1999 年度実績報告書

高分子・無機複合機能性材料に関する研究-新規合成法と応用-

研究課題

研究課題/領域番号	09045047
研究機関	東京農工大学
研究代表者	尾見信三東京農工大学, 大学院・生物システム応用科学研究所, 教授 (70016393)
研究分担者	渡邊敏行東京農工大学, 工学部, 助教授 (10210923) 宮田清蔵東京農工大学, 大学院・生物システム応用科学研究所, 教授 (90015066)
キーワード	高分子微粒子 / マイクロカプセル / 液晶 / 非線形光学素子 / ルイス酸触媒 / 中空粒子 / タイ動植物資源の利用
研究概要	東京農工大学とチュラロンコン(CU)大学とは提携校の関係にあり、学術交流の一環として高分子と無機材料を複合化して合成した機能性素材を、生化学、触媒化学、印刷、光学、電子材料などの広い分野に応用することを目的として共同研究を組織した。本年度は研究の最終年度にあたるので、これまでに両者の間で留学生の受入を通じて密接に連絡を取りながら研究を進めてきた非線形光学材料、高分子微粒子、無機微粒子マイクロカプセルに焦点を絞って検討を加えた。 1.タイの淡水魚Snakefishの皮革に含まれる蛍光物質、ココナツ果皮から抽出した液晶の同定と光学材料への応用について検討した。 2.圧電性高分子材料の合成と評価を行った 3.アナターゼ型酸化チタン微粒子のマイクロカプセルの調整法を確立した 4.ルイス酸触媒のコアセルベーション法によるマイクロカプセル化について実験を進めた。 5.膜乳化法による多孔質、中空微粒子を合成し、油分吸収材としての評価を行った。平成11年9月にはSomsakら6名が来日して、研究の打ち合わせと新しいテーマに基づいて研究組織を継続して行くことで合意した。

研究成果
(24件)

すべてその他

すべて文献書誌 (24件)

[文献書誌] S.Omi,A.Matsuda,G.-H.Ma: "Synthesis of Monodisperse Polymeric Microspheres Including Polyimide Prepolymer by Using SPG Emulsification Technique."Colloids and Surfaces A: Physicochem.Eng.Aspects. 153. 373-381 (1999)
[文献書誌] S.Omi,K.Fujikawa,G.-H.Ma: "Study of Particle Growth by Seed Emulsion Polymerization with Counter-Charged Monomer and Initiator System."Colloids and Surfaces A: Physicochem.Eng.Aspects. 153. 165-172 (1999)
[文献書誌] S.Omi,M.Nagai,G.-H.Ma: "Preparation of Monodisperse Polystyrene Spheres Incorporating Polyimide Prepolymer by Dispersion Polymerization in the Presence of L-Ascorbic Acid."J.Appl.Polym.Sci.. 68. 897-907 (1998)
[文献書誌] S.Omi,H.Yuyama,G.-H.Ma: "Note on the Numerical Solution of the Smith-Ewart Equation of n Modified for the Isolated Monomer Droplets in a Particular Suspension Polymerization."J.Polym.Sci.,Pt.A,Polym.Chem.. 36. 367-369 (1998)
[文献書誌] 戸木田雅利、宮田清蔵: "界面活性剤が形成する液晶の構造"化学と教育. 47(4). 242-244 (1999)
[文献書誌] 鈴木宏典、戸木田雅利、渡邊敏行、宮田清蔵: "界面に共蒸着層を導入した有機素子の発光特性"信学技報. 7. 77-84 (1999)
[文献書誌] H.W.Huang,K.Horie,M.Tokita,J.Watanabe: "Fluorescence Study on Intermolecular Complex Formation between Mesogenic Bipenyl Moieties of Main-Chain Thermotropic Liquid Crystaline Polyesters with 8-18 Melthylene Units."Polymer. 40. 3013-3023 (1999)
[文献書誌] M.Tokita,K.Osada,M.Yamada: "Chain-Folded Lamellar Structure in the Smectic H Phase of a Main-Chain Polymer"Macromolecule. 31. 8590-8594 (1999)
[文献書誌] H.W.Huang,K.Horie,M.Tokita: "Fluorescence Study on Intermolecular Complex Formation between Mesogenic 4,4'-Biphenyldicarboxylate Moieties of Thermotropic Liquid Crystalline Polyesters with 5 and 6 Methylene Units."Macromol.Chem.Phys.. 199. 1851 (1998)
[文献書誌] S,Damronglerd: "Waste Water Treatment in Three-Phase Fluidization"Thailand Pat.,No.8958,15 June. (1999)
[文献書誌] S.Damronglerd: "Fluidization Incinerator"Thailand Pat.,No.8959,15 June. (1999)
[文献書誌] R.Sangsirimongkolying,S.Damronglerd,S.Kiatkamjornwong: "Pilot-Scale Production of Highly Water Absorbing Polymer from Native Cassava Starch by Hydrogenperoxide-Ascorbic Acid Initation."J.Sci.Res.Chulaongkorn Univ.. 24(1). 1-12 (1999)
[文献書誌] J.Watanabe,M.Tokita,T.Watanabe,S.Miyata: "Polar Structure in Polypeptide Cholesteric Liquid Crystals Evidenced from Observation of Second-Harmonic Generation Due to the Helicolloidal Cavity Effect."Macromolecules. 31(17). 5937-5939 (1998)
[文献書誌] N.Tsutsumi,T.Watabnabe,S,Miyata: "Precise Study of Non-Linear Optical Coefficients and Hyperpolarizabilities in Cold-Drawn and Poled Ferroelectric Nylon-11 Films."J.Chem.Phys.. 108(23). 9839-9850 (1998)
[文献書誌] G.-H.Ma,M.Nagai,S.Omi: "Effect of Lauryl Alcohol on Morphology of Uniform Polystyrene-Poly(methyl Methacrylate) Composite Nicrospheres Prepared by Porous Glass Membrane Emulsification Technique."J.Coll.Interf.Sci.. 219. 110-128 (1999)
[文献書誌] G.-H.Ma,M.Nagai,S.Omi: "Study on Preparation and Morphology of Uniform Artificial Poly(styrene)-Poly(methyl Methacrylate) Composite Microspheres by Employing SPG (Shirasu Porous Glass) Membrane Emulsification Tecnique."J.Coll.Interf.Sci.. 214. 264-282 (1999)
[文献書誌] G.-H,Ma,M.Nagai,S.Omi: "Preparation of Uniform Poly(lactide) Microspheres by Employing SPG Emulsification Technique."Colloids and Surfaces A: Physicochem.Eng.Aspects. 153. 383-394 (1999)
[文献書誌] 戸木田雅利、長田健介、土屋仁、渡辺順次: "主鎖型高分子のスメクチック液晶場におけるFolding構造"高分子論文集. 56. 184-194 (1999)
[文献書誌] S.Roengsmuran,A.Petsom,D.Sommit: "Labdane Diterpenoids from Croton Oblongifolius."Phytochemistry. 50. 449-453 (1999)
[文献書誌] S.Roengsmuran,A.Petsom,K.Pudhom: "Crotocembraneic acid: A New Cembranoid from Croton Oblongifolius."J.Nat.Prod.. 61. 652-654 (1998)
[文献書誌] S.Kiatkamjornwong,S.Netpradit,T.Ikeda: "Effect of Developer Properties on Print Quality."J.Particulate Sci. & Tech.. 16(4). 295-310 (1999)
[文献書誌] S.Kiatkamijornwong,P.Phuncareon: "Influences of Reaction Parameters on Water Adsorption of Neutralized Poly(acrylic acid-co-acrylamide) Synthesized by Inverse Suspension Polymerization."J.Appl.Polym.Sci.. 72(10). 1349-1366 (1999)
[文献書誌] S.Kiatkamijornwong,N.Siwarungson,A.Nganbunsri: "In-Situ Immobilization of Alkaline Protease during Inverse Suspension Polymerization of Polyacrylamide and Poly(acrylamide-co-methacrylic acid) Hydrogel Beads."J.Appl.Polym.Sci.. 73(11). 2273-2291 (1999)
[文献書誌] S.Kiatkamjornwong,C.Poomtien,Y.Hoshino: "Effect of CCA and Charging Behavior on Print Quality."J.Particulate Sci.& Tech.. 16(4). 295-310 (1999)

1999 年度 実績報告書

高分子・無機複合機能性材料に関する研究-新規合成法と応用-

研究代表者

尾見 信三 東京農工大学, 大学院・生物システム応用科学研究所, 教授 (70016393)

研究成果

[文献書誌] S.Omi,A.Matsuda,G.-H.Ma: "Synthesis of Monodisperse Polymeric Microspheres Including Polyimide Prepolymer by Using SPG Emulsification Technique."Colloids and Surfaces A: Physicochem.Eng.Aspects. 153. 373-381 (1999)

[文献書誌] S.Omi,K.Fujikawa,G.-H.Ma: "Study of Particle Growth by Seed Emulsion Polymerization with Counter-Charged Monomer and Initiator System."Colloids and Surfaces A: Physicochem.Eng.Aspects. 153. 165-172 (1999)

[文献書誌] S.Omi,M.Nagai,G.-H.Ma: "Preparation of Monodisperse Polystyrene Spheres Incorporating Polyimide Prepolymer by Dispersion Polymerization in the Presence of L-Ascorbic Acid."J.Appl.Polym.Sci.. 68. 897-907 (1998)

[文献書誌] S.Omi,H.Yuyama,G.-H.Ma: "Note on the Numerical Solution of the Smith-Ewart Equation of n Modified for the Isolated Monomer Droplets in a Particular Suspension Polymerization."J.Polym.Sci.,Pt.A,Polym.Chem.. 36. 367-369 (1998)

[文献書誌] 戸木田雅利、宮田清蔵: "界面活性剤が形成する液晶の構造"化学と教育. 47(4). 242-244 (1999)

[文献書誌] 鈴木宏典、戸木田雅利、渡邊敏行、宮田清蔵: "界面に共蒸着層を導入した有機素子の発光特性"信学技報. 7. 77-84 (1999)

[文献書誌] H.W.Huang,K.Horie,M.Tokita,J.Watanabe: "Fluorescence Study on Intermolecular Complex Formation between Mesogenic Bipenyl Moieties of Main-Chain Thermotropic Liquid Crystaline Polyesters with 8-18 Melthylene Units."Polymer. 40. 3013-3023 (1999)

[文献書誌] M.Tokita,K.Osada,M.Yamada: "Chain-Folded Lamellar Structure in the Smectic H Phase of a Main-Chain Polymer"Macromolecule. 31. 8590-8594 (1999)

[文献書誌] H.W.Huang,K.Horie,M.Tokita: "Fluorescence Study on Intermolecular Complex Formation between Mesogenic 4,4'-Biphenyldicarboxylate Moieties of Thermotropic Liquid Crystalline Polyesters with 5 and 6 Methylene Units."Macromol.Chem.Phys.. 199. 1851 (1998)

[文献書誌] S,Damronglerd: "Waste Water Treatment in Three-Phase Fluidization"Thailand Pat.,No.8958,15 June. (1999)

[文献書誌] S.Damronglerd: "Fluidization Incinerator"Thailand Pat.,No.8959,15 June. (1999)

[文献書誌] R.Sangsirimongkolying,S.Damronglerd,S.Kiatkamjornwong: "Pilot-Scale Production of Highly Water Absorbing Polymer from Native Cassava Starch by Hydrogenperoxide-Ascorbic Acid Initation."J.Sci.Res.Chulaongkorn Univ.. 24(1). 1-12 (1999)

[文献書誌] J.Watanabe,M.Tokita,T.Watanabe,S.Miyata: "Polar Structure in Polypeptide Cholesteric Liquid Crystals Evidenced from Observation of Second-Harmonic Generation Due to the Helicolloidal Cavity Effect."Macromolecules. 31(17). 5937-5939 (1998)

[文献書誌] N.Tsutsumi,T.Watabnabe,S,Miyata: "Precise Study of Non-Linear Optical Coefficients and Hyperpolarizabilities in Cold-Drawn and Poled Ferroelectric Nylon-11 Films."J.Chem.Phys.. 108(23). 9839-9850 (1998)

[文献書誌] G.-H.Ma,M.Nagai,S.Omi: "Effect of Lauryl Alcohol on Morphology of Uniform Polystyrene-Poly(methyl Methacrylate) Composite Nicrospheres Prepared by Porous Glass Membrane Emulsification Technique."J.Coll.Interf.Sci.. 219. 110-128 (1999)

[文献書誌] G.-H.Ma,M.Nagai,S.Omi: "Study on Preparation and Morphology of Uniform Artificial Poly(styrene)-Poly(methyl Methacrylate) Composite Microspheres by Employing SPG (Shirasu Porous Glass) Membrane Emulsification Tecnique."J.Coll.Interf.Sci.. 214. 264-282 (1999)

[文献書誌] G.-H,Ma,M.Nagai,S.Omi: "Preparation of Uniform Poly(lactide) Microspheres by Employing SPG Emulsification Technique."Colloids and Surfaces A: Physicochem.Eng.Aspects. 153. 383-394 (1999)

[文献書誌] 戸木田雅利、長田健介、土屋仁、渡辺順次: "主鎖型高分子のスメクチック液晶場におけるFolding構造"高分子論文集. 56. 184-194 (1999)

[文献書誌] S.Roengsmuran,A.Petsom,D.Sommit: "Labdane Diterpenoids from Croton Oblongifolius."Phytochemistry. 50. 449-453 (1999)

[文献書誌] S.Roengsmuran,A.Petsom,K.Pudhom: "Crotocembraneic acid: A New Cembranoid from Croton Oblongifolius."J.Nat.Prod.. 61. 652-654 (1998)

[文献書誌] S.Kiatkamjornwong,S.Netpradit,T.Ikeda: "Effect of Developer Properties on Print Quality."J.Particulate Sci. & Tech.. 16(4). 295-310 (1999)

[文献書誌] S.Kiatkamijornwong,P.Phuncareon: "Influences of Reaction Parameters on Water Adsorption of Neutralized Poly(acrylic acid-co-acrylamide) Synthesized by Inverse Suspension Polymerization."J.Appl.Polym.Sci.. 72(10). 1349-1366 (1999)

[文献書誌] S.Kiatkamijornwong,N.Siwarungson,A.Nganbunsri: "In-Situ Immobilization of Alkaline Protease during Inverse Suspension Polymerization of Polyacrylamide and Poly(acrylamide-co-methacrylic acid) Hydrogel Beads."J.Appl.Polym.Sci.. 73(11). 2273-2291 (1999)

[文献書誌] S.Kiatkamjornwong,C.Poomtien,Y.Hoshino: "Effect of CCA and Charging Behavior on Print Quality."J.Particulate Sci.& Tech.. 16(4). 295-310 (1999)

1999 年度実績報告書

尾見信三東京農工大学, 大学院・生物システム応用科学研究所, 教授 (70016393)