2002 年度実績報告書

アルキル置換芳香族の100%選択的部分酸素化反応の開発

研究課題

研究課題/領域番号	13555247
研究機関	大阪大学
研究代表者	福住俊一大阪大学, 大学院・工学研究科, 教授 (40144430)
研究分担者	末延知義大阪大学, 大学院・工学研究科, 助手 (90271030) 小江誠司大阪大学, 大学院・工学研究科, 助教授 (60290904)
キーワード	芳香族アルデヒド / 部分酸素化 / 光触媒 / 電子移動 / アクリジニウムイオン / アルキルベンゼン / 酸素 / α-メチルスチレン
研究概要	アルキル置換芳香族を対応する芳香族アルデヒドに選択的に部分酸素化させる反応は、医薬品、染料、殺虫剤、香料などの種々の薬品の製造中間体として有用な芳香族アルデヒドを製造する上で、工業化学的に非常に重要な反応である。従来、アルキルベンゼンの部分酸素化には無機酸化剤が用いられて来たが、これらの酸化剤を用いてアルキルベンゼンの酸素化を行った場合には、生成する芳香族アルデヒドの収率が低く、選択性が悪いという欠点がある。また、化学量論量の無機酸化剤が必要となるため、環境汚染が深刻な問題となる。従って、酸化剤として酸素を用いる芳香族アルデヒドの触媒的製造法の開発が待ち望まれている。酸素分子は基底状態が三重項であるため、一重項分子と直接反応して一重項の生成物を与えることはできない。酸素分子は二重項であるラジカル種とは反応できるが、ラジカル反応は一般的には制御が困難であり、選択的な基質酸化が不可能である場合が多い。本研究では、適当な光増感剤(10-メチルアクリジニウムイオン)を光触媒として用い、光誘起電子移動反応を利用することにより、分子状酸素によるα-メチルスチレンおよびアルキルベンゼン類の選択的酸素化反応が可能になることを見出した。光電子移動を利用して基質の酸素化を行なうことで、基質の種類と反応性に応じた適切な酸化力を有する光増感剤を選択して反応設計が可能となり、基質の選択的酸素化反応が可能になることがわかった。

研究成果

(56件)

すべてその他

すべて文献書誌 (56件)

[文献書誌] Fukuzumi, S. et al.: "Effects of Hydrogen Bonding on Metal Ion-Promoted Intramolecular Electron Transfer and Photoinduced Electron Transfer in a Ferrocene-Quinone Dyad with a Rigid Amide Spacer"Journal of the American Chemical Society. 125・4. 1007-1013 (2003)
[文献書誌] Ogo, S.et al.: "Isolation and Crystal Structure of Water-Soluble Iridium Hydride. Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media"Journal of the American Chemical Society. 125(in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "Scandium Ion-Promoted Reduction of Heterocyclic N : N Double Bond. Hydride Transfer vs Electron Transfer"Journal of the American Chemical Society. 124・42. 12566-12573 (2002)
[文献書誌] Fukuzumi, S. et al.: "Direct detection of radical cations of NADH analogues"Journal of the American Chemical Society. 124・49. 14538-14539 (2002)
[文献書誌] Fukuzumi, S. et al.: "Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron-Transfer Step"Journal of the American Chemical Society. 124・47. 14147-14155 (2002)
[文献書誌] Fukuzumi, S. et al.: "A Negative Temperature Dependence of the Electron Self-Exchange Rates of Zinc Porphyrin π Radical Cations"Journal of the American Chemical Society. 124・37. 10974-10975 (2002)
[文献書誌] Fukuzumi, S. et al.: "Fluorescence Maxima of 10-Methylacridone-Metal Ion Salt Complexes : A Convenient and Quantitative Measure of Lewis Acidity of Metal Ion Salts"Journal of the American Chemical Society. 124・35. 10270-10271 (2002)
[文献書誌] Fukuzumi, S. et al.: "Asymmetric Sulfoxidation and Amine Binding by H64D/V68A and H64D/V68S Mb : Mechanistic Insight into the Chiral Discrimination Step"Journal of the American Chemical Society. 124・29. 8506-8507 (2003)
[文献書誌] Fukuzumi, S. et al.: "Significant Enhancement of Electron Transfer Reduction of NAD+ Analogues by Complexation with Scandium Ion and the Detection of the Radical Intermediate-Scandium Ion Complex"Journal of the American Chemical Society. 124・31. 9181-9188 (2002)
[文献書誌] Fukuzumi, S. et al.: "Exciplex intermediates in photoinduced electron transfer of porphyrin-fullerene dyads"Journal of the American Chemical Society. 124・27. 8067-8077 (2002)
[文献書誌] Fukuzumi, S. et al.: "Hydrogen-bonding dynamics in photoinduced electron transfer in a ferrocene-quinone linked dyad with a rigid amide spacer"Journal of the American Chemical Society. 124・24. 6794-6795 (2002)
[文献書誌] Fukuzumi, S. et al.: "Fine-Tuning of Copper(I)-Dioxygen Reactivity by 2-(2-Pyridyl)ethylamine Bidentate Ligands"Journal of the American Chemical Society. 124・22. 6367-6377 (2002)
[文献書誌] Fukuzumi, S. et al.: "Stepwise charge separation and charge recombination in ferrocene-meso, meso-linked porphyrin dimer-fullerene triad"Journal of the American Chemical Society. 124・18. 5165-5174 (2002)
[文献書誌] Fukuzumi, S. et al.: "Oxo-Transfer Reaction from a Bis(μ-oxo)dicopper(III) Complex to Sulfides"Journal of the American Chemical Society. 124・6. 998-1002 (2002)
[文献書誌] Fukuzumi, S. et al.: "Large Photocurrent Generation of Gold Electrodes Modified with [60]Fullerene-Linked Oligothiophenes Bearing a Tripodal Rigid Anchor"Journal of the American Chemical Society. 124・4. 532-533 (2002)
[文献書誌] Fukuzumi, S. et al.: "Comparison of reorganization energies for intra-and intermolecular electron transfer"Angewandte Chemie, International Edition. 41・13. 2344-2347 (2002)
[文献書誌] Fukuzumi, S. et al.: "Thermal intramolecular electron transfer in a ferrocene-naphthoquinone linked dyad promoted by metal ions"Angewandte Chemie, International Edition. 41・4. 620-622 (2002)
[文献書誌] Fukuzumi, S. et al.: "Mechanisms of Electron Transfer Oxidation of NADH Analogs and the Chemiluminescence. Detection of the Keto and Enol Radical Cations"Journal of the American Chemical Society. 125(in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation"Chemical Communications (Cambridge, United Kingdom). 17. 1984-1985 (2002)
[文献書誌] Fukuzumi, S. et al.: "Evidence that gold(III) porphyrins are not electrochemically inert : facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl) porphyrin"Chemical Communications (Cambridge, United Kingdom). 4. 356-357 (2002)
[文献書誌] Fukuzumi, S. et al.: "Driving Force Dependence of Intermolecular Electron Transfer Reactions of Fullerenes"Chemistry A European Journal. 9(in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "Formation of a Supramolecular Porphyrin-Spacer-Acceptor Ternary Complex and Intracomplex Electron Transfer"Journal of Physical Chemistry A. 107・3. 379-385 (2003)
[文献書誌] Fukuzumi, S. et al.: "Small Reorganization Energy of Intramolecular Electron Transfer in Fullerene-Based Dyads with Short Linkage"Journal of Physical Chemistry A. 106・46. 10991-10998 (2002)
[文献書誌] Fukuzumi, S. et al.: "Effects of Metal Ions Distinguishing between One-Step Hydrogen-and Electron-Transfer Mechanisms for the Radical-Scavenging Reaction of (+)-Catechin"Journal of Physical Chemistry A. 106・46. 11123-11126 (2002)
[文献書誌] Fukuzumi, S. et al.: "Photophysical and Electrochemical Properties of New Bacteriochlorins and Characterization of Radical Cation and Radical Anion Species"Journal of Physical Chemistry A. 106・20. 5105-5113 (2002)
[文献書誌] Fukuzumi, S. et al.: "Linkage dependent charge separation and charge recombination in porphyrin-pyromellitimide-fullerene triads"Journal of Physical Chemistry A. 106・12. 2803-2814 (2002)
[文献書誌] Fukuzumi, S. et al.: "Electron transfer properties of singlet oxygen and promoting effects of scandium ion"Journal of Physical Chemistry A. 106・7. 1241-1247 (2002)
[文献書誌] Fukuzumi, S. et al.: "Dehydrogenation vs. Oxygenation in Photosensitized Oxidation of 9-Substituted 10-Methyl-9,10-dihydroacridine in the Presence of Scandium Ion"Journal of Physical Chemistry A. 106・7. 1465-1472 (2002)
[文献書誌] Fukuzumi, S. et al.: "Uphill photooxidation of NADH analogues by hexyl viologen catalyzed by zinc porphyrin-linked fullerenes"Journal of Physical Chemistry A. 106・10. 1903-1908 (2002)
[文献書誌] Fukuzumi, S. et al.: "DNA Cleavage via Superoxide Anion Formed in Photoinduced Electron Transfer from NADH to γ-Cyclodextrin-Bicapped C_<60> in an Oxygen-Saturated Aqueous Solution"Journal of Physical Chemistry B. 106・9. 2372-2380 (2002)
[文献書誌] Ogo, S.et al.: "Structural and Spectroscopic Features of a cis (Hydroxo)-Fe^<III>-(Carboxylato) Configuration as an Active Site Model for Lipoxygenases"Inorganic Chemistry. 41・21. 5513-5520 (2002)
[文献書誌] Fukuzumi, S. et al.: "Enhancement of photocurrent generation by ITO electrodes modified chemically with self-assembled monolayers of porphyrin-fullerene dyads"Advanced Materials (Weinheim, Germany). 14・12. 892-895 (2002)
[文献書誌] Fukuzumi, S. et al.: "A key role for old yellow enzyme in the metabolism of drugs by Trypanosoma cruzi"Journal of Experimental Medicine. 196・9. 1241-1251 (2002)
[文献書誌] Fukuzumi, S. et al.: "A Planar Catechin Analogue as a Promising Antioxidant with Reduced Prooxidant Activity"Chemical Research in Toxicology. 16・1. 81-86 (2003)
[文献書誌] Fukuzumi, S. et al.: "Acceleration and deceleration of photoinduced electron transfer rates by an electric field in porphyrin-fullerene dyads"Chemical Physics Letters. 368・1,2. 230-235 (2002)
[文献書誌] Fukuzumi, S. et al.: "Porphyrin-fullerene dyad with a long linker : formation of charge transfer conformer in Langmuir-Blodgett film"Chemical Physics Letters. 366・3,4. 245-252 (2002)
[文献書誌] Fukuzumi, S. et al.: "Dioxygen activation by copper complexes. Mechanistic insights into copper monooxygenases and copper oxidases"Bulletin of the Chemical Society of Japan. 75・10. 2081-2095 (2002)
[文献書誌] Fukuzumi, S. et al.: "Formation of superoxide-metal ion complexes and the electron transfer catalysis"Coordination Chemistry Reviews. 226・1-2. 71-80 (2002)
[文献書誌] Fukuzumi, S. et al.: "Direct detection of superoxide anion generated in C_<60>-photosensitized oxidation of NADH and an analogue by molecular oxygen"Journal of the Chemical Society, Perkin Transactions 2. 11. 1829-1833 (2002)
[文献書誌] Fukuzumi, S. et al.: "Effects of magnesium ion on kinetic stability and spin distribution of phenoxyl radical derived from a vitamin E analogue : mechanistic insight into antioxidative hydrogen-transfer reaction of vitamin E"Journal of the Chemical Society, Perkin Transactions 2. 9. 1520-1524 (2002)
[文献書誌] Fukuzumi, S. et al.: "Catalysis in electron transfer reactions : Facts and mechanistic insights"Journal of Physical Organic Chemistry. 15・8. 448-460 (2002)
[文献書誌] Fukuzumi, S. et al.: "Photocurrent generation using gold electrodes modified with self-assembled monolayers of a fullerene-porphyrin dyad"Journal of Materials Chemistry. 12・7. 2034-2040 (2002)
[文献書誌] Fukuzumi, S. et al.: "Enhancement of Light-Harvesting and Photocurrent Generation by ITO Electrodes Modified with meso, meso-Linked Porphyrin Oligomers"Nano Letters. 3(in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "Electron transfer reduction of a highly electron-deficient fullerene, C_<60>F_<18>"Chemical Communications (Cambridge, United Kingdom). 17. 1952-1953 (2002)
[文献書誌] Fukuzumi, S. et al.: "Electron transfer in electron donor-acceptor ensembles containing porphyrins and metalloporphyrins"Journal of Porphyrins and Phthalocyanines. 6・4. 289-295 (2002)
[文献書誌] Fukuzumi, S. et al.: "Electron-Transfer Mechanism in Radical-Scavenging Reactions of Flavonoids"Free Radical Biol. Med.. 33. S308-S309 (2002)
[文献書誌] Fukuzumi, S. et al.: "Conducting molecular materials and electrochemistry. 1. Photoelectron transfer at electrodes modified with fullerene derivatives"Electrochemistry (Tokyo, Japan). 70・4. 274-278 (2002)
[文献書誌] Fukuzumi, S. et al.: "Clean energy from inexhaustible solar light"Gendai Kagaku. 375. 46-50 (2002)
[文献書誌] Fukuzumi, S. et al.: "Nanoscale artificial photosynthesis system using porphyrins and fullerenes"Kagaku Furontia (Bunshi Nanotekunoroji). 6. 115-125 (2003)
[文献書誌] Fukuzumi, S. et al.: "Catalytic Control of Electron Transfer Processes"Pure Appl. Chem.. (in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "C_<70> vs. C_<60> in zinc porphyrin-fullerene dyads : prolonged charge separation and ultrafast energy transfer from the second excited singlet state of porphyrin"Photochemical & Photobiological Sciences. (in press). (2003)
[文献書誌] Fukuzumi, S.: "New Perspective of Electron Transfer Chemistry"Organic & Biomolecular Chemistry. (in press). (2003)
[文献書誌] Fukuzumi, S. et al.: "Electron Transfer Properties of Bisphenol Derivatives in Relation with the Developing Properties in Silver Salt Photothermographic Systems"J. Imag. Sci. Tech.. 47(in press). (2003)
[文献書誌] Shunichi Fukuzumi et al.: "Fullerenes 2002--Volume 12. (Proceedings of the 201^<st> Meeting of the Electrochemical Society)"The Electrochemical Society, INC. 37 (2002)
[文献書誌] Fukuzumi, S. et al.: "生産と技術"生産技術振興協会. 3 (2002)
[文献書誌] Fukuzumi, S. et al.: "先端ウオッチングシリーズ「錯体化学」"日本化学会. 6 (2002)

2002 年度 実績報告書

アルキル置換芳香族の100%選択的部分酸素化反応の開発

研究代表者

福住 俊一 大阪大学, 大学院・工学研究科, 教授 (40144430)

研究成果

[文献書誌] Fukuzumi, S. et al.: "Effects of Hydrogen Bonding on Metal Ion-Promoted Intramolecular Electron Transfer and Photoinduced Electron Transfer in a Ferrocene-Quinone Dyad with a Rigid Amide Spacer"Journal of the American Chemical Society. 125・4. 1007-1013 (2003)

[文献書誌] Ogo, S.et al.: "Isolation and Crystal Structure of Water-Soluble Iridium Hydride. Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media"Journal of the American Chemical Society. 125(in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "Scandium Ion-Promoted Reduction of Heterocyclic N : N Double Bond. Hydride Transfer vs Electron Transfer"Journal of the American Chemical Society. 124・42. 12566-12573 (2002)

[文献書誌] Fukuzumi, S. et al.: "Direct detection of radical cations of NADH analogues"Journal of the American Chemical Society. 124・49. 14538-14539 (2002)

[文献書誌] Fukuzumi, S. et al.: "Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron-Transfer Step"Journal of the American Chemical Society. 124・47. 14147-14155 (2002)

[文献書誌] Fukuzumi, S. et al.: "A Negative Temperature Dependence of the Electron Self-Exchange Rates of Zinc Porphyrin π Radical Cations"Journal of the American Chemical Society. 124・37. 10974-10975 (2002)

[文献書誌] Fukuzumi, S. et al.: "Fluorescence Maxima of 10-Methylacridone-Metal Ion Salt Complexes : A Convenient and Quantitative Measure of Lewis Acidity of Metal Ion Salts"Journal of the American Chemical Society. 124・35. 10270-10271 (2002)

[文献書誌] Fukuzumi, S. et al.: "Asymmetric Sulfoxidation and Amine Binding by H64D/V68A and H64D/V68S Mb : Mechanistic Insight into the Chiral Discrimination Step"Journal of the American Chemical Society. 124・29. 8506-8507 (2003)

[文献書誌] Fukuzumi, S. et al.: "Significant Enhancement of Electron Transfer Reduction of NAD+ Analogues by Complexation with Scandium Ion and the Detection of the Radical Intermediate-Scandium Ion Complex"Journal of the American Chemical Society. 124・31. 9181-9188 (2002)

[文献書誌] Fukuzumi, S. et al.: "Exciplex intermediates in photoinduced electron transfer of porphyrin-fullerene dyads"Journal of the American Chemical Society. 124・27. 8067-8077 (2002)

[文献書誌] Fukuzumi, S. et al.: "Hydrogen-bonding dynamics in photoinduced electron transfer in a ferrocene-quinone linked dyad with a rigid amide spacer"Journal of the American Chemical Society. 124・24. 6794-6795 (2002)

[文献書誌] Fukuzumi, S. et al.: "Fine-Tuning of Copper(I)-Dioxygen Reactivity by 2-(2-Pyridyl)ethylamine Bidentate Ligands"Journal of the American Chemical Society. 124・22. 6367-6377 (2002)

[文献書誌] Fukuzumi, S. et al.: "Stepwise charge separation and charge recombination in ferrocene-meso, meso-linked porphyrin dimer-fullerene triad"Journal of the American Chemical Society. 124・18. 5165-5174 (2002)

[文献書誌] Fukuzumi, S. et al.: "Oxo-Transfer Reaction from a Bis(μ-oxo)dicopper(III) Complex to Sulfides"Journal of the American Chemical Society. 124・6. 998-1002 (2002)

[文献書誌] Fukuzumi, S. et al.: "Large Photocurrent Generation of Gold Electrodes Modified with [60]Fullerene-Linked Oligothiophenes Bearing a Tripodal Rigid Anchor"Journal of the American Chemical Society. 124・4. 532-533 (2002)

[文献書誌] Fukuzumi, S. et al.: "Comparison of reorganization energies for intra-and intermolecular electron transfer"Angewandte Chemie, International Edition. 41・13. 2344-2347 (2002)

[文献書誌] Fukuzumi, S. et al.: "Thermal intramolecular electron transfer in a ferrocene-naphthoquinone linked dyad promoted by metal ions"Angewandte Chemie, International Edition. 41・4. 620-622 (2002)

[文献書誌] Fukuzumi, S. et al.: "Mechanisms of Electron Transfer Oxidation of NADH Analogs and the Chemiluminescence. Detection of the Keto and Enol Radical Cations"Journal of the American Chemical Society. 125(in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation"Chemical Communications (Cambridge, United Kingdom). 17. 1984-1985 (2002)

[文献書誌] Fukuzumi, S. et al.: "Evidence that gold(III) porphyrins are not electrochemically inert : facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl) porphyrin"Chemical Communications (Cambridge, United Kingdom). 4. 356-357 (2002)

[文献書誌] Fukuzumi, S. et al.: "Driving Force Dependence of Intermolecular Electron Transfer Reactions of Fullerenes"Chemistry A European Journal. 9(in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "Formation of a Supramolecular Porphyrin-Spacer-Acceptor Ternary Complex and Intracomplex Electron Transfer"Journal of Physical Chemistry A. 107・3. 379-385 (2003)

[文献書誌] Fukuzumi, S. et al.: "Small Reorganization Energy of Intramolecular Electron Transfer in Fullerene-Based Dyads with Short Linkage"Journal of Physical Chemistry A. 106・46. 10991-10998 (2002)

[文献書誌] Fukuzumi, S. et al.: "Effects of Metal Ions Distinguishing between One-Step Hydrogen-and Electron-Transfer Mechanisms for the Radical-Scavenging Reaction of (+)-Catechin"Journal of Physical Chemistry A. 106・46. 11123-11126 (2002)

[文献書誌] Fukuzumi, S. et al.: "Photophysical and Electrochemical Properties of New Bacteriochlorins and Characterization of Radical Cation and Radical Anion Species"Journal of Physical Chemistry A. 106・20. 5105-5113 (2002)

[文献書誌] Fukuzumi, S. et al.: "Linkage dependent charge separation and charge recombination in porphyrin-pyromellitimide-fullerene triads"Journal of Physical Chemistry A. 106・12. 2803-2814 (2002)

[文献書誌] Fukuzumi, S. et al.: "Electron transfer properties of singlet oxygen and promoting effects of scandium ion"Journal of Physical Chemistry A. 106・7. 1241-1247 (2002)

[文献書誌] Fukuzumi, S. et al.: "Dehydrogenation vs. Oxygenation in Photosensitized Oxidation of 9-Substituted 10-Methyl-9,10-dihydroacridine in the Presence of Scandium Ion"Journal of Physical Chemistry A. 106・7. 1465-1472 (2002)

[文献書誌] Fukuzumi, S. et al.: "Uphill photooxidation of NADH analogues by hexyl viologen catalyzed by zinc porphyrin-linked fullerenes"Journal of Physical Chemistry A. 106・10. 1903-1908 (2002)

[文献書誌] Fukuzumi, S. et al.: "DNA Cleavage via Superoxide Anion Formed in Photoinduced Electron Transfer from NADH to γ-Cyclodextrin-Bicapped C_<60> in an Oxygen-Saturated Aqueous Solution"Journal of Physical Chemistry B. 106・9. 2372-2380 (2002)

[文献書誌] Ogo, S.et al.: "Structural and Spectroscopic Features of a cis (Hydroxo)-Fe^<III>-(Carboxylato) Configuration as an Active Site Model for Lipoxygenases"Inorganic Chemistry. 41・21. 5513-5520 (2002)

[文献書誌] Fukuzumi, S. et al.: "Enhancement of photocurrent generation by ITO electrodes modified chemically with self-assembled monolayers of porphyrin-fullerene dyads"Advanced Materials (Weinheim, Germany). 14・12. 892-895 (2002)

[文献書誌] Fukuzumi, S. et al.: "A key role for old yellow enzyme in the metabolism of drugs by Trypanosoma cruzi"Journal of Experimental Medicine. 196・9. 1241-1251 (2002)

[文献書誌] Fukuzumi, S. et al.: "A Planar Catechin Analogue as a Promising Antioxidant with Reduced Prooxidant Activity"Chemical Research in Toxicology. 16・1. 81-86 (2003)

[文献書誌] Fukuzumi, S. et al.: "Acceleration and deceleration of photoinduced electron transfer rates by an electric field in porphyrin-fullerene dyads"Chemical Physics Letters. 368・1,2. 230-235 (2002)

[文献書誌] Fukuzumi, S. et al.: "Porphyrin-fullerene dyad with a long linker : formation of charge transfer conformer in Langmuir-Blodgett film"Chemical Physics Letters. 366・3,4. 245-252 (2002)

[文献書誌] Fukuzumi, S. et al.: "Dioxygen activation by copper complexes. Mechanistic insights into copper monooxygenases and copper oxidases"Bulletin of the Chemical Society of Japan. 75・10. 2081-2095 (2002)

[文献書誌] Fukuzumi, S. et al.: "Formation of superoxide-metal ion complexes and the electron transfer catalysis"Coordination Chemistry Reviews. 226・1-2. 71-80 (2002)

[文献書誌] Fukuzumi, S. et al.: "Direct detection of superoxide anion generated in C_<60>-photosensitized oxidation of NADH and an analogue by molecular oxygen"Journal of the Chemical Society, Perkin Transactions 2. 11. 1829-1833 (2002)

[文献書誌] Fukuzumi, S. et al.: "Catalysis in electron transfer reactions : Facts and mechanistic insights"Journal of Physical Organic Chemistry. 15・8. 448-460 (2002)

[文献書誌] Fukuzumi, S. et al.: "Photocurrent generation using gold electrodes modified with self-assembled monolayers of a fullerene-porphyrin dyad"Journal of Materials Chemistry. 12・7. 2034-2040 (2002)

[文献書誌] Fukuzumi, S. et al.: "Enhancement of Light-Harvesting and Photocurrent Generation by ITO Electrodes Modified with meso, meso-Linked Porphyrin Oligomers"Nano Letters. 3(in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "Electron transfer reduction of a highly electron-deficient fullerene, C_<60>F_<18>"Chemical Communications (Cambridge, United Kingdom). 17. 1952-1953 (2002)

[文献書誌] Fukuzumi, S. et al.: "Electron transfer in electron donor-acceptor ensembles containing porphyrins and metalloporphyrins"Journal of Porphyrins and Phthalocyanines. 6・4. 289-295 (2002)

[文献書誌] Fukuzumi, S. et al.: "Electron-Transfer Mechanism in Radical-Scavenging Reactions of Flavonoids"Free Radical Biol. Med.. 33. S308-S309 (2002)

[文献書誌] Fukuzumi, S. et al.: "Conducting molecular materials and electrochemistry. 1. Photoelectron transfer at electrodes modified with fullerene derivatives"Electrochemistry (Tokyo, Japan). 70・4. 274-278 (2002)

[文献書誌] Fukuzumi, S. et al.: "Clean energy from inexhaustible solar light"Gendai Kagaku. 375. 46-50 (2002)

[文献書誌] Fukuzumi, S. et al.: "Nanoscale artificial photosynthesis system using porphyrins and fullerenes"Kagaku Furontia (Bunshi Nanotekunoroji). 6. 115-125 (2003)

[文献書誌] Fukuzumi, S. et al.: "Catalytic Control of Electron Transfer Processes"Pure Appl. Chem.. (in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "C_<70> vs. C_<60> in zinc porphyrin-fullerene dyads : prolonged charge separation and ultrafast energy transfer from the second excited singlet state of porphyrin"Photochemical & Photobiological Sciences. (in press). (2003)

[文献書誌] Fukuzumi, S.: "New Perspective of Electron Transfer Chemistry"Organic & Biomolecular Chemistry. (in press). (2003)

[文献書誌] Fukuzumi, S. et al.: "Electron Transfer Properties of Bisphenol Derivatives in Relation with the Developing Properties in Silver Salt Photothermographic Systems"J. Imag. Sci. Tech.. 47(in press). (2003)

[文献書誌] Shunichi Fukuzumi et al.: "Fullerenes 2002--Volume 12. (Proceedings of the 201^<st> Meeting of the Electrochemical Society)"The Electrochemical Society, INC. 37 (2002)

[文献書誌] Fukuzumi, S. et al.: "生産と技術"生産技術振興協会. 3 (2002)

[文献書誌] Fukuzumi, S. et al.: "先端ウオッチングシリーズ「錯体化学」"日本化学会. 6 (2002)

2002 年度実績報告書

福住俊一大阪大学, 大学院・工学研究科, 教授 (40144430)