有機電気化学の新領域(特異な電極界面反応場における電極反応)

1992 年度 実績報告書

• 研究課題/領域番号: 04303007
• 研究機関: 東京工業大学
• 研究代表者: 野中 勉 東京工業大学, 大学院総合理工学研究科, 教授 (00016528)
• 研究分担者: 佐々木 和夫 広島大学, 工学部, 教授 (00034322) ; 藤嶋 昭 東京大学, 工学部, 教授 (30078307) ; 竹原 善一郎 京都大学, 工学部, 教授 (00025892) ; 長 哲郎 東北大学, 薬学部, 教授 (10010753) ; 宇根山 健治 岡山大学, 工学部, 教授 (00033150)
• キーワード: 有目電極反応 / 三次元機能修飾 / 超イオン雰囲気 / エネルギー照射 / 電極界面 / 界面反応場

研究概要

20名の研究分担者の有機的連携のもとで、第一年度としての下記の研究活動を行なった。
1.つぎの3つの特異な電極界面反応場のいずれかに焦点を当てた研究を各自の自由な着想で行なった。
(1)三次元機能修飾電極界面反応場
(2)超イオン雰囲気電極界面反応場
(3)エネルギー照射電極界面反応場
その結果,(1)では興味深い多数の知見が得られ有機電気化学の進展の原動力となった。(3)では全く新しい展開が進し有機電気化学の新領域形成の基軸ともなるべき成果が得られた。ところが,(2)における進行は必ずしも十分とは言い難く,第二年度への反省点となった。既に提出した平成5年度申請ではこの点に十分配慮されている。
2.研究交流と研究視野拡大のため,内外の学会・会議へ参加および主催(組織)を積極的に行なった。研究分担者の主な活動をまとめると下記のようである。
国際会議の主催(組織):1件
国内会議の主催(組機):3件
国際会議の招待(特別)講演:4件
国内会議の招待(特別)講演:7件
3.「有機電気化学の近未来におけるあるべき姿」への提言をアンケート形式で募り,19名の分担者から回答をえた。これを他の資料とともに編集し、分担者および関連分野の研究者50名に配布した。これに対する反応は次年度に調査検討することとしている。

研究成果

• [文献書誌] Yoshihito Kunugi: "Electroorganic Reactions on Organic Electodes.Part 15.Electrolysis Using Composite-Plectrodes.Part IV" Electrochimica Acta. 37. 353-355 (1992)
• [文献書誌] Po-Chung Cheng: "Simulation of Electroreduction Process of Acrylonitrile Using a Mathematical Reaction Model" Journal of Electrochemical Society of Japan. 60. 131-136 (1992)
• [文献書誌] Kouta Fukui: "Anodically-Generated Br-C1 Composite Halogenating Reagents" Bulletin of Chemical Society of Japan. 65. 943-948 (1992)
• [文献書誌] Naotake Sato: "Electrochemical Activity and Stability of Polyaniline Films Prepared by Electrooxidative Polymerization" Chemistry Express. 7. 433-436 (1992)
• [文献書誌] Masanobu Umezawa: "Electroreductive Polymerization of Dimethyldichlorosilane in a Non-solvent System" Journal of Electrochemical Society of Japan. 60. 743-744 (1992)
• [文献書誌] Hiroki Fujiwara: "Cyclic Voltammetric Study on Carbon DioXide Reduction Using Cu Complexes as Electrocatalysts" Journal of Electroanalytical Chemistry. 332. 303-307 (1992)
• [文献書誌] Yoshihito Kunugi: "Electro-organic Reactions on Organic Electrodes.Part 17." J.Electroanal.Chem.333. 325 (1992)
• [文献書誌] N.Sato: "Product-Selective Electroreduction of 2,3,4,5,6-Pentafluorobenzoic Acid to 2,3,4,5,6-Tetrafluorobenzyl Akohol and 2,3,4,5,6-Tetrafluorobenzaldehyde in a Flow Cell System" J.Appl.Electrochem. 22. 1082 (1992)
• [文献書誌] Masaharu Wakamatsu: "Bench-Scale Performance of Pyrene Quinone Production Process by Electrooxidation of Pyrene Suspension" J.Electrochem.Soc.Jpn.60. 1005 (1992)
• [文献書誌] M.Umezawa: "Electroreductive Polymerization of Dichlorocarbosilanes" Electrochim.Acta. 38. 529 (1993)
• [文献書誌] Po-Chung Cheng: "Electroreduction of Methyl Cinnamate Using a Ratating Cylinder Electrode" J.Electrochem.Soc.Jpn.61. 218 (1993)
• [文献書誌] Shu-Yong Guo: "Maximumin Oxidizing Power of Anodically-Generated Br-Cl Composite Reagents" J.Electrochem.Soc.Jpn.61. 245 (1993)
• [文献書誌] 野中 勉: "異常原子価の電気化学" 化学工業. 34. 810 (1992)
• [文献書誌] A.Aramata: "Catalysis on immobilized Co(II)TPP modified glassy Carbon electrode:CO_<> electrooxidation" 電気化学. 60. 1063 (1992)
• [文献書誌] A.Aramata: "UPD of Zinc on Polycrystalline Platinum in various PH solusions" J.Electroanal.Chem.338. 367 (1992)
• [文献書誌] A.Aramata: "CO_2 electochemistry on CO(II)TPP cheically modified electrode" 電気化学. 60. 565 (1992)
• [文献書誌] A.Aoki: "Multichannel Electrochemical Detection with Microelectrode Array in Flowing Streams" Anal.Chem.64. 44-49 (1992)
• [文献書誌] 山田 弘: "平面脂質二分子膜に近接させた電極による膜透過の評価" 電気化学. 60. 664-665 (1992)
• [文献書誌] 渡辺 恭一: "insituXRD嘉定法による銅の無電解折出過程の検討" 表面技術. 43. 451-456 (1992)
• [文献書誌] 樺澤 明裕: "微分容量測定およびinsitu表面増強ラマン散乱によるチオール単分子膜の安定性の検討" 電気化学. 60. 986-991 (1992)
• [文献書誌] 西澤 松彦: "ポリピロール被膜マイクロアレイ電極のPHスイッチ挙動" 電気化学. 60. 1014-1015 (1992)
• [文献書誌] N.Mastuda: "Surface-Enhanced Infrared and Raman Studies of Electrochemical Reduction of Self-assembled Monolayers Formed from P-Nitrothiophenol at Silver" Chem.Lett.1385-1388 (1992)
• [文献書誌] M.Nishizawa: "A Penicullin Sensor Based on a Microarray Electrode Deposited with a PH-Sensitive Polypyrrole" Anal.Chem.64. 2642-2644 (1992)
• [文献書誌] T.Sawaguchi: "Catallytic Capability of Diaphorase Bound to a Self-assembled Thiol Monolayer at a Gold Electrode" Bioelectrochem.Broenerg.29. 127-133 (1992)
• [文献書誌] M.Shibuya: "Photo-Switching Behavior of Microarray Electrodes Coated with Polypyrrole Film" Denki Kagaku. 60. 1152-1153 (1992)
• [文献書誌] Kenji Uneyama: "Perfluoroalkylation of Olefins by Electrooxidation of Perfluoroalkanoic Acids" Bull.Chem.Soc.Jpn.65. 1976-1981 (1992)
• [文献書誌] Hisayuki Watanabe: "Homologation of Trifluoroacetimidoyl iodides by Palladium-Catalyzed Carbonylation" TetraheDron Lett.33. 4333-4336 (1992)
• [文献書誌] Kenji Uneyama: "N-Substitnted 2,2,2-Trifluoroethanimidic Acid 1-Methyl- ethylidene hydrazides as Synthetic Blocks for Trifluoromethylated Nitrogen Heterocycles" J.Org.Chem.57. 6015-6019 (1992)
• [文献書誌] 井藤 壯太郎: "COD測定廃液を陽極液に用いるフェノールの電気化学的分解" Chem.Express. 7. 737-740 (1992)
• [文献書誌] S.Ito: "Deactivation Reaction in Hydroxylation of Benzene with Fentons Reagent" J.Org.Chem.57. 6937-6941 (1992)
• [文献書誌] Tetsuo Saji: "Electrochemical Formation of an Organic Thin Film Based on Dyeing with Vat Dye" Chem.Lett.2091 (1992)
• [文献書誌] Yasuhiko Ohsawa: "Electrochemical Detection of C^<6->_<60> at Low Temperature" J.Chem.Soc,Chem.Commun. 781 (1992)
• [文献書誌] T.Shono: "The Facil Electroreduction of Methyl Esters and N,N-Drmethylamides of Aliphatic Garboxylic Acids to Primary Alcohol" J.Org.Chem. 57. 1061 (1992)
• [文献書誌] T.Shono: "Novel Synthesis of 1,4-Diazacrown Ethers by Reductive Coupling of Aromatic Diimines" Tetrahedron Lett.33. 3347 (1992)
• [文献書誌] T.Shono: "Electroreductive Synthesis of Polygermane and Germane-Silane Copolymer" J.Chem.Soc.,Chem.Commun. 896 (1992)
• [文献書誌] T.Shono: "Regioselective Synthesis of Substituted Tropones and Azulenes Using Anodic Ocidation of Cycloheptatriene System as the Key Reaction" Tetrahcdron Lett.33. 4337 (1992)
• [文献書誌] T.Shono: "Electroveductive Decyanation of Nitriles and Its Application to Synthesis of a-Alkylamines" Tetrahedron. 48. 8253 (1992)
• [文献書誌] T.Shono: "A Novel Method for Staleoselective Synthesis of (1R,2R)-Diarylethylenediamines by Reductive Intramolecular Coupling of Aromatic Dicmines" Tetrahedron Lett.33. 5559 (1992)
• [文献書誌] T.Shono: "Electrochemically Prompted Cyclocoupling of 1,3-Dienes or stylenes with Aliphatic Carboxylic Esters" J.Org.Chem.57. 5561 (1992)
• [文献書誌] Hirotaka Fujita: "Stereoselective Cyclization of S-Alkenylamines Catalyzed with Butyllitium" Tetrahedron Lett.33. 6359 (1992)
• [文献書誌] 徳田 昌生: "反応試剤として作用する電極一反応性電極" 電気化学. 60. 9 (1992)
• [文献書誌] Z.Ogumi: "Difusion of Aniline throgh Perfluorosulfonate Ion-Exchange Membrane" J.Membrane Sci.65. 205 (1992)
• [文献書誌] Z.Ogumi: "Application of the SPE Method to Organic Electrochemistry Part 13." Electrochim.Acta. 37. 1295 (1992)
• [文献書誌] 田中 秀雄: "有機電気化学の新展開II;有機電解合成におけるメディエーター系の活用" 電気化学. 60. 84 (1992)
• [文献書誌] Hideo Tanaka: "Electrooxidative Initiation of Tin Hydride-Promoted Radical Chain Reaction" Tetrahedron Lett.33. 6495 (1992)
• [文献書誌] Hideo Tanaka: "A Facile Synthesis of C(3)-Alkenyl Substituted Cephems through Addition-Cyclization of Allenecarboxylates Clerived from Penicillin" Tetrahedron Lett.33. 7029 (1992)
• [文献書誌] Tsusomu Inokuchi: "Indirect Electroreduction of α,β-Epoxy Carbonyl ComPounds and Their Analogues by Lise of a (PhSe)_2/Sacrificial Anode System" Phosphorus,sufer and Sillicon. 67. 271 (1992)
• [文献書誌] Junichiro Mizusaki: "Lithium Carbonate as a Solid Electrolyte" Solid State Ionics. 53-56. 791-797 (1992)
• [文献書誌] L.Atanasoska: "XPS Studies on Conducting Polymers:Polypyrrole Films Doped with Monomeric and polymeric Anions" Chem.Mat.4. 988-994 (1992)
• [文献書誌] T.Sotomura: "New Organodisulfide-Polyaniline Composite Cathode for Secondary Lithium Battery" Electrochim.Acta. 37. 1851-1854 (1992)
• [文献書誌] K.Naoi: "QCM Analysis on electrochemical Formation of Electroactive Polyaniline from Non-Agueous Media" 電気化学. 60. 1091-1096 (1992)
• [文献書誌] I.Nishiguchi: "Electroreductive Silylation of Activated Olefins Using a Reactive Metal Anode" Tetahedron Lett.33. 5515 (1992)
• [文献書誌] I.Nishiguchi: "Novel Reduction of Carboxylic Acids and Hydroboration of Olefins by Electrolysis"
• [文献書誌] H.Doring: "Photoelectrochemical Investigations on Al and In Co-Doped Zns Thin Film Electrodesin an Agueous Electrolyte" Phys.Chem.96. 44-49 (1992)
• [文献書誌] R.Cai: "Phagocytosis of Titanium Dioxide Particles and Titanium Dioxide Particles Chemically Modified by Hematoporphyrin" Denki Kagaku. 60. 314-321 (1992)
• [文献書誌] Z.F.Liu: "Ditterence Between the Electrochemical Reductiveties of Trans and Cis Isomers of an Azo Compound in the Assembled Monolyer Film" J.Electroanal.Chem. 324. 259-267 (1992)
• [文献書誌] A.Manivannan: "Competitive Emission Processes Due to Band and Donor-Acceptor Transition at the n-sic/Electolyte Intertace" J.Phys.Chem.96. 3766-3769 (1992)
• [文献書誌] H.Yanagi: "Molecular Orientation of Vaccum-deposited Thim Films of Zinchaphthalocyanine" J.Appl.Phys.71. 5146-5153 (1992)
• [文献書誌] R.Cai: "Induction of Cytoxicity by Photoexited TiO_2 Particles" Cancer Research. 52. 2346-2348 (1992)
• [文献書誌] R.Cai: "Conversion of Photogererated Superoxide Anion into Hydrogen Peroxide into O_2 Suspension System" J.Electoanal.Chem.326. 345-350 (1992)
• [文献書誌] R.Baba: "Colloidal Cds-Pt Photocatalyst Stabilized by Pendant Viologen Polymer for Photoinduced Election transfer and Hydrogen Evolution" J.Photochem.Photobiol.A:Chem.64. 375-382 (1992)
• [文献書誌] H.doring: "TiO_2 Thin Films Prepared by Pulsed Beam Chemical Vapor Deposition from Titanium Tetraisopropoxide and Water" Phys.Chem.96. 620-622 (1992)
• [文献書誌] K.Patel: "Application of Bron-Doped CVD-Diamond Film to Photoelectrode" Denki Kagaku. 60. 659-661 (1992)
• [文献書誌] J.N.Yao: "Photochemical Response of Vaccum-Evaporated Nb_2O_5 Thin Films in Ethanol Vapor" Phys.Chem.96. 669-701 (1992)
• [文献書誌] Z.F.Liu: "New Application of Electrochemical Technigues" J.Photochem.Photobiol.A:Chem.65. 285-292 (1992)
• [文献書誌] A.Manivannan: "Scanning Probe Microscopic Investigation of Epitaxially Grown C_<60> Film on MoS_2" J.Appl.Phys.31. 3680-3685 (1992)
• [文献書誌] T.Amemiya: "Investigation of Dynamics of Faradaic Processes in Polypyrrole Films by Electrochemical Impedance and color Admittance Spectroscopic" Denki Kagaku. 60. 1075-1081 (1992)
• [文献書誌] A.Fujishima: "Biochemical Application of Photoelectrochemistry Photo Killing of Malignant Cells with TiO_2 Powder" Electrochim.acta. 18. 153-157 (1993)
• [文献書誌] 古屋 長一: "ガス拡散電極" 鉄と鋼. 78. 354-359 (1992)
• [文献書誌] 百田 邦尭: "有機化合物の電解部分フッ素化のための新しい電解液" 電気化学. 60. 1016 (1992)
• [文献書誌] 石川 正司: "Lewis酸を触媒として用いたNADH類縁体によるアセトアルデヒド同族体の還元反応" 日本化学会誌. 782 (1992)
• [文献書誌] K.Patel: "Photoelectrochemical Investigations on Boron-Doped Chemically Vapour-Deposited Diamond Electrodes" J.Photochem.Photobiol.A:Chem.65. 419-429 (1992)
• [文献書誌] A.Manivannan: "Probing the Anion Eftects on the Charge Density Waves in IT-TaS_2 by Xcanning Tunneling Microscopy" Surface Sci.Lett.274. 1554-1558 (1992)
• [文献書誌] K Sakawaki: "In-Situ Observation of IT-TaS_<2->xSex Charge Density Waves" Ultramicroscopy. 42-44. 599-609 (1992)
• [文献書誌] L.A.Nagahara: "The Influence of Hydrofluoric acid Concentration on Electrodes Copper Deposition Silicon" J.Electroanal.Chem.333. 363-369 (1992)
• [文献書誌] A.Manivannan: "Time Resolved Electroluminescene Measurements at an n-Sic/Electrolyte Interface by Transient Study" J.Phys.Chem. 96. 7399-7403 (1992)
• [文献書誌] G.D.Zhou: "Detection on Pitting on Cast Iron with AC Impedance Spectroscopy" Bull.Chem.Soc.Jpn.65. 2315-2318 (1992)
• [文献書誌] Hiromori Tsutsumi: "Preparation and Characterization of Modified Electrode by Self-Assembling Ferrocene Derivative" J.Electrochem.Soc.139. 1552 (1992)
• [文献書誌] Hiromori Tsutsumi: "Polymer Gel Films with Simple Orgahic Electrochromics for Single-Film Electrochromic Devices" J.Polym.Sci.:Part A:Poly.Chem.30. 1725 (1992)
• [文献書誌] Masayuki Morita: "Electrosynthesis of Poly(P-Phenylene)films and Their Application to the Electrodes of Rechargeable Batteries" Electrochin.Acta. 38. 1093 (1992)
• [文献書誌] Masayuki Morita: "Anodic Oxdation of Formic Acid at Nafionmodified Palladium Electrocatalysts" Denki Kagaku. 60. 554 (1992)
• [文献書誌] 茂木 巖: "金属葉の成長形態におよぼす強磁場の影響" 新金属工業. 37. 119 (1992)
• [文献書誌] Tetsuo Saji: "Electrochemistry in Colloids and dispersion" VCH Publishers,New York, (1992)
• [文献書誌] Okubo Susumu: "Effect of Very High Magnetic Fields on Fractal of Metal-Leaves" World Science Publishers, (1992)
• [文献書誌] 手塚 還: "プラズマ材料科学ハンドブック" オーム社, (1992)