の参加を得て理論の立場からの助言を得たことは実験班員にとって有益であった。 4.平成4年1月20日(月)、21日(火)の二日間、新大阪シティプラザにおいて本年度第二回公開シンポジウムを行ない、計画班11名の研究発表があり、それぞれ極めて活発な討論があった。本シンポジウム中にも総括班会議、および班会議が開かれ、最終年度の成果取り纏め、事務連絡を行った。 5.ニュ-スレタ-No.3の発行を行った。 6.総括班で購入し阪大・理に設置されている質量分析計では、竹内(東大・教養)管原(東大・教養)、大木(岡山理大)等の班員の試料測定を行ない、有効に利用された。

研究成果

(60件)

すべてその他

すべて文献書誌 (60件)

[文献書誌] S.Sasaki,K.-U.Klabunde,I.Murata,J.Toyoda,and K.Nakasuji: "Synthesis of a Highly Amphoteric 8,16-Diisopropyl-s-indaceno[1,2,3-cd;5,6,7,-c'd']diphenalene:Switching Between Diatropism and Para-tropism Accompanied by Its Oxidation Levels" Angew. Chem.,Int.Ed.Engl.30. 172-173 (1991)
[文献書誌] K.Nakasuji,K.Sugiura,T.Kitagawa,J.Toyoda,H.Okamoto,I Murata.etal: "Exploration of New Cooperative Proton-Electron Transfer (PET) System First Example of Extended Conjugated Quinhydrones,1,5-Dihalo-2,6-naphthoquinones" J.Am.Chem.Soc.113. 1862-1864 (1991)
[文献書誌] K.Nishino,M.Takagi,T.Kawata,I.Murata,J.Inanaga,K.Nakasuji: "Thiepine-iron Tricarbonyl:Stabilization of Thermally Labile Parent Thiepine by Transition Metal Complexation" J.Am.Chem.Soc.113. 5059-5060 (1991)
[文献書誌] Y.Sugihara,J.Saito,I.Murata: "2-Triphenylmethyldicyclohept[cd,g]indene:A Novel Cata-Peri Condensed Nonalternant Hydrocarbon" Angew.Chem.Int.Ed.Engl.30. 1174-1176 (1991)
[文献書誌] J.Toyoda,K.Nakasuji,T.Kotani,I.Murata,A.Kawamoto,J.Tanaka: "The Crystal Structure and Physical Properties of the 3:2 Charge Transfer Complex of Bis(ethylenedithio)dithiapyrene (ETDTPY) and Dibenzobarrelenotetracyanoquinodimethane" Chem.Lett.1237-1240 (1991)
[文献書誌] Y.Sugihara,T.Yagi,I.Murata,A.Imamura: "1-Phenylthieno[3,4-d]borepine:A New 10 pi Electron System Isoelectronic with Azulene" J.Am.Chem.Soc.114. 1479-1481 (1992)
[文献書誌] A.Sakakibara,Y.Kabe,T.Shimizu,W.Ando: "Molecular Interactions of Polysilane and Unsaturated Nitrogen Compounds.Photochemical Addition of Disilene versus Silylene to Azobenzene" J.Chem.Soc.,Chem.Commun.43-44 (1991)
[文献書誌] T.Shimizu,K.Shimizu,W.Ando: "Synthesis,Structure,and Stabilities of trans-1,2-Diphenyl-4,4,5,5,6,6-hexamethyl-4,5,6-trisilacycloheptene" J.Am.Chem.Soc.113. 354-355 (1991)
[文献書誌] T.Akasaka,A.Sakurai,W,Ando: "Cooxidation Reaction in the Singlet Oxygenation of Cyclic and Benzylic Sulfudes:S-Hydroperoxysulfonium Ylide Intermediate as a New Epoxidizing Species" J.Am.Chem.Soc.113. 2696-2701 (1991)
[文献書誌] W.Ando,T.Yamamoto,H.Saso,Y.Kabe: "Stable η^4-Silatrimethylenemethane Transition-metal Complexes by the Reaction of Alkylidenesilirane with Metal Carbonyl" J.Am.Chem.Soc.113. 2791-2793 (1991)
[文献書誌] W.Ando,N.Tokitoh,Y.Kabe: "Synthesis and Reaction of Novel Sulfur containing Heterocyclic Systems" Phosphorus,sulfur,and Silicon. 58. 179-205 (1991)
[文献書誌] W.Ando,M.Kako,T.Akasaka: "Direct observation of an Azetidinium Imide Intermediate in[π^2+σ^2]Addition of 1,2,4-Triazoline-3,5-dione to Disirane" J.Am,Chem.Soc.113. 6286-6288 (1991)
[文献書誌] W.Ando,T.Ohtaki,T.Suzuki,T.Kabe: "The First Stable Enethiolizable Thioaldehyde via a Zirconocene η^2-Thioacyl Complex" J.Am,Chem.Soc.113. 7782-7784 (1991)
[文献書誌] W.Ando,H.Yoshida,K.Kurishima,M.Sugiyama: "Intramolecular Reaction of 1,5-Disila-1,4-Pentadiene:Formation of 2,4,5-Trisilabicyclo[1.1.1]pentane and 2,3,5-Trisilabicyclo[2.1.0]pentane" J.Am,Chem.Soc.113. 7790-7792 (1991)
[文献書誌] T.Akasaka,K.Sato,M.Kako,W.Ando: "Formation of 1,2,3,6-Dioxadisilin in Photo-induced Electron Transfer Oxygenation of 1,2-Disiletene" Tetrahedron Lett.32. 6605-6608 (1991)
[文献書誌] Shin-ichiro Hayashi: "Ab initio calculation of linear and nonlinear polariza-bilities in the side-chain direction on the conjugated polymers" Chem.Phys.Lett.,. 179. 405-409 (1991)
[文献書誌] Kazuhiro Shimofuji: "Unimolecular Thermal Decomposition of Ethyl Vinyl Ether and the Consecutive Thermal Reaction of the Intermediary Product Acetaldehyde:Shock Wave Experiment and ab Initio Calculation" J.Phys.Chem.,. 95. 155-165 (1991)
[文献書誌] Yuriko Aoki: "Self-consistent-field perturbational approach to aperiodic polymers" J.Molec.Struct.(Theochem). 235. 95-105 (1991)
[文献書誌] Akira Imamura: "A theoretical synthesis of polymers by using uniform localization of molecular orbitals Proposal of an elongation method" J.Chem.Phys.,. 95. 5419-5431 (1991)
[文献書誌] Yoshikazu Sugahara: "1-Phenylthieno(3,4-d)borepine:A New 10π Electron System Isoelectronic with Azulene" J.Amer.Chem.Soc.,.
[文献書誌] Yuriko Aoki: "A Simple Treatment to Design NBMO Denerate Systems in Altermant and Non-Altermant Hydrocarbons" Theoret.Chim .Acta.
[文献書誌] S.Toyota: "Dynamic NMR as a Nondestructive Method for the Determinaion of Rates of Dissociation.XVII.Dissociation of the N-B Bond in the Coor-Dinated form of 2-[2-Dimethylaminomethyl)phenyl]-4,4-diphenyl-1,3,2-dioxaborolane and Related Compounds" Bull.Chem,Soc.Jpn.63. 1168-1173 (1990)
[文献書誌] S.Toyota: "Dynamic NMR as a Nondestructive Method for the Determinaion of Rates of Dissociation.XVIII.Factors Affecting the Rates of Dissociation of N-B Bond in the Coordinated Form of 9[2-(Dialkylaminomethlyl)-phenyl]-9-borabicyclo[3.3.1]nonanes" Bull.Chem,Soc.Jpn.64. 1554-1562 (1991)
[文献書誌] S.Toyota: "Dynamic NMR as a Nondestructive Method for the Determinaion of Rates of Dissociation.XIX.Sulfur Inversion in 9-[2-(Ethylthiomethyl)-phenyl]-9-borabicyclo[3.3.1]nonane Proceeds via Dissociative Mechanism" Bull.Chem,Soc.Jpn.64. 1563-1569 (1991)
[文献書誌] S.Toyota: "Structure of Boron-Amine Complexes and Proposal of Tetrahedral Character for Correlation between Molecular Stucture and Barrier to Dissociation of the N-B Bonds" Bull.Chem,Soc.Jpn.
[文献書誌] S.Toyota: "Dynamic NMR as a Nondestructive Method for the Determination of Rates of Dissociation.XX.Secondary Isotope Effect on Kinetic Basicity of Amine Ligands in a Boronate-Amine Complex and an Ammonum Salt"
[文献書誌] M.Oki: "Effects of Molecular Size of Solvent on Dissociation of Coordination Compounds."
[文献書誌] M.Oki: "Effects of Molecular Size of Solvent on Dissociation of Amine Ligands in Some Intramolecular Coordination compounds"
[文献書誌] M.Oki: "Effects of Molecular Size of Solvent on Dissociation of the N-H Bond in Ammonium Salts"
[文献書誌] S.Shinkai: "Ion Template Effects on the Conformation of Water-Soluble Calixarenes." J.Org.Chem.56. 295-300 (1991)
[文献書誌] T.Matsuda: "New Water-Soluble Calixarenes Bearing Chiral Substituents." J.Org.Chem.56. 301-306 (1991)
[文献書誌] S.Shinkai: "New Syntheses and Physical Properties of p-Alkylcalix[n]arenes." Bull.Chem.Soc.Jpn.64. 381-386 (1991)
[文献書誌] K.Iwamoto: "Syntheses of New Isomers form p-t-Butyl-calix[4]arene:Strategies for Regioselective Alkylation on the Lower Rim." Chem.Lett.473-476 (1991)
[文献書誌] A.Yamada: " ^1H and ^<13>C Nuclear Magnetic Resonance Relaxation-time Studies of Ionophoric Calixarene Esters." J.Chem.Soc.Perkin Trans.2. 793-797 (1991)
[文献書誌] T.Arimura: "Formation of Molecular Complexes with Calixarenes as Detected by Induced ciruclar Dichroism." Bull.Chem.Soc.Jpn.64. 1896-1900 (1991)
[文献書誌] K.Iwamoto: "How is the 1,2-Alternate Conformer Formed in Tetra-O-alkylation of p-Tert-Butyl-calix[4]arene?" J.Chem.Soc.,Perkin Trans.1. 1611-1613 (1991)
[文献書誌] K.Iwamoto: "Syntheses of All Possible Conformational Isomers of O-Alkyl-p-t-Butylcalix[4]arenes." Tetrahedron. 47. 4325-4342 (1991)
[文献書誌] K.Tsukagoshi: "Specific Complexation with Mono-and Disaccharides That Can be Detected by Circular Dichroism." J.Org,Chem.56. 4089-4091 (1991)
[文献書誌] T.Nagasaki: "Synthesis and Solvent Extraction Studies of Novel Calixarene-based Uranophiles Bearing Hydroxamate Groups." J.Chem.Soc.,Perkin Trans.2. 1063-1066 (1991)
[文献書誌] T.Nagasaki: "A New Calix[6]arene-based Uranophile with Phosphonate Groups as Ligands." Bull.Chem.Soc.Jpn.56. 2575-2577 (1991)
[文献書誌] K.Iwamoto: "Conformations and Structures of Tetra-O-alkyl-p-tert-butylcalix-[4]arenes.How is the Conformation of Calix[4]arene Immobilized?" J.Org.Chem.56. 4955-4962 (1991)
[文献書誌] S.Shinkai: "Molecular Recognition of Mono-and Di-saccharides by Phenylboronic Acids in Solvent Extraction and as a Monolayer." J.Chem.Soc.,Chem.Commun.1039-1041 (1991)
[文献書誌] T.Nagasaki: "Kinetic Studies of Calixarene-based Cyclic and Non-cyclic 'Super-uranophiles'." J.Chem.Soc.,Perkin Trans.2. 1325-1327 (1991)
[文献書誌] T.Arimura: "Calixarene-based Molecular Capsule." Tetrahedron Lett.32. 1715-1718 (1991)
[文献書誌] S.Shinkai: "Chiral Calix[4]arene." J.Chem.Soc.,Perkin Trans.1. 2429-2434 (1991)
[文献書誌] H.Shimizu: "Chromogenic Calix[4]arene." Chem.Lett.2147-2150 (1991)
[文献書誌] S.Shinkai: "pK_a Determination of Water-Soluble Calix[4]arenes." J.Chem.Soc.,Perkin Trans.2. 1883-1886 (1991)
[文献書誌] S.Aonuma,K.Komatsu,N.Maekawa,and K.Takeuchi: "Enhanced Polarization of Heptafulvene and Tropone by Annelation with Three Bicylclo[2.2.2]octene Frameworks" Chem.Lett.767-770 (1991)
[文献書誌] K.Komatsu,H.Kamo,R.Tsuji,H.Masuda,and K.Takeuchi: "4-Homoadamantyne:Generation,Chemical Trapping and Structure of Its Pt(O) Complex" J.Chem.Soc.,Chem.Commun.71-72 (1991)
[文献書誌] K.Komatsu,S.Aonuma,Y.Jinbu,R.Tsuji,C,Hirosawa,and K.Takeuchi: "Generation and Oligomerization of Bicyclo[2.2.2]octyne and Properties of Tris(bicyclo[2.2.2]octeno)benzene Obtained from the Linear Trimer" J.Org.Chem.56. 195-203 (1991)
[文献書誌] K.Ikai,K.Takeuchi,T.Kinoshita,K.Haga,K.Komatsu,and K.Okamoto: "Stereomutation of 7-Tropylionorbornane,2-Tropyliobicyclo[2.2.2-]-octane,and 2-Tropylioadamantane:Evidence for the Intermediacy of Heptafulvenes" J.Org.Chem.56. 1052-1058 (1991)
[文献書誌] K.Komatsu,H.Akamatsu,S.Aonuma,Y.Jinbu,N.Maekawa,and K.Takeuchi: "Formation,Properties,and Reactions of the 1,2:3,4:5,6-Tris(bicyclo[2.2.2]octeno)tropylium Ion" Tetrahedron. 47. 6951-6966 (1991)
[文献書誌] R.Tsuji,K.Komatsu,Y.Inoue,and K.Takeuchi: "1-Naphtyltropylium Ions Having Condensed Aromatic Rings at the 8-P-sition:Dependence of the Intramolecular Charge-Transfer Interaction upon Geometry of the Donor" J.Org.Chem.57. 636-641 (1992)
[文献書誌] A.Miyabo,K.Takeuchi,K.Komatsu,and T.Kitagawa: "Small Difference in Cation Stability in Contyolling the Formation of Hydrocarbon Salt or Covalent Hydrocarbon" Chem.Lett.(1992)
[文献書誌] A.Miyabo,T.Kitagawa,And K.Takeuchi: "Significance of Steric Effect in the Heterolysis of Carbon-Carbon σ Bond in Ionically Dissociative Hydrocarbons" Chem.Lett.(1992)
[文献書誌] T.Kitagawa,K.Takeuchi,K.Komatsu,and T.Kinoshita: "Syntheses and Properties of Hydrocarbon Salts and Ionically Dissociative Hydrocarbons" J.Synth.Org.Chem.Jpn.
[文献書誌] T.Kinoshita,H.Kimura,I.Nakajima,K.Takeuchi,and K.Okamoto: "Synthesis and Properties of 1,2,4-Tris(7H-dibenzo[c,g]-fluorenylidenemetyl)cyclopentadienide Ion"
[文献書誌] K.Komatsu,T.Nishinaga,N.Maekawa,Y.Kagayama,and K.Takeuchi: "Syntheses and Redox Behavior of the p-Phenylenebis-and Acetylenebis[tris(bicyclo[2.2.2]octeno)tropylium]Dications"
[文献書誌] A.Miyabo,K.Takeuchi,K.Komatsu,and T.Kitagawa: "Precise Control of Covalent and Ionic Bond Formation in Carbocation-Carbanion Combination Reaction"
[文献書誌] A.Miyabo,T.Kitagawa,and K.Takeuchi: "Heterolysis of Carbon-Carbon σ Bond in Hydrocarbons:Significance of Steric Effect"

1991 年度 実績報告書

分子設計の基礎と展開

研究代表者

村田 一郎 大阪大学, 理学部, 教授 (90028077)

研究成果

[文献書誌] S.Sasaki,K.-U.Klabunde,I.Murata,J.Toyoda,and K.Nakasuji: "Synthesis of a Highly Amphoteric 8,16-Diisopropyl-s-indaceno[1,2,3-cd;5,6,7,-c'd']diphenalene:Switching Between Diatropism and Para-tropism Accompanied by Its Oxidation Levels" Angew. Chem.,Int.Ed.Engl.30. 172-173 (1991)

[文献書誌] K.Nakasuji,K.Sugiura,T.Kitagawa,J.Toyoda,H.Okamoto,I Murata.etal: "Exploration of New Cooperative Proton-Electron Transfer (PET) System First Example of Extended Conjugated Quinhydrones,1,5-Dihalo-2,6-naphthoquinones" J.Am.Chem.Soc.113. 1862-1864 (1991)

[文献書誌] K.Nishino,M.Takagi,T.Kawata,I.Murata,J.Inanaga,K.Nakasuji: "Thiepine-iron Tricarbonyl:Stabilization of Thermally Labile Parent Thiepine by Transition Metal Complexation" J.Am.Chem.Soc.113. 5059-5060 (1991)

[文献書誌] Y.Sugihara,J.Saito,I.Murata: "2-Triphenylmethyldicyclohept[cd,g]indene:A Novel Cata-Peri Condensed Nonalternant Hydrocarbon" Angew.Chem.Int.Ed.Engl.30. 1174-1176 (1991)

[文献書誌] J.Toyoda,K.Nakasuji,T.Kotani,I.Murata,A.Kawamoto,J.Tanaka: "The Crystal Structure and Physical Properties of the 3:2 Charge Transfer Complex of Bis(ethylenedithio)dithiapyrene (ETDTPY) and Dibenzobarrelenotetracyanoquinodimethane" Chem.Lett.1237-1240 (1991)

[文献書誌] Y.Sugihara,T.Yagi,I.Murata,A.Imamura: "1-Phenylthieno[3,4-d]borepine:A New 10 pi Electron System Isoelectronic with Azulene" J.Am.Chem.Soc.114. 1479-1481 (1992)

[文献書誌] A.Sakakibara,Y.Kabe,T.Shimizu,W.Ando: "Molecular Interactions of Polysilane and Unsaturated Nitrogen Compounds.Photochemical Addition of Disilene versus Silylene to Azobenzene" J.Chem.Soc.,Chem.Commun.43-44 (1991)

[文献書誌] T.Shimizu,K.Shimizu,W.Ando: "Synthesis,Structure,and Stabilities of trans-1,2-Diphenyl-4,4,5,5,6,6-hexamethyl-4,5,6-trisilacycloheptene" J.Am.Chem.Soc.113. 354-355 (1991)

[文献書誌] T.Akasaka,A.Sakurai,W,Ando: "Cooxidation Reaction in the Singlet Oxygenation of Cyclic and Benzylic Sulfudes:S-Hydroperoxysulfonium Ylide Intermediate as a New Epoxidizing Species" J.Am.Chem.Soc.113. 2696-2701 (1991)

[文献書誌] W.Ando,T.Yamamoto,H.Saso,Y.Kabe: "Stable η^4-Silatrimethylenemethane Transition-metal Complexes by the Reaction of Alkylidenesilirane with Metal Carbonyl" J.Am.Chem.Soc.113. 2791-2793 (1991)

[文献書誌] W.Ando,N.Tokitoh,Y.Kabe: "Synthesis and Reaction of Novel Sulfur containing Heterocyclic Systems" Phosphorus,sulfur,and Silicon. 58. 179-205 (1991)

[文献書誌] W.Ando,M.Kako,T.Akasaka: "Direct observation of an Azetidinium Imide Intermediate in[π^2+σ^2]Addition of 1,2,4-Triazoline-3,5-dione to Disirane" J.Am,Chem.Soc.113. 6286-6288 (1991)

[文献書誌] W.Ando,T.Ohtaki,T.Suzuki,T.Kabe: "The First Stable Enethiolizable Thioaldehyde via a Zirconocene η^2-Thioacyl Complex" J.Am,Chem.Soc.113. 7782-7784 (1991)

[文献書誌] W.Ando,H.Yoshida,K.Kurishima,M.Sugiyama: "Intramolecular Reaction of 1,5-Disila-1,4-Pentadiene:Formation of 2,4,5-Trisilabicyclo[1.1.1]pentane and 2,3,5-Trisilabicyclo[2.1.0]pentane" J.Am,Chem.Soc.113. 7790-7792 (1991)

[文献書誌] T.Akasaka,K.Sato,M.Kako,W.Ando: "Formation of 1,2,3,6-Dioxadisilin in Photo-induced Electron Transfer Oxygenation of 1,2-Disiletene" Tetrahedron Lett.32. 6605-6608 (1991)

[文献書誌] Shin-ichiro Hayashi: "Ab initio calculation of linear and nonlinear polariza-bilities in the side-chain direction on the conjugated polymers" Chem.Phys.Lett.,. 179. 405-409 (1991)

[文献書誌] Kazuhiro Shimofuji: "Unimolecular Thermal Decomposition of Ethyl Vinyl Ether and the Consecutive Thermal Reaction of the Intermediary Product Acetaldehyde:Shock Wave Experiment and ab Initio Calculation" J.Phys.Chem.,. 95. 155-165 (1991)

[文献書誌] Yuriko Aoki: "Self-consistent-field perturbational approach to aperiodic polymers" J.Molec.Struct.(Theochem). 235. 95-105 (1991)

[文献書誌] Akira Imamura: "A theoretical synthesis of polymers by using uniform localization of molecular orbitals Proposal of an elongation method" J.Chem.Phys.,. 95. 5419-5431 (1991)

[文献書誌] Yoshikazu Sugahara: "1-Phenylthieno(3,4-d)borepine:A New 10π Electron System Isoelectronic with Azulene" J.Amer.Chem.Soc.,.

[文献書誌] Yuriko Aoki: "A Simple Treatment to Design NBMO Denerate Systems in Altermant and Non-Altermant Hydrocarbons" Theoret.Chim .Acta.

[文献書誌] S.Toyota: "Dynamic NMR as a Nondestructive Method for the Determinaion of Rates of Dissociation.XIX.Sulfur Inversion in 9-[2-(Ethylthiomethyl)-phenyl]-9-borabicyclo[3.3.1]nonane Proceeds via Dissociative Mechanism" Bull.Chem,Soc.Jpn.64. 1563-1569 (1991)

[文献書誌] S.Toyota: "Structure of Boron-Amine Complexes and Proposal of Tetrahedral Character for Correlation between Molecular Stucture and Barrier to Dissociation of the N-B Bonds" Bull.Chem,Soc.Jpn.

[文献書誌] S.Toyota: "Dynamic NMR as a Nondestructive Method for the Determination of Rates of Dissociation.XX.Secondary Isotope Effect on Kinetic Basicity of Amine Ligands in a Boronate-Amine Complex and an Ammonum Salt"

[文献書誌] M.Oki: "Effects of Molecular Size of Solvent on Dissociation of Coordination Compounds."

[文献書誌] M.Oki: "Effects of Molecular Size of Solvent on Dissociation of Amine Ligands in Some Intramolecular Coordination compounds"

[文献書誌] M.Oki: "Effects of Molecular Size of Solvent on Dissociation of the N-H Bond in Ammonium Salts"

[文献書誌] S.Shinkai: "Ion Template Effects on the Conformation of Water-Soluble Calixarenes." J.Org.Chem.56. 295-300 (1991)

[文献書誌] T.Matsuda: "New Water-Soluble Calixarenes Bearing Chiral Substituents." J.Org.Chem.56. 301-306 (1991)

[文献書誌] S.Shinkai: "New Syntheses and Physical Properties of p-Alkylcalix[n]arenes." Bull.Chem.Soc.Jpn.64. 381-386 (1991)

[文献書誌] K.Iwamoto: "Syntheses of New Isomers form p-t-Butyl-calix[4]arene:Strategies for Regioselective Alkylation on the Lower Rim." Chem.Lett.473-476 (1991)

[文献書誌] A.Yamada: " ^1H and ^<13>C Nuclear Magnetic Resonance Relaxation-time Studies of Ionophoric Calixarene Esters." J.Chem.Soc.Perkin Trans.2. 793-797 (1991)

[文献書誌] T.Arimura: "Formation of Molecular Complexes with Calixarenes as Detected by Induced ciruclar Dichroism." Bull.Chem.Soc.Jpn.64. 1896-1900 (1991)

[文献書誌] K.Iwamoto: "How is the 1,2-Alternate Conformer Formed in Tetra-O-alkylation of p-Tert-Butyl-calix[4]arene?" J.Chem.Soc.,Perkin Trans.1. 1611-1613 (1991)

[文献書誌] K.Iwamoto: "Syntheses of All Possible Conformational Isomers of O-Alkyl-p-t-Butylcalix[4]arenes." Tetrahedron. 47. 4325-4342 (1991)

[文献書誌] K.Tsukagoshi: "Specific Complexation with Mono-and Disaccharides That Can be Detected by Circular Dichroism." J.Org,Chem.56. 4089-4091 (1991)

[文献書誌] T.Nagasaki: "Synthesis and Solvent Extraction Studies of Novel Calixarene-based Uranophiles Bearing Hydroxamate Groups." J.Chem.Soc.,Perkin Trans.2. 1063-1066 (1991)

[文献書誌] T.Nagasaki: "A New Calix[6]arene-based Uranophile with Phosphonate Groups as Ligands." Bull.Chem.Soc.Jpn.56. 2575-2577 (1991)

[文献書誌] K.Iwamoto: "Conformations and Structures of Tetra-O-alkyl-p-tert-butylcalix-[4]arenes.How is the Conformation of Calix[4]arene Immobilized?" J.Org.Chem.56. 4955-4962 (1991)

[文献書誌] S.Shinkai: "Molecular Recognition of Mono-and Di-saccharides by Phenylboronic Acids in Solvent Extraction and as a Monolayer." J.Chem.Soc.,Chem.Commun.1039-1041 (1991)

[文献書誌] T.Nagasaki: "Kinetic Studies of Calixarene-based Cyclic and Non-cyclic 'Super-uranophiles'." J.Chem.Soc.,Perkin Trans.2. 1325-1327 (1991)

[文献書誌] T.Arimura: "Calixarene-based Molecular Capsule." Tetrahedron Lett.32. 1715-1718 (1991)

[文献書誌] S.Shinkai: "Chiral Calix[4]arene." J.Chem.Soc.,Perkin Trans.1. 2429-2434 (1991)

[文献書誌] H.Shimizu: "Chromogenic Calix[4]arene." Chem.Lett.2147-2150 (1991)

[文献書誌] S.Shinkai: "pK_a Determination of Water-Soluble Calix[4]arenes." J.Chem.Soc.,Perkin Trans.2. 1883-1886 (1991)

[文献書誌] S.Aonuma,K.Komatsu,N.Maekawa,and K.Takeuchi: "Enhanced Polarization of Heptafulvene and Tropone by Annelation with Three Bicylclo[2.2.2]octene Frameworks" Chem.Lett.767-770 (1991)

[文献書誌] K.Komatsu,H.Kamo,R.Tsuji,H.Masuda,and K.Takeuchi: "4-Homoadamantyne:Generation,Chemical Trapping and Structure of Its Pt(O) Complex" J.Chem.Soc.,Chem.Commun.71-72 (1991)

[文献書誌] K.Komatsu,S.Aonuma,Y.Jinbu,R.Tsuji,C,Hirosawa,and K.Takeuchi: "Generation and Oligomerization of Bicyclo[2.2.2]octyne and Properties of Tris(bicyclo[2.2.2]octeno)benzene Obtained from the Linear Trimer" J.Org.Chem.56. 195-203 (1991)

[文献書誌] K.Ikai,K.Takeuchi,T.Kinoshita,K.Haga,K.Komatsu,and K.Okamoto: "Stereomutation of 7-Tropylionorbornane,2-Tropyliobicyclo[2.2.2-]-octane,and 2-Tropylioadamantane:Evidence for the Intermediacy of Heptafulvenes" J.Org.Chem.56. 1052-1058 (1991)

[文献書誌] K.Komatsu,H.Akamatsu,S.Aonuma,Y.Jinbu,N.Maekawa,and K.Takeuchi: "Formation,Properties,and Reactions of the 1,2:3,4:5,6-Tris(bicyclo[2.2.2]octeno)tropylium Ion" Tetrahedron. 47. 6951-6966 (1991)

[文献書誌] R.Tsuji,K.Komatsu,Y.Inoue,and K.Takeuchi: "1-Naphtyltropylium Ions Having Condensed Aromatic Rings at the 8-P-sition:Dependence of the Intramolecular Charge-Transfer Interaction upon Geometry of the Donor" J.Org.Chem.57. 636-641 (1992)

[文献書誌] A.Miyabo,K.Takeuchi,K.Komatsu,and T.Kitagawa: "Small Difference in Cation Stability in Contyolling the Formation of Hydrocarbon Salt or Covalent Hydrocarbon" Chem.Lett.(1992)

[文献書誌] A.Miyabo,T.Kitagawa,And K.Takeuchi: "Significance of Steric Effect in the Heterolysis of Carbon-Carbon σ Bond in Ionically Dissociative Hydrocarbons" Chem.Lett.(1992)

[文献書誌] T.Kitagawa,K.Takeuchi,K.Komatsu,and T.Kinoshita: "Syntheses and Properties of Hydrocarbon Salts and Ionically Dissociative Hydrocarbons" J.Synth.Org.Chem.Jpn.

[文献書誌] T.Kinoshita,H.Kimura,I.Nakajima,K.Takeuchi,and K.Okamoto: "Synthesis and Properties of 1,2,4-Tris(7H-dibenzo[c,g]-fluorenylidenemetyl)cyclopentadienide Ion"

[文献書誌] K.Komatsu,T.Nishinaga,N.Maekawa,Y.Kagayama,and K.Takeuchi: "Syntheses and Redox Behavior of the p-Phenylenebis-and Acetylenebis[tris(bicyclo[2.2.2]octeno)tropylium]Dications"

[文献書誌] A.Miyabo,K.Takeuchi,K.Komatsu,and T.Kitagawa: "Precise Control of Covalent and Ionic Bond Formation in Carbocation-Carbanion Combination Reaction"

[文献書誌] A.Miyabo,T.Kitagawa,and K.Takeuchi: "Heterolysis of Carbon-Carbon σ Bond in Hydrocarbons:Significance of Steric Effect"

1991 年度実績報告書

村田一郎大阪大学, 理学部, 教授 (90028077)