1999 年度実績報告書

機能界面の電気化学的形成と高効率電池

研究課題

研究課題/領域番号	09237104
研究機関	阿南工業高等専門学校
研究代表者	米山宏阿南工業高等専門学校, 校長 (80029082)
研究分担者	益田秀樹東京都立大学, 工学部, 助教授 (90190363) 小山昇東京農工大学, 工学部, 教授 (40134845) 逢坂哲弥早稲田大学, 大学院・理工学研究科, 教授 (20097249) 渡辺政廣山梨大学, 工学部, 教授 (00020412)
キーワード	量子サイズ効果 / 軟磁性薄膜 / ポーラスアルミナ / 有機電池活物質 / 電析 / 超格子 / 電極触媒 / 有機硫黄錯体
研究概要	○粒径を揃えた硫化カドミウムナノ粒子を用いて量子サイズ効果を有する光電極を作製する方法として、ラングミュア・プロジェット法の適用が有用であることを明らかにした。電気化学エピタキシャル法によって作製した量子サイズ効果を有する硫化カドミウム超薄膜の光電気化学特性は硫化亜鉛超薄膜をバリアーに用いる超格子を作製し、そのユニット数を増すことによって高められることを明らかにした。(米山) ○すでに明らかにしている電析法による高飽和磁束密度 Bs を有する CoNiFe 軟磁性薄膜の作製において、電析浴に有機系添加剤を用いて磁性薄膜中に炭素を共析させると高 Bs (=1.9T) で高比抵抗 (=90μΩcm) の薄膜が作製できることを見いだした。(逢坂) ○2.5-ジメルカプト-1,3,4-チアジアゾール (DMcT) を含む溶液と銅イオンを含む溶液に交互に浸漬することによりこれらが積み重なった構造を有する金電極を集電体に用いて作成した DMcT とポリアニリンの複合正極は、合成した DMcT 銅錯体を金電極に塗布した電極に比べて格段に優れた放電容量と充放電サイクル特性が得られ、電極界面構造の制御の重要性が明らかになった。(小山) ○孔が長距離にわたって規則配列する高規則性陽極酸化ポーラスアルミナは、陽極酸化に伴い細孔欠陥部が自動的に捕らわれることによって生成することを見出した。また、孔開始点の配列を人工的に制御することで、四角および三角状の孔を有するポーラスアルミナが作製できることを明らかにした。(益田) ○すでに見出していた白金と鉄、ルテニウムなどとの合金が示す高い一酸化炭素被毒耐性を有する高活性な燃料電池アノード触媒活性の成因を解明した。すなわち触媒表面は数原子層の白金で覆われ、そこに一酸化炭素が表面を容易に移動できるように弱く吸着するために一酸化炭素の表面被覆率が大きくならず、水素酸化に対する白金の高い触媒活性が維持される。(渡辺)

研究成果
(46件)

すべてその他

すべて文献書誌 (46件)

[文献書誌] M. Miyake: "Photoelectrochemical Characterization of Nearly Monodisperse CdS Nanoparticle-Immobilized Gold Electrodes"Langmuir. 15・4. 1503-1507 (1999)
[文献書誌] H. Yoneyama: "Electrochemistry of Size-quantized Semiconductor Nanoparticles"Electrochem.. 67・4. 324-330 (1999)
[文献書誌] T. Torimoto: "Preparation and Photoelectrochemical Properties of Two-Dimensionally Organized CdS Nanoparticle Thin Films"Langmuir. 15・5. 1853-1858 (1999)
[文献書誌] M. Miyake: "Effects of Surface Charges and Surface States of Chemically Modified Cadmium Sulfide Nanoparticles Immobilized to Gold Electrode Substrates on Photoinduced Charge Transfers"Langmuir. 15・8. 2714-2718 (1999)
[文献書誌] T. Torimoto: "Fabrication of CdS Nanoparticle Chains along DNA Double Strands"J. Phys. Chem. B. 103・42. 8799-8803 (1999)
[文献書誌] Y. Ohko: "Preparation of Monodisperse ZnS Nanoparticles by Size Selective Photocorrosion"Chem. Lett. 6. 663-664 (1999)
[文献書誌] N. Takeda: "Effects of Mordenite Support on Photodegradation of Gaseous Organic Compounds over TiO_2 Photocatalyst"Bull. Chem. Soc. Jpn. 72・7. 1615-1621 (1999)
[文献書誌] H. Yoneyama: "Photoinduced destruction of bromoform dissolved in water using TiO_2 - loaded adsorbent"Z. Phys. Chem.. 213・1. 43-48 (1999)
[文献書誌] T. Torimoto: "Photoelectrochemical Properties of Size-Quantized Semiconductor Photoelectrodes Prepared by Two-Dimensional Cross Linking of Monodisperse CdS Nanoparticles"Electrochim. Acta. (in press). (2000)
[文献書誌] T. Torimoto: "Electrochemical Preparation of ZnS/CdS Superlattice and Its Photoelectrochemical Properties"Electrochem. Commun.. (in press). (2000)
[文献書誌] 横島時彦: "無電解CoFeBめっきを用いた磁気ヘッドコア作製プロセスの基礎的検討"日本応用磁気学会誌. 23・ 4-2. 1397-1400 (1999)
[文献書誌] 増川禎道: "高B_sーCoNiFe電析膜の軟磁気特性に及ぼす成膜条件の影響"日本応用磁気学会誌. 23・ 4-2. 1405-1408 (1999)
[文献書誌] T. Osaka: "Influence of Crystalline Structure and Sulfur Inclusion on Corrosion Properties of Electrodeposited CoNiFe Soft Magnetic Films"J. Electrochem. Soc.. 146・6. 2092-2096 (1999)
[文献書誌] T. Osaka: "Effects of Saccharin and Thiourea on Sulfur Inclusion and Coercivity of Electroplated Soft Magnetic CoNiFe Film"J. Electrochem. Soc.. 146・9. 3295-3299 (1999)
[文献書誌] N. Takano: "Mechanism of the Chemical Deposition of Nickel on Silicon Wafers in Aqueous solution"J. Electrochem. Soc.. 146・4. 1407-1411 (1999)
[文献書誌] T. Yokoshima: "Increasing the Resistivity of Electrodeposited High-B_sーCoNiFe Thin Film"IEEE Trans. Magn.. 35・5. 2499-2499 (1999)
[文献書誌] Y. Sugai: "Formation of Microprobe Using Nickel Electrodeposition"J. Electrochem. Soc.. 67・12. 1150-1152 (1999)
[文献書誌] T. Osaka: Electrochimica Acta. 44・21-22. 3885-3890 (1999)
[文献書誌] T. Osaka: "Research and Development of High Performance Soft Magnetic Thin Films"J. Electrochem. Soc.. 67・9. 894-899 (1999)
[文献書誌] 逢坂哲弥: "集積回路配線における精密めっき技術"応用物理. 68・11. 1237-1242 (1999)
[文献書誌] T. Osaka: "Electrodeposition of Highly Functional Thin Films for Magnetic Recording Devices of the Next Century"Electrochimica Acta. (in press). (2000)
[文献書誌] N. Oyama: "Lithim Polymer Batteries with High Energy Density"Macromolecular Symposia. (in press). (2000)
[文献書誌] N. Oyama: "New Composite Cathodes for Lithium Rechargeable Batteries"Mol. Cryst. Liq. Cryst.. (in press). (2000)
[文献書誌] O. Hatozaki: "Redox Activity of an Organosulfur Compound and Its Application to Polymer Lithium Batteries"Electrochemistry. 67・11. 1036-1041 (1999)
[文献書誌] H. Masuda: "Change of Hole Size of Pd Hole-array Electrodes in a Controlled Fashion by Cathodic Polarization in Acidic Electrolyte"J. Electroanal. Chem.. 473. 240-244 (1999)
[文献書誌] K. Nishio: "Fabrication of Miocroporous TiO_2 Using Two-step Replication of Fine Structure of Porous Glass"Electrochemistry. 67. 1268-1270 (1999)
[文献書誌] H. Masuda: "Photonic Crystal Using Anodic Porous Alumina"Jpn. J. Appl. Phys.. 38. 1403-1405 (1999)
[文献書誌] M. Nakao: "GaAs and InP Nanohole Arrays Fabricated by Reactive Beam Etching Using Highly Ordered Alumina Membranes"Jpn. J. Appl. Phys.. 38. 1052-1055 (1999)
[文献書誌] T. Nishikawa: "Greatly Enhanced Soft X-ray Generation from Femtosecond-Laser-Produced Plasma by Using a Nanohole-Alumina Target"Appl. Phys. Lett.. 75. 4079-4081 (1999)
[文献書誌] H. Masuda: "Direct Nanomolding of Semiconductor Single Crystals"Jpn. J. Appl. Phys.. (in press).
[文献書誌] H. Masuda: "Fabrication of a Nanostructured Diamond Honeycomb Film"Adv. Mater.. (in press).
[文献書誌] K. Honda: "Electrochemical Characterization of the Nanoporous Honeycomb Diamond Electrode as an Electrical Double Layer Capacitor"J. Electrochem. Soc.. (in press).
[文献書誌] H. Uchida: "Effects of Ionic Conductivity of Zirconia Electrolytes on the Polarization Behavior of Various Cathodes in Solid Oxide Fuel Cells"J. Electrochem. Soc.. 146・1. 1-7 (1999)
[文献書誌] H. Uchida: "High-Performance Electrode for Medium-Temperature Solid Oxide Fuel Cells-Control of Microstructure of Ceria-Based Anodes with Highly Dispersed Ruthenium Electrocatalysts"J. Electrochem. Soc.. 146・5. 1677-1682 (1999)
[文献書誌] H. Uchida: "High-Performance Electrode for Medium-Temperature Solid Oxide Fuel Cells-La(Sr)CoO3 Cathode with Ceria Interlayer on Zirconia Electrolyte"Electrochem. Solid-State Lett.. 2・9. 428-430 (1999)
[文献書誌] T. Toda: "Enhancement of the Electroreduction of Oxygen on Pt Alloys with Fe, Ni and Co"J. Electrochem. Soc.. 146・10. 3750-3756 (1999)
[文献書誌] M. Watanabe: "Design of CO Tolerant Anode Catalysts for Polymer Electrolyte Fuel Cells"Electrochemistry. 67・12. 1192-1196 (1999)
[文献書誌] Y. Zhu: "Oxidation of Carbon Monoxide at a Platinum Film electrode Studied by FTIR Spectroscopy with Attenuated Total Reflection Technique"Langmuir. 15・25. 8757-8764 (1999)
[文献書誌] M. Watanabe: "Oxidation of CO on Pt-Fe Alloy Electrode Studied by Surface Enhanced Reflection Absorption Spectroscopy"J. Phys. Chem.. (in press).
[文献書誌] M. Watanabe: "Mechanism of CO Tolerance at Pt-Alloy Anode Catalysts for Polymer Electrolyte Fuel Cells"Electrochemistry. 68.4. (2000)
[文献書誌] 内田浩之: "高分子電解質型燃料電池の要素技術"日本機械学会誌. 101・952. 216-217 (1999)
[文献書誌] 内田浩之: "最近の高分子電解質型燃料電池技術"月刊「化学工業」. 58・10. 756-761 (1999)
[文献書誌] 渡辺政廣: "高分子膜燃料電池の基礎と応用"高分子. 148・12. 918-921 (1999)
[文献書誌] 渡辺政廣: "燃料電池ークリーンエネルギーデバイス"機能材料. 20・1. 47-53 (2000)
[文献書誌] 渡辺政廣: "全個体高分子型燃料電池の開発と実用"技術情報協会. 211 (1999)
[文献書誌] 渡辺政廣: "PEM・燃料電池入門"環境新聞社. 235 (1999)

1999 年度 実績報告書

機能界面の電気化学的形成と高効率電池

研究代表者

米山 宏 阿南工業高等専門学校, 校長 (80029082)

研究成果

[文献書誌] M. Miyake: "Photoelectrochemical Characterization of Nearly Monodisperse CdS Nanoparticle-Immobilized Gold Electrodes"Langmuir. 15・4. 1503-1507 (1999)

[文献書誌] H. Yoneyama: "Electrochemistry of Size-quantized Semiconductor Nanoparticles"Electrochem.. 67・4. 324-330 (1999)

[文献書誌] T. Torimoto: "Preparation and Photoelectrochemical Properties of Two-Dimensionally Organized CdS Nanoparticle Thin Films"Langmuir. 15・5. 1853-1858 (1999)

[文献書誌] M. Miyake: "Effects of Surface Charges and Surface States of Chemically Modified Cadmium Sulfide Nanoparticles Immobilized to Gold Electrode Substrates on Photoinduced Charge Transfers"Langmuir. 15・8. 2714-2718 (1999)

[文献書誌] T. Torimoto: "Fabrication of CdS Nanoparticle Chains along DNA Double Strands"J. Phys. Chem. B. 103・42. 8799-8803 (1999)

[文献書誌] Y. Ohko: "Preparation of Monodisperse ZnS Nanoparticles by Size Selective Photocorrosion"Chem. Lett. 6. 663-664 (1999)

[文献書誌] N. Takeda: "Effects of Mordenite Support on Photodegradation of Gaseous Organic Compounds over TiO_2 Photocatalyst"Bull. Chem. Soc. Jpn. 72・7. 1615-1621 (1999)

[文献書誌] H. Yoneyama: "Photoinduced destruction of bromoform dissolved in water using TiO_2 - loaded adsorbent"Z. Phys. Chem.. 213・1. 43-48 (1999)

[文献書誌] T. Torimoto: "Photoelectrochemical Properties of Size-Quantized Semiconductor Photoelectrodes Prepared by Two-Dimensional Cross Linking of Monodisperse CdS Nanoparticles"Electrochim. Acta. (in press). (2000)

[文献書誌] T. Torimoto: "Electrochemical Preparation of ZnS/CdS Superlattice and Its Photoelectrochemical Properties"Electrochem. Commun.. (in press). (2000)

[文献書誌] 横島 時彦: "無電解CoFeBめっきを用いた磁気ヘッドコア作製プロセスの基礎的検討"日本応用磁気学会誌. 23・ 4-2. 1397-1400 (1999)

[文献書誌] 増川 禎道: "高B_sーCoNiFe電析膜の軟磁気特性に及ぼす成膜条件の影響"日本応用磁気学会誌. 23・ 4-2. 1405-1408 (1999)

[文献書誌] T. Osaka: "Influence of Crystalline Structure and Sulfur Inclusion on Corrosion Properties of Electrodeposited CoNiFe Soft Magnetic Films"J. Electrochem. Soc.. 146・6. 2092-2096 (1999)

[文献書誌] T. Osaka: "Effects of Saccharin and Thiourea on Sulfur Inclusion and Coercivity of Electroplated Soft Magnetic CoNiFe Film"J. Electrochem. Soc.. 146・9. 3295-3299 (1999)

[文献書誌] N. Takano: "Mechanism of the Chemical Deposition of Nickel on Silicon Wafers in Aqueous solution"J. Electrochem. Soc.. 146・4. 1407-1411 (1999)

[文献書誌] T. Yokoshima: "Increasing the Resistivity of Electrodeposited High-B_sーCoNiFe Thin Film"IEEE Trans. Magn.. 35・5. 2499-2499 (1999)

[文献書誌] Y. Sugai: "Formation of Microprobe Using Nickel Electrodeposition"J. Electrochem. Soc.. 67・12. 1150-1152 (1999)

[文献書誌] T. Osaka: Electrochimica Acta. 44・21-22. 3885-3890 (1999)

[文献書誌] T. Osaka: "Research and Development of High Performance Soft Magnetic Thin Films"J. Electrochem. Soc.. 67・9. 894-899 (1999)

[文献書誌] 逢坂 哲弥: "集積回路配線における精密めっき技術"応用物理. 68・11. 1237-1242 (1999)

[文献書誌] T. Osaka: "Electrodeposition of Highly Functional Thin Films for Magnetic Recording Devices of the Next Century"Electrochimica Acta. (in press). (2000)

[文献書誌] N. Oyama: "Lithim Polymer Batteries with High Energy Density"Macromolecular Symposia. (in press). (2000)

[文献書誌] N. Oyama: "New Composite Cathodes for Lithium Rechargeable Batteries"Mol. Cryst. Liq. Cryst.. (in press). (2000)

[文献書誌] O. Hatozaki: "Redox Activity of an Organosulfur Compound and Its Application to Polymer Lithium Batteries"Electrochemistry. 67・11. 1036-1041 (1999)

[文献書誌] H. Masuda: "Change of Hole Size of Pd Hole-array Electrodes in a Controlled Fashion by Cathodic Polarization in Acidic Electrolyte"J. Electroanal. Chem.. 473. 240-244 (1999)

[文献書誌] K. Nishio: "Fabrication of Miocroporous TiO_2 Using Two-step Replication of Fine Structure of Porous Glass"Electrochemistry. 67. 1268-1270 (1999)

[文献書誌] H. Masuda: "Photonic Crystal Using Anodic Porous Alumina"Jpn. J. Appl. Phys.. 38. 1403-1405 (1999)

[文献書誌] M. Nakao: "GaAs and InP Nanohole Arrays Fabricated by Reactive Beam Etching Using Highly Ordered Alumina Membranes"Jpn. J. Appl. Phys.. 38. 1052-1055 (1999)

[文献書誌] T. Nishikawa: "Greatly Enhanced Soft X-ray Generation from Femtosecond-Laser-Produced Plasma by Using a Nanohole-Alumina Target"Appl. Phys. Lett.. 75. 4079-4081 (1999)

[文献書誌] H. Masuda: "Direct Nanomolding of Semiconductor Single Crystals"Jpn. J. Appl. Phys.. (in press).

[文献書誌] H. Masuda: "Fabrication of a Nanostructured Diamond Honeycomb Film"Adv. Mater.. (in press).

[文献書誌] K. Honda: "Electrochemical Characterization of the Nanoporous Honeycomb Diamond Electrode as an Electrical Double Layer Capacitor"J. Electrochem. Soc.. (in press).

[文献書誌] H. Uchida: "Effects of Ionic Conductivity of Zirconia Electrolytes on the Polarization Behavior of Various Cathodes in Solid Oxide Fuel Cells"J. Electrochem. Soc.. 146・1. 1-7 (1999)

[文献書誌] H. Uchida: "High-Performance Electrode for Medium-Temperature Solid Oxide Fuel Cells-Control of Microstructure of Ceria-Based Anodes with Highly Dispersed Ruthenium Electrocatalysts"J. Electrochem. Soc.. 146・5. 1677-1682 (1999)

[文献書誌] H. Uchida: "High-Performance Electrode for Medium-Temperature Solid Oxide Fuel Cells-La(Sr)CoO3 Cathode with Ceria Interlayer on Zirconia Electrolyte"Electrochem. Solid-State Lett.. 2・9. 428-430 (1999)

[文献書誌] T. Toda: "Enhancement of the Electroreduction of Oxygen on Pt Alloys with Fe, Ni and Co"J. Electrochem. Soc.. 146・10. 3750-3756 (1999)

[文献書誌] M. Watanabe: "Design of CO Tolerant Anode Catalysts for Polymer Electrolyte Fuel Cells"Electrochemistry. 67・12. 1192-1196 (1999)

[文献書誌] Y. Zhu: "Oxidation of Carbon Monoxide at a Platinum Film electrode Studied by FTIR Spectroscopy with Attenuated Total Reflection Technique"Langmuir. 15・25. 8757-8764 (1999)

[文献書誌] M. Watanabe: "Oxidation of CO on Pt-Fe Alloy Electrode Studied by Surface Enhanced Reflection Absorption Spectroscopy"J. Phys. Chem.. (in press).

[文献書誌] M. Watanabe: "Mechanism of CO Tolerance at Pt-Alloy Anode Catalysts for Polymer Electrolyte Fuel Cells"Electrochemistry. 68.4. (2000)

[文献書誌] 内田 浩之: "高分子電解質型燃料電池の要素技術"日本機械学会誌. 101・952. 216-217 (1999)

[文献書誌] 内田 浩之: "最近の高分子電解質型燃料電池技術"月刊「化学工業」. 58・10. 756-761 (1999)

[文献書誌] 渡辺 政廣: "高分子膜燃料電池の基礎と応用"高分子. 148・12. 918-921 (1999)

[文献書誌] 渡辺 政廣: "燃料電池ークリーンエネルギーデバイス"機能材料. 20・1. 47-53 (2000)

[文献書誌] 渡辺 政廣: "全個体高分子型燃料電池の開発と実用"技術情報協会. 211 (1999)

[文献書誌] 渡辺 政廣: "PEM・燃料電池入門"環境新聞社. 235 (1999)

1999 年度実績報告書

米山宏阿南工業高等専門学校, 校長 (80029082)

[文献書誌] 横島時彦: "無電解CoFeBめっきを用いた磁気ヘッドコア作製プロセスの基礎的検討"日本応用磁気学会誌. 23・ 4-2. 1397-1400 (1999)

[文献書誌] 増川禎道: "高B_sーCoNiFe電析膜の軟磁気特性に及ぼす成膜条件の影響"日本応用磁気学会誌. 23・ 4-2. 1405-1408 (1999)

[文献書誌] 逢坂哲弥: "集積回路配線における精密めっき技術"応用物理. 68・11. 1237-1242 (1999)

[文献書誌] 内田浩之: "高分子電解質型燃料電池の要素技術"日本機械学会誌. 101・952. 216-217 (1999)

[文献書誌] 内田浩之: "最近の高分子電解質型燃料電池技術"月刊「化学工業」. 58・10. 756-761 (1999)

[文献書誌] 渡辺政廣: "高分子膜燃料電池の基礎と応用"高分子. 148・12. 918-921 (1999)

[文献書誌] 渡辺政廣: "燃料電池ークリーンエネルギーデバイス"機能材料. 20・1. 47-53 (2000)

[文献書誌] 渡辺政廣: "全個体高分子型燃料電池の開発と実用"技術情報協会. 211 (1999)

[文献書誌] 渡辺政廣: "PEM・燃料電池入門"環境新聞社. 235 (1999)