1994 年度実績報告書

有機金属共役系の構築と物性への展開

研究課題

研究課題/領域番号	06101004
研究機関	岡崎国立共同研究機構
研究代表者	中村晃岡崎国立共同研究機構, 分子科学研究所, 教授 (80029404)
研究分担者	中野雅由大阪大学, 理学部, 助手 (80252568) 岡村高明大阪大学, 理学部, 助手 (90252569) 真島和志大阪大学, 基礎工学部, 助教授 (70159143) 武田定大阪大学, 理学部, 助手 (00155011) 森和亮大阪大学, 理学部, 助教授 (60029709)
キーワード	有機金属共役系 / 金属-金属多重結合 / 水素結合 / 磁性 / 固体NMR / 分子軌道計算 / シクロペンタジエンル
研究概要	1.金属の直線状多核錯体の合成としてPt-Mo-Mo-Pt四核構造の両端にアセチリドを結合させることに成功した。これは有機共役系でつないだ有機金属共役系への鍵となる化合物である。また、磁性的に興味もたれる第一遷移金属のd軌道共役系としてクロム二核錯体を合成し異常な磁性を示すことを見出した。またPt-Cr-Cr-Ptの様な四核錯体なと類似系についても現在合成を行っている。 2.アジピン酸や二重結合を有するジカルボン酸を配位子としCu-Cu結合を持つと考えられる新規三次元多核鋼錯体を合成し磁性を測定した。 3.シクロペンタジエニル(Cp)基を有するジルコニウムのs-トランス-ジエン分岐状複合体、新規s-トランス-トリエン複合体か金属dπ-有機pπの複合共役電子系による顕著なサーモクロミズムを示すことを見出した。これがCp環のトンネル回転によることを低温固体NMRにより明らかにした。 4分子内二重NH・・・SあるいはNH・・・0水素結合を持つ新規配位子を合成し鉄、コバルト、ニッケル、モリブデン、パラジウムなどの金属錯体を合成した。NH・・・S水素結合が金属一硫黄結合を安定化させ金属イオンの酸化還元電位の顕著な正側シフトを起こすこと、金属-硫黄結合の電子状態をNH・・・Sの角度で制御し得ることを見出した。またNH・・・0水素結合を持つ鉄錯体では結晶状態で分子間の3次元水素結合ネットワークが形成され、極低温において金属間の水素結合を通したと考えられる磁気的相互作用のあることを確認した。 5.有機金属共役系の非線形光学効果の新しい計算方法として、厳密数値解を計算できるLioville方程式に基づく非摂算動論的方法や、非線形光学効果のメカニズム解析のための方法論を開発した。

研究成果
(42件)

すべてその他

すべて文献書誌 (42件)

[文献書誌] H.Oku,N.Ueyama,M.Kondo,A.Nakamura: "Oxygen Atom transfer Systems in Which the (μ-Oxo)dimolybdenum (V)Complexe For-mation Does Not Occurs:Synteses,Structures,and Reactivities of Monooxo…" Inorg.Chem.33. 209-216 (1995)
[文献書誌] W.・Y.Sun,T.Ueno,N.Ueyama,A.Nakamura: "19F NMR Investigation of Cobalt(11)Complexes with Cysteine-Containing Peptide Ligands" Magn.Reson.Chem.33(in press). (1995)
[文献書誌] N.Ueyama,M.Kondo,H.Oku,A.Nakamura: "Structure and Properties of(NEt4)2[MoIVO(α,2-toluenedithiolato)2]" Bull.Chem.Soc.JPn.67. 1840-1847 (1994)
[文献書誌] H.Oku,N.Ueyama,A.Nakamura,Y.Kai,N.Kanehisa: "The Stabilization Dioxomolybdenum(VI)Dithiolene Complex by the Electron Withdrawing Substituent on the Dithiolene Ligand:Comparison of-" Chem.Lett. 607-610 (1994)
[文献書誌] H.Zaima,N.Ueyama,H.Adachi,A.Nakamura: "IH,13C,113Cd NMR Study of Cd(11) Complexes of a blocked Peptide,Z-Cys-Ala-Pro-His-OMe in Organic Solvens" Biopolymers. (in press). (1994)
[文献書誌] N.Ueyama,H.Oku,T.Okamura,A.Nakamura,A.Kajiwara M.Kamachi: "ESR Study of(MoVO)3+and(WVO)3+Thiolate or Selenolate Complxes" Magn.Reson Medicine. 6. 216-217 (1995)
[文献書誌] K.Mashima,K.Kusano,Y.Matsumura,N.Sato,et al.: "Cationic BINAP-Ru(11)Halide Complexes:Highly efficient Catalysts for Stereoselective Asymmetric Hydrogenation of α-and β-Functionalized Ketones." J.Org.Chem.59. 3064-3076 (1994)
[文献書誌] X.Zhang,K.Mashima,K.Koyano,N.Sayo, et al.: "Synthesis of Partially Hydrogenated BINAP Ligands and their APPlication to Catalytic Asymmetric Hydrogenation." J.Chem.Soc.,Perkin Trans.I,. 2309-2322 (1994)
[文献書誌] K.Mashima,Y.Nakayama,A.Nakamura,N.Kanehisa,et al.: "A new convenient preparation of monocyclooctatetraenyl-lanthanide complexesfrom metallic lanthanides and oxidants." J.Organomet.Chem.,. 473. 85-91 (1994)
[文献書誌] K.Mashima,H.Sugiyama,H.Yasuda,N.Kanehisa,et al.: "Diene Complexes of Calcium and Strontium:The First Crystal Structures of Calcium and Strontium-diene Complexes,M(2,3-dimethyl-1,4-diphenyl-1,3-butadiene)(thf)" J.Am.Chem.Soc. 116. 6977-6978 (1994)
[文献書誌] K.Mashima,Y.Nakayama,H.Fukumoto,N.Kaneehisa,et al: "Selective Formation of Ln(11)and Ln(111)Thiolate Complexes Derived From Metals and Organic Disulfides:Crystal Structures of[Ln(SAr)(m-SAr)(thf)3]_2(Ln=Sm,Eu)," J.Chem.Soc.,Chem Commun.,. 1847-1848 (1994)
[文献書誌] K.Mashima,H.Sugiyama,and A.Nakamura,: "Diene Complex of Lanthanum:The Crystal Structure of a Diene-bridged Dilanthanum Complex,[LaI_2(thf)_3(m-h^4:h^4-PhCH=CHCH=CHPh)laI_2(thf)_3}." J.Chem.Soc.,Chem Commun.,. 1581-1582 (1994)
[文献書誌] K.Mashima,S.Fujikawa,H.Urata,E.Tanaka,et al.: "Polyethylene with Extremely NarrowPolydispersity:New Catalyst Systems of Nb(h5-C5Me5)(h4-diene)C12/MAO and Nb(h5-C5Me5)(h4-diene)2/MAO" J.Chem.Soc.,Chem.Commun.1623-1624 (1994)
[文献書誌] W.A.Herrmann,M.J.A.Morawietz,K.Mashima,et al: "Cyclische Amine als Intramolekulare Hilfsliganden in p-Komplexen des Titans." J.Orgnomet.Chem.486. 291-295 (1995)
[文献書誌] K.Mashima,S.Fujikawa,Y.Tanaka,Y.Urata,et al.: "Living Polymerization of Ethylene Catalyzed by Diene Complexes of Niobium and Tantalum,M(h5-C5Me5)(h4-diene)X2andM(h5-C5Me5)(h4-diene)2(M=Nb and Ta)" Organometallics,. (in press).
[文献書誌] K.Mashima and A.Nakamura,: "Living PoIymerization of Ethyleneby Organometallic Complexes(inJapanese)." Shokubai. 572-579 (1994)
[文献書誌] K.Mashima: "Diene Complexes of Group2-5Metals:Synthesis,Structure,and Reactivity(inJapanese)." J.Synth.Org.Chem.Jpn.52. 1053-1062 (1994)
[文献書誌] A.Nakamura and K.Mashima: "Recent Rrogress in the Chemistry of l,3-Diene Complexes of Niobium and Tantalum." J.Organometal.Chem. 500(in press).
[文献書誌] T.lnabe,I.Luneau,T.Mitani,Y.Maruyama,S.Takeda: "Prpton Transfer in the N-(2-Hydroxy-1-naphthylidene)-1-pyrenylamine and N,N^1-Di(2-hydroxy-1-naphthylidene)-p-phenylenediamine Crystals." Bull.Chem.Soc.Jpn.67. 612-621 (1994)
[文献書誌] B.Nagasaka,S.Takeda,N.Nakamura: "Residual Dipole Splittings in 13C- CP/MAS NMR Spectra Due to Quadrupolar Halogen Nuclei in Uracil Halides." Chem.Phys.Lett.222. 486-492 (1994)
[文献書誌] K.Miyakubo,S.Takeda,N.Nakamura: "Crystal Structure of Potassimum Hydrogen Terephtalate;Symmetric Hydrogen Bond in One-Dimensional Chain." Bull.Chem.Soc.Jpn.67. 2301-2303 (1994)
[文献書誌] T.Ohtsubo,Y.Nakayama,T.Izumikawa,S.Takeda,et al: "Precise Measurement of the Quadrupole Moment of β-Emitting 12B." Hyperfine interactions. 88. 25-33 (1994)
[文献書誌] S.Tskeda,H.Kataoka,K.Shibata,S.Ikeda,T.Matsuo, et al.: "Quantum Precession of HCI Moleculein Hydroquinone Clathrate." PhysicaB. 202. 315-319 (1994)
[文献書誌] S.Nagatomo,S.Takeda,K.Yamaguchi,M,Iwata et al.: "New Cation Diffusing Phase of(CH3NH3)5Bi2CIll" J.Phys.Soc.Jpn.67. 391-394 (1995)
[文献書誌] S.Takeda,T.Inbe,T.Mitani,Y.Maruyama,K.Yamagychi: "ESR Study on the Charge Transfer Complexs of N-Salicylideneaniline Containing NHO Hydrogen Bond as a Dynamic Function" Synthetic Metals. (in press).
[文献書誌] K.Yakusi, I.Shirotani,I.I.Khairullin,S.Takeda,et al.: "Characterization of Poly-CuPc Sheet Polymers Synthesized under High Pressure" Synthetic Metals(in press).
[文献書誌] M.Fujiwara,W.Mori,and K.Yamagauchi20GB27:Magnetic Properties of Hetero Polymetallic Systems.: Synthetic Metals (in press). (in press).
[文献書誌] W.Mori,snd K.Yamaguchi: "Spin Glass Behavior of Synthetic Atacamite,Cu2Cl(OH)3" Molecular Crystals and Liquid Crystals. (in press).
[文献書誌] S.Yamanaka,M.Okumura,M.Nakano and K.Yamaguchi: "EHF THOERY OF CHEMICAL REACTIONS Part4.UNO-CASSCF,UNO CASPT2 and R(U)HF coupled-cluster(CC)wavefunctions" J.Mol.Structure(Theochem). 310. 205-218 (1994)
[文献書誌] M.Nakano,K.Yamaguchi and T.Fueno: "Coupled-Hartree-Fock calculations of the hyperpolarizabilities for mixed and segregated charge-transfer clusters" Nonlinear Optics. 6. 289-296 (1994)
[文献書誌] H.Takahashi,H.Ohoyama,T.Kasai,K.Kuwata,M.Nakano: "A theoretical study on the electron exchange mechange in the CF3H+Ar(3P)→CF3*+H+Ar reaction" Chem.Phys.Lett.224. 445-450 (1994)
[文献書誌] M.Nakanq and K.Yamaguchi: "THEORETICAL STUDIES FOR THIRD-ORDER HYPERPOLARIZABILITIES OF ALTERNANT AND CONDENSED-RING CONJUGATED SYSTEMS I" Mol.Cryst.Liq.Cryst.A255. 139-148 (1994)
[文献書誌] M.Nakano and K.Yamaguchi: "Numerical Liouville approach.A calculation method of nonlinear optical susceptibilities of N-state systems" Phys.Rev.A. 50. 2989-3004 (1994)
[文献書誌] H.Takahashi,H.Ohoyama,T.Kasai,K.Kuwata,M.Nakano: "Orientation dependences of transition matrix elements for energy transfer reaction CF3H+Ar(3P)→CF3^*+H+Ar reaction" Chem.Lett. 1985-1988 (1994)
[文献書誌] M.Nakano,K.Yamaguchi,Y.Matuzaki,K.Tanaka and T.: "Numerical Liouville approach;Third-order nonlinear optical susceptibilities in THG,EFISH and" Chem.Phys. Lett.233. 411-419 (1995)
[文献書誌] M.Nakano,K.Yamaguchi,Y.Matuzaki,K.Tanaka and T: "Numerical Liouville approach;Formulation of third-order nonlinear optical susceptibilities" J.Chem.Phys.102. 2986-2995 (1995)
[文献書誌] M.Nakano, K.Yamaguchi,Y.Matuzaki,K.Tanaka and T.: "Numerical Liouville approach;Three-type analysis of virtual excitation processes of third-order nonlinear optical spectra in third-harmonic generation" J.Chem.Phys.102. 2996-3004 (1995)
[文献書誌] M.Nakano,K.Yamaguchi: "Numerical Liouville approach;Intensity dependent transient linear and nonlinear optical susceptibilities" Chem.Phys.Lett.(in press).
[文献書誌] M.Nakano,S.Yamada and K.Yamaguchi20GB39:Theoretical Studies on Hyperpolarizabilitiues of Nitroxide Species I.: Synt.Metals,. (in press).
[文献書誌] Y.Matuzaki,M.Nakano, K.Yamaguchi,K.Tanaka and T.: "Second hyperpolarizabilies of π-conjugated silicon-ring polymers" Synt.Metals. (in press).
[文献書誌] A.Nakamura,N.Ueyama: "Iron-Sulfur Models of Protein Active Sites in Encyclopedia of Inorganic" R.B.King,John Wiley, 1883-1896 (1994)
[文献書誌] A.Nakamura,N.Ueyama: "Chemical Functions of Single and Double NH-S Hydrogen Bond in Iron-Snlfur Metalloproteins;-in Nuclear Magnetic Resonance of Paramagnetic Molecules" NATO ASI Series(in press), (1995)

1994 年度 実績報告書

有機金属共役系の構築と物性への展開

研究代表者

中村 晃 岡崎国立共同研究機構, 分子科学研究所, 教授 (80029404)

研究成果

[文献書誌] H.Oku,N.Ueyama,M.Kondo,A.Nakamura: "Oxygen Atom transfer Systems in Which the (μ-Oxo)dimolybdenum (V)Complexe For-mation Does Not Occurs:Synteses,Structures,and Reactivities of Monooxo…" Inorg.Chem.33. 209-216 (1995)

[文献書誌] W.・Y.Sun,T.Ueno,N.Ueyama,A.Nakamura: "19F NMR Investigation of Cobalt(11)Complexes with Cysteine-Containing Peptide Ligands" Magn.Reson.Chem.33(in press). (1995)

[文献書誌] N.Ueyama,M.Kondo,H.Oku,A.Nakamura: "Structure and Properties of(NEt4)2[MoIVO(α,2-toluenedithiolato)2]" Bull.Chem.Soc.JPn.67. 1840-1847 (1994)

[文献書誌] H.Oku,N.Ueyama,A.Nakamura,Y.Kai,N.Kanehisa: "The Stabilization Dioxomolybdenum(VI)Dithiolene Complex by the Electron Withdrawing Substituent on the Dithiolene Ligand:Comparison of-" Chem.Lett. 607-610 (1994)

[文献書誌] H.Zaima,N.Ueyama,H.Adachi,A.Nakamura: "IH,13C,113Cd NMR Study of Cd(11) Complexes of a blocked Peptide,Z-Cys-Ala-Pro-His-OMe in Organic Solvens" Biopolymers. (in press). (1994)

[文献書誌] N.Ueyama,H.Oku,T.Okamura,A.Nakamura,A.Kajiwara M.Kamachi: "ESR Study of(MoVO)3+and(WVO)3+Thiolate or Selenolate Complxes" Magn.Reson Medicine. 6. 216-217 (1995)

[文献書誌] K.Mashima,K.Kusano,Y.Matsumura,N.Sato,et al.: "Cationic BINAP-Ru(11)Halide Complexes:Highly efficient Catalysts for Stereoselective Asymmetric Hydrogenation of α-and β-Functionalized Ketones." J.Org.Chem.59. 3064-3076 (1994)

[文献書誌] X.Zhang,K.Mashima,K.Koyano,N.Sayo, et al.: "Synthesis of Partially Hydrogenated BINAP Ligands and their APPlication to Catalytic Asymmetric Hydrogenation." J.Chem.Soc.,Perkin Trans.I,. 2309-2322 (1994)

[文献書誌] K.Mashima,Y.Nakayama,A.Nakamura,N.Kanehisa,et al.: "A new convenient preparation of monocyclooctatetraenyl-lanthanide complexesfrom metallic lanthanides and oxidants." J.Organomet.Chem.,. 473. 85-91 (1994)

[文献書誌] K.Mashima,H.Sugiyama,H.Yasuda,N.Kanehisa,et al.: "Diene Complexes of Calcium and Strontium:The First Crystal Structures of Calcium and Strontium-diene Complexes,M(2,3-dimethyl-1,4-diphenyl-1,3-butadiene)(thf)" J.Am.Chem.Soc. 116. 6977-6978 (1994)

[文献書誌] K.Mashima,Y.Nakayama,H.Fukumoto,N.Kaneehisa,et al: "Selective Formation of Ln(11)and Ln(111)Thiolate Complexes Derived From Metals and Organic Disulfides:Crystal Structures of[Ln(SAr)(m-SAr)(thf)3]_2(Ln=Sm,Eu)," J.Chem.Soc.,Chem Commun.,. 1847-1848 (1994)

[文献書誌] K.Mashima,H.Sugiyama,and A.Nakamura,: "Diene Complex of Lanthanum:The Crystal Structure of a Diene-bridged Dilanthanum Complex,[LaI_2(thf)_3(m-h^4:h^4-PhCH=CHCH=CHPh)laI_2(thf)_3}." J.Chem.Soc.,Chem Commun.,. 1581-1582 (1994)

[文献書誌] K.Mashima,S.Fujikawa,H.Urata,E.Tanaka,et al.: "Polyethylene with Extremely NarrowPolydispersity:New Catalyst Systems of Nb(h5-C5Me5)(h4-diene)C12/MAO and Nb(h5-C5Me5)(h4-diene)2/MAO" J.Chem.Soc.,Chem.Commun.1623-1624 (1994)

[文献書誌] W.A.Herrmann,M.J.A.Morawietz,K.Mashima,et al: "Cyclische Amine als Intramolekulare Hilfsliganden in p-Komplexen des Titans." J.Orgnomet.Chem.486. 291-295 (1995)

[文献書誌] K.Mashima,S.Fujikawa,Y.Tanaka,Y.Urata,et al.: "Living Polymerization of Ethylene Catalyzed by Diene Complexes of Niobium and Tantalum,M(h5-C5Me5)(h4-diene)X2andM(h5-C5Me5)(h4-diene)2(M=Nb and Ta)" Organometallics,. (in press).

[文献書誌] K.Mashima and A.Nakamura,: "Living PoIymerization of Ethyleneby Organometallic Complexes(inJapanese)." Shokubai. 572-579 (1994)

[文献書誌] K.Mashima: "Diene Complexes of Group2-5Metals:Synthesis,Structure,and Reactivity(inJapanese)." J.Synth.Org.Chem.Jpn.52. 1053-1062 (1994)

[文献書誌] A.Nakamura and K.Mashima: "Recent Rrogress in the Chemistry of l,3-Diene Complexes of Niobium and Tantalum." J.Organometal.Chem. 500(in press).

[文献書誌] T.lnabe,I.Luneau,T.Mitani,Y.Maruyama,S.Takeda: "Prpton Transfer in the N-(2-Hydroxy-1-naphthylidene)-1-pyrenylamine and N,N^1-Di(2-hydroxy-1-naphthylidene)-p-phenylenediamine Crystals." Bull.Chem.Soc.Jpn.67. 612-621 (1994)

[文献書誌] B.Nagasaka,S.Takeda,N.Nakamura: "Residual Dipole Splittings in 13C- CP/MAS NMR Spectra Due to Quadrupolar Halogen Nuclei in Uracil Halides." Chem.Phys.Lett.222. 486-492 (1994)

[文献書誌] K.Miyakubo,S.Takeda,N.Nakamura: "Crystal Structure of Potassimum Hydrogen Terephtalate;Symmetric Hydrogen Bond in One-Dimensional Chain." Bull.Chem.Soc.Jpn.67. 2301-2303 (1994)

[文献書誌] T.Ohtsubo,Y.Nakayama,T.Izumikawa,S.Takeda,et al: "Precise Measurement of the Quadrupole Moment of β-Emitting 12B." Hyperfine interactions. 88. 25-33 (1994)

[文献書誌] S.Tskeda,H.Kataoka,K.Shibata,S.Ikeda,T.Matsuo, et al.: "Quantum Precession of HCI Moleculein Hydroquinone Clathrate." PhysicaB. 202. 315-319 (1994)

[文献書誌] S.Nagatomo,S.Takeda,K.Yamaguchi,M,Iwata et al.: "New Cation Diffusing Phase of(CH3NH3)5Bi2CIll" J.Phys.Soc.Jpn.67. 391-394 (1995)

[文献書誌] S.Takeda,T.Inbe,T.Mitani,Y.Maruyama,K.Yamagychi: "ESR Study on the Charge Transfer Complexs of N-Salicylideneaniline Containing NHO Hydrogen Bond as a Dynamic Function" Synthetic Metals. (in press).

[文献書誌] K.Yakusi, I.Shirotani,I.I.Khairullin,S.Takeda,et al.: "Characterization of Poly-CuPc Sheet Polymers Synthesized under High Pressure" Synthetic Metals(in press).

[文献書誌] M.Fujiwara,W.Mori,and K.Yamagauchi20GB27:Magnetic Properties of Hetero Polymetallic Systems.: Synthetic Metals (in press). (in press).

[文献書誌] W.Mori,snd K.Yamaguchi: "Spin Glass Behavior of Synthetic Atacamite,Cu2Cl(OH)3" Molecular Crystals and Liquid Crystals. (in press).

[文献書誌] S.Yamanaka,M.Okumura,M.Nakano and K.Yamaguchi: "EHF THOERY OF CHEMICAL REACTIONS Part4.UNO-CASSCF,UNO CASPT2 and R(U)HF coupled-cluster(CC)wavefunctions" J.Mol.Structure(Theochem). 310. 205-218 (1994)

[文献書誌] M.Nakano,K.Yamaguchi and T.Fueno: "Coupled-Hartree-Fock calculations of the hyperpolarizabilities for mixed and segregated charge-transfer clusters" Nonlinear Optics. 6. 289-296 (1994)

[文献書誌] H.Takahashi,H.Ohoyama,T.Kasai,K.Kuwata,M.Nakano: "A theoretical study on the electron exchange mechange in the CF3H+Ar(3P)→CF3*+H+Ar reaction" Chem.Phys.Lett.224. 445-450 (1994)

[文献書誌] M.Nakanq and K.Yamaguchi: "THEORETICAL STUDIES FOR THIRD-ORDER HYPERPOLARIZABILITIES OF ALTERNANT AND CONDENSED-RING CONJUGATED SYSTEMS I" Mol.Cryst.Liq.Cryst.A255. 139-148 (1994)

[文献書誌] M.Nakano and K.Yamaguchi: "Numerical Liouville approach.A calculation method of nonlinear optical susceptibilities of N-state systems" Phys.Rev.A. 50. 2989-3004 (1994)

[文献書誌] H.Takahashi,H.Ohoyama,T.Kasai,K.Kuwata,M.Nakano: "Orientation dependences of transition matrix elements for energy transfer reaction CF3H+Ar(3P)→CF3^*+H+Ar reaction" Chem.Lett. 1985-1988 (1994)

[文献書誌] M.Nakano,K.Yamaguchi,Y.Matuzaki,K.Tanaka and T.: "Numerical Liouville approach;Third-order nonlinear optical susceptibilities in THG,EFISH and" Chem.Phys. Lett.233. 411-419 (1995)

[文献書誌] M.Nakano,K.Yamaguchi,Y.Matuzaki,K.Tanaka and T: "Numerical Liouville approach;Formulation of third-order nonlinear optical susceptibilities" J.Chem.Phys.102. 2986-2995 (1995)

[文献書誌] M.Nakano, K.Yamaguchi,Y.Matuzaki,K.Tanaka and T.: "Numerical Liouville approach;Three-type analysis of virtual excitation processes of third-order nonlinear optical spectra in third-harmonic generation" J.Chem.Phys.102. 2996-3004 (1995)

[文献書誌] M.Nakano,K.Yamaguchi: "Numerical Liouville approach;Intensity dependent transient linear and nonlinear optical susceptibilities" Chem.Phys.Lett.(in press).

[文献書誌] M.Nakano,S.Yamada and K.Yamaguchi20GB39:Theoretical Studies on Hyperpolarizabilitiues of Nitroxide Species I.: Synt.Metals,. (in press).

[文献書誌] Y.Matuzaki,M.Nakano, K.Yamaguchi,K.Tanaka and T.: "Second hyperpolarizabilies of π-conjugated silicon-ring polymers" Synt.Metals. (in press).

[文献書誌] A.Nakamura,N.Ueyama: "Iron-Sulfur Models of Protein Active Sites in Encyclopedia of Inorganic" R.B.King,John Wiley, 1883-1896 (1994)

[文献書誌] A.Nakamura,N.Ueyama: "Chemical Functions of Single and Double NH-S Hydrogen Bond in Iron-Snlfur Metalloproteins;-in Nuclear Magnetic Resonance of Paramagnetic Molecules" NATO ASI Series(in press), (1995)

1994 年度実績報告書

中村晃岡崎国立共同研究機構, 分子科学研究所, 教授 (80029404)