2001 年度実績報告書

「集積型金属錯体」研究の総括

研究課題

研究課題/領域番号	10149101
研究機関	東北大学
研究代表者	伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)
研究分担者	山口兆大阪大学, 大学院・理学研究科, 教授 (80029537) 山本隆一東京工業大学, 資源化学研究所, 教授 (10016743) 大川尚士九州大学, 大学院・理学研究院, 教授 (00037219) 北川進京都大学, 大学院・工学研究科, 教授 (20140303) 加藤礼三理化学研究所, 主任研究員 (80169531)
キーワード	集積型金属錯体 / 金属クラスター / 集積型金属錯体 / 錯体集合体 / 分子集合体 / 混合原子価錯体 / 協同効果 / 多重機能
研究概要	(1)総括班会議・班長会議の開催(1):研究方針,研究実施計画,予算配分・執行に関する打合せ第1回(東京,平成13年6月30日),第2回(仙台,平成13年12月13日),総括班会議・班長会議の開催(2):次年度予定されている成果とりまとめの打ち合わせ,(大分,平成14年1月25-26日) (2)研究会の開催 (a)平成13年度研究計画発表会(東京,平成13年6月29日-30日):研究実施班員名全員による研究計画概要の発表〔参加者48名〕. (b)国際シンポジウム「集積型金属錯体における共同現象」(大阪,平成13年11月15-17日,参加者:222名〔内外国人参加者13名〕). (c)公開シンポジウム平成13年度研究成果報告会(仙台,平成13年12月11-13日):1件の招待講演を含む25件の講演およびポスター発表53件(参加者95名). (d)「集積方金属錯体研究の総括と展望」(仙台,平成14年1月30-31日). (f)研究会「集積型金属錯体の展望」〔静岡,平成14年2月21-22日〕:18件の講演,(参加者39名). (3)出版物の発行 (a)広報,ニュースレター:第10号(班員名簿・班員の研究概要,平成13年6月),第11号(ニュースレター,平成13年9月),第12号(ニュースレター,平成14年3月(予定)) (b)講演要旨集:国際シンポジウム「集積型金属錯体における共同現象」講演要旨集(平成13年11月),「平成13年度研究成果報告会・公開シンポジウム」講演要旨集(平成13年12月),「集積型金属錯体の展望」講演要旨集(平成14年2月) (c)平成13年度研究成果報告書(平成14年3月)

研究成果

(24件)

すべてその他

すべて文献書誌 (24件)

[文献書誌] 伊藤翼: "Zinc(II) Slides on a Ligand Surface : The X-ray Structure and Dynamic Behavior in Solution of [Zn(H_2L)(tacn)]"Angew.Chem.Int.Ed.. 41(印刷中). (2002)
[文献書誌] 伊藤翼: "Syntheses, Structures, and Propeties of Trinuclear Complexes [M(bpca)_2(M'(hfac)_2}_2], Constructed with the Complexed Bridging Ligand [M(bpca)_2] (M, M' = Ni(II), Mn(II) ; Cu(II), Mn(II) ; Fe(II), Mn(II) ; Ni(II), Fe(II) ; and Fe(II), Fe(II) ; Hbpca = Bis(2-pyridylcarbonyl)amine, Hhfac = Hexafluoroacetylacetone]"Inorg.Chem.. 41. 507-512 (2002)
[文献書誌] 伊藤翼: "A Helical Metal-Metal Bonded Chain via the Pt → Ag Dative Bond"J.Am.Chem.Soc.. 123. 743-744 (2001)
[文献書誌] 伊藤翼: "Comproportionation Reaction and Hindered Rotation of Coordinated Pyridine Ring in Acetate Bridged Tetraplatinum(II) Cluster Having Pyridine Derivative Ligands in the Cluster Plane"Chem.Eur.J.. (印刷中). (2001)
[文献書誌] 伊藤翼: "Tetra-and Trinuclear Platinum(II) Cluster Complexes"Adv.Inorg.Chem.. 52. 205-248 (2001)
[文献書誌] 伊藤翼: "Experimental and Theoretical Studies on Ferromagnetically Coupled Metal Complexes with Imino Nitroxides"Inorg.Chem.. 40. 5518-5525 (2001)
[文献書誌] 大川尚士: "Trinuclear Cu^<II>Mn^<II>Cu^<II> Complex of An Oxamide/Dioxime Ligand and Extension to a Bimetallic Magnetic Compound"J.Chem.Soc., Dalton Trans.. 2001. 64-70 (2001)
[文献書誌] 大川尚士: "Tetranuclear Mixed-Metal Cu^<II>_2M^<II>_2 Complexes Derived from a Phenol-based Macrocyclic Ligand Having tow N(amine)_2O_2 and N(imine)_2O_2 Metal-Binding Sites"Inorg.Chem.. 40. 3739-3744 (2001)
[文献書誌] 大川尚士: "Synthesis, Charaterization and Activation of Thermally Stable μ-12-Peroxodiiron(III) Complex"Inogr.Chem.. 40. 4821-4822 (2001)
[文献書誌] 大川尚士: "Three-Dimensional Bimetallic Ferromagnets (Mn(L)]_3[Cr(CN)_6]_2-nH_2O (L=en, N=4 ; L=glya, n=2.5) and Relevance to a Prussian Blue Analogue Mn_3[Cr(CN)_6]_2 -12H_2O"J.Solid State Chem.. 159. 328-335 (2001)
[文献書誌] 山本隆一: "Cationic Arylpalladium Complexes with Chelating diamine Ligands, [PdAr(N-N)(solv)] BF4(N-N = N, N, N', N'-tetrametthylethylenediamine, 22'-bipyridine, 4, 4' -dimethyl'2.2'-bipyridine). Preparation, Intermolecular Coupling of the Aryl Ligands, and Insertion of Alkyne and Allen into the Pd-C bond"Organometallics. 20. 1087-1101 (2001)
[文献書誌] 山本隆一: "Piezochromic Behavior of Regioregular Poly(3-hexylthiophene-2, 5-diyl) and Poly(5, 8-dihexadecyloxyanthraquinone-1, 4-diyl)"Polymer. 42. 6673-6675 (2001)
[文献書誌] 山本隆一: "Organometallic Syntheses of Head-tohead Poly(3-hexylthiophene) and a Related Polymer with a Spacinf Non-subsituted Thiophene Unit. Colloidal Solution of the Polymers"Macromol.Chem.Phys.. 202. 1031-1034 (2001)
[文献書誌] 山本隆一: "Molecylar Alignment of Head-to-Rail-Type Poly(3-hexylthiophene-2, 5 -diyl) and Related Polymers and Compounds on Substrates"J.Polym.Sci.Part B : Polym.Phys.. 39. 1713-1718 (2001)
[文献書誌] 山口兆: "Theoretical Studies of Magnetic Interactions in Mn(II)(hfac)_2{di(4-pyridyl)phenylcarbene } and Cu(II)(hfac)_2 { di(4-pyridyl)phenylcarbene }"J.Am.Chem.Soc.. 124. 450-461 (2002)
[文献書誌] 山口兆: "Third-order Nonlinear Optical Properties of Fractal-and Nonfractal-structures Oligomers Modeled after Dendron Parts in Cayley-tree-type Dendrimers"J.Chem.Phys.. 115. 6780-6784 (2001)
[文献書誌] 山口兆: "Theoretical Study of the Magnetic Interaction for M-O-N Type Metal oxides. Comparison of Broken-Symmetry Approaches"Polyhedorn. 20. 1177-1184 (2001)
[文献書誌] 山口兆: "Size-dependency of Polarizabilities of Fractal-and Nonfractal-structured Oligomers Modeled after Dendron Parts in Cayley-tree-type Dendrimers"J.Chem.Phys.. 115. 1052-1059 (2001)
[文献書誌] 加藤礼三: "Development of Molecular Conductors Derived from Metal Dithiolene Complexes"Synth.Met.. 120. 675-678 (2001)
[文献書誌] 加藤礼三: "Synthesis and Properties of Novel Donor-Tupe Metal-Dithiolene Complexes Based on 5, 6-dithydro-1, 4-dioxin-2, 3-dithiol(edo) Ligand"J.Mater.Chem.. 11. 2131-2141 (2001)
[文献書誌] 北川進: "New Molecular Assemblies of Redox Isomers, [Cr^<III>(X_4SQ)_<3-n>(X_4Cat)_n]^<-n> X-ray Crystal Structuers and Physical Properties"Inorg.Chem.. 40. 146-156 (2001)
[文献書誌] 北川進: "A New Class of Cyclic Hexmer : [Co_6L_6]^<24->(H_6L = hexaazatriphenylene hexacarboxylic acid)"Angew.Chem.Int.Ed.. 40. 3817-3819 (2001)
[文献書誌] 北川進: "Unprecedented Mixed^Charged State in a Supramolecular Assembly of Ligand-based Mixed-valence Redox Isomers"Angew.Chem.Int.Ed.. 41(印刷中). (2002)
[文献書誌] 北川進: "Novel Pillared-Layer Coordination Polymer Network with Hysteretic Sorption"Angew.Chem.Int.Ed.. 41(印刷中). (2002)

2001 年度 実績報告書

「集積型金属錯体」研究の総括

研究代表者

伊藤 翼 東北大学, 大学院・理学研究科, 教授 (90007328)

研究成果

[文献書誌] 伊藤翼: "Zinc(II) Slides on a Ligand Surface : The X-ray Structure and Dynamic Behavior in Solution of [Zn(H_2L)(tacn)]"Angew.Chem.Int.Ed.. 41(印刷中). (2002)

[文献書誌] 伊藤翼: "A Helical Metal-Metal Bonded Chain via the Pt → Ag Dative Bond"J.Am.Chem.Soc.. 123. 743-744 (2001)

[文献書誌] 伊藤翼: "Comproportionation Reaction and Hindered Rotation of Coordinated Pyridine Ring in Acetate Bridged Tetraplatinum(II) Cluster Having Pyridine Derivative Ligands in the Cluster Plane"Chem.Eur.J.. (印刷中). (2001)

[文献書誌] 伊藤翼: "Tetra-and Trinuclear Platinum(II) Cluster Complexes"Adv.Inorg.Chem.. 52. 205-248 (2001)

[文献書誌] 伊藤翼: "Experimental and Theoretical Studies on Ferromagnetically Coupled Metal Complexes with Imino Nitroxides"Inorg.Chem.. 40. 5518-5525 (2001)

[文献書誌] 大川尚士: "Trinuclear Cu^<II>Mn^<II>Cu^<II> Complex of An Oxamide/Dioxime Ligand and Extension to a Bimetallic Magnetic Compound"J.Chem.Soc., Dalton Trans.. 2001. 64-70 (2001)

[文献書誌] 大川尚士: "Tetranuclear Mixed-Metal Cu^<II>_2M^<II>_2 Complexes Derived from a Phenol-based Macrocyclic Ligand Having tow N(amine)_2O_2 and N(imine)_2O_2 Metal-Binding Sites"Inorg.Chem.. 40. 3739-3744 (2001)

[文献書誌] 大川尚士: "Synthesis, Charaterization and Activation of Thermally Stable μ-12-Peroxodiiron(III) Complex"Inogr.Chem.. 40. 4821-4822 (2001)

[文献書誌] 大川尚士: "Three-Dimensional Bimetallic Ferromagnets (Mn(L)]_3[Cr(CN)_6]_2-nH_2O (L=en, N=4 ; L=glya, n=2.5) and Relevance to a Prussian Blue Analogue Mn_3[Cr(CN)_6]_2 -12H_2O"J.Solid State Chem.. 159. 328-335 (2001)

[文献書誌] 山本隆一: "Piezochromic Behavior of Regioregular Poly(3-hexylthiophene-2, 5-diyl) and Poly(5, 8-dihexadecyloxyanthraquinone-1, 4-diyl)"Polymer. 42. 6673-6675 (2001)

[文献書誌] 山本隆一: "Organometallic Syntheses of Head-tohead Poly(3-hexylthiophene) and a Related Polymer with a Spacinf Non-subsituted Thiophene Unit. Colloidal Solution of the Polymers"Macromol.Chem.Phys.. 202. 1031-1034 (2001)

[文献書誌] 山本隆一: "Molecylar Alignment of Head-to-Rail-Type Poly(3-hexylthiophene-2, 5 -diyl) and Related Polymers and Compounds on Substrates"J.Polym.Sci.Part B : Polym.Phys.. 39. 1713-1718 (2001)

[文献書誌] 山口兆: "Theoretical Studies of Magnetic Interactions in Mn(II)(hfac)_2{di(4-pyridyl)phenylcarbene } and Cu(II)(hfac)_2 { di(4-pyridyl)phenylcarbene }"J.Am.Chem.Soc.. 124. 450-461 (2002)

[文献書誌] 山口兆: "Third-order Nonlinear Optical Properties of Fractal-and Nonfractal-structures Oligomers Modeled after Dendron Parts in Cayley-tree-type Dendrimers"J.Chem.Phys.. 115. 6780-6784 (2001)

[文献書誌] 山口兆: "Theoretical Study of the Magnetic Interaction for M-O-N Type Metal oxides. Comparison of Broken-Symmetry Approaches"Polyhedorn. 20. 1177-1184 (2001)

[文献書誌] 山口兆: "Size-dependency of Polarizabilities of Fractal-and Nonfractal-structured Oligomers Modeled after Dendron Parts in Cayley-tree-type Dendrimers"J.Chem.Phys.. 115. 1052-1059 (2001)

[文献書誌] 加藤礼三: "Development of Molecular Conductors Derived from Metal Dithiolene Complexes"Synth.Met.. 120. 675-678 (2001)

[文献書誌] 加藤礼三: "Synthesis and Properties of Novel Donor-Tupe Metal-Dithiolene Complexes Based on 5, 6-dithydro-1, 4-dioxin-2, 3-dithiol(edo) Ligand"J.Mater.Chem.. 11. 2131-2141 (2001)

[文献書誌] 北川進: "New Molecular Assemblies of Redox Isomers, [Cr^<III>(X_4SQ)_<3-n>(X_4Cat)_n]^<-n> X-ray Crystal Structuers and Physical Properties"Inorg.Chem.. 40. 146-156 (2001)

[文献書誌] 北川進: "A New Class of Cyclic Hexmer : [Co_6L_6]^<24->(H_6L = hexaazatriphenylene hexacarboxylic acid)"Angew.Chem.Int.Ed.. 40. 3817-3819 (2001)

[文献書誌] 北川進: "Unprecedented Mixed^Charged State in a Supramolecular Assembly of Ligand-based Mixed-valence Redox Isomers"Angew.Chem.Int.Ed.. 41(印刷中). (2002)

[文献書誌] 北川進: "Novel Pillared-Layer Coordination Polymer Network with Hysteretic Sorption"Angew.Chem.Int.Ed.. 41(印刷中). (2002)

2001 年度実績報告書

伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)