2000 年度実績報告書

「集積型金属錯体」研究の総括

研究課題

研究課題/領域番号	10149101
研究機関	東北大学
研究代表者	伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)
研究分担者	山口兆大阪大学, 大学院・理学研究科, 教授 (80029537) 山本隆一東京工業大学, 資源化学研究所, 教授 (10016743) 大川尚士九州大学, 大学院・理学研究院, 教授 (00037219) 北川進京都大学, 大学院・工学研究科, 教授 (20140303) 加藤礼三理化学研究所, 主任研究員 (80169531)
キーワード	集積型金属錯体 / 金属クラスター錯体 / 超分子 / 錯体集合体 / 分子集合体 / 混合原子価錯体 / 協同効果 / 多重機能
研究概要	(1)総括班会議・班長会議の開催:研究方針,研究実施計画,予算配分・執行に関する打ち合わせ. 第1回(札幌,平成12年7月1日,第2回(東京,平成12年8月12日),第3回(岐阜,平成13年1月16日) (2)研究会の開催 (a)平成12年度研究計画発表会(札幌,平成12年6月30日-7月1日):研究実施班員77名全員による研究計画概要の発表. (b)「集積型金属錯体の合成に関するシンポジウム」(熱海,平成12年10月28-29日). (c)「機能発現をめざした集積型金属錯体の設計戦略」(那覇,平成12年11月11日). (d)D.H.Buschアメリカ化学会長,H.Taube教授講演会(仙台,平成12年9月25日) (e)公開シンポジウム平成12年度研究成果報告会(岐阜,平成13年1月15-16日):2件の招待講演を含む9件の講演,並びに研究実施班員全員の研究成果報告発表. (f)研究会「ナノ金属錯体の展望」〔東京,平成13年2月3-4日):21件の講演 (g)研究会「新世紀の錯体化学」(札幌,平成13年2月17-18日):15件の講演 (3)出版物の発行 (a)広報,ニュースレター:第7号(班員名簿・班員の研究概要,平成12年6月),第8号(ニュースレター,平成12年9月),第9号(ニュースレター,平成13年3月(予定)). (b)講演要旨集:「集積型金属錯体の合成に関するシンポジウム」講演要旨集(平成12年10月),「機能発現をめざした集積型金属錯体の設計戦略」講演要旨集(平成12年11月),「平成12年度研究成果報告会・公開シンポジウム」講演要旨集(平成13年1月) (c)平成12年度研究成果報告書(平成13年3月)

研究成果
(32件)

すべてその他

すべて文献書誌 (32件)

[文献書誌] 伊藤翼: "Unusual Redox State Dependent Fermi Resonances in the Infrared Spectra of Trinuclear Ruthenium Clusters with Isocyanide Ligands"Inorg.Chem.. 39. 2696-2698 (2000)
[文献書誌] 伊藤翼: "A Strongly Coupled Mixed Valence State between Ru_3 Clusters. Intramolecular Electron Transfer on the Infrared Vibrational Time Scale in a Pyrazine (pz) Bridged dimer of Triruthenium Clusters, [{Ru_3 (μ-O)(μ-CH_3CO_2)_6(CO)(abco)}_2(μ-pz)](abco=1-azabicyclo[2,2,2]octane"Bull.Chem.Soc.Jpn.. 73. 1205-1212 (2000)
[文献書誌] 伊藤翼: "Mixed-Valent Heptairon Complex with a Ground-State Spin of S=12/2 Constructed from a Triiron Cluster Ligand"Angew.Chem.Int.Ed.. 39. 230-233 (2000)
[文献書誌] 伊藤翼: "Superparamagnetic Behavior in an Alkoxo-Bridged Iron (II) Cube"J.Am.Chem.Soc.. 122. 12602-12603 (2000)
[文献書誌] 伊藤翼: "Rational Construction of Chiral Octanuclear Metallacycles Consisting of Octahedral Co^<III>, Square-Planar Pd^<II>, and Linear Au^I or Ag^I Ions"Angew.Chem.Int.Ed.. 39. 4098-40101 (2000)
[文献書誌] 伊藤翼: "A Helical Metal-Metal Bonded Chain via the Pt→Ag Dative Bond"J.Am.Chem.Soc.. 123. 743 (2001)
[文献書誌] 大川尚士: "A Mixed-metal Cu^<II>_2Ni^<II>_2 Complex Derived from A Phenol-based Heterotetranucleating Macrocyclic Ligand"Chem.Commun.. 4. 817-818 (2000)
[文献書誌] 大川尚士: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 105-129 (2000)
[文献書誌] 大川尚士: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 200-202 (2000)
[文献書誌] 大川尚士: "A Heterodinuclear Co^<II>Cu^I Complex with 'Co (salen)' in A Macrocyclic Framework. Oxygenation Studies in Comparison with Analogous Cu^<II>Cu^I and Co^<II>Pb^<II> Complexes"Inorg.Chem.. 39. 4520-4526 (2000)
[文献書誌] 大川尚士: "Trinuclear Cu^<II>M^<II>Cu^<II> Complexes of an Oxamide/Dioxime Ligand and Extension to A Bimetallic Magnetic Compound"J.Chem.Soc., Dalton Trans.. 1. 64-70 (2001)
[文献書誌] 大川尚士: "Dinuclear Zinc Complexes of Phenol-based 'End-off' Compartmental Ligands : Synthesis, Structures and Phosphatase-Like Activity"Bull.Chem.Soc.Jpn.. 74. 85-95 (2001)
[文献書誌] 山本隆一: "New Information on Linear and Stiff π-Conjugated Poly (pyridine-2,5-diyl)"J.Polym.Sci. : B,Polym.Phys.. 38. 1348-1351 (2000)
[文献書誌] 山本隆一: "π-Conjugated Polymers Prepared by Organometallic Polycondensation and Metal Complexes of the Polymers"Polym.Adv.Tech.. 11. 658-664 (2000)
[文献書誌] 山本隆一: "Synthesis and Properties of Europium Complex of Poybenzimidazole Containing N-Eu Bond"Mol.Cryst.Liq.Cryst.. 342. 57-62 (2000)
[文献書誌] 山本隆一: "Poly (pyridine-2,5-diyl)-CuCl_2 Catalyst for Synthesis of Dimethyl Carbonate by Oxidative Carbonylation of Methanol : Catalytic Activity and Corrosion Influence"J.Catalysis. 65. 123-126 (2000)
[文献書誌] 山本隆一: "Synthesis and Chemical Properties of π-Conjugated Zinc Porphyrin Polymers with Arylene and Aryleneethynylene Groups between Zinc Porphyrin Units"Macromolecules. 33. 5688-5994 (2000)
[文献書誌] 山口兆: "Quantum-phase and Information-entropy Dynamics of a Two-state Molecular System Interacting with Strongly Amplitude- and Phase- squeezed Fields"J.Chem.Phys.. 112. 2769-2780 (2000)
[文献書誌] 山口兆: "Density Functional Study of Intramolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit (II) : Examination of Functional Dependence"J.Chem.Phys.. 113. 10486-10504 (2000)
[文献書誌] 山口兆: "Quantum Spin Dynamics by Path Integral Centroid Molecular Dynamics Method"Prog.Theoret.Phys.Suppl.. 138. 533-534 (2000)
[文献書誌] 山口兆: "Ab initio Computations of Effective Exchange Integrals for H-H, H-He-H and Mn_2O_2 Complex. Comparison of Broken-Symmetry Approaches"Chem.Phys.Lett.. 319. 223-230 (2000)
[文献書誌] 山口兆: "Theoretical Studies on Superconducting and Other Phases : Triplet Superconductivity, Ferromagnetism and Ferromagnetic Metals"Int.J.Quant.Chem.. 80. 721-732 (2000)
[文献書誌] 加藤礼三: "N, N'-Dicyanobenzoquinonediimines (DCNQIs) : Structural and Physical Properties"Bull.Chem.Soc.Jpn.. 73. 515-534 (2000)
[文献書誌] 加藤礼三: "Thermodynamical Study of (DMe-DCNQI) 2Cu System -Mechanism of Reentrant Metal-Insulator Transition-"J.Phys.Soc.Jpn.. 69. 1414-1422 (2000)
[文献書誌] 加藤礼三: "Design, Preparation, and Characterzation of Novel ET Salts with Supramolecular Assembly -Sheet and Chain Structures Based on Difluorotetraiodobenzene-"Chem.Lett.. 8. 970-971 (2000)
[文献書誌] 加藤礼三: "Magnetic Susceptibility of (DMe-DCNQI)_2Li_<1-x>CUx,"Solid State Communications. 114. 281-284 (2000)
[文献書誌] 加藤礼三: "Conducting Properties of Assembled Metal Complexes"Mol.Cryst.Liq.Cryst.. 343. 1-8 (2000)
[文献書誌] 北川進: "Allosteric Chirality Amplification in Zinc Bilinone Dimer"J.Am.Chem.Soc.. 122. 748-749 (2000)
[文献書誌] 北川進: "New Methane Adsorbent of Porous Coordination Polymer,[Cu(SiF_6)(4,4'-bipyridine)_2]^n"Angew.Che, Int.Ed.Engl.. 39. 2081-2084 (2000)
[文献書誌] 北川進: "Synthesis and Molecular Structure of the Amido-bridged Dinuclear rhodium Complex [Cp^*Rh{μ_2-(NH)_2C_<10>H_6-2,3}(μ_2-Cl)RhCp^*](Cp^*=η_5-C_5Me_5)"Mol.Cryst.Liq.Cryst.. 342. 1-6 (2000)
[文献書誌] 北川進: "Novel Layered Structures Constructed from Metal (II)-Chloranilate Monomer Compounds"J.Chem.Soc.Dalton Trans.. 2409-2417 (2000)
[文献書誌] 北川進: "New Molecular Assemblies of Redox Isomers,[CrIII (X4SQ)3-n(X4Cat)n]-n(X) Cl and Br, n)0,1, and 2), with Metallocenium Cations,[MIII Cp2]+(M) Co and Fe) : X-ray Crystal Structures and Physical Properties"Inorg.Chem. 40. 146-156 (2000)

2000 年度 実績報告書

「集積型金属錯体」研究の総括

研究代表者

伊藤 翼 東北大学, 大学院・理学研究科, 教授 (90007328)

研究成果

[文献書誌] 伊藤翼: "Unusual Redox State Dependent Fermi Resonances in the Infrared Spectra of Trinuclear Ruthenium Clusters with Isocyanide Ligands"Inorg.Chem.. 39. 2696-2698 (2000)

[文献書誌] 伊藤翼: "Mixed-Valent Heptairon Complex with a Ground-State Spin of S=12/2 Constructed from a Triiron Cluster Ligand"Angew.Chem.Int.Ed.. 39. 230-233 (2000)

[文献書誌] 伊藤翼: "Superparamagnetic Behavior in an Alkoxo-Bridged Iron (II) Cube"J.Am.Chem.Soc.. 122. 12602-12603 (2000)

[文献書誌] 伊藤翼: "Rational Construction of Chiral Octanuclear Metallacycles Consisting of Octahedral Co^<III>, Square-Planar Pd^<II>, and Linear Au^I or Ag^I Ions"Angew.Chem.Int.Ed.. 39. 4098-40101 (2000)

[文献書誌] 伊藤翼: "A Helical Metal-Metal Bonded Chain via the Pt→Ag Dative Bond"J.Am.Chem.Soc.. 123. 743 (2001)

[文献書誌] 大川尚士: "A Mixed-metal Cu^<II>_2Ni^<II>_2 Complex Derived from A Phenol-based Heterotetranucleating Macrocyclic Ligand"Chem.Commun.. 4. 817-818 (2000)

[文献書誌] 大川尚士: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 105-129 (2000)

[文献書誌] 大川尚士: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 200-202 (2000)

[文献書誌] 大川尚士: "A Heterodinuclear Co^<II>Cu^I Complex with 'Co (salen)' in A Macrocyclic Framework. Oxygenation Studies in Comparison with Analogous Cu^<II>Cu^I and Co^<II>Pb^<II> Complexes"Inorg.Chem.. 39. 4520-4526 (2000)

[文献書誌] 大川尚士: "Trinuclear Cu^<II>M^<II>Cu^<II> Complexes of an Oxamide/Dioxime Ligand and Extension to A Bimetallic Magnetic Compound"J.Chem.Soc., Dalton Trans.. 1. 64-70 (2001)

[文献書誌] 大川尚士: "Dinuclear Zinc Complexes of Phenol-based 'End-off' Compartmental Ligands : Synthesis, Structures and Phosphatase-Like Activity"Bull.Chem.Soc.Jpn.. 74. 85-95 (2001)

[文献書誌] 山本隆一: "New Information on Linear and Stiff π-Conjugated Poly (pyridine-2,5-diyl)"J.Polym.Sci. : B,Polym.Phys.. 38. 1348-1351 (2000)

[文献書誌] 山本隆一: "π-Conjugated Polymers Prepared by Organometallic Polycondensation and Metal Complexes of the Polymers"Polym.Adv.Tech.. 11. 658-664 (2000)

[文献書誌] 山本隆一: "Synthesis and Properties of Europium Complex of Poybenzimidazole Containing N-Eu Bond"Mol.Cryst.Liq.Cryst.. 342. 57-62 (2000)

[文献書誌] 山本隆一: "Poly (pyridine-2,5-diyl)-CuCl_2 Catalyst for Synthesis of Dimethyl Carbonate by Oxidative Carbonylation of Methanol : Catalytic Activity and Corrosion Influence"J.Catalysis. 65. 123-126 (2000)

[文献書誌] 山本隆一: "Synthesis and Chemical Properties of π-Conjugated Zinc Porphyrin Polymers with Arylene and Aryleneethynylene Groups between Zinc Porphyrin Units"Macromolecules. 33. 5688-5994 (2000)

[文献書誌] 山口兆: "Quantum-phase and Information-entropy Dynamics of a Two-state Molecular System Interacting with Strongly Amplitude- and Phase- squeezed Fields"J.Chem.Phys.. 112. 2769-2780 (2000)

[文献書誌] 山口兆: "Density Functional Study of Intramolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit (II) : Examination of Functional Dependence"J.Chem.Phys.. 113. 10486-10504 (2000)

[文献書誌] 山口兆: "Quantum Spin Dynamics by Path Integral Centroid Molecular Dynamics Method"Prog.Theoret.Phys.Suppl.. 138. 533-534 (2000)

[文献書誌] 山口兆: "Ab initio Computations of Effective Exchange Integrals for H-H, H-He-H and Mn_2O_2 Complex. Comparison of Broken-Symmetry Approaches"Chem.Phys.Lett.. 319. 223-230 (2000)

[文献書誌] 山口兆: "Theoretical Studies on Superconducting and Other Phases : Triplet Superconductivity, Ferromagnetism and Ferromagnetic Metals"Int.J.Quant.Chem.. 80. 721-732 (2000)

[文献書誌] 加藤礼三: "N, N'-Dicyanobenzoquinonediimines (DCNQIs) : Structural and Physical Properties"Bull.Chem.Soc.Jpn.. 73. 515-534 (2000)

[文献書誌] 加藤礼三: "Thermodynamical Study of (DMe-DCNQI) 2Cu System -Mechanism of Reentrant Metal-Insulator Transition-"J.Phys.Soc.Jpn.. 69. 1414-1422 (2000)

[文献書誌] 加藤礼三: "Design, Preparation, and Characterzation of Novel ET Salts with Supramolecular Assembly -Sheet and Chain Structures Based on Difluorotetraiodobenzene-"Chem.Lett.. 8. 970-971 (2000)

[文献書誌] 加藤礼三: "Magnetic Susceptibility of (DMe-DCNQI)_2Li_<1-x>CUx,"Solid State Communications. 114. 281-284 (2000)

[文献書誌] 加藤礼三: "Conducting Properties of Assembled Metal Complexes"Mol.Cryst.Liq.Cryst.. 343. 1-8 (2000)

[文献書誌] 北川進: "Allosteric Chirality Amplification in Zinc Bilinone Dimer"J.Am.Chem.Soc.. 122. 748-749 (2000)

[文献書誌] 北川進: "New Methane Adsorbent of Porous Coordination Polymer,[Cu(SiF_6)(4,4'-bipyridine)_2]^n"Angew.Che, Int.Ed.Engl.. 39. 2081-2084 (2000)

[文献書誌] 北川進: "Synthesis and Molecular Structure of the Amido-bridged Dinuclear rhodium Complex [Cp^*Rh{μ_2-(NH)_2C_<10>H_6-2,3}(μ_2-Cl)RhCp^*](Cp^*=η_5-C_5Me_5)"Mol.Cryst.Liq.Cryst.. 342. 1-6 (2000)

[文献書誌] 北川進: "Novel Layered Structures Constructed from Metal (II)-Chloranilate Monomer Compounds"J.Chem.Soc.Dalton Trans.. 2409-2417 (2000)

[文献書誌] 北川進: "New Molecular Assemblies of Redox Isomers,[CrIII (X4SQ)3-n(X4Cat)n]-n(X) Cl and Br, n)0,1, and 2), with Metallocenium Cations,[MIII Cp2]+(M) Co and Fe) : X-ray Crystal Structures and Physical Properties"Inorg.Chem. 40. 146-156 (2000)

2000 年度実績報告書

伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)

[文献書誌] 北川進: "Synthesis and Molecular Structure of the Amido-bridged Dinuclear rhodium Complex [Cp^Rh{μ_2-(NH)_2C_<10>H_6-2,3}(μ_2-Cl)RhCp^](Cp^*=η_5-C_5Me_5)"Mol.Cryst.Liq.Cryst.. 342. 1-6 (2000)