1992 年度実績報告書

界面電荷移動反応のダイナミックスとその分析化学的展開

研究課題

研究課題/領域番号	03303004
研究機関	福井県立大学
研究代表者	千田貢福井県立大学, 生物資源学部, 教授 (90026419)
研究分担者	仁木克己横浜国立大学, 工学部, 教授 (00017899) 岡崎敏愛媛大学, 理学部, 助教授 (40025383) 小山昇東京農工大学, 工学部, 教授 (40134845) 池田篤治京都大学, 農学部, 教授 (40026422) 木原壯林京都大学, 化学研究所, 助教授 (60161543)
キーワード	液・液界面電荷移動 / 分子修飾電極 / ウルトラマイクロ電極 / 分光電気化学 / 膜イオン透過 / 導電性高分子 / 高速電極反応 / 紫外可視反射分光法
研究概要	研究分担を4つに大別して研究を進めた。(1)液液界面電荷(イオン及び電子)移動反応(千田,木原,武田,斉藤,藤原)。イオン移動ボルタンメトリーの基礎と分析化学への応用,イオンとイオノフオアの相互作用の動力学,液膜及び二分子膜における一オン透過,ヘテロポリ酸の溶媒和と分子構造,高濃度電解質溶液における分子空間効果について多くの知見がえられた。(2)分子修飾電極反応(池田,梅沢,中嶋,後藤,小山,伊豆津)。酵素機能電極におけるメディエータ電子移動と直接電子移動の基礎的研究と分析化学への応用,生体イオンチャンネルにおける分子認識と情報変換機構の分析化学的展開,単分子膜及び導電性高分子膜修飾における界面電荷移動のダイナミックスについて多くの知見がえられた。(3)ウルトラマイクロ電極(岡崎,松村,池田,青木)。ウルトラマイクロ電極ボルタンメトリーの一般理論式の確立とその高速電極反応速度測定への応用に関する理論と実験法,金属錯体溶液内電子構造とレドックス系ダイナミックス機構について多くの知見がえられた。(4)分光電気化学測定法(仁木,山下,高村,渡辺,市村)。分光ボルタンメトリー,紫外可視反射分光法による電極界面レドックス挙動解析法,電極鏡面反射率測定による生体関連物質の界面挙動解析法,レーザ電気化学実験法の基礎,気液界面におけるイオンの直接観察法について多くの知見がえられた。また平成5年1月29,30日に開いた全員参加の成果発表会においては,これらの研究成果を総合して界面電荷移動反応のダイナミックスとその分析化学的展開に関する理論と実験法の現状と将来展望について意見を交換し、今後の研究の方向について多くの示唆をうることができた。

研究成果

(29件)

すべてその他

すべて文献書誌 (29件)

[文献書誌] 千田貢: "分子機能電極研究の現状と将来" 電気化学及び工業物理化. 61. 50-52 (1993)
[文献書誌] Yukitaka Yamamoto,Mitsugi Senda: "Amperometric ammonium ion sensor and its application to biosensors" Sensors and Acfuators,B. (1993)
[文献書誌] 木原壮林,松井正和: "液液,液膜界面反応解析法としての界面電荷移動ボルタンメトリー" 表面. 30. 367-378 (1992)
[文献書誌] Yasuyuki Takeda,Hiroya sato,Sin Sato: "Solvent efects on extraction of potassium picrate with fengo-18-crown-6,A new eguation for the defermination of ionpain formation of crown ether-metal salt complore in water" J.Solntion Chem. 21. 1069-1080 (1992)
[文献書誌] Toshiyuki Osakai,Atsuyoshi Saito: "Electrochemical Formation of 11-Molyfdophosp hate Cinion at the Nitrobenjenel Water Interface and is Applicability to the Determination o Drthophosp hate Ions" Bull.Chem.Soi.Japan. 64. 1313-1317 (1991)
[文献書誌] Toshiyuki Osakai,Atsuyoshi Saito: "Voltammetric Study of the Transfer of Dawson-thpe heteropolyonions across the nitrobenjene 1 water interface" J.Electroanal.Chem.332. 169-182 (1992)
[文献書誌] Shizno Fujiwara,Yuko Nisimoto: "Magnetic Field Effect on Freejing of agneous sidium Cheoride Solution n the Presence of Oxygen." Anal.Sci.8. 873-874 (1992)
[文献書誌] Shizno fujiwara,Yuko Nishimoto: "Magnetin Field Differentiation of Mantimain Tosomers of Amino and in Agreons Sodium Chloride Solntior" Anal.Sci.8. 875-876 (1992)
[文献書誌] T.Ikeda,S.Miyaoka,F.Matsushita,D.Kobayashi,M.Senda: "Direct Bioelectroanclysis at Metal and Carbon Electrodes Modified with GADH or ADH from Bacterial Membranes." Chem.Letters. 847-850 (1992)
[文献書誌] N.Sugo,M.Sugawara,M.Uto,Y.Umezawa: "Na^+/D-glncore Co transport Based Bilayer hipid Membrane Sensor for D-glncore" Anal.Chem. (1993)
[文献書誌] K.Odashima,M.Kotato,M.Sugawara,Y.Umezawa: "Voltammetric Study on a Condensed Monolayer of Long Cilkyl Cyclodextion Derivatives as a Channel Mimetic Seusiny Membranes" Anal.Chem. (1993)
[文献書誌] N.Nakashima,S.Wake,T.Nishimoto,M.Kunitake,O.Manabe: "Phase-fransition dependent electron to amter of electrodes coated win multi-bilayer films of a ferrocane-carrying synthefic bipid characterized by cyclin Voltammetry and by Chrono conlometry" J.Electroanal.Chem.333. 345-351 (1992)
[文献書誌] Y.Esaka,K.Kano,M.Sukeguchi,M.goto: "Electrochemical Detection of Pyrrologuinolin Quinone Conpled with Its Catalytic Function by Lighid Chromato graphy" Anal.Sci.9. (1993)
[文献書誌] O.Hatozaki,T.Ohsaka,N.Oyama: "Change-Transport Propenties of Polymer Complex Films Compozed of Poly (alkylene ciologer) and Poly(P-Styrenernefonate)" J.Phys.Chem.96. 10492-10497 (1992)
[文献書誌] Kosuge Izutsu,Toshio Nakamura,Yutaka Aoki: "Lighid jimcfin potential between different Soluents.A jimcfin with an alkali methl salt as electro by K" J.Electronal.Chem.334. 213-222 (1992)
[文献書誌] Kosuke Izutsu,Mitsuo Muramatsu,Yutaka Aoki: "Lihgid jimcfin Potential between defferent soluents.A jimcfin with different electrolytes on the two sides" J Electroancl.Chem.336. 125-132 (1992)
[文献書誌] 岡崎敏,田中和子: "微小電極を用いる電気化学測定法" 電気化学及び工業物理化学. 60. 771-776 (1992)
[文献書誌] Z,Zhong,T.Matsumura,Inoue,A.Ichimura: "Soluent Effect on the Redox Potential of Fliro cone Derivatives Using an Ultramicroelectrode" Anal.Sci.8. 877-879 (1992)
[文献書誌] K.Aoki,T.Aramoto,Y.Hoshino: "Photographie Measurements of propagation of the conducting gone in polyani line films during electrochemical switching" J.Electroanal.Chem.340. 127-135 (1992)
[文献書誌] Koichi Aoki: "Theory of Ultramicroelechodes,A Review" Electroanalysis. (1993)
[文献書誌] H.X.Wang,T.Sagara,H.Sato,K.Niki: "Electroreflectance study of redox reaction of heptylviolager at a silver electrode" J.Electroanal.Chem.331. 925-943 (1992)
[文献書誌] T.Sagara,J.Iizuka,K.Niki: "Electroreflectance study of redox reaction of metaleneblne aclsorbed on a pyrolytie hraphite electrode." Langmuir. 8. 1018-1025 (1992)
[文献書誌] Y.Harima.M.Miyatake,K.Yamaohita: "Synergism in Photocurrint induced by Simultancow Illumination of Poybyrin Solids with Vissible and Near-Infrarecl Lights" Chem.Phys.Lett.200. 263-266 (1992)
[文献書誌] Kiyoko Takamura,Fumiyo Kusu: "A dsorption Studies of Some Inongamic and Organic Splcies at gold Electrode/Solntion Interface by Specular Refleation and Magneto-optical Rotation Methods" Anal Sci.7. 1431-1436 (1991)
[文献書誌] Takashi Shibahara,Akio Ixhimura,etal.: "Synthesis and Electrochemistry of Inconylate Cnbane Type Clusfers with M_3Se_4 cores (M=Mo,W)" Tnorganic Chemistry. 31. 640-647 (1992)
[文献書誌] Khin Nwe Soe,Akio Ichimura,etal.: "Electrochemistry of Anylimido Rhenian (V) Dithiocarfamato Comgeleres ({Re(NR)(S_2CNR_2)_2}_2]O in N_1N-dimethylformamide" Inorganic Chimica Acta. (1993)
[文献書誌] Noboru Oyama,Takeo Osake: "Molecnlar Design of Slectrode Surface Voltammetui Diaghosis of Charge Transport of Polyhce Coated Electrodes" John Wiley Dul.(New York), 70 (1992)
[文献書誌] Shigero Ikeda,Iwao Watanabe,Takafumi Miyanaga: "Structure of Metal compley in Solution by EXAFS and XANES methods,in"Structure and Dynamics in Solution Studies in physical and Theoretical Chemistry 79,sd Dhtaki,Yamatere" Elsevier Sci.Publisheis,(Amsfer Qam), 39-56 (1992)
[文献書誌] Iwao Watanabe: "Electronic STates of Ions and Molecules in Solution Studies by Photoelction Emission Spetruscopy,in"Sfuructure and Dynamics in Solution,Studies in Physical and Theoretical.Chemistry 79,ed Ohtaki Yamatera" Elsevier Sci.Publisher(Amsfer Qam), 320-335 (1992)

1992 年度 実績報告書

界面電荷移動反応のダイナミックスとその分析化学的展開

研究代表者

千田 貢 福井県立大学, 生物資源学部, 教授 (90026419)

研究成果

[文献書誌] 千田 貢: "分子機能電極研究の現状と将来" 電気化学及び工業物理化. 61. 50-52 (1993)

[文献書誌] Yukitaka Yamamoto,Mitsugi Senda: "Amperometric ammonium ion sensor and its application to biosensors" Sensors and Acfuators,B. (1993)

[文献書誌] 木原 壮林,松井 正和: "液液,液膜界面反応解析法としての界面電荷移動ボルタンメトリー" 表面. 30. 367-378 (1992)

[文献書誌] Yasuyuki Takeda,Hiroya sato,Sin Sato: "Solvent efects on extraction of potassium picrate with fengo-18-crown-6,A new eguation for the defermination of ionpain formation of crown ether-metal salt complore in water" J.Solntion Chem. 21. 1069-1080 (1992)

[文献書誌] Toshiyuki Osakai,Atsuyoshi Saito: "Electrochemical Formation of 11-Molyfdophosp hate Cinion at the Nitrobenjenel Water Interface and is Applicability to the Determination o Drthophosp hate Ions" Bull.Chem.Soi.Japan. 64. 1313-1317 (1991)

[文献書誌] Toshiyuki Osakai,Atsuyoshi Saito: "Voltammetric Study of the Transfer of Dawson-thpe heteropolyonions across the nitrobenjene 1 water interface" J.Electroanal.Chem.332. 169-182 (1992)

[文献書誌] Shizno Fujiwara,Yuko Nisimoto: "Magnetic Field Effect on Freejing of agneous sidium Cheoride Solution n the Presence of Oxygen." Anal.Sci.8. 873-874 (1992)

[文献書誌] Shizno fujiwara,Yuko Nishimoto: "Magnetin Field Differentiation of Mantimain Tosomers of Amino and in Agreons Sodium Chloride Solntior" Anal.Sci.8. 875-876 (1992)

[文献書誌] T.Ikeda,S.Miyaoka,F.Matsushita,D.Kobayashi,M.Senda: "Direct Bioelectroanclysis at Metal and Carbon Electrodes Modified with GADH or ADH from Bacterial Membranes." Chem.Letters. 847-850 (1992)

[文献書誌] N.Sugo,M.Sugawara,M.Uto,Y.Umezawa: "Na^+/D-glncore Co transport Based Bilayer hipid Membrane Sensor for D-glncore" Anal.Chem. (1993)

[文献書誌] K.Odashima,M.Kotato,M.Sugawara,Y.Umezawa: "Voltammetric Study on a Condensed Monolayer of Long Cilkyl Cyclodextion Derivatives as a Channel Mimetic Seusiny Membranes" Anal.Chem. (1993)

[文献書誌] N.Nakashima,S.Wake,T.Nishimoto,M.Kunitake,O.Manabe: "Phase-fransition dependent electron to amter of electrodes coated win multi-bilayer films of a ferrocane-carrying synthefic bipid characterized by cyclin Voltammetry and by Chrono conlometry" J.Electroanal.Chem.333. 345-351 (1992)

[文献書誌] Y.Esaka,K.Kano,M.Sukeguchi,M.goto: "Electrochemical Detection of Pyrrologuinolin Quinone Conpled with Its Catalytic Function by Lighid Chromato graphy" Anal.Sci.9. (1993)

[文献書誌] O.Hatozaki,T.Ohsaka,N.Oyama: "Change-Transport Propenties of Polymer Complex Films Compozed of Poly (alkylene ciologer) and Poly(P-Styrenernefonate)" J.Phys.Chem.96. 10492-10497 (1992)

[文献書誌] Kosuge Izutsu,Toshio Nakamura,Yutaka Aoki: "Lighid jimcfin potential between different Soluents.A jimcfin with an alkali methl salt as electro by K" J.Electronal.Chem.334. 213-222 (1992)

[文献書誌] Kosuke Izutsu,Mitsuo Muramatsu,Yutaka Aoki: "Lihgid jimcfin Potential between defferent soluents.A jimcfin with different electrolytes on the two sides" J Electroancl.Chem.336. 125-132 (1992)

[文献書誌] 岡崎 敏,田中 和子: "微小電極を用いる電気化学測定法" 電気化学及び工業物理化学. 60. 771-776 (1992)

[文献書誌] Z,Zhong,T.Matsumura,Inoue,A.Ichimura: "Soluent Effect on the Redox Potential of Fliro cone Derivatives Using an Ultramicroelectrode" Anal.Sci.8. 877-879 (1992)

[文献書誌] K.Aoki,T.Aramoto,Y.Hoshino: "Photographie Measurements of propagation of the conducting gone in polyani line films during electrochemical switching" J.Electroanal.Chem.340. 127-135 (1992)

[文献書誌] Koichi Aoki: "Theory of Ultramicroelechodes,A Review" Electroanalysis. (1993)

[文献書誌] H.X.Wang,T.Sagara,H.Sato,K.Niki: "Electroreflectance study of redox reaction of heptylviolager at a silver electrode" J.Electroanal.Chem.331. 925-943 (1992)

[文献書誌] T.Sagara,J.Iizuka,K.Niki: "Electroreflectance study of redox reaction of metaleneblne aclsorbed on a pyrolytie hraphite electrode." Langmuir. 8. 1018-1025 (1992)

[文献書誌] Y.Harima.M.Miyatake,K.Yamaohita: "Synergism in Photocurrint induced by Simultancow Illumination of Poybyrin Solids with Vissible and Near-Infrarecl Lights" Chem.Phys.Lett.200. 263-266 (1992)

[文献書誌] Kiyoko Takamura,Fumiyo Kusu: "A dsorption Studies of Some Inongamic and Organic Splcies at gold Electrode/Solntion Interface by Specular Refleation and Magneto-optical Rotation Methods" Anal Sci.7. 1431-1436 (1991)

[文献書誌] Takashi Shibahara,Akio Ixhimura,etal.: "Synthesis and Electrochemistry of Inconylate Cnbane Type Clusfers with M_3Se_4 cores (M=Mo,W)" Tnorganic Chemistry. 31. 640-647 (1992)

[文献書誌] Khin Nwe Soe,Akio Ichimura,etal.: "Electrochemistry of Anylimido Rhenian (V) Dithiocarfamato Comgeleres ({Re(NR)(S_2CNR_2)_2}_2]O in N_1N-dimethylformamide" Inorganic Chimica Acta. (1993)

[文献書誌] Noboru Oyama,Takeo Osake: "Molecnlar Design of Slectrode Surface Voltammetui Diaghosis of Charge Transport of Polyhce Coated Electrodes" John Wiley Dul.(New York), 70 (1992)

[文献書誌] Shigero Ikeda,Iwao Watanabe,Takafumi Miyanaga: "Structure of Metal compley in Solution by EXAFS and XANES methods,in"Structure and Dynamics in Solution Studies in physical and Theoretical Chemistry 79,sd Dhtaki,Yamatere" Elsevier Sci.Publisheis,(Amsfer Qam), 39-56 (1992)

[文献書誌] Iwao Watanabe: "Electronic STates of Ions and Molecules in Solution Studies by Photoelction Emission Spetruscopy,in"Sfuructure and Dynamics in Solution,Studies in Physical and Theoretical.Chemistry 79,ed Ohtaki Yamatera" Elsevier Sci.Publisher(Amsfer Qam), 320-335 (1992)

1992 年度実績報告書

千田貢福井県立大学, 生物資源学部, 教授 (90026419)

[文献書誌] 千田貢: "分子機能電極研究の現状と将来" 電気化学及び工業物理化. 61. 50-52 (1993)

[文献書誌] 木原壮林,松井正和: "液液,液膜界面反応解析法としての界面電荷移動ボルタンメトリー" 表面. 30. 367-378 (1992)

[文献書誌] 岡崎敏,田中和子: "微小電極を用いる電気化学測定法" 電気化学及び工業物理化学. 60. 771-776 (1992)