1999 年度実績報告書

「集積型金属錯体」研究の総括

研究課題

研究課題/領域番号	10149101
研究機関	東北大学
研究代表者	伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)
研究分担者	山口兆大阪大学, 大学院・理学研究科, 教授 (80029537) 山本隆一東京工業大学, 資源化学研究所, 教授 (10016743) 大川尚士九州大学, 大学院・理学研究科, 教授 (00037219) 北川進京都大学, 大学院・工学研究科, 教授 (20140303) 加藤礼三理化学研究所, 主任研究員 (80169531)
キーワード	集積型金属錯体 / 金属クラスター錯体 / 超分子 / 錯体集合体 / 分子集合体 / 混合原子価錯体 / 協同効果 / 多重機能
研究概要	(1)総括班会議の開催 : 研究方針,研究実施計画,予算配分・執行に関する打ち合わせ. 第1回(東京,平成11年6月26日),第2回(京都,平成11年11月30日),第3回(大阪,平成12年1月24日) (2)研究会の開催 (a)平成11年度研究計画発表会(東京,平成11年6月24-26日) :研究実施班員79名全員による研究計画概要の発表. (b)A03/A05合同班会議(和光市,平成11年8月16-17日). (c)A04班会議(北海道,平成11年9月27日). (d)国際シンポジウム"Molecular Design and Functionality of Assembled Metal Complexes"(京都,平成11年11月30日-12月2日) :外国人11名,日本人11名による講演,ポスター発表117件.参加者185名. (e)公開シンポジウム平成11年度研究成果報告会(大阪,平成12年1月24-25日) :2件の招待講演を含む12件の講演」,並びに研究実施班員全員の研究成果豊国発表. (3)出版物の発行 (a)広報,ニュースレター:第4号(班員名簿・班員の研究概要,平成11年6月),第5号(ニュースレター,平成11年9月),第6号(ニュースレター,平成12年3月). (b)講演要旨集:A03/A05合同班会議講演要旨集(平成11年8月),A04班会議要旨集(平成11年9月),国際シンポジウム"Molecular Design and Functionality of Assembled Metal Complexes"要旨集(平成11年11月),公開シンポジウム要旨集(平成12年1月) (c)平成11年度研究成果報告書(平成12年3月)

研究成果

(28件)

すべてその他

すべて文献書誌 (28件)

[文献書誌] 大川尚士: "Teracopperassemblry Complexes Comprised of One Dimetallic and Two Monometallic Auxiliaries : Intramolecular Electron-Transfer Relevant to Multicopper Oxidases"Inorg. Chem.. 38. 1825-1830 (1999)
[文献書誌] 大川尚士: "Template Syntheses and Properties of Copper(II)-Lanthanide(III)Complexes of Phenol-Based Symmetric and Unsymmetric Dinucleating Macrocycles"Inorg. Chem.. 48. 1-13 (1999)
[文献書誌] 大川尚士: "Oxygenation of Heterodinuclear Di(m-phenoxo)CoIIMII(M=Mn, Fe, Co) Complexes Having 'Co(salen)' Entity in A Macrocyclic Framework"J. Chem. Soc., Dalton Trans.. 12. 2197-2203 (1999)
[文献書誌] 大川尚士: "Di(μ-phenoxo)CoIIMII(M=Mn, Co, Zn)Complexes with 'Co(salen)' Entity in Macrocyclic Framework : Core Structures and Neighboring MII Effect upon Oxygenation at the 'Co(salen)' Center"Inorg. Chem.. 38. 4038-4044 (1999)
[文献書誌] 大川尚士: "[Mn(en)]_3[Cr(CN)_6]_2・4H_2O : A Three-dimensional Dimetallic Ferrimagnet (Tc=69K) with A Defective Cubane Unit"Angew. Chem. Int. Ed.. 38. 1795-1798 (1999)
[文献書誌] 大川尚士: "Dinuclear and Tetanuclear Copper(II) Complexes with Bridging (N-N) Diazine Ligands : Variable Magnetic Topologies"J. Chem. Soc. Dalton Trans. 1. 69-77 (2000)
[文献書誌] 山本隆一: "Synthesis of Ru-and Os-Complexes of pi-Conjugated Oligomers of 2,2'-Bipyridine and 5,5-Bipyrimidine. Optical Properties and Catalytic Activity for Photoevolution of Hydrogen from Aqueous Media"Bull. Chem. Soc. Jpn.. 72. 1153-1162 (1999)
[文献書誌] 山本隆一: "Ni-Promoted Syntheses of New 3,3'-Dichloro-5,5'-bipyrazoles and Poly(bipyrazole-5,5'-diyl)s and Isolation of Nickel Complexes Relevant to the Synthesis"Bull. Chem. Soc. Jpn.. 72. 1629-1635 (1999)
[文献書誌] 山本隆一: "Preparation of pi-Conjugated Polymers Composed of Hydroquinone, π-Benzquinone, and π-Diacetoxyphenylene Units, Optical and Redox Properties of the Polymers"Macromolecules. 32. 8886-8896 (1999)
[文献書誌] 山本隆一: "1 : 2 Polycondensation of 3,3', 4,4'-Biphenyltetramine and 1.1'-Ferrocenedimethanol Catalyzed by Dichlorotris(triphenylphosphine)ruthenium(II) to Give Polybenzimidazole Containing Ferrocenylene Group"Bull. Chem. Soc. Jpn.. 72. 2557-2562 (1999)
[文献書誌] 山本隆一: "Control of Reductive Elimination and Acidolysis of Diarylnickel(II) Complexes by the Kind of Broensted Acid and the Presence of Oxygen"Chem, Lett.. 419-420 (1999)
[文献書誌] 山本隆一: "Theoretical Studics on Anomalous Phases in Molecular Systems with External Field : Possibility of Photo-Induced Superconductivity"Int. J. Quant. Chem.. 75. 549-561 (1999)
[文献書誌] 山口兆: "Formulation and Numerical Approach to Molecular System by the Green Function Method without the Born-Oppenheimer Approximation"J. Chem. Phys.. 111. 6171-6179 (1999)
[文献書誌] 山口兆: "Dynamics of Photon Phase and Information Entropy for a Two-state Molecular System Interacting with Amplitude- and Phase-squeezed Fields"J. Phys. Chem.. A103. 6036-6048 (1999)
[文献書誌] 山口兆: "Density Functional Study of Intermolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit. III. Possibility of High Spin Polymer"J. Chem. Phys.. 111. 1309-1324 (1999)
[文献書誌] 山口兆: "Calculation of Frequency-Dependent First Hyperpolsaizabilities Using the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 110. 1720-1733 (1999)
[文献書誌] 山口兆: "Calculation of Frequency-Dependent Second Hyperpolsrizabilities for Electronic Field Induced Second Harmonic Generation in the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 111. 842-848 (1999)
[文献書誌] 伊藤翼: "A Short Platinum to Silver Dative Bond and its Application in the Construction of Extended Structures : Syntheses and Structures of Ag_2[Pt(ox)_2]・2H_2O and [Ag_2(H_2O]_2[Ag_2(CF_2SO_3)_4][Pt(acac)_2]_2"J. Chem. Soc., Dalton Trans.. 273-274 (1999)
[文献書誌] 伊藤翼: "Electron Transfer on Infrared Vibational Time Scale in the Mixed Valence State of 1,4-Pyrazinc and 4,4'-Bipyridine Bridged Ruthenium Cluster Complexes"J. Am. Chem. Soc.. 121. 4625-4632 (1999)
[文献書誌] 伊藤翼: "The First Examples of Platinum(II)-Cadmium(II) Bonds : The Role of Strong Field Ligands in Making Dative Pt-M bonds"J. Am. Chem. Soc.. 121. 7405-7406 (1999)
[文献書誌] 伊藤翼: "Syntheses and Properties of a Series of Oxo-Centered Triruthenium Complexes and Their Bridged Dimers with Isocyanide Ligands at Terminal and Bridging Positions"Inorg. Chem.. 38. 4070-4078 (1999)
[文献書誌] 伊藤翼: "Syntheses and Structures of Bridge and Chelate Isomers of Tetraplatinum(II) Cluster Complex with Diethydithiophosphate ion (Et_2dtp) at In-planc Sites. [Pt_4(CH_3COO)_4(Et_2dtp)_4]. And Their Mutual Isomerization via Cluster Core Rotation"J. Am. Chem. Soc.. 121. 10738-10742 (1999)
[文献書誌] 伊藤翼: "Cyanide-Bridged Iron-Copper Molecular Squares with Doublet and Quintet Spin Ground States"Inorg. Chem.. 38. 5686-5689 (1999)
[文献書誌] 伊藤翼: "Low Temperature Structural Studies in the Molecular β'-Pd(dmit)_2 Conductors"Phys. Rev.. B60. 3113-3119 (1999)
[文献書誌] 加藤礼三: "Two-band System : A Candidate for New Molecular Materials"Synth. Met.. 103. 2020-2023 (1999)
[文献書誌] 加藤礼三: "Conductive Copper Salts of 2,5-Disubstituted N,N'Dicyanobenzoquinonediimines (DCNOIs) : Structural and Physical Properties" (Accounts)"Bull, Chem. Soc. Jpn.. 73(in press). (2000)
[文献書誌] 加藤礼三: "Anomalous Rolr of Carbon and Nitrogen Isotopes in (DMe-DCNQI)_2Cu System"Synth. Met.. 102. 1749-1750 (1999)
[文献書誌] 加藤礼三: "Low Temperature X-ray Study of Purely One-dimensional Electronic System, Me_4X(CPDT-TCNO)_2(X=As, N)"Synth. Met.. 103. 2212-2213 (1999)

1999 年度 実績報告書

「集積型金属錯体」研究の総括

研究代表者

伊藤 翼 東北大学, 大学院・理学研究科, 教授 (90007328)

研究成果

[文献書誌] 大川 尚士: "Teracopperassemblry Complexes Comprised of One Dimetallic and Two Monometallic Auxiliaries : Intramolecular Electron-Transfer Relevant to Multicopper Oxidases"Inorg. Chem.. 38. 1825-1830 (1999)

[文献書誌] 大川 尚士: "Template Syntheses and Properties of Copper(II)-Lanthanide(III)Complexes of Phenol-Based Symmetric and Unsymmetric Dinucleating Macrocycles"Inorg. Chem.. 48. 1-13 (1999)

[文献書誌] 大川 尚士: "Oxygenation of Heterodinuclear Di(m-phenoxo)CoIIMII(M=Mn, Fe, Co) Complexes Having 'Co(salen)' Entity in A Macrocyclic Framework"J. Chem. Soc., Dalton Trans.. 12. 2197-2203 (1999)

[文献書誌] 大川 尚士: "Di(μ-phenoxo)CoIIMII(M=Mn, Co, Zn)Complexes with 'Co(salen)' Entity in Macrocyclic Framework : Core Structures and Neighboring MII Effect upon Oxygenation at the 'Co(salen)' Center"Inorg. Chem.. 38. 4038-4044 (1999)

[文献書誌] 大川 尚士: "[Mn(en)]_3[Cr(CN)_6]_2・4H_2O : A Three-dimensional Dimetallic Ferrimagnet (Tc=69K) with A Defective Cubane Unit"Angew. Chem. Int. Ed.. 38. 1795-1798 (1999)

[文献書誌] 大川 尚士: "Dinuclear and Tetanuclear Copper(II) Complexes with Bridging (N-N) Diazine Ligands : Variable Magnetic Topologies"J. Chem. Soc. Dalton Trans. 1. 69-77 (2000)

[文献書誌] 山本 隆一: "Synthesis of Ru-and Os-Complexes of pi-Conjugated Oligomers of 2,2'-Bipyridine and 5,5-Bipyrimidine. Optical Properties and Catalytic Activity for Photoevolution of Hydrogen from Aqueous Media"Bull. Chem. Soc. Jpn.. 72. 1153-1162 (1999)

[文献書誌] 山本 隆一: "Ni-Promoted Syntheses of New 3,3'-Dichloro-5,5'-bipyrazoles and Poly(bipyrazole-5,5'-diyl)s and Isolation of Nickel Complexes Relevant to the Synthesis"Bull. Chem. Soc. Jpn.. 72. 1629-1635 (1999)

[文献書誌] 山本 隆一: "Preparation of pi-Conjugated Polymers Composed of Hydroquinone, π-Benzquinone, and π-Diacetoxyphenylene Units, Optical and Redox Properties of the Polymers"Macromolecules. 32. 8886-8896 (1999)

[文献書誌] 山本 隆一: "1 : 2 Polycondensation of 3,3', 4,4'-Biphenyltetramine and 1.1'-Ferrocenedimethanol Catalyzed by Dichlorotris(triphenylphosphine)ruthenium(II) to Give Polybenzimidazole Containing Ferrocenylene Group"Bull. Chem. Soc. Jpn.. 72. 2557-2562 (1999)

[文献書誌] 山本 隆一: "Control of Reductive Elimination and Acidolysis of Diarylnickel(II) Complexes by the Kind of Broensted Acid and the Presence of Oxygen"Chem, Lett.. 419-420 (1999)

[文献書誌] 山本 隆一: "Theoretical Studics on Anomalous Phases in Molecular Systems with External Field : Possibility of Photo-Induced Superconductivity"Int. J. Quant. Chem.. 75. 549-561 (1999)

[文献書誌] 山口 兆: "Formulation and Numerical Approach to Molecular System by the Green Function Method without the Born-Oppenheimer Approximation"J. Chem. Phys.. 111. 6171-6179 (1999)

[文献書誌] 山口 兆: "Dynamics of Photon Phase and Information Entropy for a Two-state Molecular System Interacting with Amplitude- and Phase-squeezed Fields"J. Phys. Chem.. A103. 6036-6048 (1999)

[文献書誌] 山口 兆: "Density Functional Study of Intermolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit. III. Possibility of High Spin Polymer"J. Chem. Phys.. 111. 1309-1324 (1999)

[文献書誌] 山口 兆: "Calculation of Frequency-Dependent First Hyperpolsaizabilities Using the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 110. 1720-1733 (1999)

[文献書誌] 山口 兆: "Calculation of Frequency-Dependent Second Hyperpolsrizabilities for Electronic Field Induced Second Harmonic Generation in the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 111. 842-848 (1999)

[文献書誌] 伊藤 翼: "A Short Platinum to Silver Dative Bond and its Application in the Construction of Extended Structures : Syntheses and Structures of Ag_2[Pt(ox)_2]・2H_2O and [Ag_2(H_2O]_2[Ag_2(CF_2SO_3)_4][Pt(acac)_2]_2"J. Chem. Soc., Dalton Trans.. 273-274 (1999)

[文献書誌] 伊藤 翼: "Electron Transfer on Infrared Vibational Time Scale in the Mixed Valence State of 1,4-Pyrazinc and 4,4'-Bipyridine Bridged Ruthenium Cluster Complexes"J. Am. Chem. Soc.. 121. 4625-4632 (1999)

[文献書誌] 伊藤 翼: "The First Examples of Platinum(II)-Cadmium(II) Bonds : The Role of Strong Field Ligands in Making Dative Pt-M bonds"J. Am. Chem. Soc.. 121. 7405-7406 (1999)

[文献書誌] 伊藤 翼: "Syntheses and Properties of a Series of Oxo-Centered Triruthenium Complexes and Their Bridged Dimers with Isocyanide Ligands at Terminal and Bridging Positions"Inorg. Chem.. 38. 4070-4078 (1999)

[文献書誌] 伊藤 翼: "Cyanide-Bridged Iron-Copper Molecular Squares with Doublet and Quintet Spin Ground States"Inorg. Chem.. 38. 5686-5689 (1999)

[文献書誌] 伊藤 翼: "Low Temperature Structural Studies in the Molecular β'-Pd(dmit)_2 Conductors"Phys. Rev.. B60. 3113-3119 (1999)

[文献書誌] 加藤 礼三: "Two-band System : A Candidate for New Molecular Materials"Synth. Met.. 103. 2020-2023 (1999)

[文献書誌] 加藤 礼三: "Conductive Copper Salts of 2,5-Disubstituted N,N'Dicyanobenzoquinonediimines (DCNOIs) : Structural and Physical Properties" (Accounts)"Bull, Chem. Soc. Jpn.. 73(in press). (2000)

[文献書誌] 加藤 礼三: "Anomalous Rolr of Carbon and Nitrogen Isotopes in (DMe-DCNQI)_2Cu System"Synth. Met.. 102. 1749-1750 (1999)

[文献書誌] 加藤 礼三: "Low Temperature X-ray Study of Purely One-dimensional Electronic System, Me_4X(CPDT-TCNO)_2(X=As, N)"Synth. Met.. 103. 2212-2213 (1999)

1999 年度実績報告書

伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)

[文献書誌] 大川尚士: "Teracopperassemblry Complexes Comprised of One Dimetallic and Two Monometallic Auxiliaries : Intramolecular Electron-Transfer Relevant to Multicopper Oxidases"Inorg. Chem.. 38. 1825-1830 (1999)

[文献書誌] 大川尚士: "Template Syntheses and Properties of Copper(II)-Lanthanide(III)Complexes of Phenol-Based Symmetric and Unsymmetric Dinucleating Macrocycles"Inorg. Chem.. 48. 1-13 (1999)

[文献書誌] 大川尚士: "Oxygenation of Heterodinuclear Di(m-phenoxo)CoIIMII(M=Mn, Fe, Co) Complexes Having 'Co(salen)' Entity in A Macrocyclic Framework"J. Chem. Soc., Dalton Trans.. 12. 2197-2203 (1999)

[文献書誌] 大川尚士: "Di(μ-phenoxo)CoIIMII(M=Mn, Co, Zn)Complexes with 'Co(salen)' Entity in Macrocyclic Framework : Core Structures and Neighboring MII Effect upon Oxygenation at the 'Co(salen)' Center"Inorg. Chem.. 38. 4038-4044 (1999)

[文献書誌] 大川尚士: "[Mn(en)]_3[Cr(CN)_6]_2・4H_2O : A Three-dimensional Dimetallic Ferrimagnet (Tc=69K) with A Defective Cubane Unit"Angew. Chem. Int. Ed.. 38. 1795-1798 (1999)

[文献書誌] 大川尚士: "Dinuclear and Tetanuclear Copper(II) Complexes with Bridging (N-N) Diazine Ligands : Variable Magnetic Topologies"J. Chem. Soc. Dalton Trans. 1. 69-77 (2000)

[文献書誌] 山本隆一: "Synthesis of Ru-and Os-Complexes of pi-Conjugated Oligomers of 2,2'-Bipyridine and 5,5-Bipyrimidine. Optical Properties and Catalytic Activity for Photoevolution of Hydrogen from Aqueous Media"Bull. Chem. Soc. Jpn.. 72. 1153-1162 (1999)

[文献書誌] 山本隆一: "Ni-Promoted Syntheses of New 3,3'-Dichloro-5,5'-bipyrazoles and Poly(bipyrazole-5,5'-diyl)s and Isolation of Nickel Complexes Relevant to the Synthesis"Bull. Chem. Soc. Jpn.. 72. 1629-1635 (1999)

[文献書誌] 山本隆一: "Preparation of pi-Conjugated Polymers Composed of Hydroquinone, π-Benzquinone, and π-Diacetoxyphenylene Units, Optical and Redox Properties of the Polymers"Macromolecules. 32. 8886-8896 (1999)

[文献書誌] 山本隆一: "1 : 2 Polycondensation of 3,3', 4,4'-Biphenyltetramine and 1.1'-Ferrocenedimethanol Catalyzed by Dichlorotris(triphenylphosphine)ruthenium(II) to Give Polybenzimidazole Containing Ferrocenylene Group"Bull. Chem. Soc. Jpn.. 72. 2557-2562 (1999)

[文献書誌] 山本隆一: "Control of Reductive Elimination and Acidolysis of Diarylnickel(II) Complexes by the Kind of Broensted Acid and the Presence of Oxygen"Chem, Lett.. 419-420 (1999)

[文献書誌] 山本隆一: "Theoretical Studics on Anomalous Phases in Molecular Systems with External Field : Possibility of Photo-Induced Superconductivity"Int. J. Quant. Chem.. 75. 549-561 (1999)

[文献書誌] 山口兆: "Formulation and Numerical Approach to Molecular System by the Green Function Method without the Born-Oppenheimer Approximation"J. Chem. Phys.. 111. 6171-6179 (1999)

[文献書誌] 山口兆: "Dynamics of Photon Phase and Information Entropy for a Two-state Molecular System Interacting with Amplitude- and Phase-squeezed Fields"J. Phys. Chem.. A103. 6036-6048 (1999)

[文献書誌] 山口兆: "Density Functional Study of Intermolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit. III. Possibility of High Spin Polymer"J. Chem. Phys.. 111. 1309-1324 (1999)

[文献書誌] 山口兆: "Calculation of Frequency-Dependent First Hyperpolsaizabilities Using the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 110. 1720-1733 (1999)

[文献書誌] 山口兆: "Calculation of Frequency-Dependent Second Hyperpolsrizabilities for Electronic Field Induced Second Harmonic Generation in the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 111. 842-848 (1999)

[文献書誌] 伊藤翼: "A Short Platinum to Silver Dative Bond and its Application in the Construction of Extended Structures : Syntheses and Structures of Ag_2[Pt(ox)_2]・2H_2O and [Ag_2(H_2O]_2[Ag_2(CF_2SO_3)_4][Pt(acac)_2]_2"J. Chem. Soc., Dalton Trans.. 273-274 (1999)

[文献書誌] 伊藤翼: "Electron Transfer on Infrared Vibational Time Scale in the Mixed Valence State of 1,4-Pyrazinc and 4,4'-Bipyridine Bridged Ruthenium Cluster Complexes"J. Am. Chem. Soc.. 121. 4625-4632 (1999)

[文献書誌] 伊藤翼: "The First Examples of Platinum(II)-Cadmium(II) Bonds : The Role of Strong Field Ligands in Making Dative Pt-M bonds"J. Am. Chem. Soc.. 121. 7405-7406 (1999)

[文献書誌] 伊藤翼: "Syntheses and Properties of a Series of Oxo-Centered Triruthenium Complexes and Their Bridged Dimers with Isocyanide Ligands at Terminal and Bridging Positions"Inorg. Chem.. 38. 4070-4078 (1999)

[文献書誌] 伊藤翼: "Cyanide-Bridged Iron-Copper Molecular Squares with Doublet and Quintet Spin Ground States"Inorg. Chem.. 38. 5686-5689 (1999)

[文献書誌] 伊藤翼: "Low Temperature Structural Studies in the Molecular β'-Pd(dmit)_2 Conductors"Phys. Rev.. B60. 3113-3119 (1999)

[文献書誌] 加藤礼三: "Two-band System : A Candidate for New Molecular Materials"Synth. Met.. 103. 2020-2023 (1999)

[文献書誌] 加藤礼三: "Conductive Copper Salts of 2,5-Disubstituted N,N'Dicyanobenzoquinonediimines (DCNOIs) : Structural and Physical Properties" (Accounts)"Bull, Chem. Soc. Jpn.. 73(in press). (2000)

[文献書誌] 加藤礼三: "Anomalous Rolr of Carbon and Nitrogen Isotopes in (DMe-DCNQI)_2Cu System"Synth. Met.. 102. 1749-1750 (1999)

[文献書誌] 加藤礼三: "Low Temperature X-ray Study of Purely One-dimensional Electronic System, Me_4X(CPDT-TCNO)_2(X=As, N)"Synth. Met.. 103. 2212-2213 (1999)