1993 年度実績報告書

冷中性子散乱による物質の高次構造とその物性

研究課題

研究課題/領域番号	03305003
研究機関	東京大学
研究代表者	藤井保彦東京大学, 物性研究所, 教授 (00013524)
研究分担者	伊藤雄而東京大学, 物性研究所, 助教授 (10013517) 山岡仁史京都大学, 工学部, 教授 (80026004) 山口泰男東北大学, 金属材料研究所, 教授 (80005917) 池田宏信高エネルギー物理学研究所, 教授 (90013523) 遠藤康夫東北大学, 理学部, 教授 (00013483)
キーワード	冷中性子散乱 / 高次構造 / 磁気構造と励起 / 高分子構造 / 蛋白質構造 / 誘体構造と運動 / 超伝導と磁性 / 相分離構造
研究概要	主に原研改造3号炉に設置した冷中性子、および熱中性子散乱用測定装置を用いて、広範な分野で見られる物質の高次構造と1次構造の関係、それらの構造や運動と物性や機能の関係を中心テーマとして研究を行ってきた。最終年度である今年度は、特に非弾性散乱、および時分割実験法を用いた物質の運動の研究に重点をおき、総合的な取りまとめを行った。金属・合金や高分子材料の諸性質が相分離後の高次構造と密接に関係しているので、各種物質の相分離過程を小角散乱によって時間追跡し、その機構と構造形態を明らかにし、物性制御(物質設計)の可能性を示した。同様に磁性材料については、中性子磁気散乱によりその磁気構造と磁化過程を追跡した。また、広範な高温酸化物超伝導体の示す特異な磁気的励起・揺らぎや格子振動を観測し、超伝導性と磁性の関係を整理した。さらに競合する相互作用を持つ系や重い電子系の示す特異な相転移現象や磁気構造、低温、強磁場中での弾性、非弾性両手法によりその発現機構を明らかにした。高分子においては、ABA型三元ブロック共重合体のミクロ相分離構造中での分子形態を明らかにし、アモルファス高分子の分子鎖の運動の様子や結晶化過程の誘導期のミクロな機構を解明した。生体物質においては、酵母産生B型肝炎ワクチン中での外殻蛋白質の分布の決定、リゾチーム結晶の分子レベルでの凝集会合構造の解明、ATP合成酵素の構造と機構の解明などに成功した。さらに、開発研究においては熱発光蛍光体検出器を用いた中性子カメラの開発に成功する一方、動的回折現象を利用したフォノンの固有ベクトル決定方法を新しく開発した。

研究成果

(43件)

すべてその他

すべて文献書誌 (43件)

[文献書誌] N.Motozawa and Y.Yamaguchi: "Field induced commensulate intermediate phases in helimagnet(Ba_<1-x>Sr_x)_2Zn_2Fe_<12>O_<22>(x=0.748)" J.Phys.Soc.Jpn.62. 1292-1304 (1993)
[文献書誌] T.Ono et al.: "Magnetic properties in intermetallic compounds DyMn_2(Si_<1-x>Ge_x)_2(0<x<1)" J.Magn.Magn.Mater.123. 133-140 (1993)
[文献書誌] H.Sun et al.: "Neutron powder-diffraction study of YFe_<12-x>Mo_x and YFe_<12-x>Mo_xN_<1.0>(x=1 and 3)" Phys.Rev.B. 48. 13333-13339 (1993)
[文献書誌] Y.Fujii et al.: "Unusual Magnetic,Transport and Thermodynamical Properties of the Uranium Ternries UNiSn UPdln and UNiGa" Physica B. 192. 219-227 (1993)
[文献書誌] H.Aruga et al.: "Magnetic phase diagrams of the triangular lattice antiferromagnets CsMnI_3 and CsNiBr_3" J.Phys.Soc.Jpn.62. 743-749 (1993)
[文献書誌] T.Kato et al.: "Neutron Diffraction Study of the Magnetic Phase Diagram of RbMnBr_3" J.Phys.Soc.Jpn.62. 3384-3387 (1993)
[文献書誌] H.Kawano et al.: "Two succesive spin glass transitions in nondiluted Heisenberg-like spin glass Ni0.42Mn0.58TiO3" J.Phys.Soc.Jpn.62. 2575-2578 (1993)
[文献書誌] Y.Okayama et al.: "Neutron scattering investigations of magnetic ordering and crystal field excitations in CeAs under pressure" Physica B. 186-188. 531-534 (1993)
[文献書誌] A.Ito et al.: "Magnetic Properties and Phase Diagram of Ni_xMn_<1-x>TiO_3" J.Magn.Magn.Mater.104-107. 1637-1638 (1992)
[文献書誌] H.Yoshizawa et al.: "Phase Diagram of a Heisenberg-like Spin Glass Ni_xMn_<1-x>TiO_3" Physica B. 180&181. 94-96 (1992)
[文献書誌] M.Takahashi and H.Ikeda: "Crossover from propagating spin waves to localized Ising-cluster excitations in diluted Heisenberg antiferromagnets" Phys.Rev.B. 47. 9132 (1993)
[文献書誌] H.Ikeda et al.: "Self-similarity of magnetic order in two-dimensional percolating antiferromagnets" J.Phys.Soc.Jpn.62. 3832 (1992)
[文献書誌] Y.Tsunoda and K.Motoya: "Antisotropic Thermoremanet Magnetization in the Antiferromagnetic γ-MnCu Alloy" J.Phys.Soc.Jpn.62. 376-377 (1993)
[文献書誌] K.Motoya and Y.Muraoka: "Neutron Scattering Study of Concentrated Spin Glass Alloys Fe65(Ni_<1-x>Mn_x)35" J.Phys.Soc.Jpn.62. 2819-2831 (1993)
[文献書誌] K.Nakajima et al.: "Quasielastic and Inelastic Neutron Scattering on RbNiCl_3" J.Phys.Soc.Jpn.61. 3355-3360 (1992)
[文献書誌] S.Itoh et al.: "Spin dynamics along the chain direction in an S=3/2,quasi one-dimensional Heisenberg antiferromagnet CsVCl_3" J.Phys.Condens.Matter. 5. 6767-6772 (1993)
[文献書誌] T.Den et al.: "Superconductor with T_c up to 80K in the Compoud(Ln,Ca)(Sr,Ba)_2(C,Cu)Cu_2O_<7-8>" Physica C. 351 (1993)
[文献書誌] S.Noma et al.: "New Superconducting Phase in Nb_<1-x>Ta_xSe_3(0.135<x<0.16)" Phys.Rev.B. 48. 9620 (1993)
[文献書誌] M.Sato et al.: "Magnetic Excitations in Superconducting YBa_2Cu_3O_<6+x> Crystals Studied by Neutron Inelastic Scattering" J.Phys.Soc.Jpn.62. 263-273 (1993)
[文献書誌] H.Harashina et al.: "Temperature Dependence of the Magnetic Excitation Spectra of YBa_2Cu_<2.9>Zn_<0.1>O_<6.75>" J.Phys.Soc.Jpn.62. 4009-4015 (1993)
[文献書誌] K.Osamura et al.: "Small Angle Scattering Study of Phase Decomposition in Fe-Cu Binary Alloy" Mater.Trans.,JIM. 34. 305-311 (1993)
[文献書誌] H.Ishibashi et al.: "Neutron Diffraction Studies in Cr Fine Particles" J.Phys.Cond.Matt.5. L415-L418 (1993)
[文献書誌] Y.Tsunoda and R.M.Nicklow: "Magnetic Structure of γ-Fe Precipitates in Cu(2)" J.Phys.Cond.Matt.5. 8999-9008 (1993)
[文献書誌] S.Takeda et al.: "Electron-ion correlation in liquid tellurium" J.Non-Cryst.Solids.156. 683-686 (1993)
[文献書誌] S.Takeda et al.: "Electron-Charge Distribution in Liquid Te" J.Phys.Soc.Jpn.62. 4277-4286 (1993)
[文献書誌] T.Kanaya et al.: "Small Angle Neutron Scattering from Poly(vinyl alcohol) Gels" Physica B. 180&181. 549-551 (1992)
[文献書誌] Y.Izumi et al.: "Neutron Scattering Evidence of Polymer Branching Caused by Physical Gelation III" Rept.Progr.Polym.Phys.Jpn.36. 47-48 (1993)
[文献書誌] H.Jinnai et al.: "Time-resolved Small-angle Neutron Scattering Study on Self-assembling Process of DPB/HPI Blends via Spinodal Decomposition" J.Chem.Phys.99. 4845-4854 (1993)
[文献書誌] T.Hashimoto and T.Izumitani: "Effect of a Block Copolymer on the Kinetics of Spinodal Decomposition of Polymer Blends" Macromolecules. 26. 3631-3638 (1993)
[文献書誌] T.Izumitani et al.: "Spontaneous Pinning of Domain Growth during Spinodal Decomposition of Off-critical Polymer Mixtures,II,Scaling Analysis" J.Chem.Phys.98. 3528-3539 (1993)
[文献書誌] T.Kanaya et al.: "Low-energy Excitation and Fast Motion near Tg in Amorphous cis-1,4-Polybutadiene" J.Chem.Phys.98. 8262-8270 (1993)
[文献書誌] M.Ohkura et al.: "Geration Rates of Poly(vinyl alcohol) Solution" Polymer. 33. 5045-5048 (1992)
[文献書誌] K.Inoue et al.: "A Crystal Analyzer Type Inelastic Spectrometer Using the Pulsed Thermal Neutron Source" Nucl.Instr.Meth.A327. 433-440 (1993)
[文献書誌] C.Matsuda et al.: "Gene structure of human mitochondrial ATP synthase γ-subunit;Tissue specificity produced by RNA splicing" J.Biol.Chem.268(33). 24950-24958 (1993)
[文献書誌] Y.Kagawa et al.: "The αβ complexes of ATP synthase;theα3β3 oligomer and α1β1 protomer" J.Bioener.Biomembrane. 24(5). 441-445 (1992)
[文献書誌] N.Niimura et al.: "Small Angle Thermal Neutron Scattering Spectrometer(WIT)" Phys.B. 180&181. 941-943 (1992)
[文献書誌] S.Nakatani et al: "Phase Shift of Neutrons in Magnetic Domains Observed by Interforomotry" Jpn.J.Appl.Phys.31. L1137-L1139 (1992)
[文献書誌] 遠藤康夫: "スピンの揺らぎと中性子散乱" 「遍歴電子系の磁性と超伝導」川畑有郷.安岡弘志編. (1992)
[文献書誌] 秋光純,富本晃吉: "新超伝導体探索研究の現状と展望" 日本結晶学会誌. 34. 5 (1992)
[文献書誌] 佐藤正俊: "YBa_2Cu_3O_<6+x>の中性子磁気非弾性散乱" 固体物理. 27. 19-28 (1992)
[文献書誌] 伊藤雄而: "中性子小角散乱" Radioisotopes. 41. 514 (1992)
[文献書誌] 野田幸男,池田進,山田安定: "KDPにおける水素の分布と運動-トンネルモードは存在するか-" 固体物理. 28. 605-615 (1993)
[文献書誌] 和泉義信: "物理ゲルの構造形成" 日本物理学会誌. 48. 808-810 (1993)

1993 年度 実績報告書

冷中性子散乱による物質の高次構造とその物性

研究代表者

藤井 保彦 東京大学, 物性研究所, 教授 (00013524)

研究成果

[文献書誌] N.Motozawa and Y.Yamaguchi: "Field induced commensulate intermediate phases in helimagnet(Ba_<1-x>Sr_x)_2Zn_2Fe_<12>O_<22>(x=0.748)" J.Phys.Soc.Jpn.62. 1292-1304 (1993)

[文献書誌] T.Ono et al.: "Magnetic properties in intermetallic compounds DyMn_2(Si_<1-x>Ge_x)_2(0<x<1)" J.Magn.Magn.Mater.123. 133-140 (1993)

[文献書誌] H.Sun et al.: "Neutron powder-diffraction study of YFe_<12-x>Mo_x and YFe_<12-x>Mo_xN_<1.0>(x=1 and 3)" Phys.Rev.B. 48. 13333-13339 (1993)

[文献書誌] Y.Fujii et al.: "Unusual Magnetic,Transport and Thermodynamical Properties of the Uranium Ternries UNiSn UPdln and UNiGa" Physica B. 192. 219-227 (1993)

[文献書誌] H.Aruga et al.: "Magnetic phase diagrams of the triangular lattice antiferromagnets CsMnI_3 and CsNiBr_3" J.Phys.Soc.Jpn.62. 743-749 (1993)

[文献書誌] T.Kato et al.: "Neutron Diffraction Study of the Magnetic Phase Diagram of RbMnBr_3" J.Phys.Soc.Jpn.62. 3384-3387 (1993)

[文献書誌] H.Kawano et al.: "Two succesive spin glass transitions in nondiluted Heisenberg-like spin glass Ni0.42Mn0.58TiO3" J.Phys.Soc.Jpn.62. 2575-2578 (1993)

[文献書誌] Y.Okayama et al.: "Neutron scattering investigations of magnetic ordering and crystal field excitations in CeAs under pressure" Physica B. 186-188. 531-534 (1993)

[文献書誌] A.Ito et al.: "Magnetic Properties and Phase Diagram of Ni_xMn_<1-x>TiO_3" J.Magn.Magn.Mater.104-107. 1637-1638 (1992)

[文献書誌] H.Yoshizawa et al.: "Phase Diagram of a Heisenberg-like Spin Glass Ni_xMn_<1-x>TiO_3" Physica B. 180&181. 94-96 (1992)

[文献書誌] M.Takahashi and H.Ikeda: "Crossover from propagating spin waves to localized Ising-cluster excitations in diluted Heisenberg antiferromagnets" Phys.Rev.B. 47. 9132 (1993)

[文献書誌] H.Ikeda et al.: "Self-similarity of magnetic order in two-dimensional percolating antiferromagnets" J.Phys.Soc.Jpn.62. 3832 (1992)

[文献書誌] Y.Tsunoda and K.Motoya: "Antisotropic Thermoremanet Magnetization in the Antiferromagnetic γ-MnCu Alloy" J.Phys.Soc.Jpn.62. 376-377 (1993)

[文献書誌] K.Motoya and Y.Muraoka: "Neutron Scattering Study of Concentrated Spin Glass Alloys Fe65(Ni_<1-x>Mn_x)35" J.Phys.Soc.Jpn.62. 2819-2831 (1993)

[文献書誌] K.Nakajima et al.: "Quasielastic and Inelastic Neutron Scattering on RbNiCl_3" J.Phys.Soc.Jpn.61. 3355-3360 (1992)

[文献書誌] S.Itoh et al.: "Spin dynamics along the chain direction in an S=3/2,quasi one-dimensional Heisenberg antiferromagnet CsVCl_3" J.Phys.Condens.Matter. 5. 6767-6772 (1993)

[文献書誌] T.Den et al.: "Superconductor with T_c up to 80K in the Compoud(Ln,Ca)(Sr,Ba)_2(C,Cu)Cu_2O_<7-8>" Physica C. 351 (1993)

[文献書誌] S.Noma et al.: "New Superconducting Phase in Nb_<1-x>Ta_xSe_3(0.135<x<0.16)" Phys.Rev.B. 48. 9620 (1993)

[文献書誌] M.Sato et al.: "Magnetic Excitations in Superconducting YBa_2Cu_3O_<6+x> Crystals Studied by Neutron Inelastic Scattering" J.Phys.Soc.Jpn.62. 263-273 (1993)

[文献書誌] H.Harashina et al.: "Temperature Dependence of the Magnetic Excitation Spectra of YBa_2Cu_<2.9>Zn_<0.1>O_<6.75>" J.Phys.Soc.Jpn.62. 4009-4015 (1993)

[文献書誌] K.Osamura et al.: "Small Angle Scattering Study of Phase Decomposition in Fe-Cu Binary Alloy" Mater.Trans.,JIM. 34. 305-311 (1993)

[文献書誌] H.Ishibashi et al.: "Neutron Diffraction Studies in Cr Fine Particles" J.Phys.Cond.Matt.5. L415-L418 (1993)

[文献書誌] Y.Tsunoda and R.M.Nicklow: "Magnetic Structure of γ-Fe Precipitates in Cu(2)" J.Phys.Cond.Matt.5. 8999-9008 (1993)

[文献書誌] S.Takeda et al.: "Electron-ion correlation in liquid tellurium" J.Non-Cryst.Solids.156. 683-686 (1993)

[文献書誌] S.Takeda et al.: "Electron-Charge Distribution in Liquid Te" J.Phys.Soc.Jpn.62. 4277-4286 (1993)

[文献書誌] T.Kanaya et al.: "Small Angle Neutron Scattering from Poly(vinyl alcohol) Gels" Physica B. 180&181. 549-551 (1992)

[文献書誌] Y.Izumi et al.: "Neutron Scattering Evidence of Polymer Branching Caused by Physical Gelation III" Rept.Progr.Polym.Phys.Jpn.36. 47-48 (1993)

[文献書誌] H.Jinnai et al.: "Time-resolved Small-angle Neutron Scattering Study on Self-assembling Process of DPB/HPI Blends via Spinodal Decomposition" J.Chem.Phys.99. 4845-4854 (1993)

[文献書誌] T.Hashimoto and T.Izumitani: "Effect of a Block Copolymer on the Kinetics of Spinodal Decomposition of Polymer Blends" Macromolecules. 26. 3631-3638 (1993)

[文献書誌] T.Izumitani et al.: "Spontaneous Pinning of Domain Growth during Spinodal Decomposition of Off-critical Polymer Mixtures,II,Scaling Analysis" J.Chem.Phys.98. 3528-3539 (1993)

[文献書誌] T.Kanaya et al.: "Low-energy Excitation and Fast Motion near Tg in Amorphous cis-1,4-Polybutadiene" J.Chem.Phys.98. 8262-8270 (1993)

[文献書誌] M.Ohkura et al.: "Geration Rates of Poly(vinyl alcohol) Solution" Polymer. 33. 5045-5048 (1992)

[文献書誌] K.Inoue et al.: "A Crystal Analyzer Type Inelastic Spectrometer Using the Pulsed Thermal Neutron Source" Nucl.Instr.Meth.A327. 433-440 (1993)

[文献書誌] C.Matsuda et al.: "Gene structure of human mitochondrial ATP synthase γ-subunit;Tissue specificity produced by RNA splicing" J.Biol.Chem.268(33). 24950-24958 (1993)

[文献書誌] Y.Kagawa et al.: "The αβ complexes of ATP synthase;theα3β3 oligomer and α1β1 protomer" J.Bioener.Biomembrane. 24(5). 441-445 (1992)

[文献書誌] N.Niimura et al.: "Small Angle Thermal Neutron Scattering Spectrometer(WIT)" Phys.B. 180&181. 941-943 (1992)

[文献書誌] S.Nakatani et al: "Phase Shift of Neutrons in Magnetic Domains Observed by Interforomotry" Jpn.J.Appl.Phys.31. L1137-L1139 (1992)

[文献書誌] 遠藤康夫: "スピンの揺らぎと中性子散乱" 「遍歴電子系の磁性と超伝導」川畑有郷.安岡弘志 編. (1992)

[文献書誌] 秋光純,富本晃吉: "新超伝導体探索研究の現状と展望" 日本結晶学会誌. 34. 5 (1992)

[文献書誌] 佐藤正俊: "YBa_2Cu_3O_<6+x>の中性子磁気非弾性散乱" 固体物理. 27. 19-28 (1992)

[文献書誌] 伊藤雄而: "中性子小角散乱" Radioisotopes. 41. 514 (1992)

[文献書誌] 野田幸男,池田進,山田安定: "KDPにおける水素の分布と運動-トンネルモードは存在するか-" 固体物理. 28. 605-615 (1993)

[文献書誌] 和泉義信: "物理ゲルの構造形成" 日本物理学会誌. 48. 808-810 (1993)

1993 年度実績報告書

藤井保彦東京大学, 物性研究所, 教授 (00013524)

[文献書誌] 遠藤康夫: "スピンの揺らぎと中性子散乱" 「遍歴電子系の磁性と超伝導」川畑有郷.安岡弘志編. (1992)