1991 年度実績報告書

分子認識場の設計

研究課題

研究課題/領域番号	03214106
研究機関	九州大学
研究代表者	新海征治九州大学, 工学部, 教授 (20038045)
研究分担者	中辻洋司大阪大学, 工学部, 助教授 (00127268) 戸田芙三夫愛媛大学, 工学部, 教授 (50036232) 古賀憲司東京大学, 薬学部, 教授 (10012600) 笠井暢民大阪大学, 工学部, 教授 (50028958) 稲津孝彦九州大学, 理学部, 教授 (60037207)
キーワード	カリックスアレ-ン / デオキシコ-ル酸 / クラウンエ-テル / シクロファン / シクロデキストリン / 分子認識 / 包接化合物 / 光学分割
研究概要	カリックスアレ-ンの自己組織化能を利用することにより,ゲスト分子の識別を分子集合体の変化で読み出す新しいセンシングシステムを開発した(新海)。デオキシコ-ル酸骨格を巧みに利用してC_3対称性を有する疎水空孔の開発に成功し,有機ゲストをピンセット的に取り込む試みを行なった(稲津)。金属を包接したカリックスアレ-ンの構造的特性をX線構造解析により明らかにし,そのカルボニル基の配向が錯化により著しく変化することを明らかにした(笠井)。ジフェニルメタン骨格を有するシクロファンを合成し,静電相互作用を利用した基質選択性を新しい方法論として例示した(古賀)。ヒドロキシホスト化学物を用いる結晶中の分子認識作用について研究し,画期的な光学分割能力を有することが明らかにされた(戸田)。カルボン酸側鎖を持つ18ークラウンー6誘導体を用いて人工液膜輸送を行ない,pH勾配を利用してNa^+とK^+の対向輸送が可能なことを初めて示した(中辻)。レゾルシノ-ル四量体を用いて糖類の識別を行う方法論を開発し,その認識の由来について一般化することに成功した(青山)。合成二分子膜を反応場とする系で高選択性の人工酵素系を組み立てることに成功し,その理論的評価を行なった(大久保)。ジペプチド固相系でCHーπ相互作用が存在することを立証し,その作用を利用して高度の分子識別が可能なことを示した(小倉)。コンホメ-ションが固定されたカリックスアレ-ン類縁体を合成し,そのゲスト認識能が著しく改良されることを明らかにした(西村)。アミノ化シクロデキストリンと無機アニオンの相互作用をNMRで検討し,硫酸イオンと特異的に錯体を形成することを明らかにした(松井)。以上の研究の結果,多種多様の分子認識場が開発され,分子認識化学の新しい方法論を例示することができた。

研究成果

(62件)

すべてその他

すべて文献書誌 (62件)

[文献書誌] H.Shimizu: "Chromogenic Calix[4]arene." Chem.Lett.2147-2150 (1991)
[文献書誌] S.Shinkai: "pK_a Determination of Water-Soluble Calix[4]arenes." J.Chem.Soc.,Perkin Trans.2. 1883-1886 (1991)
[文献書誌] T.Sugimoto: "Tercalicen und Quatercalicen" Angew.Chem.103. 454-456 (1991)
[文献書誌] T.Sugimoto: "Biradical Character of a Closed-Shell Heteroaromatic Quinone" J.Am.Chem.Soc.(1991)
[文献書誌] M.Miyake: "Anionic Cyclophanes as Hosts for Cationic Aromatic Guests" Tetrahedron Lett.32. 7295-7298 (1991)
[文献書誌] K.Manabe: "Chromatographic Separation of Aromatic Guest Compounds by a Gel-Immobilized Water-Soluble Cyclophane" Chem.Pharm.Bull.
[文献書誌] Y.Nakatsuji: "Transport of Calcium and Potassium Ions in Opposite Directions in a Liquid Membrane System" J.Inclusion Phenom.Mol.Recog.Chem.10. 379-386 (1991)
[文献書誌] M Okahara: "Bis(crown ether)s as Na^+-K^+ ATPase Model in a Liquid Membrane" J.Inclusion Phenom.Mol.Recog.Chem.
[文献書誌] K.Tsukagoshi: "Specific Complexation with Mono- and Disaccharides That Can be Detected by Circular Dichroism." J.Org.Chem.56. 4089-4091 (1991)
[文献書誌] T.Nagasaki: "Synthesis and Solvent Extraction Studies of Novel Calixarene-based Uranophiles Bearing Hydroxamate Groups." J.Chem.Soc.,Perkin Trans.2. 1063-1066 (1991)
[文献書誌] T.Nagasaki: "A New Calix[6]arene-based Uranophile with Phosphonate Groups as Ligands." Bull.Chem.Soc.Jpn.56. 2575-2577 (1991)
[文献書誌] K.Iwamoto: "Conformations and Structures of Tetra-O-alkyl-p-tert-butylcalix-[4]arenes.How is the Conformation of Calix[4]arene Immobilized?" J.Org.Chem.56. 4955-4962 (1991)
[文献書誌] S.Shinkai: "Molecular Recognition of Mono- and Di-saccharides by Phenylboronic Acids in Solvent Extranction and as a Monolayer." J.Chem.Soc.,Chem.Commun.1039-1041 (1991)
[文献書誌] T.Nagasaki: "Kinetic-Studies of Calixarene-based Cyclic and Non-cyclic 'Super-uranophiles'." J.Chem.Soc.,Perkin Trans.2. 1325-1327 (1991)
[文献書誌] T.Arimura: "Calixarene-based Molecular Capsule." Tetrahedron Lett.32. 1715-1718 (1991)
[文献書誌] S.Shinkai: "Chiral Calix[4]arene." J.Chem.Soc.,Perkin Trans.1. 2429-2434 (1991)
[文献書誌] S.Shinkai: "Ion Template Effects on the Conformation of Water-Soluble Calixarenes." J.Org.Chem.56. 295-300 (1991)
[文献書誌] T.Matsuda: "New Water-Soluble Calixarenes Bearing Chiral Substituents." J.Org.Chem.56. 301-306 (1991)
[文献書誌] S.Shinkai: "New Syntheses and Physical Properties of p-Alkylcalix[n]arenes." Bull.Chem.Soc.Jpn.64. 381-386 (1991)
[文献書誌] K.Iwamoto: "Syntheses of New Isomers from p-t-Butyl-calix[4]arene:Strategies for Regioselective Alkylation on the Lower Rim." Chem.Lett.473-476 (1991)
[文献書誌] A.Yamada: " ^1H and ^<13>C Nuclear Magnetic Resonance Relaxation-time Studies of Ionophoric Calixarene Esters." J.Chem.Soc.,Perkin Trans.2. 793-797 (1991)
[文献書誌] T.Arimura: "Formation of Molecular Complexes with Calixarenes as Detected by Induced Circular Dichroism." Bull.Chem.Soc.Jpn.64. 1896-1900 (1991)
[文献書誌] K.Iwamoto: "How is the 1,2-Alternate Conformer Formed in Tetra-O-alkylation of p-tert-Butyl-calix[4]arene?" J.Chem.Soc.,Perkin Trans.1. 1611-1613 (1991)
[文献書誌] K.Iwamoto: "Syntheses of All Possible Conformational Isomers of O-Alkyl-p-t-butylcalix[4]arenes." Tetrahedron. 47. 4325-4342 (1991)
[文献書誌] Takahiko Inazu: "Syntheses and Properties of Highly Symmetrical Cage Compounds;Pyridine Analogs of "Hexa-m-xylylenetetramine"." J.Am.Chem.Soc.,. 113. 1323-1331 (1991)
[文献書誌] Takahiko Inazu: "Synthesis of Triple- and Quadruple-layered[3.3]-Metacyclophanes." J.Org.Chem.
[文献書誌] Takahiko Inazu: "Synthesis and X-ray Structure Determination of anti-[3.3]Metacyclophane Quinhydrone Dimethyl Ether;anti-15,18-Dimethoxy[3](2,6)-p-benzoquinono[3]-metacyclophane-2,ll-dione." J.Org.Chem.
[文献書誌] Takahiko Inazu: "An Approach to the Synthesis of Tetraaza[3.3.3.3]-cyclophanes by Alkylation of N-Substituted Trifluoroacet-amide." Synthesis.
[文献書誌] Takahiko Inazu: "A Conformational Study of [3.3]Metacyclophane through Variable Temperature ^1H NMR Method and Optical Rotation." J.Org.Chem.
[文献書誌] M.Fujita: "Spectroscopic Observation of Self-Assembly of a Macrocyclic Tetranuclear Complex Composed of Pt^<2+> and 4,4'-Bipyridine" Chem.Lett.1031-1032 (1991)
[文献書誌] M.Fujita: "Macrocyclic Polynuclear Complexes [(en)Pd(4,4')]_4 (NO_3)_8 (M=Pd or Pt) as "Inorganic Cyclophane."Their Ability for Molecular Recognition" Tetrahedron Lett.32. 5589-5592 (1991)
[文献書誌] K.Ogura: "Is CH-π Interaction between Methyl and Phenyl Groups Possible?Streoselective Molecular Recognition of Methyl Sulfoxides by Solid (R)-Phenylglycyl-(R)-phehygly"
[文献書誌] M.Kitamura: "Precipitation Behavior of 1,1-Di(p-hydroxyphenyl)-cyclohexane Clathrate Crystals from Acetone Solutions Containing d-Limonene" J.Inclu.Phenom.and Mol.Recog.In Chem.10. 305-312 (1991)
[文献書誌] D.R.Bond: "Complexation with Diol Host Compounds.Part 6.Structure and Dynamics of Enclathration by 1,1,6,6-Tetraphenyl-hexa-2,4-diyne-1.6-diol" J.Solid State Chem.92. 68-79 (1991)
[文献書誌] F.Toda,: "A New Preparative Method for Optically Active Diaryl-carbinols" Tetrahedron.Assym.2. 873-874 (1991)
[文献書誌] S.A.Bourne: "Complexation with Hydroxy Host Compounds.Part.4.Structures and Thermal Stabilities of Inclusion Compounds with Dioxane as the Guest" J.Chem.Soc.Perkin Trans.2. 1707-1713 (1991)
[文献書誌] F.Toda: "Efficient Resolution of Secondary Alcohols,Cyanohydrins,and Glycerol Acetals by Complexation with the Host Derived form Tartaric Acid" Tetrahedron Assym.2. 983-986 (1991)
[文献書誌] F.Toda: "Optical Resolution of Amino Acid and Hydroxycarboxylic Acid Esters by Complexation with Optically Active Host Compounds:a Crystallographic Result" J.Chem.Soc.Perkin Trans 2. 1971-1975 (1991)
[文献書誌] S.Sakaki: "Chiral Recognition of Ferrocytochrome c(II) in Electron-transfer Reactions with Cobalt(III) Complexes" J.Chem.Soc.,Dalton Trans.1143-1148 (1991)
[文献書誌] K.Ohkubo: "Enantioselective Hydrolysis of N-Acyl Amino Acid Esters by Tripeptide-type L-Histidine Derivative in a Bilayer Vesicular System" Chem.Lett.1723-1726 (1991)
[文献書誌] T.Sagawa: "Stereoselective Dioxygenolysis of a Tryptophan Derivative Catalyzed by a Manganese Porphyrin Bound to Bovine Serum Albumin" Chem.Lett.2083-2086 (1991)
[文献書誌] K.Ohkubo: "Enantioselective Photoreduction of Tris(acetylacetonato)cobalt(III) by 1,4-Dihydropyridine Derivatives in the Presence of Molecular Aggregates" J.Chem.Soc.,Perkin Trans.2. 1833-1838 (1991)
[文献書誌] K.Ohkubo: "Catalytic and Stereoselective Activities of Manganese Achiral and Chiral Porphyrins in Dioxygenation of Tryptophan Derivatives" Inorg.Chem.(1992)
[文献書誌] K.Yamashita: "Micellar Accelerated Reduction of Ethylenediaminetetraacetatocobaltate(III) by 1-Benzyl-1,4-dihydronicotinamide" Bull.Chem.Soc.Jpn.64. 410-415 (1991)
[文献書誌] K.Yamashita: "Micellar Promoted Photoreduction of Ethylenediaminetetraacetatocobaltate(III) by 1-Benzyl-1,4-dihydronicotinamide" J.Chem.Soc.,Perkin Trans.2. 367-372 (1991)
[文献書誌] K.Yamashita: "Micellar Effects on Photoinduced Electron Transfer from 1,4-Dihydronicotinamide Derivatives to Tris(acetylacetonato)cobalto(III)" J.Phys.Chem.95. 5204-5210 (1991)
[文献書誌] K.Yamashita: "Photoinduced Electron and Hydrogen-Transfer Reaction in Micellar-Promoted Reaction of vic-Styrene Dibromide with 1-Benzyl-1,4-dihydronicotinamide" Chem.Lett.1637-1640 (1991)
[文献書誌] S.Sakaki: "New Reduction Catalysis of Metalloporphyrins.Catalytic Reduction of Nitrobenzene to Aniline with Tetraphenylporphyrinato-iron(III) Chloride-NaBH_4 System" Chem.Lett.195-198 (1991)
[文献書誌] Y.Kikuchi: "Molecular Recognition and Stereoselectivity:Geometrical Requirements for the Multiple Hydrogen-Bonding interaction of Diols with a Multidentate Polyhydroxyl Macto" J.Am.Chem.Soc.113. 1349-1354 (1991)
[文献書誌] Y.Aoyama: "Molecular Recognition of Qunones:Two-Point Hydrogen-Bonding Strategy for the Construction of Face-to-Face Porphyrin-Quinone Architecture" J.Am.Chem.Soc.113. 6233-6240 (1991)
[文献書誌] T.Motomura: "Transition-State Stabilization via Dynamic Molecular Recognition:A Concerted Acid-Base Bifunctional Catalysis in Ester Hydrolysis" Tetrahedron Lett.32. 4757-4760 (1991)
[文献書誌] T.Motomura: "Accumulation OF Hydrogen-Bonding and Electostatic Binding Sites:Satbilization of Salts in Hydroxylic Media via Intramolecular Hydrogen Bonding" J.Org.Chem.56. 7224-7228 (1991)
[文献書誌] 松井佳久: "化学修飾シクロデキストリンによる超分子の構築ー無機アニオン認識ホストの分子設計ー" 化学工業. 42. 272-277 (1991)
[文献書誌] Y.Matsui: "Interactions between modified cyclodextrins and the iodide ion in organic media."
[文献書誌] Y.Matsui: "Specific interactions between aminated cyclodextrins and the sulfate ion in an acidic aqueous solution."
[文献書誌] J.Nishimura: "Intramolecular [2+2] Photocycloaddition 10.Conformationally Stable-syn-[2,2]Metacyclophanes" J.Am.Chem.Soc.113. 3485-3489 (1991)
[文献書誌] Y.Okada: "Synthesis and Structural Analysis of Dimethoxy-[2,n]metacyclophanes" Chem.Lett.1345-1348 (1991)
[文献書誌] S.Inokuma: "Synthesis of Three-Bridged Cyclophanes via Meta- and Ortho-Cyclophane" Tetrahedron Lett.32. 2367-2370 (1991)
[文献書誌] F.Toda: "Inclusion Compounds Vol.4" oxford University Press, 511 (1991)
[文献書誌] S.Shinkai: "Calixarenes:A Versatile Class of Macrocyclic Compounds" Kluwer Academic Publishers, 26 (1991)
[文献書誌] K.Yoshinaga: "Biomedical Applications of Poly(ethylene glycol) Chemistry 2章「PEGーmodified Protein Hybrid Catalyst」" Plenum Publishing Cooperation, (1992)
[文献書誌] J.Nishimura: "Chemistry of Three-Dimensional Polycyclic Molecules" Verlag Chemie,

1991 年度 実績報告書

分子認識場の設計

研究代表者

新海 征治 九州大学, 工学部, 教授 (20038045)

研究成果

[文献書誌] H.Shimizu: "Chromogenic Calix[4]arene." Chem.Lett.2147-2150 (1991)

[文献書誌] S.Shinkai: "pK_a Determination of Water-Soluble Calix[4]arenes." J.Chem.Soc.,Perkin Trans.2. 1883-1886 (1991)

[文献書誌] T.Sugimoto: "Tercalicen und Quatercalicen" Angew.Chem.103. 454-456 (1991)

[文献書誌] T.Sugimoto: "Biradical Character of a Closed-Shell Heteroaromatic Quinone" J.Am.Chem.Soc.(1991)

[文献書誌] M.Miyake: "Anionic Cyclophanes as Hosts for Cationic Aromatic Guests" Tetrahedron Lett.32. 7295-7298 (1991)

[文献書誌] K.Manabe: "Chromatographic Separation of Aromatic Guest Compounds by a Gel-Immobilized Water-Soluble Cyclophane" Chem.Pharm.Bull.

[文献書誌] Y.Nakatsuji: "Transport of Calcium and Potassium Ions in Opposite Directions in a Liquid Membrane System" J.Inclusion Phenom.Mol.Recog.Chem.10. 379-386 (1991)

[文献書誌] M Okahara: "Bis(crown ether)s as Na^+-K^+ ATPase Model in a Liquid Membrane" J.Inclusion Phenom.Mol.Recog.Chem.

[文献書誌] K.Tsukagoshi: "Specific Complexation with Mono- and Disaccharides That Can be Detected by Circular Dichroism." J.Org.Chem.56. 4089-4091 (1991)

[文献書誌] T.Nagasaki: "Synthesis and Solvent Extraction Studies of Novel Calixarene-based Uranophiles Bearing Hydroxamate Groups." J.Chem.Soc.,Perkin Trans.2. 1063-1066 (1991)

[文献書誌] T.Nagasaki: "A New Calix[6]arene-based Uranophile with Phosphonate Groups as Ligands." Bull.Chem.Soc.Jpn.56. 2575-2577 (1991)

[文献書誌] K.Iwamoto: "Conformations and Structures of Tetra-O-alkyl-p-tert-butylcalix-[4]arenes.How is the Conformation of Calix[4]arene Immobilized?" J.Org.Chem.56. 4955-4962 (1991)

[文献書誌] S.Shinkai: "Molecular Recognition of Mono- and Di-saccharides by Phenylboronic Acids in Solvent Extranction and as a Monolayer." J.Chem.Soc.,Chem.Commun.1039-1041 (1991)

[文献書誌] T.Nagasaki: "Kinetic-Studies of Calixarene-based Cyclic and Non-cyclic 'Super-uranophiles'." J.Chem.Soc.,Perkin Trans.2. 1325-1327 (1991)

[文献書誌] T.Arimura: "Calixarene-based Molecular Capsule." Tetrahedron Lett.32. 1715-1718 (1991)

[文献書誌] S.Shinkai: "Chiral Calix[4]arene." J.Chem.Soc.,Perkin Trans.1. 2429-2434 (1991)

[文献書誌] S.Shinkai: "Ion Template Effects on the Conformation of Water-Soluble Calixarenes." J.Org.Chem.56. 295-300 (1991)

[文献書誌] T.Matsuda: "New Water-Soluble Calixarenes Bearing Chiral Substituents." J.Org.Chem.56. 301-306 (1991)

[文献書誌] S.Shinkai: "New Syntheses and Physical Properties of p-Alkylcalix[n]arenes." Bull.Chem.Soc.Jpn.64. 381-386 (1991)

[文献書誌] K.Iwamoto: "Syntheses of New Isomers from p-t-Butyl-calix[4]arene:Strategies for Regioselective Alkylation on the Lower Rim." Chem.Lett.473-476 (1991)

[文献書誌] A.Yamada: " ^1H and ^<13>C Nuclear Magnetic Resonance Relaxation-time Studies of Ionophoric Calixarene Esters." J.Chem.Soc.,Perkin Trans.2. 793-797 (1991)

[文献書誌] T.Arimura: "Formation of Molecular Complexes with Calixarenes as Detected by Induced Circular Dichroism." Bull.Chem.Soc.Jpn.64. 1896-1900 (1991)

[文献書誌] K.Iwamoto: "How is the 1,2-Alternate Conformer Formed in Tetra-O-alkylation of p-tert-Butyl-calix[4]arene?" J.Chem.Soc.,Perkin Trans.1. 1611-1613 (1991)

[文献書誌] K.Iwamoto: "Syntheses of All Possible Conformational Isomers of O-Alkyl-p-t-butylcalix[4]arenes." Tetrahedron. 47. 4325-4342 (1991)

[文献書誌] Takahiko Inazu: "Syntheses and Properties of Highly Symmetrical Cage Compounds;Pyridine Analogs of "Hexa-m-xylylenetetramine"." J.Am.Chem.Soc.,. 113. 1323-1331 (1991)

[文献書誌] Takahiko Inazu: "Synthesis of Triple- and Quadruple-layered[3.3]-Metacyclophanes." J.Org.Chem.

[文献書誌] Takahiko Inazu: "Synthesis and X-ray Structure Determination of anti-[3.3]Metacyclophane Quinhydrone Dimethyl Ether;anti-15,18-Dimethoxy[3](2,6)-p-benzoquinono[3]-metacyclophane-2,ll-dione." J.Org.Chem.

[文献書誌] Takahiko Inazu: "An Approach to the Synthesis of Tetraaza[3.3.3.3]-cyclophanes by Alkylation of N-Substituted Trifluoroacet-amide." Synthesis.

[文献書誌] Takahiko Inazu: "A Conformational Study of [3.3]Metacyclophane through Variable Temperature ^1H NMR Method and Optical Rotation." J.Org.Chem.

[文献書誌] M.Fujita: "Spectroscopic Observation of Self-Assembly of a Macrocyclic Tetranuclear Complex Composed of Pt^<2+> and 4,4'-Bipyridine" Chem.Lett.1031-1032 (1991)

[文献書誌] M.Fujita: "Macrocyclic Polynuclear Complexes [(en)Pd(4,4')]_4 (NO_3)_8 (M=Pd or Pt) as "Inorganic Cyclophane."Their Ability for Molecular Recognition" Tetrahedron Lett.32. 5589-5592 (1991)

[文献書誌] K.Ogura: "Is CH-π Interaction between Methyl and Phenyl Groups Possible?Streoselective Molecular Recognition of Methyl Sulfoxides by Solid (R)-Phenylglycyl-(R)-phehygly"

[文献書誌] M.Kitamura: "Precipitation Behavior of 1,1-Di(p-hydroxyphenyl)-cyclohexane Clathrate Crystals from Acetone Solutions Containing d-Limonene" J.Inclu.Phenom.and Mol.Recog.In Chem.10. 305-312 (1991)

[文献書誌] D.R.Bond: "Complexation with Diol Host Compounds.Part 6.Structure and Dynamics of Enclathration by 1,1,6,6-Tetraphenyl-hexa-2,4-diyne-1.6-diol" J.Solid State Chem.92. 68-79 (1991)

[文献書誌] F.Toda,: "A New Preparative Method for Optically Active Diaryl-carbinols" Tetrahedron.Assym.2. 873-874 (1991)

[文献書誌] S.A.Bourne: "Complexation with Hydroxy Host Compounds.Part.4.Structures and Thermal Stabilities of Inclusion Compounds with Dioxane as the Guest" J.Chem.Soc.Perkin Trans.2. 1707-1713 (1991)

[文献書誌] F.Toda: "Efficient Resolution of Secondary Alcohols,Cyanohydrins,and Glycerol Acetals by Complexation with the Host Derived form Tartaric Acid" Tetrahedron Assym.2. 983-986 (1991)

[文献書誌] F.Toda: "Optical Resolution of Amino Acid and Hydroxycarboxylic Acid Esters by Complexation with Optically Active Host Compounds:a Crystallographic Result" J.Chem.Soc.Perkin Trans 2. 1971-1975 (1991)

[文献書誌] S.Sakaki: "Chiral Recognition of Ferrocytochrome c(II) in Electron-transfer Reactions with Cobalt(III) Complexes" J.Chem.Soc.,Dalton Trans.1143-1148 (1991)

[文献書誌] K.Ohkubo: "Enantioselective Hydrolysis of N-Acyl Amino Acid Esters by Tripeptide-type L-Histidine Derivative in a Bilayer Vesicular System" Chem.Lett.1723-1726 (1991)

[文献書誌] T.Sagawa: "Stereoselective Dioxygenolysis of a Tryptophan Derivative Catalyzed by a Manganese Porphyrin Bound to Bovine Serum Albumin" Chem.Lett.2083-2086 (1991)

[文献書誌] K.Ohkubo: "Enantioselective Photoreduction of Tris(acetylacetonato)cobalt(III) by 1,4-Dihydropyridine Derivatives in the Presence of Molecular Aggregates" J.Chem.Soc.,Perkin Trans.2. 1833-1838 (1991)

[文献書誌] K.Ohkubo: "Catalytic and Stereoselective Activities of Manganese Achiral and Chiral Porphyrins in Dioxygenation of Tryptophan Derivatives" Inorg.Chem.(1992)

[文献書誌] K.Yamashita: "Micellar Accelerated Reduction of Ethylenediaminetetraacetatocobaltate(III) by 1-Benzyl-1,4-dihydronicotinamide" Bull.Chem.Soc.Jpn.64. 410-415 (1991)

[文献書誌] K.Yamashita: "Micellar Promoted Photoreduction of Ethylenediaminetetraacetatocobaltate(III) by 1-Benzyl-1,4-dihydronicotinamide" J.Chem.Soc.,Perkin Trans.2. 367-372 (1991)

[文献書誌] K.Yamashita: "Micellar Effects on Photoinduced Electron Transfer from 1,4-Dihydronicotinamide Derivatives to Tris(acetylacetonato)cobalto(III)" J.Phys.Chem.95. 5204-5210 (1991)

[文献書誌] K.Yamashita: "Photoinduced Electron and Hydrogen-Transfer Reaction in Micellar-Promoted Reaction of vic-Styrene Dibromide with 1-Benzyl-1,4-dihydronicotinamide" Chem.Lett.1637-1640 (1991)

[文献書誌] S.Sakaki: "New Reduction Catalysis of Metalloporphyrins.Catalytic Reduction of Nitrobenzene to Aniline with Tetraphenylporphyrinato-iron(III) Chloride-NaBH_4 System" Chem.Lett.195-198 (1991)

[文献書誌] Y.Kikuchi: "Molecular Recognition and Stereoselectivity:Geometrical Requirements for the Multiple Hydrogen-Bonding interaction of Diols with a Multidentate Polyhydroxyl Macto" J.Am.Chem.Soc.113. 1349-1354 (1991)

[文献書誌] Y.Aoyama: "Molecular Recognition of Qunones:Two-Point Hydrogen-Bonding Strategy for the Construction of Face-to-Face Porphyrin-Quinone Architecture" J.Am.Chem.Soc.113. 6233-6240 (1991)

[文献書誌] T.Motomura: "Transition-State Stabilization via Dynamic Molecular Recognition:A Concerted Acid-Base Bifunctional Catalysis in Ester Hydrolysis" Tetrahedron Lett.32. 4757-4760 (1991)

[文献書誌] T.Motomura: "Accumulation OF Hydrogen-Bonding and Electostatic Binding Sites:Satbilization of Salts in Hydroxylic Media via Intramolecular Hydrogen Bonding" J.Org.Chem.56. 7224-7228 (1991)

[文献書誌] 松井 佳久: "化学修飾シクロデキストリンによる超分子の構築ー無機アニオン認識ホストの分子設計ー" 化学工業. 42. 272-277 (1991)

[文献書誌] Y.Matsui: "Interactions between modified cyclodextrins and the iodide ion in organic media."

[文献書誌] Y.Matsui: "Specific interactions between aminated cyclodextrins and the sulfate ion in an acidic aqueous solution."

[文献書誌] J.Nishimura: "Intramolecular [2+2] Photocycloaddition 10.Conformationally Stable-syn-[2,2]Metacyclophanes" J.Am.Chem.Soc.113. 3485-3489 (1991)

[文献書誌] Y.Okada: "Synthesis and Structural Analysis of Dimethoxy-[2,n]metacyclophanes" Chem.Lett.1345-1348 (1991)

[文献書誌] S.Inokuma: "Synthesis of Three-Bridged Cyclophanes via Meta- and Ortho-Cyclophane" Tetrahedron Lett.32. 2367-2370 (1991)

[文献書誌] F.Toda: "Inclusion Compounds Vol.4" oxford University Press, 511 (1991)

[文献書誌] S.Shinkai: "Calixarenes:A Versatile Class of Macrocyclic Compounds" Kluwer Academic Publishers, 26 (1991)

[文献書誌] K.Yoshinaga: "Biomedical Applications of Poly(ethylene glycol) Chemistry 2章「PEGーmodified Protein Hybrid Catalyst」" Plenum Publishing Cooperation, (1992)

[文献書誌] J.Nishimura: "Chemistry of Three-Dimensional Polycyclic Molecules" Verlag Chemie,

1991 年度実績報告書

新海征治九州大学, 工学部, 教授 (20038045)

[文献書誌] 松井佳久: "化学修飾シクロデキストリンによる超分子の構築ー無機アニオン認識ホストの分子設計ー" 化学工業. 42. 272-277 (1991)