1996 年度実績報告書

表面電子励起と反応素過程

研究課題

研究課題/領域番号	07304031
研究機関	電気通信大学
研究代表者	村田好正電気通信大学, 電気通信学部, 教授 (10080467)
研究分担者	中辻博京都大学, 大学院・工学系研究科, 教授 (90026211) 並木章九州工業大学, 工学部, 教授 (40126941) 太田俊明東京大学, 大学院・理学系研究科, 教授 (80011675) 潮田資勝東北大学, 電気通信研究所, 教授 (90176652) 興地斐男大阪大学, 大学部・工学研究科, 教授 (20029002)
キーワード	表面電子励起 / 反応素過程 / 非平衡原子線・分子線 / 光励起脱離 / 非断熱過程 / 理論と実験 / 表面反応 / 励起状態
研究概要	表面物性の研究は急速に進展し、表面の原子配列や電子構造などの静的物性は方法論が確立し、多くの系に適用され、理解は大きく進展した。また熱平衡状態での表面反応も多くの研究者によって多角的に調べられてきている。本研究ではこのことをふまえ、次世代の研究の発展につながるものを目指した。それには表面物性の動的現象の典型例である表面上での原子の組み替えを、通常のアプローチとは異なる方法で取り組んだ。具体的には、表面電子励起に誘起された脱離と反応、非平衡な修飾原子線・分子線を用いた表面の動的現象を、実験と理論の両面から進めた。特に、金属表面上の反応に見られる高い反応選択性の原因を明らかにし、物性物理の見地から一般概念の確立を目指した。これは未だに解明されていない金属の触媒作用の本質の理解につながると思っている。また、生体をはじめさまざまに現れる電子系から格子系へのエネルギー転換過程の解明にも効果的である。直接観測できない反応の遷移状態を表面電子励起の側から眺めることで、光励起脱離、光化学反応に反応選択性に関連した成果を得ている。また非平衡の原子線と分子線の持つ特徴を生かして、表面反応が非平衡状態で進行している様子を追跡するため、非平衡ビームの作製が行われた。これを用いた表面物性の研究は緒についたところである。理論面からは、量子論の立場から励起状態と非断熱過程による脱励起を論じたり、励起状態や電子相関が関与する複雑な系を取り扱う必要がある。このように多くの困難を伴うが、夢のある研究領域を実験との協力のもとに、効果的に研究を進める方法を構築しはじめている。本研究に続く成果を期待したい。

研究成果
(31件)

すべてその他

すべて文献書誌 (31件)

[文献書誌] 村田好正他: "Selectivity of laser-induced desorption of NO and CO from transition metal surfaces" Zeitschrift fur Physikalische Chemie. 198. 149-156 (1997)
[文献書誌] 村田好正他: "Repulsive interaction of CO and a Pt surface derived from very-low-energy ion scattering" Surface Science. 363. 112-120 (1996)
[文献書誌] 潮田資勝他: "Surface SHG and photoemission from Cs/p-Ga As and the Cs/O_2/p-GaAs" Surface Science. 363. 385-390 (1996)
[文献書誌] 潮田資勝他: "Nanometer-scale characterization of surface materials by STM light emission spectroscopy" Applied Surface Science. 107. 247-254 (1996)
[文献書誌] 太田俊明他: "One-dimensional electronic states on stepped surfaces of Ni studied by ARUPS" Surface Science. 357/358. 238-241 (1996)
[文献書誌] 太田俊明他: "Adsorbate-substrate dynamics for C (2×2) Cl/Ni (100) : A SEXAFS Study" Surface Science. 371. 409-419 (1997)
[文献書誌] 松本吉泰他: "Laser-induced photochemistry of methane on Pt (111) : Excitation mechanism and dissociation dynamics" Journal of Chemical Physics. 105. 4775-4788 (1996)
[文献書誌] 松本吉泰他: "Absorbate-localized excitation in surface photo-chemistry : Methane on Pt (111)" Physical Review Letters. 76. 1751-1754 (1996)
[文献書誌] 福谷克之他: "Adsorption and Desorption of NO and CO on a Pt (111) -Ge surface alloy" Surface Science. 363. 185-194 (1996)
[文献書誌] 福谷克之他: "Interaction of Ultraviolet Photons with NO/Ni (111)" Surface Science. 363. 281-288 (1996)
[文献書誌] 並木章他: "Poisonous effect of alkali adatoms on Cl_2 sticleing" Surface Science. 363. 11-21 (1996)
[文献書誌] 並木章他: "Promoted O_2 sticleing on Li-covered Si (100)" Surface Science. 357/358. 684-689 (1996)
[文献書誌] 鳥養映子他: "Spin-polarized atomic beam as a probe of spin correlation at the topmost layer of surfaces" Springer Series in Solid-State Sciences. 121. 126-137 (1996)
[文献書誌] 有賀哲也他: "Restraint of NH_3 dissociation on oxygen-modified Mo (112)" Surface Science. 324. 17-24 (1995)
[文献書誌] 有賀哲也他: "Quantum glelocalization of H on Pd (110) : A vibrational study" Physical Review B. 53. 13767-13771 (1996)
[文献書誌] 興地斐男他: "Combined effect of molecular rotational-and surface vibrational excitations on the adsorption dynamics of D_2/Cu (111)" Surface Science. 363. 52-61 (1996)
[文献書誌] 興地斐男他: "Role of rotational motion in the dissociative adsorption and associative desorption dynamics" Physical Review Letters. 78. 286-289 (1997)
[文献書誌] 中辻博他: "Theoretical study on the photostimulated desorption of CO from a Pt surface" Journal Chemical Physics. 104. 714-726 (1996)
[文献書誌] 名取晃子他: "Atomic structures of Ag on √<3>×√<3> Ag/Si (111) and on 7×7 Si (111)" Surface Science. 357/358. 47-50 (1996)
[文献書誌] 名取晃子他: "Atomic structures and atomic dynamics an 1×1 Si (111) at high temperatures" Surface Science. 367. 56-66 (1996)
[文献書誌] 馬越健次他: "An interpolation formular for electron transfer in atom-surface collision and its validity" Surface Science. 363. 145-149 (1996)
[文献書誌] 馬越健次他: "Second order selt-energy and interpolation formula for the change transfer probability in time-dependent models" Springer Series in Solid-State Science. 121. 157-164 (1996)
[文献書誌] 笠井秀明他: "Effects of electoronic excitations on translational energy destribution of ion・sca Hering" Journal of Physical Society of Japan. 64. 4308-4316 (1995)
[文献書誌] 笠井秀明他: "A microscopic theory of desorption induced by electronic transitions" Surface Science. 363. 214-222 (1996)
[文献書誌] 石田浩: "Microscopic theory of surface resistivity" Physical Review B. 52. 10819-10822 (1995)
[文献書誌] 石田浩: "On the life time of the parallel vibrational motion of adsorbates on metallic surfaces" Surface Science. 363. 354-359 (1996)
[文献書誌] 常行真司他: "First-principles investigation of photo-induced desorption of CO and NO from Pt (111)" Surface Science. 363. 223-228 (1996)
[文献書誌] 常行真司他: "Inverse isotope effects in the surface diffusion of atoms" Surface Science. 363. 403-408 (1996)
[文献書誌] 興地斐男他編: "Elementary Processes in Excitations and Reactions on Solid Surfaces" Springer, 243 (1996)
[文献書誌] 興地斐男他編: "DQPSS '95" North-Holland, 456 (1996)
[文献書誌] 村田好正他編: "IVC-13/ICSS-9 Yokohama 1995 Surface Science" North-Holland, 1013 (1995)

1996 年度 実績報告書

表面電子励起と反応素過程

研究代表者

村田 好正 電気通信大学, 電気通信学部, 教授 (10080467)

研究成果

[文献書誌] 村田好正他: "Selectivity of laser-induced desorption of NO and CO from transition metal surfaces" Zeitschrift fur Physikalische Chemie. 198. 149-156 (1997)

[文献書誌] 村田好正他: "Repulsive interaction of CO and a Pt surface derived from very-low-energy ion scattering" Surface Science. 363. 112-120 (1996)

[文献書誌] 潮田資勝他: "Surface SHG and photoemission from Cs/p-Ga As and the Cs/O_2/p-GaAs" Surface Science. 363. 385-390 (1996)

[文献書誌] 潮田資勝他: "Nanometer-scale characterization of surface materials by STM light emission spectroscopy" Applied Surface Science. 107. 247-254 (1996)

[文献書誌] 太田俊明他: "One-dimensional electronic states on stepped surfaces of Ni studied by ARUPS" Surface Science. 357/358. 238-241 (1996)

[文献書誌] 太田俊明他: "Adsorbate-substrate dynamics for C (2×2) Cl/Ni (100) : A SEXAFS Study" Surface Science. 371. 409-419 (1997)

[文献書誌] 松本吉泰他: "Laser-induced photochemistry of methane on Pt (111) : Excitation mechanism and dissociation dynamics" Journal of Chemical Physics. 105. 4775-4788 (1996)

[文献書誌] 松本吉泰他: "Absorbate-localized excitation in surface photo-chemistry : Methane on Pt (111)" Physical Review Letters. 76. 1751-1754 (1996)

[文献書誌] 福谷克之他: "Adsorption and Desorption of NO and CO on a Pt (111) -Ge surface alloy" Surface Science. 363. 185-194 (1996)

[文献書誌] 福谷克之他: "Interaction of Ultraviolet Photons with NO/Ni (111)" Surface Science. 363. 281-288 (1996)

[文献書誌] 並木章他: "Poisonous effect of alkali adatoms on Cl_2 sticleing" Surface Science. 363. 11-21 (1996)

[文献書誌] 並木章他: "Promoted O_2 sticleing on Li-covered Si (100)" Surface Science. 357/358. 684-689 (1996)

[文献書誌] 鳥養映子他: "Spin-polarized atomic beam as a probe of spin correlation at the topmost layer of surfaces" Springer Series in Solid-State Sciences. 121. 126-137 (1996)

[文献書誌] 有賀哲也他: "Restraint of NH_3 dissociation on oxygen-modified Mo (112)" Surface Science. 324. 17-24 (1995)

[文献書誌] 有賀哲也他: "Quantum glelocalization of H on Pd (110) : A vibrational study" Physical Review B. 53. 13767-13771 (1996)

[文献書誌] 興地斐男他: "Combined effect of molecular rotational-and surface vibrational excitations on the adsorption dynamics of D_2/Cu (111)" Surface Science. 363. 52-61 (1996)

[文献書誌] 興地斐男他: "Role of rotational motion in the dissociative adsorption and associative desorption dynamics" Physical Review Letters. 78. 286-289 (1997)

[文献書誌] 中辻博他: "Theoretical study on the photostimulated desorption of CO from a Pt surface" Journal Chemical Physics. 104. 714-726 (1996)

[文献書誌] 名取晃子他: "Atomic structures of Ag on √<3>×√<3> Ag/Si (111) and on 7×7 Si (111)" Surface Science. 357/358. 47-50 (1996)

[文献書誌] 名取晃子他: "Atomic structures and atomic dynamics an 1×1 Si (111) at high temperatures" Surface Science. 367. 56-66 (1996)

[文献書誌] 馬越健次他: "An interpolation formular for electron transfer in atom-surface collision and its validity" Surface Science. 363. 145-149 (1996)

[文献書誌] 馬越健次他: "Second order selt-energy and interpolation formula for the change transfer probability in time-dependent models" Springer Series in Solid-State Science. 121. 157-164 (1996)

[文献書誌] 笠井秀明他: "Effects of electoronic excitations on translational energy destribution of ion・sca Hering" Journal of Physical Society of Japan. 64. 4308-4316 (1995)

[文献書誌] 笠井秀明他: "A microscopic theory of desorption induced by electronic transitions" Surface Science. 363. 214-222 (1996)

[文献書誌] 石田浩: "Microscopic theory of surface resistivity" Physical Review B. 52. 10819-10822 (1995)

[文献書誌] 石田浩: "On the life time of the parallel vibrational motion of adsorbates on metallic surfaces" Surface Science. 363. 354-359 (1996)

[文献書誌] 常行真司他: "First-principles investigation of photo-induced desorption of CO and NO from Pt (111)" Surface Science. 363. 223-228 (1996)

[文献書誌] 常行真司他: "Inverse isotope effects in the surface diffusion of atoms" Surface Science. 363. 403-408 (1996)

[文献書誌] 興地斐男他編: "Elementary Processes in Excitations and Reactions on Solid Surfaces" Springer, 243 (1996)

[文献書誌] 興地斐男他編: "DQPSS '95" North-Holland, 456 (1996)

[文献書誌] 村田好正他編: "IVC-13/ICSS-9 Yokohama 1995 Surface Science" North-Holland, 1013 (1995)

1996 年度実績報告書

村田好正電気通信大学, 電気通信学部, 教授 (10080467)