1999 年度実績報告書

新高分子・ナノ組織体

研究課題

研究課題/領域番号	08246105
研究機関	理化学研究所
研究代表者	国武豊喜理化学研究所, 時空間機能材料研究グループ, グループディレクター(研究職) (40037734)
研究分担者	高橋成年大阪大学, 産業科学研究所, 教授 (70029875) 中浜精一東京工業大学, 工学部, 教授 (90016410) 戸嶋直樹山口東京理科大学, 基礎工学部, 教授 (50011010) 東村敏延滋賀県立大学, 工学部, 教授 (20025860) 西出宏之早稲田大学, 理工学部, 教授 (90120930)
キーワード	新高分子 / ナノ組織体 / 重合規制 / 精密重合 / キラル高分子 / 有機薄膜 / クラスター / 触媒
研究概要	1)特定領域研究「新高分子・ナノ組織体」の3年間にわたる研究成果を、各班および研究分野ごとにまとめ、その内容を検討した。個々の総括班員の間で打ち合わせを行うと共に、全班員による検討会(総括班会議)を2回開催し、総括した。 2)これらの検討会により、研究内容についてチェック・アンド・レビューを実施し、プロジェクト研究として総括し、特定領域研究「新高分子・ナノ組織体」の研究成果を730ページの研究成果報告書としてまとめた。また、本研究成果を(社)高分子学会発行のPolymer Journal誌に"New Polymers and Their Nano-Organized Systems"特集号としてまとめ、第31巻11-2号として平成11年11月15日に発行した。さらに、別予算であるが、300余頁の英文学術書"Precision Polymers and Nano-Organized Systems"を講談社により平成12年2月に発行する。 3)上記の成果とりまとめの結果に基づき、特定領域研究「新高分子・ナノ組織体」の成果を公開するシンポジウムを、第7回公開シンポジウムとして平成11年10月25日に東京の日本化学会化学会館ホールで開催し、外国人2人を含む10件の講演を行った。また、別予算であるが「大学と科学」公開シンポジウムとして「分子がつくるナノの不思議」と題した公開シンポジウムを、平成11年11月29-30日に大阪の千里ライフサイエンスセンターで開催した。

研究成果

(24件)

すべてその他

すべて文献書誌 (24件)

[文献書誌] I.Ichinose and T.Kunitake: "Polymerization-Induced Adsorption : A Preparative Method of Ultrathin Polymer Films"Advanced Materials. 11(5). 413-415 (1999)
[文献書誌] T.Yonezawa, H.Matsune, and T.Kunitake: "Layered Nanocomposite of Close-Packed Gold Nanoparticles and TiO_2 Gel Layers"Chemistry of Materials. 11(1). 33-35 (1999)
[文献書誌] Y.Lvov, K.Ariga, M.Onda, I.Ichinose, and T.kunitake: "A Careful Examination of the Adsorption Step in the Alternate Layer-by-Layer Assembly of Linear Polyanion and Polycation"Colloids & Surfaces. 146. 337-346 (1999)
[文献書誌] P.Lu, T.Teranishi, K.Asakura, M.Miyake, and N.Toshima: "Polymer-Protected Ni/Pd Bimetallic Nano-Clusters : Preparation, Characterization and Catalysis for Hydroganetion of Nitrobenzene"Lournal of Physical Chemistry B. 103(44). 9673-9682 (1999)
[文献書誌] N.Toshima and K.Hirakawa: "Polymer-Protected Bimetallic Nanocluster Catalysts Having Core/Shell Structure for Accelerated Electron Transfer in Visible-Light-Induced Hydrogen Generation"Polymer Journal. 31(11-2). 1127-1132 (1999)
[文献書誌] Y.Shiraishi and N.Toshima: "Colloidal Silver Catalysts for Oxidation of Ethylene"Journal of Molecular Chatalysis A, Chemistry. 141(1-3). 187-192 (1999)
[文献書誌] T.Ishizone, K.Sugiyama, Y.Sakano, H.Mori, A.Hirao, and S.Nakahama: "Anionic Polymerizations of Perfluoroalkyl Methacrylates and Synthesis of Well-Defined ABC Triblock Copolymers of Methacrylates Containing Hydrophilic Hydrophobic and Perfluoroalkyl Groups"Polymer Journal. 31(11-2). 983-988 (1999)
[文献書誌] M.Kobayashi, S.Okuyama, T.Ishizone, and Nakahama: "Stereospecific Anionic Polymerization of N,N-Dialkylacrylamides"Macromolecules. 32. 6466-6477 (1999)
[文献書誌] K.Senshu, S.Yamashita, H.Mori, M.Itoh, A.Hirao, and S.Nakahama: "Time-Resolved Surface Rearrangements of Poly(2-hydroxyethyl methacrylate-block-isoprene) in Response to Enviornmental Change"Langmuir. 15. 1754-1762 (1999)
[文献書誌] T.Ishizone, K.Yoshimura, E.Yanase, and S.Nakahama: "Controlled Anionic Polymerization of tert-Butyl Acrylate with Diphenylmethylpotassium in the Presence of Triethylborane"Macromolecules. 32. 955-957 (1999)
[文献書誌] K.Onitsuka, S.Yamamoto, and S.Takahashi: "A Novel Organometallic Macrocycle Composed of a Tetranuclear Palladium Acetylide"Angew. Chem. Int. Ed.. 38. 174-176 (1999)
[文献書誌] K.Onitsuka, M.Fujimoto, N.Ohshiro, and S.Takahashi: "Convergent Route to Organometallic Dendrimers Composed of Platinum-Acetylide Units"Angew. Chem. Int. Ed.. 38. 689-692 (1999)
[文献書誌] F.Takei, K.Onitsuka, and S.Takahashi: "Nonproportional Effects of Optical Purity of Chiral Aryl Isocyanide Monomers Possessing(d) or (I)-Methoxycarbonyl Groups on Induction of Screw-Sense in Poly(aryl isocyanide)s"Polymer Journal. 31. 1029-1032 (1999)
[文献書誌] F.Takei, K.Yanai, K.Onitsuka, and S.Takahashi: "Screw-Sence Selective Polymerization of Aryl Isocyanides Initiated by Pd-Pt m-Ethynediyl Dinuclear Complex : Novel Method for Synthesis of Single-Hande dHelical Poly(isocyanide)s Using Block Copolymerization Technique"European Journal of Chemistry. 6(in press). (2000)
[文献書誌] H.Nishide, M.Takahashi, J.Takashima, and E.Tsuchida: "Synthesis and Ferromagnetic Spin Alignment in Poly(4-oxyphenyl-1, 2-phenyleneethynylene)s"Polymer Journal. 31(11-2). 1171-1174 (1999)
[文献書誌] H.Nishide, M.Takahashi, J.Takashima, Y-J. Pu, and E.Tsuchida: "Acyclic and Cyclic Di- and Tri(4-oxyphenyl-1, 2-phenyleneethynylene)s : Their Synthesis and Ferromagnetic Spin Interaction"Journal of Organic Chemistry. 64(20). 7375-7380 (1999)
[文献書誌] H.Nishide, T.Maeda, K.Oyaizu, and E.Tsuchida: "High-Spin Polyphenoxyl Based on Poly(1, 4-phenyleneethynylene)"Journal of Organic Chemistry. 64(19). 7129-7134 (1999)
[文献書誌] M.Takahashi, T.Nakazawa, E.Tsuchida, and H.Nishide: "Poly(4-diphenylaminium-1, 2-phenylenevinylene) : A High-Spin and Durable Polyradical"Macromolecules. 32(19). 6383-6385 (1999)
[文献書誌] Y.Terada, S.Kanaoka and T.Higashimura: "Living Cationic Polymerization of n-butyl Propenyl Ether"Journal of Polymer Science : Part A ; Polymer Chemistry. 32(1). 229-236 (2000)
[文献書誌] E.Tsuchida: "Synthesis of Semicrystalline Aromatic Poly(thioether thioether ketone)s (PTTK and PTBTK) and Their Copolymers with Ether Analogues"Macromolecules. 32(2). 315-321 (1999)
[文献書誌] T.Aoki, K.Nakamura, K.Sanui, A.Kikuchi, T.Okano, Y.Sakurai, and N.Ogata: "Adenosine-Induced Changes of the Phase Transition of Poly(6-(acryloxymethyl)uracil) Aqueous Sollution"Polymer Journal. 31(11-2). 1185-1188 (1999)
[文献書誌] T.Kunitake: "Functionality of Molecular Systems 2"Springer-Verlag. 245(31-42) (1999)
[文献書誌] 戸嶋直樹: "季刊化学総説42「無機有機ナノ複合物質」"学会出版センター. 203(145-160) (1999)
[文献書誌] 蒲池幹治、遠藤剛: "ラジカル重合ハンドブック"エス・ティー・エス社. 759 (1999)

1999 年度 実績報告書

新高分子・ナノ組織体

研究代表者

国武 豊喜 理化学研究所, 時空間機能材料研究グループ, グループディレクター(研究職) (40037734)

研究成果

[文献書誌] I.Ichinose and T.Kunitake: "Polymerization-Induced Adsorption : A Preparative Method of Ultrathin Polymer Films"Advanced Materials. 11(5). 413-415 (1999)

[文献書誌] T.Yonezawa, H.Matsune, and T.Kunitake: "Layered Nanocomposite of Close-Packed Gold Nanoparticles and TiO_2 Gel Layers"Chemistry of Materials. 11(1). 33-35 (1999)

[文献書誌] Y.Lvov, K.Ariga, M.Onda, I.Ichinose, and T.kunitake: "A Careful Examination of the Adsorption Step in the Alternate Layer-by-Layer Assembly of Linear Polyanion and Polycation"Colloids & Surfaces. 146. 337-346 (1999)

[文献書誌] P.Lu, T.Teranishi, K.Asakura, M.Miyake, and N.Toshima: "Polymer-Protected Ni/Pd Bimetallic Nano-Clusters : Preparation, Characterization and Catalysis for Hydroganetion of Nitrobenzene"Lournal of Physical Chemistry B. 103(44). 9673-9682 (1999)

[文献書誌] N.Toshima and K.Hirakawa: "Polymer-Protected Bimetallic Nanocluster Catalysts Having Core/Shell Structure for Accelerated Electron Transfer in Visible-Light-Induced Hydrogen Generation"Polymer Journal. 31(11-2). 1127-1132 (1999)

[文献書誌] Y.Shiraishi and N.Toshima: "Colloidal Silver Catalysts for Oxidation of Ethylene"Journal of Molecular Chatalysis A, Chemistry. 141(1-3). 187-192 (1999)

[文献書誌] M.Kobayashi, S.Okuyama, T.Ishizone, and Nakahama: "Stereospecific Anionic Polymerization of N,N-Dialkylacrylamides"Macromolecules. 32. 6466-6477 (1999)

[文献書誌] K.Senshu, S.Yamashita, H.Mori, M.Itoh, A.Hirao, and S.Nakahama: "Time-Resolved Surface Rearrangements of Poly(2-hydroxyethyl methacrylate-block-isoprene) in Response to Enviornmental Change"Langmuir. 15. 1754-1762 (1999)

[文献書誌] T.Ishizone, K.Yoshimura, E.Yanase, and S.Nakahama: "Controlled Anionic Polymerization of tert-Butyl Acrylate with Diphenylmethylpotassium in the Presence of Triethylborane"Macromolecules. 32. 955-957 (1999)

[文献書誌] K.Onitsuka, S.Yamamoto, and S.Takahashi: "A Novel Organometallic Macrocycle Composed of a Tetranuclear Palladium Acetylide"Angew. Chem. Int. Ed.. 38. 174-176 (1999)

[文献書誌] K.Onitsuka, M.Fujimoto, N.Ohshiro, and S.Takahashi: "Convergent Route to Organometallic Dendrimers Composed of Platinum-Acetylide Units"Angew. Chem. Int. Ed.. 38. 689-692 (1999)

[文献書誌] F.Takei, K.Onitsuka, and S.Takahashi: "Nonproportional Effects of Optical Purity of Chiral Aryl Isocyanide Monomers Possessing(d) or (I)-Methoxycarbonyl Groups on Induction of Screw-Sense in Poly(aryl isocyanide)s"Polymer Journal. 31. 1029-1032 (1999)

[文献書誌] H.Nishide, M.Takahashi, J.Takashima, and E.Tsuchida: "Synthesis and Ferromagnetic Spin Alignment in Poly(4-oxyphenyl-1, 2-phenyleneethynylene)s"Polymer Journal. 31(11-2). 1171-1174 (1999)

[文献書誌] H.Nishide, M.Takahashi, J.Takashima, Y-J. Pu, and E.Tsuchida: "Acyclic and Cyclic Di- and Tri(4-oxyphenyl-1, 2-phenyleneethynylene)s : Their Synthesis and Ferromagnetic Spin Interaction"Journal of Organic Chemistry. 64(20). 7375-7380 (1999)

[文献書誌] H.Nishide, T.Maeda, K.Oyaizu, and E.Tsuchida: "High-Spin Polyphenoxyl Based on Poly(1, 4-phenyleneethynylene)"Journal of Organic Chemistry. 64(19). 7129-7134 (1999)

[文献書誌] M.Takahashi, T.Nakazawa, E.Tsuchida, and H.Nishide: "Poly(4-diphenylaminium-1, 2-phenylenevinylene) : A High-Spin and Durable Polyradical"Macromolecules. 32(19). 6383-6385 (1999)

[文献書誌] Y.Terada, S.Kanaoka and T.Higashimura: "Living Cationic Polymerization of n-butyl Propenyl Ether"Journal of Polymer Science : Part A ; Polymer Chemistry. 32(1). 229-236 (2000)

[文献書誌] E.Tsuchida: "Synthesis of Semicrystalline Aromatic Poly(thioether thioether ketone)s (PTTK and PTBTK) and Their Copolymers with Ether Analogues"Macromolecules. 32(2). 315-321 (1999)

[文献書誌] T.Aoki, K.Nakamura, K.Sanui, A.Kikuchi, T.Okano, Y.Sakurai, and N.Ogata: "Adenosine-Induced Changes of the Phase Transition of Poly(6-(acryloxymethyl)uracil) Aqueous Sollution"Polymer Journal. 31(11-2). 1185-1188 (1999)

[文献書誌] T.Kunitake: "Functionality of Molecular Systems 2"Springer-Verlag. 245(31-42) (1999)

[文献書誌] 戸嶋 直樹: "季刊化学総説42「無機有機ナノ複合物質」"学会出版センター. 203(145-160) (1999)

[文献書誌] 蒲池 幹治、遠藤 剛: "ラジカル重合ハンドブック"エス・ティー・エス社. 759 (1999)

1999 年度実績報告書

国武豊喜理化学研究所, 時空間機能材料研究グループ, グループディレクター(研究職) (40037734)

[文献書誌] 戸嶋直樹: "季刊化学総説42「無機有機ナノ複合物質」"学会出版センター. 203(145-160) (1999)

[文献書誌] 蒲池幹治、遠藤剛: "ラジカル重合ハンドブック"エス・ティー・エス社. 759 (1999)