1994 年度実績報告書

電子移動反応場の設計と制御

研究課題

研究課題/領域番号	05235103
研究機関	東京工業大学
研究代表者	野中勉東京工業大学, 大学院・総合理工学研究科, 教授 (00016528)
研究分担者	渡辺正東京大学, 生産技術研究所, 教授 (70092385) 茂木巌東北大学, 金属材料研究所, 助手 (50210084) 松岡英明東京農工大学, 工学部, 教授 (10143653) 藤嶋昭東京大学, 工学部, 教授 (30078307) 池田篤治京都大学, 農学部, 教授 (40026422)
キーワード	電子移動 / 電極界面 / 電極修飾 / 電極反応
研究概要	本研究課題である「電子移動反応場の設計と制御」は、電極表面のみならず、電極界面全体に及ぶ新しい電極修飾の概念、原理および手法の確立によって初めて達成されうるとの基本理念が、以下に述べる研究成果に基づいて検証された。すなわち、電極修飾の新しい概念は下記の4つに大別され、その各々が独立して、また相互に連携して、次世代の有機電気化学の展開を主導するものであり、その骨子とするところは有機電極反応の帰納的、能動的かつ合目的な超精密制御にあると結論された。以下の記述は計画班員による成果を中心にするが、今年度は公募班員による貢献も大きい。 (1)電極界面の物資修飾のよる反応場の設計と制御レドックス対、分子識別物資、不斉誘導物資、親/疎水性物資、光感応物資、触媒、酵素、生体系物資などの広範な機能性物資で修飾した電極が設計・作製され、それらの高度な機能を活用した高効率あるいは新規な分子変換の実現ガ大巾に拡充された。 (2)電極界面の形態/状態修飾による反応場の設計と制御電極表面の超高表面積化、巨視的不均一化、浸透性化など、並びに電解液界面の気相化、固相化、超流動化などによる新しいタイプの有機電気化学分子変換が創成され、従来の古典的な電解質溶液論や電気二重層概念を超越した理論の展開をみた。 (3)電解液界面のエネルギー照射修飾による反応場の設計と制御電導体電極系の電解液界面にプラズマ、光、磁場、超音波などの物理的エネルギーを照射することにり、電気化学的エネルギーだけでは不可能な新しい多様な有機電極反応が実現された。 (4)超微小電極界面反応場の設計と制御公募研究のより着手され、炭素繊維電極について成果が蓄積されつつある。

研究成果
(46件)

すべてその他

すべて文献書誌 (46件)

[文献書誌] Akinori KONNO: "Reduction of 4-Bromosydnone Derivatives" J.Electrochem.Soc.Jpn. 62. 260-263 (1994)
[文献書誌] Akiko YOSHIYAMA: "Preparation of PTFE Composite-plated Hydrophobic β-PbO_2 Electrodes" Chem.Lett. 1565-1568 (1994)
[文献書誌] Kazuya MATSUDA: "Ultrasonic Effects on Electroorganic Processes" Chem.Lett. 1619-1622 (1994)
[文献書誌] Yasushi ONO: "Electrolysis Using Composite Plated Electrodes" Chem.Lett. 1623-1626 (1994)
[文献書誌] Toyoaki ISHIWATA: "Electrochemical Formation of Dimeric Organostannyl Compounds" Chem.Lett. 1631-1634 (1994)
[文献書誌] Yasushi ONO: "Electrolysis Using Composite-plated Electrodes X" J.Electrochem.Soc.Jpn. 62. 1048-1053 (1994)
[文献書誌] Toshio FUCHIGAMI: "Electrocatalysis of a Self-assembled Thiol-modified Electrode" J.Electrochem.Soc.Jpn. 62. 1251-1253 (1994)
[文献書誌] Yasushi ONO: "Electrolysis Using Composite-plated Electrodes XII" J.Electrochem.Soc.Jpn. 62. 1264-1268 (1994)
[文献書誌] Shu-Yong GUO: "Anodic Generation of Composite Halogen Reagents" J.Electrochem.Soc.Jpn. 62. 1179-1182 (1994)
[文献書誌] Mahita ATOBE: "Ultrasonic Effects on Electroorganic processes II" J.Electrochem.Soc.Jpn. 62. 1298-1299 (1994)
[文献書誌] 野中勉: "疎水性電極による有機電解" 化学工業. 15-18 (1994)
[文献書誌] Hideaki KINOSHITA: "Electroanalysis of NADH using a new electrode prepared from plastic formed carbon" Microchemical Journal. 49. 226-234 (1994)
[文献書誌] Koujiro MIKI: "Electrocatalytic activity of cytoohrome c for the reduction of nituc oxide" Electroanalysis. 6. 703-705 (1994)
[文献書誌] Katsumi TAKAYAMA: "Bicelectrocatalytic hydroxylation of nicotinic acid at an electrode modified with immobilized loacterial cells of Pseudomonas flucrescens in the presence of electron transfer mediaters" J.Electroanal.Chem.(印刷中). (1995)
[文献書誌] Y.Nishiyama,H.Hayashi T.Watanabe,N.Murata: "Photosynthetic Oxygen Evolution is stabilized by Cytochrome C-550 against Heat Inactivation in Synechococcus sp.PCC 7002" Plant Physiology. 105. 1313-1319 (1994)
[文献書誌] S.Yoshida,H.Kanno T.Watanabe: "Glutamate Sensors Carrying Glutamate Oxidase/Peroxidase Bienzyme System on Tin Oxide Electrode" Analytical Sciences. 11(印刷中). (1995)
[文献書誌] Hidenori YANAI: "Bioelectrocatalysis by alcohol dehydrogenuse from Acetobacter aceti Adsorbed on bare and chemically modified electrodes" DENKI KAGAKU. 62. 1247-1248 (1994)
[文献書誌] Koujiro MIKI: "Bioelectrocatalysis at the Yeast cell-immobilized electrode with mediators" DENKI KAGAKU. 62. 1249-1250 (1994)
[文献書誌] Hideaki KINOSHITA: "An amperometric-enzymatic method for assays of inorganic phosphate and adenosine deaminuse in serum loased on the measurement of uric acid with a dialysis membrane-covered carbon electrode" Anul.chim.Acta. (印刷中). (1995)
[文献書誌] S.Miyazaki,H.Shin,Y.Miyoshi and M.Hirose: "Real Time Monitoring of Surface Reactions during Plasma Enhanced CVD of Silicon" Extended Abstracts of the 1994 Intern.Conf.on Solid State Devices and Materials. 724-726 (1994)
[文献書誌] I.Mogi: "Electrochemical Polymerization of Aniline in High Magnetic Fields" Denki Kagaku. 62. 1287-1289 (1994)
[文献書誌] I.Mogi: "An Electrochemical Impedance Study in High Magnetic Fields" Denki Kagaku. 62. 1295-1297 (1994)
[文献書誌] R.Aogaki: "Hysteresis Effect of Magnetic Field on Electron Transfer Processes in Electrochemical Reaction" Physica B. 201. 611-615 (1994)
[文献書誌] I.Mogi: "Magnetic Field Effects on Fractal Morphology in Electrochemical Deposition" Physica B. in press (1995)
[文献書誌] Y.Miyoshi,S.George,L.Okada,S.Miyazaki and M.Hirose: "In Situ Observation of Surface Reactions during Plasma Enhanced CVD using FT-IR-ATR" The 16th Symposium on Dry Process. 151-156 (1994)
[文献書誌] 広瀬全孝・宮崎誠一: "高流動性プラズマCVDによる薄膜形成" 応用物理. 63. 1118-1122 (1994)
[文献書誌] S.Miyazaki,H.Shin,Y.Miyoshi and M.Hirose: "Real time Monitoring of Surface Reactions during Plasma Enhanced CVD of Silicon" Japanese Journal of Applied Physics. 34(掲載決定). (1995)
[文献書誌] Tomoo Homma: "Analysis of Electric and Electrochemical Connection Between Leaf Cells of Tradesoantia virginiana L That Responds to CO_2 Stress by Changing Intracellular Potential" Bioelectrochem.Bioenerg.33. 67-70 (1994)
[文献書誌] Yasushi Kazuno: "Use of Lone Cell of PC12h-R as a Sensing Material for Neurite Growth Initiating Activity." J.Intell.Matl.Systs.& Struct.5. 117-121 (1994)
[文献書誌] Jong-Chul Park: "Adaptation of Aspergillus niger to Several Antifungal Agents Treated as Short-Term Stress." Microbiology. 140. 2409-2414 (1994)
[文献書誌] Hyeon-Cheol Yang: "Application of a Microscopic Fluorescence Indicator to the Determination of Antimycotic Activity." J.Antibacterial Antifungal Agent. 23. 3-7 (1995)
[文献書誌] Hideaki Matsuoka: "Use of Congo Red as a Microscopic Fluorescence Indicator of Hyphal Growth" Appl.Microbiol.Bitechnol.41(in press). (1995)
[文献書誌] Hyeon-Cheol Yang: "Rapid Viability Asessment of Spores of Several Fangi by Ionic Intensified FDA Method." Current Microbiol.(in press).
[文献書誌] Hideaki Matsuoka: "Adaptation of Aspergillus niger to Multiple Agents Whose Action Mechanisms are different." Jpn.J.Med.Mycol.36(in press). (1995)
[文献書誌] Ki-Bong Oh: "Combined Effect of Amphotericin B and Flucytosine on Hyphal Growth of Candida albicans Estimated at a Single Hypha Level." J.Med.Vet.Mycol.(in press). (1994)
[文献書誌] 松岡英明: "植物の環境認識機能" システム/制御/情報,. 38. 485-491 (1994)
[文献書誌] 松岡英明: "植物センサーの働き" ESTaP. 27. 8-11 (1994)
[文献書誌] T.Yano: "Observation and Surfaces Modification of Electropolymerized Poly(N-Methylpyrrole)Using Atomic Force Microscopy" J.Voc.Sci.Technol.B. 12(3). 1596-1599 (1994)
[文献書誌] O.Sato: "A Novel Approach to the Polydiacetylene Langmuir-Blodegett Film by the Surface-Specific Optical Third Harmonic Generation Based on the Angular Homentum Concervation Rule" J.Electroanal.Chem.372. 279-281 (1994)
[文献書誌] J.F.Zhi: "Conjugated Mdecular System of Photochromism and Electrochromism Photoelectrochemical Behavier of Nitrospirobenzopyran at Low Temperature." Chem.Lett.1521-1524 (1994)
[文献書誌] A.Manivannan: "Observation of Vacuum-Deposited Napthalocyanine Molecules Using Scanning Tunneling Microscopy." J.Vac.Sci.Technol.B. 12(3). 2000-2003 (1994)
[文献書誌] L.Jiang.: "Surface Photovoltage Spectroscopy and Mapping by Atomic Force Microscopy" Chem.Lett.1975-1978 (1994)
[文献書誌] T.Amemiya: "Coldor Impedance Spectroscopy of Polypyrrole Films" J.Electroanal.Chem.377. 143-148 (1994)
[文献書誌] 野中勉ほか: "先端電気化学" 丸善(株), 398 (1994)
[文献書誌] 渡辺正(分担執筆): "先端電気化学" 丸善, (1994)
[文献書誌] 渡辺正(分担執筆): "ナノバイオロジー入門-時間と空間の生物学" 講談社サイエンティフィク, (1994)

1994 年度 実績報告書

電子移動反応場の設計と制御

研究代表者

野中 勉 東京工業大学, 大学院・総合理工学研究科, 教授 (00016528)

研究成果

[文献書誌] Akinori KONNO: "Reduction of 4-Bromosydnone Derivatives" J.Electrochem.Soc.Jpn. 62. 260-263 (1994)

[文献書誌] Akiko YOSHIYAMA: "Preparation of PTFE Composite-plated Hydrophobic β-PbO_2 Electrodes" Chem.Lett. 1565-1568 (1994)

[文献書誌] Kazuya MATSUDA: "Ultrasonic Effects on Electroorganic Processes" Chem.Lett. 1619-1622 (1994)

[文献書誌] Yasushi ONO: "Electrolysis Using Composite Plated Electrodes" Chem.Lett. 1623-1626 (1994)

[文献書誌] Toyoaki ISHIWATA: "Electrochemical Formation of Dimeric Organostannyl Compounds" Chem.Lett. 1631-1634 (1994)

[文献書誌] Yasushi ONO: "Electrolysis Using Composite-plated Electrodes X" J.Electrochem.Soc.Jpn. 62. 1048-1053 (1994)

[文献書誌] Toshio FUCHIGAMI: "Electrocatalysis of a Self-assembled Thiol-modified Electrode" J.Electrochem.Soc.Jpn. 62. 1251-1253 (1994)

[文献書誌] Yasushi ONO: "Electrolysis Using Composite-plated Electrodes XII" J.Electrochem.Soc.Jpn. 62. 1264-1268 (1994)

[文献書誌] Shu-Yong GUO: "Anodic Generation of Composite Halogen Reagents" J.Electrochem.Soc.Jpn. 62. 1179-1182 (1994)

[文献書誌] Mahita ATOBE: "Ultrasonic Effects on Electroorganic processes II" J.Electrochem.Soc.Jpn. 62. 1298-1299 (1994)

[文献書誌] 野中 勉: "疎水性電極による有機電解" 化学工業. 15-18 (1994)

[文献書誌] Hideaki KINOSHITA: "Electroanalysis of NADH using a new electrode prepared from plastic formed carbon" Microchemical Journal. 49. 226-234 (1994)

[文献書誌] Koujiro MIKI: "Electrocatalytic activity of cytoohrome c for the reduction of nituc oxide" Electroanalysis. 6. 703-705 (1994)

[文献書誌] Katsumi TAKAYAMA: "Bicelectrocatalytic hydroxylation of nicotinic acid at an electrode modified with immobilized loacterial cells of Pseudomonas flucrescens in the presence of electron transfer mediaters" J.Electroanal.Chem.(印刷中). (1995)

[文献書誌] Y.Nishiyama,H.Hayashi T.Watanabe,N.Murata: "Photosynthetic Oxygen Evolution is stabilized by Cytochrome C-550 against Heat Inactivation in Synechococcus sp.PCC 7002" Plant Physiology. 105. 1313-1319 (1994)

[文献書誌] S.Yoshida,H.Kanno T.Watanabe: "Glutamate Sensors Carrying Glutamate Oxidase/Peroxidase Bienzyme System on Tin Oxide Electrode" Analytical Sciences. 11(印刷中). (1995)

[文献書誌] Hidenori YANAI: "Bioelectrocatalysis by alcohol dehydrogenuse from Acetobacter aceti Adsorbed on bare and chemically modified electrodes" DENKI KAGAKU. 62. 1247-1248 (1994)

[文献書誌] Koujiro MIKI: "Bioelectrocatalysis at the Yeast cell-immobilized electrode with mediators" DENKI KAGAKU. 62. 1249-1250 (1994)

[文献書誌] Hideaki KINOSHITA: "An amperometric-enzymatic method for assays of inorganic phosphate and adenosine deaminuse in serum loased on the measurement of uric acid with a dialysis membrane-covered carbon electrode" Anul.chim.Acta. (印刷中). (1995)

[文献書誌] S.Miyazaki,H.Shin,Y.Miyoshi and M.Hirose: "Real Time Monitoring of Surface Reactions during Plasma Enhanced CVD of Silicon" Extended Abstracts of the 1994 Intern.Conf.on Solid State Devices and Materials. 724-726 (1994)

[文献書誌] I.Mogi: "Electrochemical Polymerization of Aniline in High Magnetic Fields" Denki Kagaku. 62. 1287-1289 (1994)

[文献書誌] I.Mogi: "An Electrochemical Impedance Study in High Magnetic Fields" Denki Kagaku. 62. 1295-1297 (1994)

[文献書誌] R.Aogaki: "Hysteresis Effect of Magnetic Field on Electron Transfer Processes in Electrochemical Reaction" Physica B. 201. 611-615 (1994)

[文献書誌] I.Mogi: "Magnetic Field Effects on Fractal Morphology in Electrochemical Deposition" Physica B. in press (1995)

[文献書誌] Y.Miyoshi,S.George,L.Okada,S.Miyazaki and M.Hirose: "In Situ Observation of Surface Reactions during Plasma Enhanced CVD using FT-IR-ATR" The 16th Symposium on Dry Process. 151-156 (1994)

[文献書誌] 広瀬全孝・宮崎誠一: "高流動性プラズマCVDによる薄膜形成" 応用物理. 63. 1118-1122 (1994)

[文献書誌] S.Miyazaki,H.Shin,Y.Miyoshi and M.Hirose: "Real time Monitoring of Surface Reactions during Plasma Enhanced CVD of Silicon" Japanese Journal of Applied Physics. 34(掲載決定). (1995)

[文献書誌] Tomoo Homma: "Analysis of Electric and Electrochemical Connection Between Leaf Cells of Tradesoantia virginiana L That Responds to CO_2 Stress by Changing Intracellular Potential" Bioelectrochem.Bioenerg.33. 67-70 (1994)

[文献書誌] Yasushi Kazuno: "Use of Lone Cell of PC12h-R as a Sensing Material for Neurite Growth Initiating Activity." J.Intell.Matl.Systs.& Struct.5. 117-121 (1994)

[文献書誌] Jong-Chul Park: "Adaptation of Aspergillus niger to Several Antifungal Agents Treated as Short-Term Stress." Microbiology. 140. 2409-2414 (1994)

[文献書誌] Hyeon-Cheol Yang: "Application of a Microscopic Fluorescence Indicator to the Determination of Antimycotic Activity." J.Antibacterial Antifungal Agent. 23. 3-7 (1995)

[文献書誌] Hideaki Matsuoka: "Use of Congo Red as a Microscopic Fluorescence Indicator of Hyphal Growth" Appl.Microbiol.Bitechnol.41(in press). (1995)

[文献書誌] Hyeon-Cheol Yang: "Rapid Viability Asessment of Spores of Several Fangi by Ionic Intensified FDA Method." Current Microbiol.(in press).

[文献書誌] Hideaki Matsuoka: "Adaptation of Aspergillus niger to Multiple Agents Whose Action Mechanisms are different." Jpn.J.Med.Mycol.36(in press). (1995)

[文献書誌] Ki-Bong Oh: "Combined Effect of Amphotericin B and Flucytosine on Hyphal Growth of Candida albicans Estimated at a Single Hypha Level." J.Med.Vet.Mycol.(in press). (1994)

[文献書誌] 松岡英明: "植物の環境認識機能" システム/制御/情報,. 38. 485-491 (1994)

[文献書誌] 松岡英明: "植物センサーの働き" ESTaP. 27. 8-11 (1994)

[文献書誌] T.Yano: "Observation and Surfaces Modification of Electropolymerized Poly(N-Methylpyrrole)Using Atomic Force Microscopy" J.Voc.Sci.Technol.B. 12(3). 1596-1599 (1994)

[文献書誌] O.Sato: "A Novel Approach to the Polydiacetylene Langmuir-Blodegett Film by the Surface-Specific Optical Third Harmonic Generation Based on the Angular Homentum Concervation Rule" J.Electroanal.Chem.372. 279-281 (1994)

[文献書誌] J.F.Zhi: "Conjugated Mdecular System of Photochromism and Electrochromism Photoelectrochemical Behavier of Nitrospirobenzopyran at Low Temperature." Chem.Lett.1521-1524 (1994)

[文献書誌] A.Manivannan: "Observation of Vacuum-Deposited Napthalocyanine Molecules Using Scanning Tunneling Microscopy." J.Vac.Sci.Technol.B. 12(3). 2000-2003 (1994)

[文献書誌] L.Jiang.: "Surface Photovoltage Spectroscopy and Mapping by Atomic Force Microscopy" Chem.Lett.1975-1978 (1994)

[文献書誌] T.Amemiya: "Coldor Impedance Spectroscopy of Polypyrrole Films" J.Electroanal.Chem.377. 143-148 (1994)

[文献書誌] 野中勉ほか: "先端電気化学" 丸善(株), 398 (1994)

[文献書誌] 渡辺正(分担執筆): "先端電気化学" 丸善, (1994)

[文献書誌] 渡辺正(分担執筆): "ナノバイオロジー入門-時間と空間の生物学" 講談社サイエンティフィク, (1994)

1994 年度実績報告書

野中勉東京工業大学, 大学院・総合理工学研究科, 教授 (00016528)

[文献書誌] 野中勉: "疎水性電極による有機電解" 化学工業. 15-18 (1994)