1999 年度実績報告書

カーボンアロイ―炭素材料の空間制御と新機能の展開―

研究課題

研究課題/領域番号	09243103
研究機関	東京工業大学
研究代表者	安田榮一東京工業大学, 応用セラミックス研究所, 教授 (70016830)
研究分担者	大谷朝男群馬大学, 工学部, 教授 (10008469) 金子克美千葉大学, 理学部, 教授 (20009608) 遠藤守信信州大学, 工学部, 教授 (10021015) 田邊靖博東京工業大学, 応用セラミックス研究所, 助教授 (70163607) 稲垣道夫北海道大学, 工学部, 教授 (20023054)
キーワード	カーボンアロイ / 黒煙 / ダイヤモンド / カルビン / ヘテロアトムアロイ / ホモアトミックアロイ / 炭素
研究概要	計画班30名、公募班46名の計76名を原子・結晶アロイ班、界面・微構造アロイ班、表面・裏面アロイ班、機能展開班ならびに総括班に分け、それぞれの分担者会議を2回、全体会議を2回、総括班会議を2回開催した。その中で、今年度の特徴は、本研究から発展しそうな新分野として「B-C-N物質」「生物関連物質」「新しい反応系」の3つを取り上げ、検討を行った。また、昨年同様、分担者会議でカーボンの基本のセミナーを開催し、1泊2日で、全員同じ宿舎に泊まり、夜遅くまで議論を深めることができた。また、炭素の用語辞典が世界的に無かったことから、用語辞典の編集の第一段階としての用語の洗い出しを行ない、研究費とは別に編集委員会を作り、この委員会に洗い出した用語を引き継いだ。シンポジウムは7月27・28日に仙台において行った。その中で増本健氏の講演があり、長期的スパンに立った研究の進め方に関してお話を伺うことができた。また、成果報告会は長野市で炭素材料学会の研究会と合同で行った。68件の発表を全員で勉強し、議論を可能とするように1人6分のプレゼンテーションと4分の質疑を行った。以上の全体会議、分担者会議、総括班会議によりカーボンアロイ学の検討を行い、成果として「カーボンアロイ」の解説書を英語で出版することを検討し、先端研究の進展、共同研究の実施により、新分野の展開等が可能となった。

研究成果
(100件)

すべてその他

すべて文献書誌 (100件)

[文献書誌] 阿久沢昇: "GICの新しい反応場への応用"表面. 35. 647-651 (1997)
[文献書誌] N. Kobayashi, T. Enoki, Y. Murakami, H. Suematsu and M. Endo: "Magnetic Properties of Adsorbed Oxygen in Microporous Carbon"Mol. Cryst. Liq. Cryst.. 360. 103-110 (1997)
[文献書誌] M. Endo, K. Takeuchi, T. Hiraoka, T. Furuta, T. Kasai, X. Sun, C.H. Kiang and M.S. Dresselhaus: "Stacking Nature of Graphene Layers in Carbon Nonotubes and Nanofibers"J. Phys. Chem. Solids. 58 [11]. 1702-1712 (1997)
[文献書誌] 押田京一、小林稔、古田照実、遠藤守信、オバランアグネス: "アモルファスカーボンフィルムの透過電子顕微鏡像への画像解析法の適用"電子情報通信学会論文誌. J80-C-[12]II. 421-426 (1997)
[文献書誌] T. Yamashita, T. Enoki, M. Uruichi, K. Yakushi, T. Miyamae and T. Miyazaki: "Galvanomagnetic, Optical Properties and Ultraviolet Photoelectron Spectra of Potassium-Oxygen-Graphite Intercalation Compounds"J. Phys. Soc. Jpn.. 66 [1]. 158-168 (1997)
[文献書誌] N. Kobayashi, T. Enoki, Y. Murakami, H. Suematsu and M. Endo: "Magnetic Properties of Adsorbed Oxygen in Microporpous Carbon"Mol. Cryst. Liq. Cryst.. 306. 103-110 (1997)
[文献書誌] I. Suzuki, M. Suzuki, H. Sato and T. Enoki: "Successive Magnetic Phase Transitions in CucCo1-cCl2-Fecl3 GBICs"Solid State Commun.. 104 [10]. 581-585 (1997)
[文献書誌] 榎敏明: "グラファイト層間化合物の水素吸収と金属水素の創生"ニューダイヤモンド. 13[3]. 14-19 (1997)
[文献書誌] T. Ishii, R. Sekine, T. Enoki, E. Miyazaki, T. Miyamae and T. Miyazaki: "DV-Xα Calculation and Ultraviolet Photoelectron Spectra of old Trichloride-Graphite Intercalation Compound 8AuCl3-GIC)"J. Phys. Soc. Jpn.. 66 [11]. 3424-3433 (1997)
[文献書誌] M. Yoshida, M. Fujita, P.W. Fowler and E.C. Kirby: "Non-Bonding Orbitals in Graphite, Carbon Tubules, Toroids and Fullerenes"J. Chem. Soc., Faraday Trans.. 93. 1037-1043 (1997)
[文献書誌] M. Fujita, M. Igami and K. Nakada: "Lattice Distortion in Nanographite Ribbons"J. Phys. Soc. Jpn.. 66 [7]. 1864-1867 (1997)
[文献書誌] 藤田光孝、若林克法、伊神正貫、中田恭子、草部浩一: "ナノグラファイトの電子物性―端のあるπ電子系におけるナノメター効果―"固体物理. 32[3]. 179-188 (1997)
[文献書誌] 藤田光孝: "π電子系カーボン材料と次元性"炭素. [180]. 257-265 (1997)
[文献書誌] K. Kusanabe, K. Wakabayashi, M. Igami, K. Nakada and M. Fujita: "Magnetism of Nanometer-scale Graphite with Edge or Topological Defects"Mol. Cryst. Liq. Cryst.. 305. 445-454 (1997)
[文献書誌] M. Fujita: "π Electronic States of Nanographite. "Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials""4. 445-454 (1997)
[文献書誌] 藤田光孝: "多面体としてみたフラーレンの構造―グラファイトの立体化―"SUT BULLETIN(東京理科大学出版会). 14[2]. 16-19 (1997)
[文献書誌] Y. Hishiyama, K. Igarashi, I. Kanaoka, H. Fujii, T. Koidesawa, Y. Shimazawa and A. Yoshioka: "Graphitization Behavior of Kapton-derived Carbon Film Related to Structure, Microtexture and Transport Properties"Carbon. 35 [5]. 657-668 (1997)
[文献書誌] Y. Kaburagi and Y. Hishiyama: "A Scaling Approach to the Transverse Magnetoresistance of Kish Graphite at 77K"Carbon. 35 [8]. 1151-1156 (1997)
[文献書誌] N. Iwashita, M. Inagaki and Y. Hishiyama: "Relations Between Degree of Graphitization and Galvanomagnetic Properties of Pyrolitic Carbons and Cokes"Carbon. 35 [8]. 1073-1077 (1997)
[文献書誌] T. Iiyama, K. Nishikawa, T. Suzuki and K. Kaneko: "Study of the Structure of Water Molecular Assembly in a Hydrophobic Nanospace at Low Temperature with in situ X-ray Diffraction"Chem. Phys. Lett.. 274. 152-158 (1997)
[文献書誌] M. Sato, T. Sukegawa, T. Suzuki and K. Kaneko: "Surface Fractal Dimension of Less-Crystalline Carbon Micropore Walls"J. Phys. Chem.. B101 [10]. 1845-1850 (1997)
[文献書誌] Y. Hanzawa and K. Kaneko: "Lack of a Predominant Adsorption of Water Vapor on Carbon Mesopores"Langmuir. 13 [22]. 5802-5804 (1997)
[文献書誌] T. Iiyama, K. Nishikawa, T. Suzuki, T. Otowa, M. Hijiriyama, Y. Nojima and K. Kaneko: "Molecular Assembly Structure of CCl4 in Graphic Nanospaces"J. Phys. Chem.. 101 [16]. 3037-3042 (1997)
[文献書誌] H.A. Yu, K. Kaneko, S. Otani, Y. Sasaki and S. Yoshimura: "A Carbonacrous Thin Film Made by CVD and A Caron/n-Type Silicon (C/n-Si) Photovoltanic Cell"Carbon. 36 [1-2]. 139-145 (1997)
[文献書誌] 木塚徳志、平原佳織、出口俊二、成瀬幹夫: "カーボンナノチューブの疲労の原子過程"日本金属学会会報 37(1997)(5). (1997)
[文献書誌] 小島昭、平野徳彦: "炭素繊維による河川およびため池の水質浄化"環境技術. 26[11]. 720-723 (1997)
[文献書誌] Y. Korai, S. Ishida, F. Watanabe, S.H. Yoon, Y.G. Wang, I. Mochida, I. Kato, T. Nakamura, Y. Sasaki and K. Komatsu: "Preparation of Carbon Fiber from Isotropic Pitch Containing Mesophase Spheres"Carbon. 35 [12]. 1733-1737 (1997)
[文献書誌] M. Yamamoto, K. Kusakabe, J. Hayashi, and S. Murooka: "Carbon Molecular Sieve Membrane Formed by Oxidative Carbonization of a Copolyimide Film Coated on a Porous Support Tube"J. Membr. Sci.. 133 [2]. 195-205 (1997)
[文献書誌] J. Hayashi, M. Yamamoto, K. Kusakabe and S. Murooka: "Effect of Oxidation on Gas Permeation of Carbon Molecular Sieving Membranes Based on BPDA-pp'ODA polyimide"Industrial & Engineering Chemistry Research. 36 [6]. 2134-2140 (1997)
[文献書誌] J. Hayashi, H. Mizuta, M. Yamamoto, K. Kusakabe and S. Murooka: "Pore Size Control of Carbonized BPDA-pp'ODA Polyimide Membrane by Chemical Vapor Deposition of Carbon"Journal of Membrane Science. 124 [2]. 243-251 (1997)
[文献書誌] B.-K. Sea, K. Kusakabe and S. Murooka: "Pore Size Control and Gas Permeation Kinetics of Silica Membranes by Pyrolysis of Phenyl-Substituted Ethoxysilanes with Cross-Flow through a Porous Support Wall"Journal of Membrane Science. 130. 41-52 (1997)
[文献書誌] S. Murooka, M. Yamamoto and K. Kusakabe: "Polyimide-Based Carbon Molecular Sieving Membranes"Theories and Applications of Chem. Eng.. 3. 313-316 (1997)
[文献書誌] T. Kyotani, L. Tsai and A. Tomita: "Formation of Platinum Nanorods and Nanoparticles in Uniform Carbon Nanotubes Prepared by a Template Carbonization Method"J. Chem. Soc., Chem. Commun.. 701-702 (1997)
[文献書誌] T. Kyotani, H. Moriyama and A. Tomita: "High Temperature Treatment of Polyfurfurly Alcohol/Graphite Oxide Intercalation Compound"Carbon. 35 [8]. 1185-1187 (1997)
[文献書誌] M. Matsuhashi, K. Endoh, A.N. Pankrushina, H. Watanabe, H. Yamamura, M. Komiyama, S. Endo, M. Tobi, H. Oshima, Y. Mano, M. Hyodo, T. Kaneko and S. Otani: "Growth-Promoting Effect of Carbon Material Upon Bacterial Cells Propagating Through a Distance"J. Gen. Appl. Microbiol.. 43 [4]. 225-230 (1997)
[文献書誌] S. Motojima, K. Kojima, T. Hamamoto, N. Ueshima and H. Iwanaga: "Preparation and High Temperature Properties of Novel Ceramics Microcoils"Electrochem. Soc. Proc.. 97-39. 595-602 (1997)
[文献書誌] S. Motojima, T. Hamamoto, N. Ueshima, K. Kojima and H. Iwanaga: "Preparation and Properties of Ceramic Micro-coils by CVD Process"Electrochem. Soc. Proc.. 97-25. 433-440 (1997)
[文献書誌] 元島栖二、岩永浩: "新規の電磁波吸収材料:カーボンマイクロコイルの気相合成とその電磁波吸収特性"機能材料. 17[7]. 37-44 (1997)
[文献書誌] 元島栖二: "TiC/Cマイクロコイル"材料技術. 15[3]. (1997)
[文献書誌] T. Nakajima and M. Koh: "Synthesis of High Crystalline Carbon-Nitrogen Layered Compounds by CVD Using Nickel and Cobalt Catalyst"Carbon. 35 [2]. 203-208 (1997)
[文献書誌] T. Iiyama, K. Nishikawa, T. Suzuki, T. Otowa, M. Hijiriyama, Y. Nojima and K. Kaneko: "Molecular Assembly Structure of CCl4 in Graphite Nanospaces"J. Phys. Chem.. B101. 3037-3042 (1997)
[文献書誌] T. Iiyama, K. Nishikawa, T. Suzuki, K. Kaneko: "Study of the Structure of a Water Molecular Assembly in a Hydrophobic Nanospace at Low Temperature with in Situ X-ray Diffraction"Chem. Phys. Lett.. 274. 152-158 (1997)
[文献書誌] T. Nagano, Y. Iizuka, T. Shimazaki and C. Oshima: "Surface Phonons of Na-induced superstructures on Al(111)"Phys. Rev.. B55 [15]. 10064-10073 (1997)
[文献書誌] C. Oshima and A. Nagashima: "Ultra-Thin Epitaxial Films of Graphite and Hexagonal Boron Nitride on Solid Surfaces"J. Phys. ; Condens. Matter 9. 1-20 (1997)
[文献書誌] Y. Gamo, A. Nagashima, M. Wakabayashi, M. Terai and C. Oshima: "Atomic Structure of Monolayer Graphite Formed on Ni(111)"Surface Sci. 374. 61-64 (1997)
[文献書誌] M. Terai, Y. Gamo, N. Hasegawa and C. Oshima: "Electronic Band Structures of Monolayer Hexagonal Boron Nitride on TaC(111)"J. Surface Analysis. [3]. 473-477 (1997)
[文献書誌] C. Oshima: "Characterization of Ultra Thin Films and Solid Surfaces by High Resolution Electron Energy Loss Spectroscopy"J. Surface Analysis. [3]. 322-327 (1997)
[文献書誌] Y. Gamo, M. Terai, A. Nagashima and C. Oshima: "Atomic Structural Analysis of a Monolayer Epitaxial Film of Hexagon Boron Nitride/Ni(111) by LEED Intensity Analysis"Sci. Rep. Ritu.. A44. 211-214 (1997)
[文献書誌] E. Rokuta, Y. Hasegawa, K. Suzuki, Y. Gamou and C. Oshima: "Phonon Dispersion of an Epitaxial Monolayer Film of Hexagonal Boron Nitride on Ni(111)"Phys. Rev. Lett.. 79 [23]. 4609-4612 (1997)
[文献書誌] 大島忠平、六田英治、長島礼人: "単原子層六方晶窒化ホウ素のフォノン"日本物理学会誌. 52[8]. 610-613 (1997)
[文献書誌] 長谷川徳慶、蒲生康男、寺井真之、奥沢昌彦、大島忠平、大谷茂樹: "グラファイト・ナノクリスタルおよびグラファイト・ナノリボンの作製"炭素. [180]. 229-234 (1997)
[文献書誌] C. Oshima: "An Apparatus for High Resolution Field Emission Spectroscopy"Advances in Colloid and Interface Science. 71/72. 353-369 (1997)
[文献書誌] J. Ozaki, N. Endo, W. Ohizumi, K. Igarashi, M. Nakamura, A. Oya, S. Yoshida and T. Iizuka: "Novel Preparation Method for the Production of Mesoporous Carbon Fiber from a Polymer Blend"Carbon. 35 [7]. 1031-1033 (1997)
[文献書誌] 王寧、大谷朝男: "抗菌力を有する銀/酸化マンガン担持脱臭性活性炭素繊維の調製と性質"臭気の研究. 28[6]. 399-403 (1997)
[文献書誌] J. Ozaki, N. Ohkawa and A. Oya: "A Spectroscopic Study on Benzene Soluble Faction from Naphthalene Pitch"Carbon. 35 [10-11]. 1651-1653 (1997)
[文献書誌] J. Ozaki, W. Ohizumi, N. Endo, A. Oya, S. Yoshida, T. Iizuka, M.C.Roman-Martinez and Linares-Solano: "Preparation of Platinum Loaded Carbon Fiber By Using Polymer Blend"Carbon. 35 [10-11]. 1676-1677 (1997)
[文献書誌] 尾崎純一、大谷朝男: "活性炭素繊維の高機能化―表面機能を意識した材料設計―"表面. 35[10]. 535-543 (1997)
[文献書誌] 大谷朝男: "活性炭素繊維に金属を均一担持"化学工業日報. (1997)
[文献書誌] K. Kokaji, A. Oya, K. Maruama, M. Yamada and M. Shiraishi: "Carbonization and Graphitization Behavior of Decacyclene"Carbon. 35 [2]. 253-258 (1997)
[文献書誌] J. Przepiorsk, Y. Abe, S. Yoshida and A. Oya: "Preferential Supporting of Potassium Carbonate around the Peripheral Region of Activated Carbon Fibre"J. Mater. Sci. Lett.. [16]. 1312-1314 (1997)
[文献書誌] J. Alcaniz-Monge, D. Cazorla-Amoros, A. Linares-Solano, A. Oya, A. Sakamoto and K. Hoshi: "Preparation of General Purpose Carbon Fibers from Coal Tar Pitches with Low Softening point"Carbon. 35 [8]. 1079-1087 (1997)
[文献書誌] 大谷朝男: "浄水用抗菌性活性炭素繊維"防菌防黴. 25[3]. 175-182 (1997)
[文献書誌] 大谷朝男: "金属粒子を担持した消臭性活性炭素繊維―調整法と構造、性質―"臭気の研究. 28[2]. 57-63 (1997)
[文献書誌] S. Shimada, K. Nakajima and M. Inagaki: "Oxidation of Single Crystals of Hafnium Carbide in a Temperature Range of 600 to 900゜"J. Am. Ceram. Soc.. 80 [7]. 1749-1756 (1997)
[文献書誌] S. Shimada: "Microstructural Observation of ZrO2 Scales Formed by Oxidation of ZrC Single Crystals with Formation of Carbon"Solid State Ionics. 101-103. 749-753 (1997)
[文献書誌] H. Noguchi, Y. Kubota and T. Takarada: "Diamond/SiC Double Layer Membrane for X-Ray Mask"J. Electrochem. Soc.. 144 [8]. 2909-2912 (1997)
[文献書誌] H. Noguchi, Y. Kubota and T. Takarada: "Fabrication and Evaluation of Diamond/SiC Double Layer Membrane for X-Ray Mask"J. Electrochem. Soc.. 144 [9]. 3304-3308 (1997)
[文献書誌] H. Tamai, M. Ikeuchi, S. Kojima, H. Yasuda: "Extremely Large Mesoporous Carbon Fibers Synthesized by the Addition of Rare Earth Metal Complexes and Their Unique Adsorption Behaviors"Ad. Mateirals, 1997. 55-58 (1997)
[文献書誌] N. Yoshizawa, Y. Yamada, T. Furuta, M. Shiraishi, H. Tamai, S. Kojima and H. Yasuda: "Coal-based Activated Carbons Prepared with Organometallics and Their Mesoporous Structure"Energy & Fuels. 11. 327-330 (1997)
[文献書誌] 玉井久司: "有機金属錯体とピッチ焼成均一分散の炭素材"化学工業日報. (1997)
[文献書誌] Y. Tanabe, Y. Hotta, T. Akatsu, S. Yamada and E. Yasuda: "Shear Strength of C/C Composites Containing a Inorganic Compound Effective for Anti-oxidation"J. Mater. Sci. Lett.. [16]. 557-559 (1997)
[文献書誌] K. Yamada, G. Burkard, Y. Tanabe and A.B. Sawaoka: "Concentric Shell Carbon : Curling Process of Graphite Layers"Carbon. 35 [12]. 1844-1846 (1997)
[文献書誌] T. Terai, Y. Takanashi, Masumura and T. Yoneoka: "Heat Capacity and Phase Transition of Zircaloy-4"Journal of Nuclear Materials. 247. 222-226 (1997)
[文献書誌] Takayuki Terai: "Research and Development on Ceramic Coatings for Fusion Reactor Blankets"Journal of Nuclear Materials. 248. 153-158 (1997)
[文献書誌] T. Yamabe, K. Tanaka, H. Ago, K. Yoshizawa and S. Yata: "Structure and Properties of Deeply Li-Doped Polyacenic Semiconductor (PAS)"Synth. Met.. 86. 2411-2414 (1997)
[文献書誌] H. Ago, K. Nagata, K. Yoshizawa, K. Tanaka, and T. Yamabe: "Theoretical Study of Lithium-Doped Polycyclic Aromatic Hydrocarbons"Bull. Chem. Soc. Jpn.. 70. 1717-1726 (1997)
[文献書誌] K. Tanaka, H. Ago, T. Yamabe, K. Okahara and M. Okada: "Bond Alternation in Carbon Nanotubes Including σ (sigma)-Electrons"International Journal of Quantum Chemistry. 63. 637-644 (1997)
[文献書誌] K. Yoshizawa, K. Kato and T. Yamabe: "Possible D6h Structures in Neutral and Negatively-Charged Cyclic Polyenes"Synth. Met.. 86. 2397-2398 (1997)
[文献書誌] K. Yoshizawa, K. Yahara, K. Tanaka and T. Yamabe: "Bandgap Oscillation in Polyphenanthrenes"J. Phys. Chem.. B102 [3]. 498-506 (1997)
[文献書誌] T. Yamamoto, H. Suganuma, T. Maruyama, T. Inoue, Y. Muramatsu, M. Arai, D. Domarudin, N. Ooba, S. Tomaru, S. Sasaki and K. Kubota: "Pi-Conjugated and Light Emitting Poly (4,4'0dialkyl-2,2'-bithiazole-5,5'-diyl) and Their Analogues Constituted of electron accepting Five Membered Ring. Preparation, Regioregular Structure, Face-to-face Stacking, and Electrochemical and Optical Properties"Chemistry of Materials. 9. 1217-1225 (1997)
[文献書誌] T. Yamamoto and H. Hayashi: "π-Conjugated Soluble and Fluorescent Poly (thiophene-2,3-diyl)s with Phenolic, Hindered Phenolic and p-C6H4OCH3 Substituents. Preparation, Optical Properties, and Redox Reaction"Journal of Polymer Science : Part A : Polymer Chemistry. 35. 463-474 (1997)
[文献書誌] I. Yamaguchi, K. Osakada and T. Yamamoto: "Introduction of Long Alkyl Side Chain to Poly (benzimidazole)s. N-Alkylation of the Imidazole Ring and Synthesis of Nobel side Chain Polyotaxanes"Macromolecules. 30 [15]. 4288-4294 (1997)
[文献書誌] T. Yamamoto and T. Shimizu: "New π-conjugated Polymers Containing Tetrathiavulvalence as the Monomeric Unit"J. Meter. Chem.. 7 [10]. 1967-1968 (1997)
[文献書誌] K. Honda, T. Maruyama and T. Yamamoto: "An Attempt to Synthesis Star-type Conjugated Polymer, Poly(areleneethnylene), Formed by Palladium-catalyzed Coupling of π-conjugated Oligomeric Poly (arylene ethnylene) with 1,3,5-triethynylbenzene and 1,2,4,5-tetradthynylbenezene"Synthetic Metals. 90. 153-155 (1997)
[文献書誌] T. Yamamoto, Bang-Linlee, H. Hayashi, N. Saito and T. Maruyama: "N-oxides and N-ylides of pi-Conjugated Poly(arylene)s. Preparation and Properties of the Polymers"Polymer. 38. 4233-4239 (1997)
[文献書誌] S.G. Zhang, Y. Fujii, H.: "Relationship Between the Local Structures of Titanium Oxide Photocatalysts and their Reactivities -XAFS UV, Photoluminescence and Photoreaction Investigations-"J. de Phys. (Colloq.). 7 [2]. 883-885 (1997)
[文献書誌] Y. Ichihashi, H. Yamashita and M. Anpo: "Photocatalytics Reduction of CO2 with H2O on Ti-MCM-41 and Ti-MCM-48 Mesoporous Zeolites at 328 K"J. de Phys. (Colloq.). [7]. 659-660 (1997)
[文献書誌] Yamashita, K Koyano, T. Tatsumi and M. Anpo: "XAFS Studies on The Metal Ion (Cu, Ag) Photocatalysts Prepared within Zeolite Cavities Using an Ion-Exchange Method"J. de Phys. (Colloq.). 7 [2]. 941-942 (1997)
[文献書誌] 安保正一、市橋祐一、山下弘巳: "NOx除去を目指した高活性な酸化チタンおよび可視光で作用する第2世代の酸化cイタン光触媒の開発"ペテロテック. 20[1]. 66-72 (1997)
[文献書誌] 山下弘巳、安保正一: "イオンビームを利用する新しい光機能材料の創製"化学. 52[9]. 74-75 (1997)
[文献書誌] 山下弘巳、安保正一、原田賢: "ナノサイズ酸化チタン光触媒の調製と光触媒特性―超微粒子酸化チタンと高分散固定化酸化チタン―"酸化チタン光触媒の開発と環境・エネルギーへの応用展開、技術情報協会編. 53-66 (1997)
[文献書誌] 山下弘巳、安保正一、市橋裕一: "酸化チタン光触媒の可視光化と太陽光の有効利用に向けて"酸化チタン光触媒の開発と環境・エネルギーへの応用展開、技術情報協会編. 87-100 (1997)
[文献書誌] H. Kajiura, Y. Tanabe and E. Yasuda: "Carbonization and Graphitization Behavior of Iodine-Treated Coal Tar Pitch"Carbon. 35 [2]. 169-174 (1997)
[文献書誌] *. Hoshi, Y. Tanabe and E. Yasuda: "Effects of Sonication on Curing Process in Furan Resin"Tanso. 1997 [184]. 199-201 (1997)
[文献書誌] C. Kim, K. Hakamada and M. Endo: "Raman Spectroscopy of Kapton-derived Carbon Film"Carbon. 36 [9]. 1401-1403 (1998)
[文献書誌] M. Endo, C. Kim, T. Karaki, T. Fujino, M.J. Matthews, S.D.M. Brown and M.S. Dresselhaus: "In-situ Raman Study on Electrochemical Li Insertion into Polyparaphenylene-based Disordered Carbon"Carbon. 36 [9]. 1403-1406 (1998)
[文献書誌] M. Endo, C. Kim, T. Hiraoka, T. Karaki, Y. Nishimura, M.J. Matthews, S.D.M. Brown and M.S. Dresselhaus: "Structural Characterization of Carbons Obtained from Polyparaphenylenes Prepared by the Kovacic and Yamamoto Methods"Journal of Materials Research. 13 [7]. 2023-2030 (1998)
[文献書誌] M. Endo, C. Kim, T. Hiraoka, T. Karaki, M.J. Matthews, S.D.M. Brown and M.S. Dresselhaus: "Li Storage, Behavior in Polyparaphenylen (PPP)-Based Disordered Carbon as a Negative Electrode for Li Ion Batteries"Mol. Cryst. Liq. Cryst.. 310. 353-358 (1998)
[文献書誌] 遠藤守信、唐木俊明、藤野剛正: "リチウムイオン電池と炭素負極におけるインターカレーション現象"ニューセラミクス. 11[4]. 46-52 (1998)
[文献書誌] R. Saito, M.S. Dresselhaus, and G. Dresselhaus: "Physical Properties of Carbon Nanotubes"Imperial College Press, UK. 258 (1998)

1999 年度 実績報告書

カーボンアロイ―炭素材料の空間制御と新機能の展開―

研究代表者

安田 榮一 東京工業大学, 応用セラミックス研究所, 教授 (70016830)

研究成果

[文献書誌] 阿久沢昇: "GICの新しい反応場への応用"表面. 35. 647-651 (1997)

[文献書誌] N. Kobayashi, T. Enoki, Y. Murakami, H. Suematsu and M. Endo: "Magnetic Properties of Adsorbed Oxygen in Microporous Carbon"Mol. Cryst. Liq. Cryst.. 360. 103-110 (1997)

[文献書誌] M. Endo, K. Takeuchi, T. Hiraoka, T. Furuta, T. Kasai, X. Sun, C.H. Kiang and M.S. Dresselhaus: "Stacking Nature of Graphene Layers in Carbon Nonotubes and Nanofibers"J. Phys. Chem. Solids. 58 [11]. 1702-1712 (1997)

[文献書誌] 押田京一、小林稔、古田照実、遠藤守信、オバランアグネス: "アモルファスカーボンフィルムの透過電子顕微鏡像への画像解析法の適用"電子情報通信学会論文誌. J80-C-[12]II. 421-426 (1997)

[文献書誌] T. Yamashita, T. Enoki, M. Uruichi, K. Yakushi, T. Miyamae and T. Miyazaki: "Galvanomagnetic, Optical Properties and Ultraviolet Photoelectron Spectra of Potassium-Oxygen-Graphite Intercalation Compounds"J. Phys. Soc. Jpn.. 66 [1]. 158-168 (1997)

[文献書誌] N. Kobayashi, T. Enoki, Y. Murakami, H. Suematsu and M. Endo: "Magnetic Properties of Adsorbed Oxygen in Microporpous Carbon"Mol. Cryst. Liq. Cryst.. 306. 103-110 (1997)

[文献書誌] I. Suzuki, M. Suzuki, H. Sato and T. Enoki: "Successive Magnetic Phase Transitions in CucCo1-cCl2-Fecl3 GBICs"Solid State Commun.. 104 [10]. 581-585 (1997)

[文献書誌] 榎敏明: "グラファイト層間化合物の水素吸収と金属水素の創生"ニューダイヤモンド. 13[3]. 14-19 (1997)

[文献書誌] T. Ishii, R. Sekine, T. Enoki, E. Miyazaki, T. Miyamae and T. Miyazaki: "DV-Xα Calculation and Ultraviolet Photoelectron Spectra of old Trichloride-Graphite Intercalation Compound 8AuCl3-GIC)"J. Phys. Soc. Jpn.. 66 [11]. 3424-3433 (1997)

[文献書誌] M. Yoshida, M. Fujita, P.W. Fowler and E.C. Kirby: "Non-Bonding Orbitals in Graphite, Carbon Tubules, Toroids and Fullerenes"J. Chem. Soc., Faraday Trans.. 93. 1037-1043 (1997)

[文献書誌] M. Fujita, M. Igami and K. Nakada: "Lattice Distortion in Nanographite Ribbons"J. Phys. Soc. Jpn.. 66 [7]. 1864-1867 (1997)

[文献書誌] 藤田光孝、若林克法、伊神正貫、中田恭子、草部浩一: "ナノグラファイトの電子物性―端のあるπ電子系におけるナノメター効果―"固体物理. 32[3]. 179-188 (1997)

[文献書誌] 藤田光孝: "π電子系カーボン材料と次元性"炭素. [180]. 257-265 (1997)

[文献書誌] K. Kusanabe, K. Wakabayashi, M. Igami, K. Nakada and M. Fujita: "Magnetism of Nanometer-scale Graphite with Edge or Topological Defects"Mol. Cryst. Liq. Cryst.. 305. 445-454 (1997)

[文献書誌] M. Fujita: "π Electronic States of Nanographite. "Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials""4. 445-454 (1997)

[文献書誌] 藤田光孝: "多面体としてみたフラーレンの構造―グラファイトの立体化―"SUT BULLETIN(東京理科大学出版会). 14[2]. 16-19 (1997)

[文献書誌] Y. Hishiyama, K. Igarashi, I. Kanaoka, H. Fujii, T. Koidesawa, Y. Shimazawa and A. Yoshioka: "Graphitization Behavior of Kapton-derived Carbon Film Related to Structure, Microtexture and Transport Properties"Carbon. 35 [5]. 657-668 (1997)

[文献書誌] Y. Kaburagi and Y. Hishiyama: "A Scaling Approach to the Transverse Magnetoresistance of Kish Graphite at 77K"Carbon. 35 [8]. 1151-1156 (1997)

[文献書誌] N. Iwashita, M. Inagaki and Y. Hishiyama: "Relations Between Degree of Graphitization and Galvanomagnetic Properties of Pyrolitic Carbons and Cokes"Carbon. 35 [8]. 1073-1077 (1997)

[文献書誌] T. Iiyama, K. Nishikawa, T. Suzuki and K. Kaneko: "Study of the Structure of Water Molecular Assembly in a Hydrophobic Nanospace at Low Temperature with in situ X-ray Diffraction"Chem. Phys. Lett.. 274. 152-158 (1997)

[文献書誌] M. Sato, T. Sukegawa, T. Suzuki and K. Kaneko: "Surface Fractal Dimension of Less-Crystalline Carbon Micropore Walls"J. Phys. Chem.. B101 [10]. 1845-1850 (1997)

[文献書誌] Y. Hanzawa and K. Kaneko: "Lack of a Predominant Adsorption of Water Vapor on Carbon Mesopores"Langmuir. 13 [22]. 5802-5804 (1997)

[文献書誌] T. Iiyama, K. Nishikawa, T. Suzuki, T. Otowa, M. Hijiriyama, Y. Nojima and K. Kaneko: "Molecular Assembly Structure of CCl4 in Graphic Nanospaces"J. Phys. Chem.. 101 [16]. 3037-3042 (1997)

[文献書誌] H.A. Yu, K. Kaneko, S. Otani, Y. Sasaki and S. Yoshimura: "A Carbonacrous Thin Film Made by CVD and A Caron/n-Type Silicon (C/n-Si) Photovoltanic Cell"Carbon. 36 [1-2]. 139-145 (1997)

[文献書誌] 木塚徳志、平原佳織、出口俊二、成瀬幹夫: "カーボンナノチューブの疲労の原子過程"日本金属学会会報 37(1997)(5). (1997)

[文献書誌] 小島昭、平野徳彦: "炭素繊維による河川およびため池の水質浄化"環境技術. 26[11]. 720-723 (1997)

[文献書誌] Y. Korai, S. Ishida, F. Watanabe, S.H. Yoon, Y.G. Wang, I. Mochida, I. Kato, T. Nakamura, Y. Sasaki and K. Komatsu: "Preparation of Carbon Fiber from Isotropic Pitch Containing Mesophase Spheres"Carbon. 35 [12]. 1733-1737 (1997)

[文献書誌] M. Yamamoto, K. Kusakabe, J. Hayashi, and S. Murooka: "Carbon Molecular Sieve Membrane Formed by Oxidative Carbonization of a Copolyimide Film Coated on a Porous Support Tube"J. Membr. Sci.. 133 [2]. 195-205 (1997)

[文献書誌] J. Hayashi, M. Yamamoto, K. Kusakabe and S. Murooka: "Effect of Oxidation on Gas Permeation of Carbon Molecular Sieving Membranes Based on BPDA-pp'ODA polyimide"Industrial & Engineering Chemistry Research. 36 [6]. 2134-2140 (1997)

[文献書誌] J. Hayashi, H. Mizuta, M. Yamamoto, K. Kusakabe and S. Murooka: "Pore Size Control of Carbonized BPDA-pp'ODA Polyimide Membrane by Chemical Vapor Deposition of Carbon"Journal of Membrane Science. 124 [2]. 243-251 (1997)

[文献書誌] B.-K. Sea, K. Kusakabe and S. Murooka: "Pore Size Control and Gas Permeation Kinetics of Silica Membranes by Pyrolysis of Phenyl-Substituted Ethoxysilanes with Cross-Flow through a Porous Support Wall"Journal of Membrane Science. 130. 41-52 (1997)

[文献書誌] S. Murooka, M. Yamamoto and K. Kusakabe: "Polyimide-Based Carbon Molecular Sieving Membranes"Theories and Applications of Chem. Eng.. 3. 313-316 (1997)

[文献書誌] T. Kyotani, L. Tsai and A. Tomita: "Formation of Platinum Nanorods and Nanoparticles in Uniform Carbon Nanotubes Prepared by a Template Carbonization Method"J. Chem. Soc., Chem. Commun.. 701-702 (1997)

[文献書誌] T. Kyotani, H. Moriyama and A. Tomita: "High Temperature Treatment of Polyfurfurly Alcohol/Graphite Oxide Intercalation Compound"Carbon. 35 [8]. 1185-1187 (1997)

[文献書誌] S. Motojima, K. Kojima, T. Hamamoto, N. Ueshima and H. Iwanaga: "Preparation and High Temperature Properties of Novel Ceramics Microcoils"Electrochem. Soc. Proc.. 97-39. 595-602 (1997)

[文献書誌] S. Motojima, T. Hamamoto, N. Ueshima, K. Kojima and H. Iwanaga: "Preparation and Properties of Ceramic Micro-coils by CVD Process"Electrochem. Soc. Proc.. 97-25. 433-440 (1997)

[文献書誌] 元島栖二、岩永浩: "新規の電磁波吸収材料:カーボンマイクロコイルの気相合成とその電磁波吸収特性"機能材料. 17[7]. 37-44 (1997)

[文献書誌] 元島栖二: "TiC/Cマイクロコイル"材料技術. 15[3]. (1997)

[文献書誌] T. Nakajima and M. Koh: "Synthesis of High Crystalline Carbon-Nitrogen Layered Compounds by CVD Using Nickel and Cobalt Catalyst"Carbon. 35 [2]. 203-208 (1997)

[文献書誌] T. Iiyama, K. Nishikawa, T. Suzuki, T. Otowa, M. Hijiriyama, Y. Nojima and K. Kaneko: "Molecular Assembly Structure of CCl4 in Graphite Nanospaces"J. Phys. Chem.. B101. 3037-3042 (1997)

[文献書誌] T. Iiyama, K. Nishikawa, T. Suzuki, K. Kaneko: "Study of the Structure of a Water Molecular Assembly in a Hydrophobic Nanospace at Low Temperature with in Situ X-ray Diffraction"Chem. Phys. Lett.. 274. 152-158 (1997)

[文献書誌] T. Nagano, Y. Iizuka, T. Shimazaki and C. Oshima: "Surface Phonons of Na-induced superstructures on Al(111)"Phys. Rev.. B55 [15]. 10064-10073 (1997)

[文献書誌] C. Oshima and A. Nagashima: "Ultra-Thin Epitaxial Films of Graphite and Hexagonal Boron Nitride on Solid Surfaces"J. Phys. ; Condens. Matter 9. 1-20 (1997)

[文献書誌] Y. Gamo, A. Nagashima, M. Wakabayashi, M. Terai and C. Oshima: "Atomic Structure of Monolayer Graphite Formed on Ni(111)"Surface Sci. 374. 61-64 (1997)

[文献書誌] M. Terai, Y. Gamo, N. Hasegawa and C. Oshima: "Electronic Band Structures of Monolayer Hexagonal Boron Nitride on TaC(111)"J. Surface Analysis. [3]. 473-477 (1997)

[文献書誌] C. Oshima: "Characterization of Ultra Thin Films and Solid Surfaces by High Resolution Electron Energy Loss Spectroscopy"J. Surface Analysis. [3]. 322-327 (1997)

[文献書誌] Y. Gamo, M. Terai, A. Nagashima and C. Oshima: "Atomic Structural Analysis of a Monolayer Epitaxial Film of Hexagon Boron Nitride/Ni(111) by LEED Intensity Analysis"Sci. Rep. Ritu.. A44. 211-214 (1997)

[文献書誌] E. Rokuta, Y. Hasegawa, K. Suzuki, Y. Gamou and C. Oshima: "Phonon Dispersion of an Epitaxial Monolayer Film of Hexagonal Boron Nitride on Ni(111)"Phys. Rev. Lett.. 79 [23]. 4609-4612 (1997)

[文献書誌] 大島忠平、六田英治、長島礼人: "単原子層六方晶窒化ホウ素のフォノン"日本物理学会誌. 52[8]. 610-613 (1997)

[文献書誌] 長谷川徳慶、蒲生康男、寺井真之、奥沢昌彦、大島忠平、大谷茂樹: "グラファイト・ナノクリスタルおよびグラファイト・ナノリボンの作製"炭素. [180]. 229-234 (1997)

[文献書誌] C. Oshima: "An Apparatus for High Resolution Field Emission Spectroscopy"Advances in Colloid and Interface Science. 71/72. 353-369 (1997)

[文献書誌] J. Ozaki, N. Endo, W. Ohizumi, K. Igarashi, M. Nakamura, A. Oya, S. Yoshida and T. Iizuka: "Novel Preparation Method for the Production of Mesoporous Carbon Fiber from a Polymer Blend"Carbon. 35 [7]. 1031-1033 (1997)

[文献書誌] 王寧、大谷朝男: "抗菌力を有する銀/酸化マンガン担持脱臭性活性炭素繊維の調製と性質"臭気の研究. 28[6]. 399-403 (1997)

[文献書誌] J. Ozaki, N. Ohkawa and A. Oya: "A Spectroscopic Study on Benzene Soluble Faction from Naphthalene Pitch"Carbon. 35 [10-11]. 1651-1653 (1997)

[文献書誌] J. Ozaki, W. Ohizumi, N. Endo, A. Oya, S. Yoshida, T. Iizuka, M.C.Roman-Martinez and Linares-Solano: "Preparation of Platinum Loaded Carbon Fiber By Using Polymer Blend"Carbon. 35 [10-11]. 1676-1677 (1997)

[文献書誌] 尾崎純一、大谷朝男: "活性炭素繊維の高機能化―表面機能を意識した材料設計―"表面. 35[10]. 535-543 (1997)

[文献書誌] 大谷朝男: "活性炭素繊維に金属を均一担持"化学工業日報. (1997)

[文献書誌] K. Kokaji, A. Oya, K. Maruama, M. Yamada and M. Shiraishi: "Carbonization and Graphitization Behavior of Decacyclene"Carbon. 35 [2]. 253-258 (1997)

[文献書誌] J. Przepiorsk, Y. Abe, S. Yoshida and A. Oya: "Preferential Supporting of Potassium Carbonate around the Peripheral Region of Activated Carbon Fibre"J. Mater. Sci. Lett.. [16]. 1312-1314 (1997)

[文献書誌] J. Alcaniz-Monge, D. Cazorla-Amoros, A. Linares-Solano, A. Oya, A. Sakamoto and K. Hoshi: "Preparation of General Purpose Carbon Fibers from Coal Tar Pitches with Low Softening point"Carbon. 35 [8]. 1079-1087 (1997)

[文献書誌] 大谷朝男: "浄水用抗菌性活性炭素繊維"防菌防黴. 25[3]. 175-182 (1997)

[文献書誌] 大谷朝男: "金属粒子を担持した消臭性活性炭素繊維―調整法と構造、性質―"臭気の研究. 28[2]. 57-63 (1997)

[文献書誌] S. Shimada, K. Nakajima and M. Inagaki: "Oxidation of Single Crystals of Hafnium Carbide in a Temperature Range of 600 to 900゜"J. Am. Ceram. Soc.. 80 [7]. 1749-1756 (1997)

[文献書誌] S. Shimada: "Microstructural Observation of ZrO2 Scales Formed by Oxidation of ZrC Single Crystals with Formation of Carbon"Solid State Ionics. 101-103. 749-753 (1997)

[文献書誌] H. Noguchi, Y. Kubota and T. Takarada: "Diamond/SiC Double Layer Membrane for X-Ray Mask"J. Electrochem. Soc.. 144 [8]. 2909-2912 (1997)

[文献書誌] H. Noguchi, Y. Kubota and T. Takarada: "Fabrication and Evaluation of Diamond/SiC Double Layer Membrane for X-Ray Mask"J. Electrochem. Soc.. 144 [9]. 3304-3308 (1997)

[文献書誌] H. Tamai, M. Ikeuchi, S. Kojima, H. Yasuda: "Extremely Large Mesoporous Carbon Fibers Synthesized by the Addition of Rare Earth Metal Complexes and Their Unique Adsorption Behaviors"Ad. Mateirals, 1997. 55-58 (1997)

[文献書誌] N. Yoshizawa, Y. Yamada, T. Furuta, M. Shiraishi, H. Tamai, S. Kojima and H. Yasuda: "Coal-based Activated Carbons Prepared with Organometallics and Their Mesoporous Structure"Energy & Fuels. 11. 327-330 (1997)

[文献書誌] 玉井久司: "有機金属錯体とピッチ焼成 均一分散の炭素材"化学工業日報. (1997)

[文献書誌] Y. Tanabe, Y. Hotta, T. Akatsu, S. Yamada and E. Yasuda: "Shear Strength of C/C Composites Containing a Inorganic Compound Effective for Anti-oxidation"J. Mater. Sci. Lett.. [16]. 557-559 (1997)

[文献書誌] K. Yamada, G. Burkard, Y. Tanabe and A.B. Sawaoka: "Concentric Shell Carbon : Curling Process of Graphite Layers"Carbon. 35 [12]. 1844-1846 (1997)

[文献書誌] T. Terai, Y. Takanashi, Masumura and T. Yoneoka: "Heat Capacity and Phase Transition of Zircaloy-4"Journal of Nuclear Materials. 247. 222-226 (1997)

[文献書誌] Takayuki Terai: "Research and Development on Ceramic Coatings for Fusion Reactor Blankets"Journal of Nuclear Materials. 248. 153-158 (1997)

[文献書誌] T. Yamabe, K. Tanaka, H. Ago, K. Yoshizawa and S. Yata: "Structure and Properties of Deeply Li-Doped Polyacenic Semiconductor (PAS)"Synth. Met.. 86. 2411-2414 (1997)

[文献書誌] H. Ago, K. Nagata, K. Yoshizawa, K. Tanaka, and T. Yamabe: "Theoretical Study of Lithium-Doped Polycyclic Aromatic Hydrocarbons"Bull. Chem. Soc. Jpn.. 70. 1717-1726 (1997)

1999 年度実績報告書

安田榮一東京工業大学, 応用セラミックス研究所, 教授 (70016830)

[文献書誌] 玉井久司: "有機金属錯体とピッチ焼成均一分散の炭素材"化学工業日報. (1997)