2001 年度実績報告書

二酸化炭素を用いる新しい有機反応と新規高分子合成

研究課題

研究課題/領域番号	13450376
研究機関	山形大学
研究代表者	遠藤剛山形大学, 工学部, 教授 (40016738)
研究分担者	羽場修山形大学, 工学部, 助教授 (70261328)
キーワード	二酸化炭素 / 第3級アミン / 環境保護 / 有機合成化学 / 高分子合成 / 固定化反応
研究概要	二酸化炭素の化学的な回収、利用は環境、資源問題につながる重要な分野である。これまで二酸化炭素と第三級アミンとの直接的な反応は知られていなかったが、我々は各種の第三級アミンとの反応により、二酸化炭素と直接反応する第三級アミンであるN,N.N'-トリアルキルアミジンを新しく見出し、その基礎的データの収集(IR spectrum,elemental analysis)により双性イオンが生成することを明らかにした。この双性イオンは第一級および第二級アミンとの反応では得られない化合物であり、従来の第ー級、第二級アミンのカルバミン酸塩生成による二酸化炭素のトラップよりも、脱着が容易に効果的に行える。特に二酸化炭素の脱離の際、65℃という少ない熱量で行える(カルバミン酸塩の場合100℃>)。さらに二酸化炭素の脱着で大きく物性が変化するため高分子に応用することにより効果的な二酸化炭素トラップ剤としてだけでなく、物性を可逆的に変化させ得る液晶材料、光学活性材料としての応用が今後、期待される。またトラップされた二酸化炭素は活性化されており、反応性の低い二酸化炭素を有用な有機化合物へと固定化することも可能であり、現在検討中である。これまでの二酸化炭素のトラップおよび合成反応はいかにトラップおよび合成反応に適用するかに留まり、個別の技術を部分的に評価している。そのため、反応自体は効率よいが、その原料合成に多大な労力を要するものなどが多い。その点、我々の研究は、簡単で安価な有機化合物で容易に二酸化炭素のトラップおよび活性化が行えるトータルな視点から効率の良い二酸化炭素利用法といえる。さらにその応用展開の幅広い可能性からも、工業化に向けて高いポテンシャルを持つ研究といえ、現在さらなる展開を検討中である。

研究成果

(19件)

すべてその他

すべて文献書誌 (19件)

[文献書誌] 富田秀敏: "Polyaddition of Bis(cyclic thiocarbonate)with Diamines. Novel Efficient Synthetic Method of Polyhydroxythiourethanes"Macromolecules. 34巻. 727-733 (2001)
[文献書誌] 小林稔: "Application of (Triphenylphosphinemethylene)boranes to Thermally Latent Catalysts for Polyaddition of Bisphenol A Diglycidyl Ether with Bisphenol A:Model System of Epoxy-Novolac Resin"Macromolecules. 34巻. 1134-1136 (2001)
[文献書誌] 舎人達也: "Cationic Polymerization of Epoxide by Fluorenylphosphonium Salts as Thermally Latent Initiators. Substituent Effect on the Initiator Activity"Macromolecules. 34巻. 1518-1521 (2001)
[文献書誌] 三田文雄: "Synthesis and Anionic Ring-Opening Polymerization Behavior of Amino Acid-Derived Cyclic Carbonates"Macromolecules. 34巻. 1564-1569 (2001)
[文献書誌] 根本修克: "Cationic Ring-opening Polymerization of Six-Membered Cyclic Carbonates with Ester Groups"Journal of Polymer Science PartA:Polymer Chemistry. 39巻. 1305-1317 (2001)
[文献書誌] 山本進一: "Spontaneous Alternating Copolymerization of Isobutoxyallene with 4-Phenyl-1,2,4-triazoline-3,5-dione"Journal of Polymer Science PartA:Polymer Chemistry. 39巻. 1564-1571 (2001)
[文献書誌] 宮川豊治: "A Novel Route to Poly(a-hydroxyacrylic acid)Derivatives by the Hydrolysis of Polymers Containing 1,3-Dioxolan-4-one Moiety"Journal of Polymer Science PartA:Polymer Chemistry. 39巻. 1629-1633 (2001)
[文献書誌] 福地巌: "Synthesis and Cationic Polymerization of 2-Phenyl-1,6-dioxaspiro[4,6]undecane.A Novel Expandable Monomer Undergoing Cationic Double Ring-Opening Polymerization"Macromolecules. 34巻. 4296-4298 (2001)
[文献書誌] 工藤宏人: "Synthesis and Self-Polyaddition of Optically Active Monomers Derived from Tyrosine"Macromolecules. 34巻. 5355-5357 (2001)
[文献書誌] 三田文雄: "Synthesis and Cationic Polymerization of Bicyclo Orthoester-Based Poly(ε-caprolactone)Macromonomer and Depolymerization of the Obtained Graft Copolymer"Macromolecules. 34巻. 5364-5366 (2001)
[文献書誌] 富田秀敏: "Self-Polyaddition of Six-Membered Cyclic Carbonate Having Fmoc-Protected Amino Group:Novel Synthetic Method of Polyhydroxyurethane"Macromolecules. 34巻. 7601-7607 (2001)
[文献書誌] 根本修克: "Cationic Ring-Opening Polymerization of Cyclic Monothiocarbonates:Varying the Polymer Main Chain by Neighboring Group Participation"Macromolecules. 34巻. 7642-7647 (2001)
[文献書誌] 宮川豊治: "Radical Copolymerization Behavior of 2,2-Dimethyl-5-methylene-1,3-dioxolan-4-one with Common Monomers"Macromolecular Chemistry and Physics. 202巻. 1602-1605 (2001)
[文献書誌] 亀島久光: "Synthesis and Properties of Fluorene-Based Fluorinated Polymers"Journal of Polymer Science PartA:Polymer Chemistry. 39巻. 3143-3150 (2001)
[文献書誌] 工藤宏人: "Efficient Synthesis of Macrocycles by Oxidation of Cysteine-Based Dithiols"Tetrahedron Letters. 42巻. 7847-7850 (2001)
[文献書誌] 小林稔: "Substituent Effect of(Triphenylphosphinemethylene)boranes on Latent Catalytic Activity for Polyaddition of Bisphenol A Diglycidyl Ether with Bisphenol A:Model System of Epoxy-Novolac Resin"Macromolecules. 35巻. 346-348 (2002)
[文献書誌] 三田文雄: "Star Polymer Synthesis from ε-Caprolactone Utilizing Polyol/Protonic Acid Initiator"Macromolecules. 35巻. 680-683 (2002)
[文献書誌] 柿本圭一郎: "Substituent Effect of(Triphenylphosphinemethylene)boranes on Latent Catalytic Activity for Polyaddition of Bisphenol A Diglycidyl Ether with Bisphenol A:Model System of Epoxy-Novolac Resin"Chemistry Letters. 2号. 156-157 (2002)
[文献書誌] 遠藤剛: "高分子合成化学"(株)化学同人. 153 (2001)

2001 年度 実績報告書

二酸化炭素を用いる新しい有機反応と新規高分子合成

研究代表者

遠藤 剛 山形大学, 工学部, 教授 (40016738)

研究成果

[文献書誌] 富田秀敏: "Polyaddition of Bis(cyclic thiocarbonate)with Diamines. Novel Efficient Synthetic Method of Polyhydroxythiourethanes"Macromolecules. 34巻. 727-733 (2001)

[文献書誌] 小林 稔: "Application of (Triphenylphosphinemethylene)boranes to Thermally Latent Catalysts for Polyaddition of Bisphenol A Diglycidyl Ether with Bisphenol A:Model System of Epoxy-Novolac Resin"Macromolecules. 34巻. 1134-1136 (2001)

[文献書誌] 舎人達也: "Cationic Polymerization of Epoxide by Fluorenylphosphonium Salts as Thermally Latent Initiators. Substituent Effect on the Initiator Activity"Macromolecules. 34巻. 1518-1521 (2001)

[文献書誌] 三田文雄: "Synthesis and Anionic Ring-Opening Polymerization Behavior of Amino Acid-Derived Cyclic Carbonates"Macromolecules. 34巻. 1564-1569 (2001)

[文献書誌] 根本修克: "Cationic Ring-opening Polymerization of Six-Membered Cyclic Carbonates with Ester Groups"Journal of Polymer Science PartA:Polymer Chemistry. 39巻. 1305-1317 (2001)

[文献書誌] 山本進一: "Spontaneous Alternating Copolymerization of Isobutoxyallene with 4-Phenyl-1,2,4-triazoline-3,5-dione"Journal of Polymer Science PartA:Polymer Chemistry. 39巻. 1564-1571 (2001)

[文献書誌] 宮川豊治: "A Novel Route to Poly(a-hydroxyacrylic acid)Derivatives by the Hydrolysis of Polymers Containing 1,3-Dioxolan-4-one Moiety"Journal of Polymer Science PartA:Polymer Chemistry. 39巻. 1629-1633 (2001)

[文献書誌] 福地 巌: "Synthesis and Cationic Polymerization of 2-Phenyl-1,6-dioxaspiro[4,6]undecane.A Novel Expandable Monomer Undergoing Cationic Double Ring-Opening Polymerization"Macromolecules. 34巻. 4296-4298 (2001)

[文献書誌] 工藤宏人: "Synthesis and Self-Polyaddition of Optically Active Monomers Derived from Tyrosine"Macromolecules. 34巻. 5355-5357 (2001)

[文献書誌] 三田文雄: "Synthesis and Cationic Polymerization of Bicyclo Orthoester-Based Poly(ε-caprolactone)Macromonomer and Depolymerization of the Obtained Graft Copolymer"Macromolecules. 34巻. 5364-5366 (2001)

[文献書誌] 富田秀敏: "Self-Polyaddition of Six-Membered Cyclic Carbonate Having Fmoc-Protected Amino Group:Novel Synthetic Method of Polyhydroxyurethane"Macromolecules. 34巻. 7601-7607 (2001)

[文献書誌] 根本修克: "Cationic Ring-Opening Polymerization of Cyclic Monothiocarbonates:Varying the Polymer Main Chain by Neighboring Group Participation"Macromolecules. 34巻. 7642-7647 (2001)

[文献書誌] 宮川豊治: "Radical Copolymerization Behavior of 2,2-Dimethyl-5-methylene-1,3-dioxolan-4-one with Common Monomers"Macromolecular Chemistry and Physics. 202巻. 1602-1605 (2001)

[文献書誌] 亀島久光: "Synthesis and Properties of Fluorene-Based Fluorinated Polymers"Journal of Polymer Science PartA:Polymer Chemistry. 39巻. 3143-3150 (2001)

[文献書誌] 工藤宏人: "Efficient Synthesis of Macrocycles by Oxidation of Cysteine-Based Dithiols"Tetrahedron Letters. 42巻. 7847-7850 (2001)

[文献書誌] 小林 稔: "Substituent Effect of(Triphenylphosphinemethylene)boranes on Latent Catalytic Activity for Polyaddition of Bisphenol A Diglycidyl Ether with Bisphenol A:Model System of Epoxy-Novolac Resin"Macromolecules. 35巻. 346-348 (2002)

[文献書誌] 三田文雄: "Star Polymer Synthesis from ε-Caprolactone Utilizing Polyol/Protonic Acid Initiator"Macromolecules. 35巻. 680-683 (2002)

[文献書誌] 柿本圭一郎: "Substituent Effect of(Triphenylphosphinemethylene)boranes on Latent Catalytic Activity for Polyaddition of Bisphenol A Diglycidyl Ether with Bisphenol A:Model System of Epoxy-Novolac Resin"Chemistry Letters. 2号. 156-157 (2002)

[文献書誌] 遠藤 剛: "高分子合成化学"(株)化学同人. 153 (2001)

2001 年度実績報告書

遠藤剛山形大学, 工学部, 教授 (40016738)

[文献書誌] 小林稔: "Application of (Triphenylphosphinemethylene)boranes to Thermally Latent Catalysts for Polyaddition of Bisphenol A Diglycidyl Ether with Bisphenol A:Model System of Epoxy-Novolac Resin"Macromolecules. 34巻. 1134-1136 (2001)

[文献書誌] 福地巌: "Synthesis and Cationic Polymerization of 2-Phenyl-1,6-dioxaspiro[4,6]undecane.A Novel Expandable Monomer Undergoing Cationic Double Ring-Opening Polymerization"Macromolecules. 34巻. 4296-4298 (2001)

[文献書誌] 小林稔: "Substituent Effect of(Triphenylphosphinemethylene)boranes on Latent Catalytic Activity for Polyaddition of Bisphenol A Diglycidyl Ether with Bisphenol A:Model System of Epoxy-Novolac Resin"Macromolecules. 35巻. 346-348 (2002)

[文献書誌] 遠藤剛: "高分子合成化学"(株)化学同人. 153 (2001)