2002 年度実績報告書

酸素活性種の分子論と反応制御に関する研究の総括

研究課題

研究課題/領域番号	11228204
研究機関	大阪大学
研究代表者	福住俊一大阪大学, 大学院・工学研究科, 教授 (40144430)
研究分担者	諸岡良彦常磐大学, コミュニティー振興学部, 教授 (70016731)
キーワード	酵素反応 / 環境対応 / 触媒・化学プロセス / 生体内分子論 / 錯体化学 / 光エネルギー変換 / 酸素活性種 / 反応制御
研究概要	本研究領域は、様々な酸素活性種の構造と反応性を分子レベルで明らかにし、その反応性を制御する方法を確立することにより、水を電子源とするクリーンな光エネルギー変換を達成するとともに、酸素活性種による新しい高効率かつ高選択的な物質変換手法を開発し、さらに酸素活性種の生体内分子論を解明して、その臨床応用に関する展望を見いだすことを目的としている。研究計画に基づき、「酸素活性種の分子論と反応制御」に関する研究を総合的に推進した。特に、各研究グループ間の協力体制を強化するため、情報交換や装置の共同利用を頻繁に行った。その共同研究の成果は研究目的を達成する上で不可欠のものとなった(研究発表参照)。グループ内の研究成果報告および研究打ち合わせについては、平成14年秋に淡路国際会議場において研究代表者が班会議を開催した。諸岡は、錯体化学的および触媒化学的な両者の視点から、各研究グループの研究成果を総合的に評価し、今後の研究展開に関する助言を行った。また、福住は、領域代表者として、研究全体の展開に配慮しながら、効率的な研究の展開を図った。

研究成果
(56件)

すべてその他

すべて文献書誌 (56件)

[文献書誌] Fukuzumi, S. et al.: "Effects of Hydrogen Bonding on Metal Ion-Promoted Intramolecular Electron Transfer and Photoinduced Electron Transfer in a Ferrocene-Quinone Dyad with a Rigid Amide Spacer"Journal of the American Chemical Society. 125・4. 1007-1013 (2003)
[文献書誌] Ogo, S.et al.: "Isolation and Crystal Structure of Water-Soluble Iridium Hydride. Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media"Journal of the American Chemical Society. 125(in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "Scandium Ion-Promoted Reduction of Heterocyclic N : N Double Bond. Hydride Transfer vs Electron Transfer"Journal of the American Chemical Society. 124・42. 12566-12573 (2002)
[文献書誌] Fukuzumi, S. et al.: "Direct detection of radical cations of NADH analogues"Journal of the American Chemical Society. 124・49. 14538-14539 (2002)
[文献書誌] Fukuzumi, S. et al.: "Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron-Transfer Step"Journal of the American Chemical Society. 124・47. 14147-14155 (2002)
[文献書誌] Fukuzumi, S. et al.: "A Negative Temperature Dependence of the Electron Self-Exchange Rates of Zinc Porphyrin π Radical Cations"Journal of the American Chemical Society. 124・37. 10974-10975 (2002)
[文献書誌] Fukuzumi, S. et al.: "Fluorescence Maxima of 1O-Methylacridone-Metal Ion Salt Complexes : A Convenient and Quantitative Measure of Lewis Acidity of Metal Ion Salts"Journal of the American Chemical Society. 124・35. 10270-10271 (2002)
[文献書誌] Fukuzumi, S. et al.: "Asymmetric Sulfoxidation and Amine Binding by H64D/V68A and H64D/V68S Mb : Mechanistic Insight into the Chiral Discrimination Step"Journal of the American Chemical Society. 124・29. 8506-8507 (2003)
[文献書誌] Fukuzumi, S. et al.: "Significant Enhancement of Electron Transfer Reduction of NAD+ Analogues by Complexation with Scandium Ion and the Detection of the Radical Intermediate-Scandium Ion complex"Journal of the American Chemical Society. 124・31. 9181-9188 (2002)
[文献書誌] Fukuzumi, S. et al.: "Exciplex intermediates in photoinduced electron transfer of porphyrin-fullerene dyads"Journal of the American Chemical Society. 124・27. 8067-8077 (2002)
[文献書誌] Fukuzumi, S. et al.: "Hydrogen-bonding dynamics in photoinduced electron transfer in a ferrocene-quinone linked dyad with a rigid amide spacer"Journal of the American Chemical Society. 124・24. 6794-6795 (2002)
[文献書誌] Fukuzumi, S. et al.: "Fine-Tuning of Copper(I)-Dioxygen Reactivity by 2-(2-Pyridyl)ethylamine Bidentate Ligands"Journal of the American Chemical Society. 124・22. 6367-6377 (2002)
[文献書誌] Fukuzumi, S. et al.: "Stepwise charge separation and charge recombination in ferrocene-meso, meso-linked porphyrin dimer-fullerene triad"Journal of the American Chemical Society. 124・18. 5165-5174 (2002)
[文献書誌] Fukuzumi, S. et al.: "Oxo-Transfer Reaction from a Bis(μ-oxo) dicopper(III) Complex to Sulfides"Journal of the American Chemical Society. 124・6. 998-1002 (2002)
[文献書誌] Fukuzumi, S. et al.: "Large Photocurrent Generation of Gold Electrodes Modified with [60] Fullerene-Linked Oligothiophenes Bearing a Tripodal Rigid Anchor"Journal of the American Chemical Society. 124・4. 532-533 (2002)
[文献書誌] Fukuzumi, S. et al.: "Comparison of reorganization energies for intra-and intermolecular electron transfer"Angewandte Chemie, International Edition. 41・13. 2344-2347 (2002)
[文献書誌] Fukuzumi, S. et al.: "Thermal intramolecular electron transfer in a ferrocene-naphthoquinone linked dyad promoted by metal ions"Angewandte Chemie, International Edition. 41・4. 620-622 (2002)
[文献書誌] Fukuzumi, S. et al.: "Mechanisms of Electron Transfer Oxidation of NADH Analogs and the Chemiluminescence. Detection of the Keto and Enol Radical Cations"Journal of the American Chemical Society. 125(in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation"Chemical Communications (Cambridge, United Kingdom). 17. 1984-1985 (2002)
[文献書誌] Fukuzumi, S. et al.: "Evidence that gold(III) porphyrins are not electrochemically inert : facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl) porphyrin"Chemical Communications (Cambridge, United Kingdom). 4. 356-357 (2002)
[文献書誌] Fukuzumi, S. et al.: "Driving Force Dependence of Intermolecular Electron Transfer Reactions of Fullerenes"Chemistry A European Journal. 9(in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "Formation of a Supramolecular Porphyrin-Spacer-Acceptor Ternary Complex and Intracomplex Electron Transfer"Journal of Physical Chemistry A. 107・3. 379-385 (2003)
[文献書誌] Fukuzumi, S. et al.: "Small Reorganization Energy of Intramolecular Electron Transfer in Fullerene-Based Dyads with Short Linkage"Journal of Physical Chemistry A. 106・46. 10991-10998 (2002)
[文献書誌] Fukuzumi, S. et al.: "Effects of Metal Ions Distinguishing between One-Step Hydrogen-and Electron-Transfer Mechanisms for the Radical-Scavenging Reaction of (+)-Catechin"Journal of Physical Chemistry A. 106・46. 11123-11126 (2002)
[文献書誌] Fukuzumi, S. et al.: "Photophysical and Electrochemical Properties of New Bacteriochlorins and Characterization of Radical Cation and Radical Anion Species"Journal of Physical Chemistry A. 106・20. 5105-5113 (2002)
[文献書誌] Fukuzumi, S. et al.: "Linkage dependent charge separation and charge recombination in porphyrin-pyromellitimide-fullerene triads"Journal of Physical Chemistry A. 106・12. 2803-2814 (2002)
[文献書誌] Fukuzumi, S. et al.: "Electron transfer properties of singlet oxygen and promoting effects of scandium ion"Journal of Physical Chemistry A. 106・7. 1241-1247 (2002)
[文献書誌] Fukuzumi, S. et al.: "Dehydrogenation vs. Oxygenation in Rhotosensitized Oxidation of 9-Substituted 1O-Methyl-9,10-dihydroacridine in the Presence of Scandium Ion"Journal of Physical Chemistry A. 106・7. 1465-1472 (2002)
[文献書誌] Fukuzumi, S. et al.: "Uphill photooxidation of NADH analogues by hexyl viologen catalyzed by zinc porphyrin-linked fullerenes"Journal of Physical Chemistry A. 106・10. 1903-1908 (2002)
[文献書誌] Fukuzumi, S. et al.: "DNA Cleavage via Superoxide Anion Formed in Photoinduced Electron Transfer from NADH to γ-Cyclodextrin-Bicapped C_<60> in an Oxygen-Saturated Aqueous Solution"Journal of Physical Chemistry B. 106・9. 2372-2380 (2002)
[文献書誌] Ogo, S.et al.: "Structural and Spectroscopic Features of a cis (Hydroxo)-Fe^<III>-(Carboxylato) Configuration as an Active Site Model for Lipoxygenases"Inorganic Chemistry. 41・21. 5513-5520 (2002)
[文献書誌] Fukuzumi, S. et al.: "Enhancement of photocurrent generation by ITO electrodes modified chemically with self-assembled monolayers of porphyrin-fullerene dyads"Advanced Materials (Weinheim, Germany). 14・12. 892-895 (2002)
[文献書誌] Fukuzumi, S. et al.: "A key role for old yellow enzyme in the metabolism of drugs by Trypanosoma cruzi"Journal of Experimental Medicine. 196・9. 1241-1251 (2002)
[文献書誌] Fukuzumi, S. et al.: "A Planar Catechin Analogue as a Promising Antioxidant with Reduced Prooxidant Activity"Chemical Research in Toxicology. 16・1. 81-86 (2003)
[文献書誌] Fukuzumi, S. et al.: "Acceleration and deceleration of photoinduced electron transfer rates by an electric field in porphyrin-fullerene dyads"Chemical Physics Letters. 368・1, 2. 230-235 (2002)
[文献書誌] Fukuzumi, S. et al.: "Porphyrin-fullerene dyad with a long linker : formation of charge transfer conformer in Langmuir-Blodgett film"Chemical Physics Letters. 366・3, 4. 245-252 (2002)
[文献書誌] Fukuzumi, S. et al.: "Dioxygen activation by copper complexes. Mechanistic insights into copper monooxygenases and copper oxidases"Bulletin of the Chemical Society of Japan. 75・10. 2081-2095 (2002)
[文献書誌] Fukuzumi, S. et al.: "Formation of superoxide-metal ion complexes and the electron transfer catalysis"Coordination Chemistry Reviews. 226・1-2. 71-80 (2002)
[文献書誌] Fukuzumi, S. et al.: "Direct detection of superoxide anion generated in C_<60>-photosensitized oxidation of NADH and an analogue by molecular oxygen"Journal of the Chemical Society, Perkin Transactions 2. 11. 1829-1833 (2002)
[文献書誌] Fukuzumi, S. et al.: "Effects of magnesium ion on kinetic stability and spin distribution of phenoxyl radical derived from a vitamin E analogue : mechanistic insight into antioxidative hydrogen-transfer reaction of vitamin E"Journal of the Chemical Society, Perkin Transactions 2. 9. 1520-1524 (2002)
[文献書誌] Fukuzumi, S. et al.: "Catalysis in electron transfer reactions : Facts and mechanistic insights"Journal of Physical Organic Chemistry. 15・8. 448-460 (2002)
[文献書誌] Fukuzumi, S. et al.: "Photocurrent generation using gold electrodes modified with self-assembled monolayers of a fullerene-porphyrin dyad"Journal of Materials Chemistry. 12・7. 2034-2040 (2002)
[文献書誌] Fukuzumi, S. et al.: "Enhancement of Light-Harvesting and Photocurrent Generation by ITO Electrodes Modified with meso, meso-Linked Porphyrin Oligomers"Nano Letters. 3(in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "Electron transfer reduction of a highly electron-deficient fullerene, C_<60>F_<18>"Chemical Communications (Cambridge, United Kingdom). 17. 1952-1953 (2002)
[文献書誌] Fukuzumi, S. et al.: "Electron transfer in electron donor-acceptor ensembles containing porphyrins and metalloporphyrins"Journal of Porphyrins and Phthalocyanines. 6・4. 289-295 (2002)
[文献書誌] Fukuzumi, S. et al.: "Electron Transfer Mechanism in Radical-Scavenging Reactions of Flavonoids"Free Radical Biol. Med.. 33. S308-S309 (2002)
[文献書誌] Fukuzumi, S. et al.: "Conducting molecular materials and electrochemistry. 1. Photoelectron transfer at electrodes modified with fullerene derivatives"Electrochemistry (Tokyo, Japan). 70・4. 274-278 (2002)
[文献書誌] Fukuzumi, S. et al.: "Clean energy from inexhaustible solar light"Gendai Kagaku. 375. 46-50 (2002)
[文献書誌] Fukuzumi, S. et al.: "Nanoscale artificial photosynthesis system using porphyrins and fullerenes"Kagaku Furontia (Bunshi Nanotekunoroji). 6. 115-125 (2003)
[文献書誌] Fukuzumi, S. et al.: "Catalytic Control of Electron Transfer Processes"Pure Appl. Chem.. (in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "C_<70> vs. C_<60> in zinc porphyrin-fullerene dyads : prolonged charge separation and ultrafast energy transfer from the second excited singlet state of porphyrin"Photochemical & Photobiological Sciences. (in press). (2003)
[文献書誌] Fukuzumi, S.: "New Perspective of Electron Transfer Chemistry"Organic & Biomolecular Chemistry. (in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "Electron Transfer Properties of Bisphenol Derivatives in Relation with the Developing Properties in Silver Salt Photothermographic Systems"J. Imag. Sci. Tech.. 47(in press). (2003)
[文献書誌] Shunichi Fukuzumi et al.: "Fullerenes 2002--Volume 12. (Proceedings of the 201^<st> Meeting of the Electrochemical Society)"The Electrochemical Society, INC. 37 (2002)
[文献書誌] Fukuzumi, S.et al.: "生産と技術"生産技術振興協会. 3 (2002)
[文献書誌] Fukuzumi, S.et al.: "先端ウオッチングシリーズ「錯体化学」"日本化学会. 6 (2002)

2002 年度 実績報告書

酸素活性種の分子論と反応制御に関する研究の総括

研究代表者

福住 俊一 大阪大学, 大学院・工学研究科, 教授 (40144430)

研究成果

[文献書誌] Fukuzumi, S. et al.: "Effects of Hydrogen Bonding on Metal Ion-Promoted Intramolecular Electron Transfer and Photoinduced Electron Transfer in a Ferrocene-Quinone Dyad with a Rigid Amide Spacer"Journal of the American Chemical Society. 125・4. 1007-1013 (2003)

[文献書誌] Ogo, S.et al.: "Isolation and Crystal Structure of Water-Soluble Iridium Hydride. Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media"Journal of the American Chemical Society. 125(in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "Scandium Ion-Promoted Reduction of Heterocyclic N : N Double Bond. Hydride Transfer vs Electron Transfer"Journal of the American Chemical Society. 124・42. 12566-12573 (2002)

[文献書誌] Fukuzumi, S. et al.: "Direct detection of radical cations of NADH analogues"Journal of the American Chemical Society. 124・49. 14538-14539 (2002)

[文献書誌] Fukuzumi, S. et al.: "Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron-Transfer Step"Journal of the American Chemical Society. 124・47. 14147-14155 (2002)

[文献書誌] Fukuzumi, S. et al.: "A Negative Temperature Dependence of the Electron Self-Exchange Rates of Zinc Porphyrin π Radical Cations"Journal of the American Chemical Society. 124・37. 10974-10975 (2002)

[文献書誌] Fukuzumi, S. et al.: "Fluorescence Maxima of 1O-Methylacridone-Metal Ion Salt Complexes : A Convenient and Quantitative Measure of Lewis Acidity of Metal Ion Salts"Journal of the American Chemical Society. 124・35. 10270-10271 (2002)

[文献書誌] Fukuzumi, S. et al.: "Asymmetric Sulfoxidation and Amine Binding by H64D/V68A and H64D/V68S Mb : Mechanistic Insight into the Chiral Discrimination Step"Journal of the American Chemical Society. 124・29. 8506-8507 (2003)

[文献書誌] Fukuzumi, S. et al.: "Significant Enhancement of Electron Transfer Reduction of NAD+ Analogues by Complexation with Scandium Ion and the Detection of the Radical Intermediate-Scandium Ion complex"Journal of the American Chemical Society. 124・31. 9181-9188 (2002)

[文献書誌] Fukuzumi, S. et al.: "Exciplex intermediates in photoinduced electron transfer of porphyrin-fullerene dyads"Journal of the American Chemical Society. 124・27. 8067-8077 (2002)

[文献書誌] Fukuzumi, S. et al.: "Hydrogen-bonding dynamics in photoinduced electron transfer in a ferrocene-quinone linked dyad with a rigid amide spacer"Journal of the American Chemical Society. 124・24. 6794-6795 (2002)

[文献書誌] Fukuzumi, S. et al.: "Fine-Tuning of Copper(I)-Dioxygen Reactivity by 2-(2-Pyridyl)ethylamine Bidentate Ligands"Journal of the American Chemical Society. 124・22. 6367-6377 (2002)

[文献書誌] Fukuzumi, S. et al.: "Stepwise charge separation and charge recombination in ferrocene-meso, meso-linked porphyrin dimer-fullerene triad"Journal of the American Chemical Society. 124・18. 5165-5174 (2002)

[文献書誌] Fukuzumi, S. et al.: "Oxo-Transfer Reaction from a Bis(μ-oxo) dicopper(III) Complex to Sulfides"Journal of the American Chemical Society. 124・6. 998-1002 (2002)

[文献書誌] Fukuzumi, S. et al.: "Large Photocurrent Generation of Gold Electrodes Modified with [60] Fullerene-Linked Oligothiophenes Bearing a Tripodal Rigid Anchor"Journal of the American Chemical Society. 124・4. 532-533 (2002)

[文献書誌] Fukuzumi, S. et al.: "Comparison of reorganization energies for intra-and intermolecular electron transfer"Angewandte Chemie, International Edition. 41・13. 2344-2347 (2002)

[文献書誌] Fukuzumi, S. et al.: "Thermal intramolecular electron transfer in a ferrocene-naphthoquinone linked dyad promoted by metal ions"Angewandte Chemie, International Edition. 41・4. 620-622 (2002)

[文献書誌] Fukuzumi, S. et al.: "Mechanisms of Electron Transfer Oxidation of NADH Analogs and the Chemiluminescence. Detection of the Keto and Enol Radical Cations"Journal of the American Chemical Society. 125(in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation"Chemical Communications (Cambridge, United Kingdom). 17. 1984-1985 (2002)

[文献書誌] Fukuzumi, S. et al.: "Evidence that gold(III) porphyrins are not electrochemically inert : facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl) porphyrin"Chemical Communications (Cambridge, United Kingdom). 4. 356-357 (2002)

[文献書誌] Fukuzumi, S. et al.: "Driving Force Dependence of Intermolecular Electron Transfer Reactions of Fullerenes"Chemistry A European Journal. 9(in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "Formation of a Supramolecular Porphyrin-Spacer-Acceptor Ternary Complex and Intracomplex Electron Transfer"Journal of Physical Chemistry A. 107・3. 379-385 (2003)

[文献書誌] Fukuzumi, S. et al.: "Small Reorganization Energy of Intramolecular Electron Transfer in Fullerene-Based Dyads with Short Linkage"Journal of Physical Chemistry A. 106・46. 10991-10998 (2002)

[文献書誌] Fukuzumi, S. et al.: "Effects of Metal Ions Distinguishing between One-Step Hydrogen-and Electron-Transfer Mechanisms for the Radical-Scavenging Reaction of (+)-Catechin"Journal of Physical Chemistry A. 106・46. 11123-11126 (2002)

[文献書誌] Fukuzumi, S. et al.: "Photophysical and Electrochemical Properties of New Bacteriochlorins and Characterization of Radical Cation and Radical Anion Species"Journal of Physical Chemistry A. 106・20. 5105-5113 (2002)

[文献書誌] Fukuzumi, S. et al.: "Linkage dependent charge separation and charge recombination in porphyrin-pyromellitimide-fullerene triads"Journal of Physical Chemistry A. 106・12. 2803-2814 (2002)

[文献書誌] Fukuzumi, S. et al.: "Electron transfer properties of singlet oxygen and promoting effects of scandium ion"Journal of Physical Chemistry A. 106・7. 1241-1247 (2002)

[文献書誌] Fukuzumi, S. et al.: "Dehydrogenation vs. Oxygenation in Rhotosensitized Oxidation of 9-Substituted 1O-Methyl-9,10-dihydroacridine in the Presence of Scandium Ion"Journal of Physical Chemistry A. 106・7. 1465-1472 (2002)

[文献書誌] Fukuzumi, S. et al.: "Uphill photooxidation of NADH analogues by hexyl viologen catalyzed by zinc porphyrin-linked fullerenes"Journal of Physical Chemistry A. 106・10. 1903-1908 (2002)

[文献書誌] Fukuzumi, S. et al.: "DNA Cleavage via Superoxide Anion Formed in Photoinduced Electron Transfer from NADH to γ-Cyclodextrin-Bicapped C_<60> in an Oxygen-Saturated Aqueous Solution"Journal of Physical Chemistry B. 106・9. 2372-2380 (2002)

[文献書誌] Ogo, S.et al.: "Structural and Spectroscopic Features of a cis (Hydroxo)-Fe^<III>-(Carboxylato) Configuration as an Active Site Model for Lipoxygenases"Inorganic Chemistry. 41・21. 5513-5520 (2002)

[文献書誌] Fukuzumi, S. et al.: "Enhancement of photocurrent generation by ITO electrodes modified chemically with self-assembled monolayers of porphyrin-fullerene dyads"Advanced Materials (Weinheim, Germany). 14・12. 892-895 (2002)

[文献書誌] Fukuzumi, S. et al.: "A key role for old yellow enzyme in the metabolism of drugs by Trypanosoma cruzi"Journal of Experimental Medicine. 196・9. 1241-1251 (2002)

[文献書誌] Fukuzumi, S. et al.: "A Planar Catechin Analogue as a Promising Antioxidant with Reduced Prooxidant Activity"Chemical Research in Toxicology. 16・1. 81-86 (2003)

[文献書誌] Fukuzumi, S. et al.: "Acceleration and deceleration of photoinduced electron transfer rates by an electric field in porphyrin-fullerene dyads"Chemical Physics Letters. 368・1, 2. 230-235 (2002)

[文献書誌] Fukuzumi, S. et al.: "Porphyrin-fullerene dyad with a long linker : formation of charge transfer conformer in Langmuir-Blodgett film"Chemical Physics Letters. 366・3, 4. 245-252 (2002)

[文献書誌] Fukuzumi, S. et al.: "Dioxygen activation by copper complexes. Mechanistic insights into copper monooxygenases and copper oxidases"Bulletin of the Chemical Society of Japan. 75・10. 2081-2095 (2002)

[文献書誌] Fukuzumi, S. et al.: "Formation of superoxide-metal ion complexes and the electron transfer catalysis"Coordination Chemistry Reviews. 226・1-2. 71-80 (2002)

[文献書誌] Fukuzumi, S. et al.: "Direct detection of superoxide anion generated in C_<60>-photosensitized oxidation of NADH and an analogue by molecular oxygen"Journal of the Chemical Society, Perkin Transactions 2. 11. 1829-1833 (2002)

[文献書誌] Fukuzumi, S. et al.: "Catalysis in electron transfer reactions : Facts and mechanistic insights"Journal of Physical Organic Chemistry. 15・8. 448-460 (2002)

[文献書誌] Fukuzumi, S. et al.: "Photocurrent generation using gold electrodes modified with self-assembled monolayers of a fullerene-porphyrin dyad"Journal of Materials Chemistry. 12・7. 2034-2040 (2002)

[文献書誌] Fukuzumi, S. et al.: "Enhancement of Light-Harvesting and Photocurrent Generation by ITO Electrodes Modified with meso, meso-Linked Porphyrin Oligomers"Nano Letters. 3(in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "Electron transfer reduction of a highly electron-deficient fullerene, C_<60>F_<18>"Chemical Communications (Cambridge, United Kingdom). 17. 1952-1953 (2002)

[文献書誌] Fukuzumi, S. et al.: "Electron transfer in electron donor-acceptor ensembles containing porphyrins and metalloporphyrins"Journal of Porphyrins and Phthalocyanines. 6・4. 289-295 (2002)

[文献書誌] Fukuzumi, S. et al.: "Electron Transfer Mechanism in Radical-Scavenging Reactions of Flavonoids"Free Radical Biol. Med.. 33. S308-S309 (2002)

[文献書誌] Fukuzumi, S. et al.: "Conducting molecular materials and electrochemistry. 1. Photoelectron transfer at electrodes modified with fullerene derivatives"Electrochemistry (Tokyo, Japan). 70・4. 274-278 (2002)

[文献書誌] Fukuzumi, S. et al.: "Clean energy from inexhaustible solar light"Gendai Kagaku. 375. 46-50 (2002)

[文献書誌] Fukuzumi, S. et al.: "Nanoscale artificial photosynthesis system using porphyrins and fullerenes"Kagaku Furontia (Bunshi Nanotekunoroji). 6. 115-125 (2003)

[文献書誌] Fukuzumi, S. et al.: "Catalytic Control of Electron Transfer Processes"Pure Appl. Chem.. (in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "C_<70> vs. C_<60> in zinc porphyrin-fullerene dyads : prolonged charge separation and ultrafast energy transfer from the second excited singlet state of porphyrin"Photochemical & Photobiological Sciences. (in press). (2003)

[文献書誌] Fukuzumi, S.: "New Perspective of Electron Transfer Chemistry"Organic & Biomolecular Chemistry. (in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "Electron Transfer Properties of Bisphenol Derivatives in Relation with the Developing Properties in Silver Salt Photothermographic Systems"J. Imag. Sci. Tech.. 47(in press). (2003)

[文献書誌] Shunichi Fukuzumi et al.: "Fullerenes 2002--Volume 12. (Proceedings of the 201^<st> Meeting of the Electrochemical Society)"The Electrochemical Society, INC. 37 (2002)

[文献書誌] Fukuzumi, S.et al.: "生産と技術"生産技術振興協会. 3 (2002)

[文献書誌] Fukuzumi, S.et al.: "先端ウオッチングシリーズ「錯体化学」"日本化学会. 6 (2002)

2002 年度実績報告書

福住俊一大阪大学, 大学院・工学研究科, 教授 (40144430)