2001 年度実績報告書

ナノメータ粒子の寸法制御による新材料機能の創出

研究課題

研究課題/領域番号	10354005
研究機関	東北大学
研究代表者	粕谷厚生東北大学, 学際科学研究センター, 教授 (10005986)
研究分担者	鎌田正史 GLサイエンス(株), 開発部主任研究員田路和幸東北大学, 工学研究科, 教授 (10175474) 恒川信東北大学, 金属材料研究所, 助手 (00023218) BALACHANDRAN Jeyadevan 秋田大学, 工学資源学部, 講師 (80261593) 須藤彰三東北大学, 理学研究科, 助教授 (40171277)
キーワード	ナノ粒子 / 微粒子 / 超微粒子 / マイクロクラスター / クラスター / クラスター集合体 / CdSe / CdS
研究概要	本研究では1)1ナノメータ程度の極微少物質を寸法を揃えて安定に単離する手法を確立し、2)その寸法に依存する特異な物性を明らかにし、3)これを基本単位とした巨視的な大きさの物質を組み上げて新しい電子的機能を有する材料の創出を試みることを目的とした。初(平成10)年度ではその第一ステップとして、CdS等のII-VI族半導体、CeO2等の金属酸化物のナノメータ粒子を溶液法で作製し、界面活性剤で安定化させる技術を開発した。得られた試料を各種フィルター或いは液体クロマトグラフでサイズ選別することに成功した。次年度ではこの手法を用いて直径が1 10ナノメータの粒子を各サイズに選別して光学測定を行い、基礎吸収端が短波長側に移動することによる量子閉じこめ効果を確認した。 3年度においてはCdSナノ粒子の集合体について光電気化学効果を調べた。その結果、この集合体が硫化水素水溶液を光分解して効率よく水素を発生することがわかった。これにより公害物質を分解してクリーンエネルギーを得る新しい光触媒機能がナノ粒子集合体において見出された。最終年度ではCdSeの安定なマイクロクラスター(CdSe)33と(CdSe)34の合成と単離及び結晶化に成功した。この結果は、これまでのC60のように元素のみに限られていた安定なマイクロクラスターの種類が化合物にまで一気に広げられたことを意味し、本研究の最大の成果である。高性能の光触媒効果も確認されている。

研究成果

(20件)

すべてその他

すべて文献書誌 (20件)

[文献書誌] A.Kasuya, G.Milczarek, I.Dmitruk, Y.barnakov, R.czajka, O.Perales, X.Liu: "Nanometer-size Semiconductors and Oxide Clusters Prepared via Colloidal Processes"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 50-52 (2001)
[文献書誌] I.Dmitruk, Y.Barnakov, T.Nirasawa, T.Arai, K.Tohji-, O.Terasaki, A.Kasuya: "Stablilties and Optical Properties of Nanometer CdSe Clusters Prepared in Solution"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 53-55 (2001)
[文献書誌] Y.Barnakov, R.Sivamohan, I.Dmitruk, T.Kudo, A.Kasuya, T.Nirasawa, T.Kudo, K.Tohji, B.Jeyadevan, K.Shinoda, Z.Liu, O.Terasaki: "Synthesis of CdSe microclusters"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 56-58 (2001)
[文献書誌] B.Sundarakannan, G.Milczarek, A.Kasuya, T.Ogawa, B.Jeyadevan, K.Tohji: "Investigation on the effect of particale size of CdS film on the hydrogen production"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 59-62 (2001)
[文献書誌] S.Mamykin, G.Milczarek, A.Kasuya, K.Shinoda, B.Jeyadevan, K.Tohji: "Characterization and optimization of electrodeposited CdS thin films for photoelectrochemical cells"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 63-66 (2001)
[文献書誌] G.Milczarek, A.Kasuya, S.Mamykin, T.Arai, K.Tohji, K.Shinoda: "Novel method for the electrodeposition of thin ZnS films based on cathodic reduction of polysulphide in the presence of zinc hydroxyl complex"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 67-70 (2001)
[文献書誌] K.Shinoda, H.Oshima, Y.Sato, T.Ogawa, B.Jeyadevan, A.Kasuya, K.Tohji: "Local structure and photocatalytic property in ZnS cluster films"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 71-74 (2001)
[文献書誌] T.Arai, S.Sakima, H.Yoshimura, K.Shinoda, B.Jeyadevan, K.Tohji, A.Kasuya, Y.Nishima: "Synthesis of stratified semiconductors for photocatalytic hydrogen generation"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 75-78 (2001)
[文献書誌] S.Tsunekawa, A.Kasuya, Y.Kawazoe: "Blue shifts in ultraviolet absorption spectra of oxide nanoparticles-CeOX and -SnOY"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 88-92 (2001)
[文献書誌] B.Jeyadevan, Y.Sato, K.Tohji, K.Motomiya, A.Kasuya, R.Hatakeyama, H.Ishida, K.Ueno, T.Takagi: "The effect of strong and week magnetic fields on the synthesis of SWNTs"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 93-95 (2001)
[文献書誌] T.Ogawa, Y.Sato, K.Shinoda, K.Motomiya, B.Jeyadevan, K.Tohji, A.Kasuya, Y.Nishina: "Purification method for SWNTs and its automation"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 97-100 (2001)
[文献書誌] O.Perales-Perez, H.Sasaki, B.Jeyadevan, T.Hihara, K.Tohji, K.Sumiyama, A.Kasuya: "Production of monodispersed particles by using effective size selection methods at the nanosize level"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 101-104 (2001)
[文献書誌] O.Perales-Perez, B.Jeyadevan, C.N.Chinnasamy, K.Tohji, A.Kasuya: "Solution synthesis of monodispersed nanocrystalline metal particles : the case of cobalt"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 105-108 (2001)
[文献書誌] C.N.Chinnasamy, A.Narayanasamy, B.Jeyadevan, K.Shinoda, K.Tohji, A.Kasuya, K.Sumiyama: "Structural and magnetic properties of mixed spinel type nanocrystalline NiFe204"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 162-164 (2001)
[文献書誌] H.Takahashi, E.Matsubara, A.Kasuya, K.Kikuchi, Y.Chiba, T.Kudo, B.Jeyadewan, K.Tohji: "Extraction of fullerenes from residual soot using HIDE method"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 113-117 (2001)
[文献書誌] H.Takahashi, E.Matsubara, A.Kasuya, Y.Akimoto, T.Kudo, Y.Akimoto, B.Jeyadewan, K.Tohji: "Efficient and simple preparation method for dimeric fullerene oxides"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 118-122 (2001)
[文献書誌] Y.Akimoto, T.Kudo, K.Shinoda, B.Jeyadewan, K.Tohji, T.Nirasawa, A.Kasuya, Y.Nishina: "Synthesis of water-soluble fullerene and its isolation"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 123-126 (2001)
[文献書誌] R.Czajka, A.Kasuya, T.Hihara, K.Sumiyama: "Variable temperature STM/AFM investigations of transition metal clusters produced by PGC source"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 137-141 (2001)
[文献書誌] R.Nishitani, T.Yoshida, H.Arakawa, A.Kasuya, K.Sumiyama: "Circular polarization measurements of STM-induced luminescence from magnetic metal particles"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 142-145 (2001)
[文献書誌] S.Suto, F.Sawano, H.Harada, T.Chiba, K.Sakamoto, A.Watanabe, M.Nanjo, XiLiu, R.Czajka, A.Kasuya: "Adsorption and thermal reaction of cyclohexasilane adsorbed on Si(111) 7x7 and Si(100)2x1 surfaces"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 146-149 (2001)

2001 年度 実績報告書

ナノメータ粒子の寸法制御による新材料機能の創出

研究代表者

粕谷 厚生 東北大学, 学際科学研究センター, 教授 (10005986)

研究成果

[文献書誌] A.Kasuya, G.Milczarek, I.Dmitruk, Y.barnakov, R.czajka, O.Perales, X.Liu: "Nanometer-size Semiconductors and Oxide Clusters Prepared via Colloidal Processes"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 50-52 (2001)

[文献書誌] I.Dmitruk, Y.Barnakov, T.Nirasawa, T.Arai, K.Tohji-, O.Terasaki, A.Kasuya: "Stablilties and Optical Properties of Nanometer CdSe Clusters Prepared in Solution"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 53-55 (2001)

[文献書誌] Y.Barnakov, R.Sivamohan, I.Dmitruk, T.Kudo, A.Kasuya, T.Nirasawa, T.Kudo, K.Tohji, B.Jeyadevan, K.Shinoda, Z.Liu, O.Terasaki: "Synthesis of CdSe microclusters"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 56-58 (2001)

[文献書誌] B.Sundarakannan, G.Milczarek, A.Kasuya, T.Ogawa, B.Jeyadevan, K.Tohji: "Investigation on the effect of particale size of CdS film on the hydrogen production"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 59-62 (2001)

[文献書誌] S.Mamykin, G.Milczarek, A.Kasuya, K.Shinoda, B.Jeyadevan, K.Tohji: "Characterization and optimization of electrodeposited CdS thin films for photoelectrochemical cells"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 63-66 (2001)

[文献書誌] K.Shinoda, H.Oshima, Y.Sato, T.Ogawa, B.Jeyadevan, A.Kasuya, K.Tohji: "Local structure and photocatalytic property in ZnS cluster films"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 71-74 (2001)

[文献書誌] T.Arai, S.Sakima, H.Yoshimura, K.Shinoda, B.Jeyadevan, K.Tohji, A.Kasuya, Y.Nishima: "Synthesis of stratified semiconductors for photocatalytic hydrogen generation"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 75-78 (2001)

[文献書誌] S.Tsunekawa, A.Kasuya, Y.Kawazoe: "Blue shifts in ultraviolet absorption spectra of oxide nanoparticles-CeOX and -SnOY"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 88-92 (2001)

[文献書誌] B.Jeyadevan, Y.Sato, K.Tohji, K.Motomiya, A.Kasuya, R.Hatakeyama, H.Ishida, K.Ueno, T.Takagi: "The effect of strong and week magnetic fields on the synthesis of SWNTs"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 93-95 (2001)

[文献書誌] T.Ogawa, Y.Sato, K.Shinoda, K.Motomiya, B.Jeyadevan, K.Tohji, A.Kasuya, Y.Nishina: "Purification method for SWNTs and its automation"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 97-100 (2001)

[文献書誌] O.Perales-Perez, H.Sasaki, B.Jeyadevan, T.Hihara, K.Tohji, K.Sumiyama, A.Kasuya: "Production of monodispersed particles by using effective size selection methods at the nanosize level"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 101-104 (2001)

[文献書誌] O.Perales-Perez, B.Jeyadevan, C.N.Chinnasamy, K.Tohji, A.Kasuya: "Solution synthesis of monodispersed nanocrystalline metal particles : the case of cobalt"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 105-108 (2001)

[文献書誌] C.N.Chinnasamy, A.Narayanasamy, B.Jeyadevan, K.Shinoda, K.Tohji, A.Kasuya, K.Sumiyama: "Structural and magnetic properties of mixed spinel type nanocrystalline NiFe204"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 162-164 (2001)

[文献書誌] H.Takahashi, E.Matsubara, A.Kasuya, K.Kikuchi, Y.Chiba, T.Kudo, B.Jeyadewan, K.Tohji: "Extraction of fullerenes from residual soot using HIDE method"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 113-117 (2001)

[文献書誌] H.Takahashi, E.Matsubara, A.Kasuya, Y.Akimoto, T.Kudo, Y.Akimoto, B.Jeyadewan, K.Tohji: "Efficient and simple preparation method for dimeric fullerene oxides"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 118-122 (2001)

[文献書誌] Y.Akimoto, T.Kudo, K.Shinoda, B.Jeyadewan, K.Tohji, T.Nirasawa, A.Kasuya, Y.Nishina: "Synthesis of water-soluble fullerene and its isolation"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 123-126 (2001)

[文献書誌] R.Czajka, A.Kasuya, T.Hihara, K.Sumiyama: "Variable temperature STM/AFM investigations of transition metal clusters produced by PGC source"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 137-141 (2001)

[文献書誌] R.Nishitani, T.Yoshida, H.Arakawa, A.Kasuya, K.Sumiyama: "Circular polarization measurements of STM-induced luminescence from magnetic metal particles"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 142-145 (2001)

[文献書誌] S.Suto, F.Sawano, H.Harada, T.Chiba, K.Sakamoto, A.Watanabe, M.Nanjo, XiLiu, R.Czajka, A.Kasuya: "Adsorption and thermal reaction of cyclohexasilane adsorbed on Si(111) 7x7 and Si(100)2x1 surfaces"Proc. Int. Symp. on Cluster Assembled Materials, IPAP Conf.. Series3. 146-149 (2001)

2001 年度実績報告書

粕谷厚生東北大学, 学際科学研究センター, 教授 (10005986)