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1996 年度 実績報告書

固体表面における光反応と光触媒反応

研究課題

研究課題/領域番号 06239110
研究機関大阪府立大学

研究代表者

安保 正一  大阪府立大学, 工学部, 教授 (70094498)

研究分担者 小嶋 政信  信州大学, 農学部, 助教授 (20153538)
田中 庸裕  京都大学, 工学部, 助手 (70201621)
桑畑 進  大阪大学, 工学部, 助教授 (40186565)
佐藤 真理  北海道大学, 触媒化学研究センター, 助教授 (70001724)
沢木 泰彦  名古屋大学, 工学部, 教授 (30023120)
堂免 一成  東京工業大学, 資源化学研究所, 教授 (10155624)
橋本 和仁  東京大学, 工学部, 助教授 (00172859)
川崎 昌博  北海道大学, 電子科学研究所, 教授 (70110723)
キーワード光化学 / 固体光触媒 / 反応ダイナミックス / 固体表面 / ミクロ空間 / ゼオライト / 光反応過程 / 光機能分子
研究概要

安保正一 : ゼオライトの細孔空間を利用し、新しい光触媒系の構築が可能であること、ゼオライト種や担持方法により、局所構造と光触媒特性が制御できることを明確にした。川崎昌博 : 表面吸着種と基板表面の関係について、各基板への吸着機構、光分解過程を角度分解型XPS法により研究し、吸着種が光吸収により表面脱離することが分かった。橋本和仁 : 微小電極を用いて、酸化チタン薄膜光触媒を用いた有機物の分解の酸化反応と還元反応の分離観察に初めて成功し、ジカル連鎖反応過程を明らかにした。堂免一成 : Ni(110)表面に吸着したCO分子をピコ秒の紫外(266nm)レーザーで励起したときの振動ダイナミクスをピコ秒の赤外・可視SFGをプローブとして検討した。沢木泰彦 : ハイドロタルサイト粘土にビニル安息香酸をインターカレートし、光重合の制御について検討し、シンジオタクチックの立体規則性が推定された。田中庸裕 : シリカ担持酸化バナジウムにアルカリイオンを添加すると、可視光を利用でき、気相酸素によるベンゼンの水酸化が効率良く進行することが見いだされた。小嶋政信 : ゼオライト細孔内での芳香族オレフィン・酸素分子間電荷移動錯体の形成への交換カチオン種、細孔径の大きさを検討し、プロトン付加や電子移動機構を解明した。佐藤真理 : 銀(111)面に物理吸着したペンタ鉄カルボニルの光分解について研究した結果、320nm付近では銀の表面プラズモン励起によって分解が促進されるがわかった。桑畑進 : 半導体超微粒子を固定した電極として、電気泳動電着によりTiO2超微粒子を固定した電極、自己集合単分子膜により、CdS超微粒子を共有結合した電極を調製した。

  • 研究成果

    (58件)

すべて その他

すべて 文献書誌 (58件)

  • [文献書誌] Masakazu Anpo: "In-situ Characterization of the Vanadium Silicalite-2 Catalyst and Its Photocatalytic Reactivity.," Stud. Surf. Sci. Catal.101. 941-950 (1996)

  • [文献書誌] Masakazu Anpo: "Photoinduced Surface Chemistry" Curent Opinion in Solid State & Materials Science. 1. 630-635 (1996)

  • [文献書誌] Hiromi Yamashita: "In Situ XAFS, photoluminescence, and IR Investigations of Copper Ions Included within Various Kinds of Zeolies. -Structure of Cu (I) Ions and Their Interaction with CO Molecules-" J. Phys. Chem.100. 397-402 (1996)

  • [文献書誌] Hiromi Yamashita: "Photocatalytic Direct Decomposition of NO on Titanium Oxides Included within Y-Zeolites at 275K : The Structre and Role of the Active Sites.," J. Phys. Chem.100. 16041-16044 (1996)

  • [文献書誌] Hiromi Yamashita: "Photocatalytic Degradation of 1-Octanol on Anchored Titanium Oxide and on TiO_2 Powder Catalysts.," J. Catal.158. 97-101 (1996)

  • [文献書誌] Hiromi Yamashita: "Photochemistry of Alkyl Ketones Included within the Zeolite Cavities : The Effect of Ion-exchanged Alkali Metal Cations and Types of Zeolites." Stud. Surf. Sci. Catal.105. 1141-1146 (1996)

  • [文献書誌] Masaya Matsuoka: "The Photocatalytic Decomposition of Nitric Oxide on the Ag/ZSM-5 Catalyst Prepared by Ion-exchange.," J. Mol. Catal. A : Chem.107. 399-403 (1996)

  • [文献書誌] Shu Guo Zhang: "Photoluminescence Property of Titanium Silicalite-2 Catalysts and Its Photocatalyic Reactivity for the Direct Decomposition of NO at 295K.," Chem. Lett.895-896 (1996)

  • [文献書誌] Yuichi Ichihashi: "The In-situ Characterization of Titanium Oxides Prepared the Zeolite Cavities and Framework and Their Photocatalytic Reactivities for the Direct Decomposition of NO into N_2 at 275K.," Stud. Surf. Sci. Catal.105. 1609-1616 (1996)

  • [文献書誌] 安保正一: "光触媒による環境浄化と可視光利用への挑戦" ファインケミカル. 25. 39-51 (1996)

  • [文献書誌] 山下弘巳: "EXAFS/XANESによる局所構造の解析" 色材協会誌. 69. 266-281 (1996)

  • [文献書誌] 山下弘巳: "ゼオライトによる光化学反応の制御" 表面科学. 17. 270-275 (1996)

  • [文献書誌] 市橋祐一: "環境問題と関連した酸化チタン系光触媒の研究動向と可視光化の試み" 機能材料. 16. 25-35 (1996)

  • [文献書誌] 市橋祐一: "ゼオライト細孔内での光触媒反応(2)酸化チタンや酸化バナジウム上での光触媒反応" 表面. 34. 516-526 (1996)

  • [文献書誌] 松岡雅也: "銀(I)ゼオライト触媒によるNOの常温での光触媒分解" 触媒. 38. 434-437 (1996)

  • [文献書誌] 張樹国: "V-シリカライト-2の発光特性と光触媒活性" 触媒. 38. 86-89 (1996)

  • [文献書誌] Sang Chul Moon: "Characterization of Zirconium-Silicon Binary Oxide Catalysts Prepared by the Sol-Gel Method and Their Photocatalytic Activity for the Isomerization of 2-Butene.," J. Phys. Chem.101. 369-373 (1997)

  • [文献書誌] 安保正一: "NOx除去を目指した高活性な酸化チタンおよび可視光で作用する第2世代の酸化チタン光触媒の開発," ペロテック. 20. 66-72 (1997)

  • [文献書誌] Hiromi Yamashita: "Photocatalytic Decomposition of NO at 275K on Titanium Oxide Catalysts Anchored within Zeolite Cavities and Frameworks.," Appl. Surf. Sci.(in press). (1997)

  • [文献書誌] Masakazu Anpo: "The Design of Photocatalysts for the Removal of NOx at Normal Temperatures Copper (I) and Silver (I) Ion Catalysts Anchores within Zeolite Cavities.," Res. Chem. Intermed.(in press). (1997)

  • [文献書誌] Masakazu Anpo: "Design of the Photocatalysts within Zeolite Frameworks and Cavities for the Decomposition of NO into N_2 and O_2 at Normal Temperaure.," Catal. Today. (in press). (1997)

  • [文献書誌] Masakazu Anpo: "Photocatalysis on Titanium Oxide Catalysts Appoaches in Achieving Highy Efficient Reactions and Realizing the Use of Visible Light," Japanese Catalysis Surveys. (in press). (1997)

  • [文献書誌] T.Tanaka: "Photo-assisted Oxidation of 2-Methylpropane over Rb+-Modified V2O5/SiO2. Formation of 2-Methylpropan-2-Methylpropane and O2," J. Chem. Soc.,Faraday Trans.,. 92. 1975-1979 (1996)

  • [文献書誌] T.Tanaka: "Fine Structure in Phosphorescence Spectra of Silica-alumina," J. Chem. Son.,Chem. Commun.,. 1153-1154 (1996)

  • [文献書誌] T.Tanaka: "Photooxidation of Propylene by O2 over Silica and Mg-loaded Silica," J. Chem. Soc.,Chem. Commun.2125-2126 (1996)

  • [文献書誌] T.Tanaka: "Selevtive Partial Oxidation of Light Alkanes over Alkali-Ion-Modified Silica-supported Vanadium Oxides excited with Visible Light," Catal. Lett.(in press). (1997)

  • [文献書誌] M.Kojima: "Dimerization of 1-Phenylcycloalkene Cation Radicals Dependent on their Structure," J. Am. Chem. Soc.Vol.118 No.11. 2612-2617 (1996)

  • [文献書誌] M.Kojima: "F2 Laser (158 nm) Photolysis of CO2 and Hydrofluorocarbon Systerns," J. Photochem. Photobiol. A : Chem.95. 197-202 (1996)

  • [文献書誌] M.Kojima: "A New Synthesis of 5-Aminolevrinic Acid via Dye Sensitized Oxygenation of N-Furfurylphthalimide," J. Photochem. Photobiol. A : Chem.94. 167-171 (1996)

  • [文献書誌] K.Domen: "Vibrational relaxation of hydroxyl groups in zeolite : the effect of adsorbed Xe" Surf. Sci.363,. 397-402 (1996)

  • [文献書誌] K.Domen: "The effect of adsorbed noble gas atoms on vibrational relaxation of hydroxyl group in zeolite" J. Chem. Phys.105. 279-288 (1996)

  • [文献書誌] K.Domen: "Transient absorption spectra of vibrationally excited OH/OD groups in mordenite zeolite : Effect of Xe adsorption" J. Chem. Phys.105. 6665-6672 (1996)

  • [文献書誌] K.Domen: "Population lifetime of the OH stretching band of water molecules on zeolite surfaces" Chem. Phys. Lett.261. 534-538 (1996)

  • [文献書誌] S.Sato: "Photochemistry of iron pentacarbonyl adsorbed on Au (111)." J. Phys. Chem.100. 14769-14775 (1996)

  • [文献書誌] S.Sato: "Size effects of platinum particles on the electroreduction of oxygen." Electrochim. Acta.41. 2595-2600 (1996)

  • [文献書誌] S.Sato: "Infrared reflection absorption spetra of Fe (CO)5 adsorbed on Au surfaces." J. Electron Spectrosc. Relat. Phenom.(in press). (1996)

  • [文献書誌] 安保正一: "ホトルミネッセンス分光法の触媒研究への応用" 触媒. 39. 45-49 (1997)

  • [文献書誌] Masakazu Anpo: "Photocatalytic Reduction of CO_2 with H_2O on Titanium Oxides Anchored within Micropores of Zeolites : Effects of the Structure of the Active Sites and the Addition of Pt.," J. Phys. Chem.(in press). (1997)

  • [文献書誌] Masakazu Anpo: "The Photocatalytic Decomposition of Nitric Oxide on the Ag/ZSM-5 Catalyst Prepared by the Ion-Exchange Method.," Catal. Today. (in press). (1997)

  • [文献書誌] Hiromi Yamashita: "XAFS Studies on The Metal Ion (Cu, Ag) Photocatalysts Prepared within Zeolite Cavities Using an Ion-Exchange Method.," J. de Phys. IV (Colloq.). (in press). (1997)

  • [文献書誌] Masaya Matsuoka: "Local Structures of Copper Ion Catalysts Anchored onto Various Oxide Supports and Their Photocatalytic Reactivities for the Decomposition of N_2O at 295K-In Situ XAFS.," J. de Phys. IV (Colloq.). (in press). (1997)

  • [文献書誌] Yuichi Ichihashi: "Relationship Between The Local Structures of Titanium Oxide Photocatalysts and Their Reactivites-XAFS, UV, Photoluminescence and Photoreaction Investigations-"." J. de Phys. IV (Colloq.). (in press). (1997)

  • [文献書誌] K.Hashimoto: "Photocatalytic bactericidal Effect of TiO2 Thin Film : Dynamic View for the Active Oxygen Species Responsible for the Effect" J. Photochem. Photobiol.(in press). (1996)

  • [文献書誌] K.Hashimoto: "Studies on Photocatalytic Reactions involving radical Chain Reactions using Microelectrodes" J. Phys. Chem.(in press). (1996)

  • [文献書誌] M.Kawasaki: "Chemical dry etching mechanisms of GaAs surface by HCl and Cl2." J. Vac. Sci. Technol. B. 14. 3230-3238 (1996)

  • [文献書誌] M.Kawasaki: "Photodissociation of adsorbed diemthylcadmium at 193 nm." Jpn. J. Appl. Phys.35. 5879-5881 (1996)

  • [文献書誌] M.Kawasaki: "Ion fragment imaging of the ion-pair photodissociation of CH3Cl, CH3Br, C2H5Cl and C2H5Br near 118 nm." J. Phys. Chem.101. 1222-1226 (1997)

  • [文献書誌] M.Kawasaki: "Photofragment imaging of CH3Br+from (CH3Br)2+ at 355 nm." J. Phys. Chem.101. 1227-1230 (1996)

  • [文献書誌] S.Kuwabata: "Effects of Adsorbents Used as Supports for Titanium Dioxide Loading on Photocatalytic Degradation of Propyzamide" Environ. Sci. Technol.30(4). 1275-81 (1996)

  • [文献書誌] S.Kuwabata: "Photoimage Formation in TiO2 Particles-incorporated Prussian Blue Film" J. Electrochem. Soc.143(11). 3462-3465 (1996)

  • [文献書誌] S.Kuwabata: "EQCM Studies on Polypyrrole in Aqueous Solutions" J. Electroanal. Chem.(in press). (1997)

  • [文献書誌] S.Kuwabata: "Characterization of Covalently Immobilized Q-CdS Particles on Au(111) by Scanning Tunneling Microscopy and Tunneling Spctroscopy with High Reproducibility" Langmuiri. (in press). (1997)

  • [文献書誌] K.Hashimoto: "An Efficient TiO2 Thin Film Photocatalyst : Photocatalytic properties in Gas-Phase Acetaldehyde Degradation" J. Photochem. Photobiol.98. 79-86 (1996)

  • [文献書誌] K.Hashimoto: "A Film-Type Photocatalyst Incorporating Highly Active TiO2 Powder and Fluoresin Binder : Photocatalytic Activity and Long-Term Stability." J. Electroanal.415. 183-186 (1996)

  • [文献書誌] Masakazu Anpo: "Surface Photochemistry" J. Wiley & Sons Inc., 173 (1996)

  • [文献書誌] 安保正一: "光化学エネルギー変換-基礎と応用-" IPC (印刷中), (1997)

  • [文献書誌] 安保正一: "触媒技術の動向と展望1997" 触媒学会 (印刷中), (1997)

  • [文献書誌] 橋本和仁: "光クリーン革命:酸化チタン光触媒が活躍する" シ-・エム・シ-出版, 155 (1997)

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公開日: 1999-03-08   更新日: 2016-04-21  

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