1998 年度実績報告書

カーボンアロイ-炭素材料の空間制御と新機能の展開-

研究課題

研究課題/領域番号	09243103
研究種目	特定領域研究(A)
研究機関	東京工業大学
研究代表者	安田榮一東京工業大学, 応用セラミックス研究所, 教授 (70016830)
研究分担者	田邊靖博東京工業大学, 応用セラミックス研究所, 助教授 (70163607) 稲垣道夫北海道大学, 工学部, 教授 (20023054) 大谷朝男群馬大学, 工学部, 教授 (10008469) 金子克美千葉大学, 理学部, 教授 (20009608) 遠藤守信信州大学, 工学部, 教授 (10021015)
キーワード	カーボンアロイ / 黒鉛 / ダイヤモンド / カルビン / ヘテロアトムアロイ / ホモアトミックアロイ / 炭素
研究概要	計画班29名、公募班48名の計77名を原子・結晶アロイ班、界面・微構造アロイ班、表面・裏面アロイ班、機能展開班ならびに総括班に分け、それぞれの分担者会議を3回、全体会議を2回、総括班会議を2回開催した。その中で、今年度の特徴は炭素分野以外からのメンバーが多いことから分担者会議でカーボンの基本のセミナーを開催し、1泊2日で、全員同じ宿舎に泊まり、夜遅くまで議論を深めることができた。また、炭素の用語辞典が世界的に無かったことから、用語辞典の編集の第一段階としての用語の洗い出しを行った。シンポジウムは7月28日・29日に群馬県桐生市において行った。また、成果報告会は千葉大学で炭素材料学会の研究会と合同で行った。70件以上の発表を全員で勉強し、議論を可能とするように1人2分のポスタープレビューを行い、その後ポスターで約3時間の個別な質疑が交わされた。これにより、幅広い議論が可能であった。成果報告会での全体会議において井口洋夫・元分子研所長の講演があり、炭素に関する研究の重要性に関してお話を伺うことができた。以上の全体会議、分担者会議、総括班会議によりカーボンアロイ学の検討、先端研究の進展、共同研究の実施により新分野の展開等が可能となった。

研究成果

(31件)

すべてその他

すべて文献書誌 (31件)

[文献書誌] 安田榮一: "C/C複合材料の新展開" まてりあ(Materia Japan). 37[4]. 226-229 (1998)
[文献書誌] 安田榮一、田邊靖博: "「炭素材料」から「カーボンアロイ」へ" 材料. 47[7]. 768-769 (1998)
[文献書誌] 安田榮一、早田喜穂: "炭素-炭素複合材料の展開" 高分子. 47[8]. 555-558 (1998)
[文献書誌] M.Endo,C.Kim,T.Hiraoka,T.Karaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown,M.S.Dresselhaus: "Structural Characterization of Carbons Obtained from Polyparaphenylenes Prepared by the Kovacic and Yamamoto Methods" Journal of Materials Research.13[7]. 2023-2030 (1998)
[文献書誌] M.Endo,C.Kim,T.Hiraoka,T.Karaki,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Li Storage Behavior in Polyparaphenylene(PPP)-Based Disordered Carbon as a Negative Electrode for Li Ion Batteries" Mol.Cryst.Liq.Sryst.310. 353-358 (1998)
[文献書誌] M.Endo,C.Kim,T.Karaki,T.Tamaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Structural Analysis of the B-doped Mesophase Pitch-based Graphite Fibers by Raman Spectroscopy" Phys.Rev.B. 58[14]. 8991-8996 (1998)
[文献書誌] M.Endo,C.Kim,T.Karaki,T.Tamaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Structural Characterization of Milled Mesophase Pitch-based Carbon Fibers" Carbon. 36[11]. 1633-1641 (1998)
[文献書誌] M.Endo,C.Kim,T.Karaki,T.Fujino,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "In-situ Raman Study of PPP-based Disordered Carbon as an Anode in a Li Ion Battery" Synth.Met.98. 17-24 (1998)
[文献書誌] M.Endo,K.Oshida,T.Furuta,F.Minoura,C.Kim,G.Dresselhaus and M.S.Dresselhaus: "Visualized Observation of Pores in Activated Carbon Fibers by HRTEM and Combined Image Processor" Supramolecular Science. 5[3]. 261-266 (1998)
[文献書誌] C.-H.Kiang,M.Endo,P.M.Ajayan,G.Dresselhaus and M.S.Dresselhaus: "Size Effects in Carbon Nanotubes" Phys.Rev.Lett.81[9]. 1869-1872 (1998)
[文献書誌] M.Endo,C.Kim,T.Karaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Anoda Performance in a Li Ion Battery based on Graphitized and B-doped Milled Mesophase Pitch-based Carbon Fibers" Carbon. (in press).
[文献書誌] M.J.Matthews,M.A.Pimenta,G.Dresselhaus,M.S.Dresselhaus and M.Endo: "Origin of Dispersive Effects of the Raman D Band in Carbon Materials" Phys.Rev.B. (in press).
[文献書誌] K.Kaneko,C.Ishii,N.Nagai,Y.Hanzawa,N.Setoyama and T.Suzuki: "Characterization of Porous Carbons with High Resolution αs-analysis and Low Temperature Magnetic Susceptibility" Advances Colloid Sci.[76-77]. 295-320 (1998)
[文献書誌] K.Kaneko: "Nanospace Geometry Sensitive Molecular Assembly" Supramolecular Sci.5. 267-273 (1998)
[文献書誌] K.Kaneko,Y.Hanzawa,T.Iiyama,T.Kanda,and T.Suzuki: "Cluster-mediated Water Adsorption on Carbon Nanospaces" Adsorption. [5]. 7-13 (1999)
[文献書誌] Y.Hanzawa,K.Kaneko,N.Yoshizawa,R.W.Pekala and M.S.Dresselhaus: "The Pore Structure Determination of Carbon Aerogels" Adsorption. [4]. 187-195 (1998)
[文献書誌] Y.Nishi,T.Suzuki,and K.Kaneko: "NO Reduction Over Ultrafine Metal-tailored Microporous Carbon at Ambient Temperature" Carbon. [36]. 1870-1871 (1998)
[文献書誌] M.E.-Merraoui,H.Tamai,H.Yasuda,T.Kanata,J.Mondori,K.Nadai and K.Kaneko: "Pore Structures of Activated Carbon Fibers from Organometallics/pitch Composites by Nitrogen Adsorption" Carbon. [36]. 1769-1774 (1998)
[文献書誌] N.Setoyama,T.Suzuki,K.Kaneko: "Simulation Study on Relationship between High Resolution alpha s-plot and Pore Size Distribution for Activated Carbon" Carbon. 36[10]. 1459-1467 (1998)
[文献書誌] M.Ruike,N.Murase,J.Imai,C.Ishii,T.Suzuki and K.Kaneko: "Intrasolid Interfacial Fractality of a Less-Crystalline Solid" J.Colloid Interface Sci.[207]. 355-362 (1998)
[文献書誌] K.Kaneko,J.Suzuki,and C.Ishii: "Low Temperature Mgnetic Properties of an O_2 and H_2O Mixed Molecular Assembly Confined in a Graphite Nanospace" Chem.Phys.Lett.[282]. 176-180 (1998)
[文献書誌] J.Miyawaki,T.Kanda,T.Suzuki,T.Okui,Y.Maeda and K.Kaneko: "Macroscpic Evidence of Enhanced Formation of Methane Nanohydrates in Hydrophobic Nanospaces" J.Phys.Chem.102B[12]. 2187-2192
[文献書誌] T.Ohkubo,T.Iiyama,K.Nishikawa,T.Suzuki and K.Kaneko: "Pore Width-Dependent Ordering of C_2H_5OH Molecules Confined in Graphitic Slit Nanospaces" J.Phys.Chem.(in press).
[文献書誌] K.Kaneko,N.Setoyama,G.Li and H.Touhara: "Pore Structures and adsorption properties of fluorinated activated carbon fibers" Tanso. (in press).
[文献書誌] J.Przepiorski,S.Shiraishi and A.Oya: "Potassium-Loaded ACF against H2S Gas by Blending and Dipping Method:Effect of Subsequent Deodorizations and Regenerations on Deodorant Abilities" J.Odor Res.and Eng.29[2]. 108-114 (1998)
[文献書誌] J.Przepiorski and A.Oya: "K_2CO_3-Loaded Deodorizing Activated Carbon Fibre against H_2S Gas:Factors Influencing the Deodorizing Efficiency and the Regeneration Method" J.Mater.Sci.Lett.17. 679-682 (1998)
[文献書誌] J.m.Skowronski,P.Krawczyk,A.Hirano,J.Ozaki and A.Oya: "Elektrochemiczne Wlasciwosci Wlokien Weglowych W Roztworze Alkalicznym(Electrochemical Properties of Carbon Fibers in Alkaline Solution)" Karbo. 43. 49-52 (1998)
[文献書誌] J.Ozaki,K.Nozawa and A.Oya: "Controlling Factor of Electrocatalytic Activity of Iron-Containing Carbon Materials" Chem.Lett.573-574 (1998)
[文献書誌] R.Imamura,K.Matsui,J.Ozaki and A.Oya: "Steam Activation of a Phosphorous-Containing Phenolic Resin-Based Carbon Fiber" Carbon. 36. 1243-1245 (1998)
[文献書誌] R.Imamura,K.Matsui,S.Takeda,J.Ozaki and A.Oya: "A New Role for Phosphorus in Graphitization of Phenolic Resin" Carbon. 37. 261-267 (1999)
[文献書誌] R.Imamura,K.Matsui,J.Ozaki and A.Oya: "Ammonia Deodorization Ability of Activated Carbon Fibers Prepared from Phenolic Resin Incorporating Phosphorus in the Network Structure" Carbon. (in press).

1998 年度 実績報告書

カーボンアロイ-炭素材料の空間制御と新機能の展開-

研究代表者

安田 榮一 東京工業大学, 応用セラミックス研究所, 教授 (70016830)

研究成果

[文献書誌] 安田榮一: "C/C複合材料の新展開" まてりあ(Materia Japan). 37[4]. 226-229 (1998)

[文献書誌] 安田榮一、田邊靖博: "「炭素材料」から「カーボンアロイ」へ" 材料. 47[7]. 768-769 (1998)

[文献書誌] 安田榮一、早田喜穂: "炭素-炭素複合材料の展開" 高分子. 47[8]. 555-558 (1998)

[文献書誌] M.Endo,C.Kim,T.Hiraoka,T.Karaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown,M.S.Dresselhaus: "Structural Characterization of Carbons Obtained from Polyparaphenylenes Prepared by the Kovacic and Yamamoto Methods" Journal of Materials Research.13[7]. 2023-2030 (1998)

[文献書誌] M.Endo,C.Kim,T.Hiraoka,T.Karaki,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Li Storage Behavior in Polyparaphenylene(PPP)-Based Disordered Carbon as a Negative Electrode for Li Ion Batteries" Mol.Cryst.Liq.Sryst.310. 353-358 (1998)

[文献書誌] M.Endo,C.Kim,T.Karaki,T.Tamaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Structural Analysis of the B-doped Mesophase Pitch-based Graphite Fibers by Raman Spectroscopy" Phys.Rev.B. 58[14]. 8991-8996 (1998)

[文献書誌] M.Endo,C.Kim,T.Karaki,T.Tamaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Structural Characterization of Milled Mesophase Pitch-based Carbon Fibers" Carbon. 36[11]. 1633-1641 (1998)

[文献書誌] M.Endo,C.Kim,T.Karaki,T.Fujino,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "In-situ Raman Study of PPP-based Disordered Carbon as an Anode in a Li Ion Battery" Synth.Met.98. 17-24 (1998)

[文献書誌] M.Endo,K.Oshida,T.Furuta,F.Minoura,C.Kim,G.Dresselhaus and M.S.Dresselhaus: "Visualized Observation of Pores in Activated Carbon Fibers by HRTEM and Combined Image Processor" Supramolecular Science. 5[3]. 261-266 (1998)

[文献書誌] C.-H.Kiang,M.Endo,P.M.Ajayan,G.Dresselhaus and M.S.Dresselhaus: "Size Effects in Carbon Nanotubes" Phys.Rev.Lett.81[9]. 1869-1872 (1998)

[文献書誌] M.Endo,C.Kim,T.Karaki,Y.Nishimura,M.J.Matthews,S.D.M.Brown and M.S.Dresselhaus: "Anoda Performance in a Li Ion Battery based on Graphitized and B-doped Milled Mesophase Pitch-based Carbon Fibers" Carbon. (in press).

[文献書誌] M.J.Matthews,M.A.Pimenta,G.Dresselhaus,M.S.Dresselhaus and M.Endo: "Origin of Dispersive Effects of the Raman D Band in Carbon Materials" Phys.Rev.B. (in press).

[文献書誌] K.Kaneko,C.Ishii,N.Nagai,Y.Hanzawa,N.Setoyama and T.Suzuki: "Characterization of Porous Carbons with High Resolution αs-analysis and Low Temperature Magnetic Susceptibility" Advances Colloid Sci.[76-77]. 295-320 (1998)

[文献書誌] K.Kaneko: "Nanospace Geometry Sensitive Molecular Assembly" Supramolecular Sci.5. 267-273 (1998)

[文献書誌] K.Kaneko,Y.Hanzawa,T.Iiyama,T.Kanda,and T.Suzuki: "Cluster-mediated Water Adsorption on Carbon Nanospaces" Adsorption. [5]. 7-13 (1999)

[文献書誌] Y.Hanzawa,K.Kaneko,N.Yoshizawa,R.W.Pekala and M.S.Dresselhaus: "The Pore Structure Determination of Carbon Aerogels" Adsorption. [4]. 187-195 (1998)

[文献書誌] Y.Nishi,T.Suzuki,and K.Kaneko: "NO Reduction Over Ultrafine Metal-tailored Microporous Carbon at Ambient Temperature" Carbon. [36]. 1870-1871 (1998)

[文献書誌] M.E.-Merraoui,H.Tamai,H.Yasuda,T.Kanata,J.Mondori,K.Nadai and K.Kaneko: "Pore Structures of Activated Carbon Fibers from Organometallics/pitch Composites by Nitrogen Adsorption" Carbon. [36]. 1769-1774 (1998)

[文献書誌] N.Setoyama,T.Suzuki,K.Kaneko: "Simulation Study on Relationship between High Resolution alpha s-plot and Pore Size Distribution for Activated Carbon" Carbon. 36[10]. 1459-1467 (1998)

[文献書誌] M.Ruike,N.Murase,J.Imai,C.Ishii,T.Suzuki and K.Kaneko: "Intrasolid Interfacial Fractality of a Less-Crystalline Solid" J.Colloid Interface Sci.[207]. 355-362 (1998)

[文献書誌] K.Kaneko,J.Suzuki,and C.Ishii: "Low Temperature Mgnetic Properties of an O_2 and H_2O Mixed Molecular Assembly Confined in a Graphite Nanospace" Chem.Phys.Lett.[282]. 176-180 (1998)

[文献書誌] J.Miyawaki,T.Kanda,T.Suzuki,T.Okui,Y.Maeda and K.Kaneko: "Macroscpic Evidence of Enhanced Formation of Methane Nanohydrates in Hydrophobic Nanospaces" J.Phys.Chem.102B[12]. 2187-2192

[文献書誌] T.Ohkubo,T.Iiyama,K.Nishikawa,T.Suzuki and K.Kaneko: "Pore Width-Dependent Ordering of C_2H_5OH Molecules Confined in Graphitic Slit Nanospaces" J.Phys.Chem.(in press).

[文献書誌] K.Kaneko,N.Setoyama,G.Li and H.Touhara: "Pore Structures and adsorption properties of fluorinated activated carbon fibers" Tanso. (in press).

[文献書誌] J.Przepiorski,S.Shiraishi and A.Oya: "Potassium-Loaded ACF against H2S Gas by Blending and Dipping Method:Effect of Subsequent Deodorizations and Regenerations on Deodorant Abilities" J.Odor Res.and Eng.29[2]. 108-114 (1998)

[文献書誌] J.Przepiorski and A.Oya: "K_2CO_3-Loaded Deodorizing Activated Carbon Fibre against H_2S Gas:Factors Influencing the Deodorizing Efficiency and the Regeneration Method" J.Mater.Sci.Lett.17. 679-682 (1998)

[文献書誌] J.m.Skowronski,P.Krawczyk,A.Hirano,J.Ozaki and A.Oya: "Elektrochemiczne Wlasciwosci Wlokien Weglowych W Roztworze Alkalicznym(Electrochemical Properties of Carbon Fibers in Alkaline Solution)" Karbo. 43. 49-52 (1998)

[文献書誌] J.Ozaki,K.Nozawa and A.Oya: "Controlling Factor of Electrocatalytic Activity of Iron-Containing Carbon Materials" Chem.Lett.573-574 (1998)

[文献書誌] R.Imamura,K.Matsui,J.Ozaki and A.Oya: "Steam Activation of a Phosphorous-Containing Phenolic Resin-Based Carbon Fiber" Carbon. 36. 1243-1245 (1998)

[文献書誌] R.Imamura,K.Matsui,S.Takeda,J.Ozaki and A.Oya: "A New Role for Phosphorus in Graphitization of Phenolic Resin" Carbon. 37. 261-267 (1999)

[文献書誌] R.Imamura,K.Matsui,J.Ozaki and A.Oya: "Ammonia Deodorization Ability of Activated Carbon Fibers Prepared from Phenolic Resin Incorporating Phosphorus in the Network Structure" Carbon. (in press).

1998 年度実績報告書

安田榮一東京工業大学, 応用セラミックス研究所, 教授 (70016830)