1994 年度実績報告書

高分子系における秩序と乱れ:構造とダイナミックス

研究課題

研究課題/領域番号	05303009
研究機関	大阪大学
研究代表者	寺本明夫大阪大学, 理学部, 教授 (00028151)
研究分担者	根本紀夫九州大学, 工学部, 教授 (90027053) 尾崎邦宏京都大学, 化学研究所, 教授 (00027046) 野田一郎名古屋大学, 工学部, 教授 (30023055) 野瀬卓平東京工業大学, 工学部, 教授 (20016405) 早川礼之助東京大学, 工学部, 教授 (00011106)
キーワード	高分子 / 分子形態 / ダイナミックス / 相分離 / ゲル / 界面 / ブロック共重合 / 分岐高分子
研究概要	線状高分子の濃厚溶液や固体の動的・静的性質に関して、分子レベルより理解することに努めた。濃厚系中での屈曲性高分子のダイナミックスを誘電分散実験により調べ、レプテーションモデルを用いた理論の問題点とその改良への指針を提供した。また、高分子固体の大変形に対する力学応答及びガラス転移点近傍における高分子の運動性という問題を、(1)2様分布を持った高分子試料を用いる、(2)微分動的弾性率測定を行う、(3)1軸・2軸伸長変形様式について調べる、(4)動的粘弾性と複屈折の同時測定を行う、という方法を用いて詳しく研究した。ガラス転移点近傍における高分子運動は2種の成分に分けられ、高分子の化学構造との相関を調べた。静的性質については、まず半屈曲性高分子系の熱力学的性質と局所構造は屈曲性高分子系とは全く異なった理論体系によって説明されることが分かった。また屈曲性高分子の分子内排除体積相互作用が濃厚系では遮蔽されるという問題を計算機シミュレーションにより研究し、高分子ブレンド系については、高分子間の異方的相互作用を赤外吸収の二色性測定により調べて、それが相溶性に重要な影響を与えることを見いだした。以上述べた線状高分子の均一系に対する研究成果を基礎として、最近注目されている高分子及び高分子系、具体的には、分岐高分子[星型、樹状、ポリ(マクロモノマー)]、化学及び物理架橋した高分子ゲル、マクロ及びミクロ相分離した高分子系、表面・界面における高分子等の静的・動的性質について、新しい実験手法や理論、またシミュレーションを用いて詳細に調べた。(紙面の都合上、それらの成果の詳細については省略する。)これらの成果は高分子を用いた材料の設計に対する指針を与えることが期待される。

研究成果
(38件)

すべてその他

すべて文献書誌 (38件)

[文献書誌] Kohzo Ito: "New Measurement Method for the Quasielastic Light Scattering with the Sinusodal Electric Field by Use of an Extended Wiener-Khinchin Theorem" Journal of Chemical Physics. 101. 4463-4465 (1994)
[文献書誌] Takeshi Shimomura: "Intrachain Conduction and Main-Chain Conformation of Conducting Polymers as Studied by Frequency-Domain Electric Birefringence Spectroscopy" Physical Review Letters. 72. 2073-2076 (1994)
[文献書誌] Kunihiro Osaki: "Dynamic Birefringence of Amorphous Polymers" Journal of Non-Crystalline Solids. 172-174. 838-849 (1994)
[文献書誌] Hirotoshi Toratani: "Cooling Rate Dependence of Glass Transition Temperatures under High Pressure" Reports on Progress in Polymer Physics in Japan. 37. 339-342 (1994)
[文献書誌] A.Koike: "Dynamic Light Scattering of CTAB:NaSal threadlike Micelles in the Semidilute Regime.II.Effect of Surfactant Concentration" Colloid & Polymer Science. 272. 955-961 (1994)
[文献書誌] Keiko Ono: "Local Chain Dynamics of Poly(cis-1,4-isoprene)in Dilute Solutions Studied by the Fluorescence Depolarization Method" Polymer Journal. 26. 1345-1351 (1994)
[文献書誌] Keiko Ono: "Chain Dynamics of Styrene Polymers Studied by the Fluorescence Depolarization Method" Macromolecules. 27. 6482-6486 (1994)
[文献書誌] Akihiko Takada: "Chain-Length Dependence of the Mesomorphic Properties of Fully Decanoated Cellulose and Cellooligosaccharides" Macromolecules. 27. 1651-1653 (1994)
[文献書誌] Yoshiaki Takahashi: "Viscoelastic Properties of Polyelectrolyte Solutions.III.Dynamic Moduli from Terminal to Plateau Regions" Journal of Non-Crystalline Solids. 172-174. 911-916 (1994)
[文献書誌] Yoshinobu Isono: "Stress Relaxation and Change in Entanglement Structure of Polyisobutylene in Large Shearing Deformation" Polymer. (印刷中).
[文献書誌] Osamu Urakawa: "Dielectric Normal Mode Relaxation of Poly(lactone)s in Solution" Macromolecules. 27. 7410-7414 (1994)
[文献書誌] Keiichiro Adachi: "Dielectric Study of Subchain Dynamics and Dimension:Butadiene-Isoprene Block Copolymers" Journal of Non-Crystalline Solids. 172-174. 661-667 (1994)
[文献書誌] Takahiro Sato: "Dynamics of Stiff-Chain Polymers in Isotropic Solutions.4.Multicomponent Systems" Macromolecules. 27. 1477-1483 (1994)
[文献書誌] Takashi Norisuye: "Effects of Three-Segment Interactions on the Temperature Dependence of the Third Virial Coefficient for Flexible Chains near θ Point" Macromolecules. 27. 2054-2057 (1994)
[文献書誌] Takashi Norisuye: "Viscosity Behavior and Conformation of Amylose in Various Solvents" Polymer Journal. 26. 1303-1307 (1994)
[文献書誌] K.Ohno: "Dynamics of Star Polymers in a Good Solvent:A Kramers Potential Treatment" Journal of Chemical Physics. 101. 4452-4460 (1994)
[文献書誌] Takao Minato: "Asphericity of Star Polymer" Reports on Progress in Polymer Physics in Japan. 37. 65-68 (1994)
[文献書誌] Fumihiko Tanaka: "Phase Formation of Two-Component Physical Gels" Physica. A204. 660-672 (1994)
[文献書誌] Fumihiko Tanaka: "Thermoreversible Gelation with Junctions of Variable Multiplicity" Macromolecules. 27. 3943-3954 (1994)
[文献書誌] Masaoki Takahashi: "Dynamic Viscoelasticity and Critical Exponents in Sol-Gel Transition of an End-Linking Polymer" Journal of Chemical Physics. 101. 798-804 (1994)
[文献書誌] K.Urayama: "Stress Relaxation and Creep of Polymer Gels in Solvent under Uniaxial and Biaxial Deformations" Rheologica Acta. 33. 89-98 (1994)
[文献書誌] Akihiko Koike: "Dynamic Viscoelasticity of End-Linking α,ω-Dimethyl Silyl Poly(propyleneoxide)Solutions near the Gel Point" Polymer. 35. 3005-3010 (1994)
[文献書誌] Tsutomu Tomari: "Swelling Dynamics of a Gel Undergoing Volume Transition" Journal of the Physical Society of Japan. 63. 2093-2101 (1994)
[文献書誌] Masamichi Kobayashi: "Structure of Physical Gels Formed in Syndiotactic Polystyrene/Solvent Systems Studied by Small-Angle Neutron Scattering" Macromolecules. 27. 1349-1354 (1994)
[文献書誌] Pingfan Chen: "Effect of Scission of Hydrogen Bonds by Phenol on Phase Behavior and Physical Properties of Polydiacetylene Gels:P(3BCMU)and P(4BCMU)" Polymer. 34. 4953-4960 (1994)
[文献書誌] T.Ohta: "Dynamics of Phase-Separated Fluids under External Fields" International Journal of Thermophyics. 15. 1135-1143 (1994)
[文献書誌] Takao Ohta: "Domain-Lattice Ordering in Microphase Separated Copolymers" Physical Review B. (印刷中).
[文献書誌] Elisha Moses: "Shear Microscopy of the "Butterfly Pattern"in Polymer Mixtures" Physical Review Letters. 72. 2037-2040 (1994)
[文献書誌] Satoshi Koizumi: "Spatial Distribution of Homopolymers in Block Copolymer Microdomains as Observed by a Combined SANS and SAXS Method" Macromolecules. 27. 7893-7906 (1994)
[文献書誌] Yasuhiro Mogi: "Superlattice Structures in Morphologies of the ABC Triblock Copolymers" Macromolecules. 27. 6755-6760 (1994)
[文献書誌] Irina Nyrkova: "Microdomain Structures in Polyelectrolyte Systems:Calculation of the Phase Diagrams by Direct Minimization of the Free Energy" Macromolecules. 27. 4220-4230 (1994)
[文献書誌] Akira Hatano: "Computer Simulations to Condensed Symmetric AB Diblock Copolymer Systems" Reports on Progress in Polymer Physics in Japan. 37. 279-282 (1994)
[文献書誌] H.Sato: "Phase Separation in a Dilute Polymer Solution in a Metastable Region" Physical Review E. 50. R1752-R1754 (1994)
[文献書誌] K.Kubota: "Critical Behavior of a Cationic Surfactant in an Aqueous Salt Solution" Journal of Chemical Physics. 100. 4543-4547 (1994)
[文献書誌] Naoshi Miyashita: "Critical Dynamics and Diffusion Behavior of Polymer Blend Solutions of Polystyrene/Poly(methylmethacrylate)/d^6-benzene" Journal of Chemical Physics. 100. 6028-6037 (1994)
[文献書誌] Kohzoh Shiokawa: "Chain Dimensions of a Polymer Confined between Two Interacting Plates" Polymer Journal. 26. 688-693 (1994)
[文献書誌] Masami Kawaguchi: "Poly(N-isopropylacrylamide)Films at the Air-Water Interface" Macromolecules. 27. 5882-5884 (1994)
[文献書誌] Masami Kawaguchi: "Effects of Polymer Adsorption and Desorption on Rheological Properties of Silica Suspensions" Colloid Surfaces A:Physicochemical and Engineering Aspects. 86. 283-289 (1994)

1994 年度 実績報告書

高分子系における秩序と乱れ:構造とダイナミックス

研究代表者

寺本 明夫 大阪大学, 理学部, 教授 (00028151)

研究成果

[文献書誌] Kohzo Ito: "New Measurement Method for the Quasielastic Light Scattering with the Sinusodal Electric Field by Use of an Extended Wiener-Khinchin Theorem" Journal of Chemical Physics. 101. 4463-4465 (1994)

[文献書誌] Takeshi Shimomura: "Intrachain Conduction and Main-Chain Conformation of Conducting Polymers as Studied by Frequency-Domain Electric Birefringence Spectroscopy" Physical Review Letters. 72. 2073-2076 (1994)

[文献書誌] Kunihiro Osaki: "Dynamic Birefringence of Amorphous Polymers" Journal of Non-Crystalline Solids. 172-174. 838-849 (1994)

[文献書誌] Hirotoshi Toratani: "Cooling Rate Dependence of Glass Transition Temperatures under High Pressure" Reports on Progress in Polymer Physics in Japan. 37. 339-342 (1994)

[文献書誌] A.Koike: "Dynamic Light Scattering of CTAB:NaSal threadlike Micelles in the Semidilute Regime.II.Effect of Surfactant Concentration" Colloid & Polymer Science. 272. 955-961 (1994)

[文献書誌] Keiko Ono: "Local Chain Dynamics of Poly(cis-1,4-isoprene)in Dilute Solutions Studied by the Fluorescence Depolarization Method" Polymer Journal. 26. 1345-1351 (1994)

[文献書誌] Keiko Ono: "Chain Dynamics of Styrene Polymers Studied by the Fluorescence Depolarization Method" Macromolecules. 27. 6482-6486 (1994)

[文献書誌] Akihiko Takada: "Chain-Length Dependence of the Mesomorphic Properties of Fully Decanoated Cellulose and Cellooligosaccharides" Macromolecules. 27. 1651-1653 (1994)

[文献書誌] Yoshiaki Takahashi: "Viscoelastic Properties of Polyelectrolyte Solutions.III.Dynamic Moduli from Terminal to Plateau Regions" Journal of Non-Crystalline Solids. 172-174. 911-916 (1994)

[文献書誌] Yoshinobu Isono: "Stress Relaxation and Change in Entanglement Structure of Polyisobutylene in Large Shearing Deformation" Polymer. (印刷中).

[文献書誌] Osamu Urakawa: "Dielectric Normal Mode Relaxation of Poly(lactone)s in Solution" Macromolecules. 27. 7410-7414 (1994)

[文献書誌] Keiichiro Adachi: "Dielectric Study of Subchain Dynamics and Dimension:Butadiene-Isoprene Block Copolymers" Journal of Non-Crystalline Solids. 172-174. 661-667 (1994)

[文献書誌] Takahiro Sato: "Dynamics of Stiff-Chain Polymers in Isotropic Solutions.4.Multicomponent Systems" Macromolecules. 27. 1477-1483 (1994)

[文献書誌] Takashi Norisuye: "Effects of Three-Segment Interactions on the Temperature Dependence of the Third Virial Coefficient for Flexible Chains near θ Point" Macromolecules. 27. 2054-2057 (1994)

[文献書誌] Takashi Norisuye: "Viscosity Behavior and Conformation of Amylose in Various Solvents" Polymer Journal. 26. 1303-1307 (1994)

[文献書誌] K.Ohno: "Dynamics of Star Polymers in a Good Solvent:A Kramers Potential Treatment" Journal of Chemical Physics. 101. 4452-4460 (1994)

[文献書誌] Takao Minato: "Asphericity of Star Polymer" Reports on Progress in Polymer Physics in Japan. 37. 65-68 (1994)

[文献書誌] Fumihiko Tanaka: "Phase Formation of Two-Component Physical Gels" Physica. A204. 660-672 (1994)

[文献書誌] Fumihiko Tanaka: "Thermoreversible Gelation with Junctions of Variable Multiplicity" Macromolecules. 27. 3943-3954 (1994)

[文献書誌] Masaoki Takahashi: "Dynamic Viscoelasticity and Critical Exponents in Sol-Gel Transition of an End-Linking Polymer" Journal of Chemical Physics. 101. 798-804 (1994)

[文献書誌] K.Urayama: "Stress Relaxation and Creep of Polymer Gels in Solvent under Uniaxial and Biaxial Deformations" Rheologica Acta. 33. 89-98 (1994)

[文献書誌] Akihiko Koike: "Dynamic Viscoelasticity of End-Linking α,ω-Dimethyl Silyl Poly(propyleneoxide)Solutions near the Gel Point" Polymer. 35. 3005-3010 (1994)

[文献書誌] Tsutomu Tomari: "Swelling Dynamics of a Gel Undergoing Volume Transition" Journal of the Physical Society of Japan. 63. 2093-2101 (1994)

[文献書誌] Masamichi Kobayashi: "Structure of Physical Gels Formed in Syndiotactic Polystyrene/Solvent Systems Studied by Small-Angle Neutron Scattering" Macromolecules. 27. 1349-1354 (1994)

[文献書誌] Pingfan Chen: "Effect of Scission of Hydrogen Bonds by Phenol on Phase Behavior and Physical Properties of Polydiacetylene Gels:P(3BCMU)and P(4BCMU)" Polymer. 34. 4953-4960 (1994)

[文献書誌] T.Ohta: "Dynamics of Phase-Separated Fluids under External Fields" International Journal of Thermophyics. 15. 1135-1143 (1994)

[文献書誌] Takao Ohta: "Domain-Lattice Ordering in Microphase Separated Copolymers" Physical Review B. (印刷中).

[文献書誌] Elisha Moses: "Shear Microscopy of the "Butterfly Pattern"in Polymer Mixtures" Physical Review Letters. 72. 2037-2040 (1994)

[文献書誌] Satoshi Koizumi: "Spatial Distribution of Homopolymers in Block Copolymer Microdomains as Observed by a Combined SANS and SAXS Method" Macromolecules. 27. 7893-7906 (1994)

[文献書誌] Yasuhiro Mogi: "Superlattice Structures in Morphologies of the ABC Triblock Copolymers" Macromolecules. 27. 6755-6760 (1994)

[文献書誌] Irina Nyrkova: "Microdomain Structures in Polyelectrolyte Systems:Calculation of the Phase Diagrams by Direct Minimization of the Free Energy" Macromolecules. 27. 4220-4230 (1994)

[文献書誌] Akira Hatano: "Computer Simulations to Condensed Symmetric AB Diblock Copolymer Systems" Reports on Progress in Polymer Physics in Japan. 37. 279-282 (1994)

[文献書誌] H.Sato: "Phase Separation in a Dilute Polymer Solution in a Metastable Region" Physical Review E. 50. R1752-R1754 (1994)

[文献書誌] K.Kubota: "Critical Behavior of a Cationic Surfactant in an Aqueous Salt Solution" Journal of Chemical Physics. 100. 4543-4547 (1994)

[文献書誌] Naoshi Miyashita: "Critical Dynamics and Diffusion Behavior of Polymer Blend Solutions of Polystyrene/Poly(methylmethacrylate)/d^6-benzene" Journal of Chemical Physics. 100. 6028-6037 (1994)

[文献書誌] Kohzoh Shiokawa: "Chain Dimensions of a Polymer Confined between Two Interacting Plates" Polymer Journal. 26. 688-693 (1994)

[文献書誌] Masami Kawaguchi: "Poly(N-isopropylacrylamide)Films at the Air-Water Interface" Macromolecules. 27. 5882-5884 (1994)

[文献書誌] Masami Kawaguchi: "Effects of Polymer Adsorption and Desorption on Rheological Properties of Silica Suspensions" Colloid Surfaces A:Physicochemical and Engineering Aspects. 86. 283-289 (1994)

1994 年度実績報告書

寺本明夫大阪大学, 理学部, 教授 (00028151)