ミクロ・メソ多孔性結晶内における新反応場の構築

2001 年度 実績報告書

• 研究課題/領域番号: 13895016
• 研究機関: 鳥取大学
• 研究代表者: 丹羽 幹 鳥取大学, 工学部, 教授 (10023334)
• 研究分担者: 山下 弘巳 大阪府立大学, 大学院・工学研究科, 助教授 (40200688) ; 岩本 正和 東京工業大学, 資源化学研究所, 教授 (10108342) ; 寺崎 治 東北大学, 大学院・理学研究科, 助教授 (30004401) ; 松方 正彦 早稲田大学, 理工学部, 教授 (00219411) ; 黒田 一幸 早稲田大学, 理工学部, 教授 (90130872)
• キーワード: ゼオライト / メソポーラス金属酸化物 / ミクロ・メソ規則性多孔体 / 触媒 / 合成 / ノンハロゲンプロセス / 光触媒 / ナノ細線

研究概要

最近のこの分野における研究動向を調査した.
固体酸性質に関して,(1)ゼオライトとメソポーラス物質内の強い固体酸点の発現,(2)メソポーラス物質内の固体酸点の発現,(3)アルカリ処理によるメソ細孔の発生と触媒活性,およびゼオライト種からのメソポーラス物質の合成,(4)固体酸ゼオライトのノンハロゲン化プロセスヘの応用,(5)ミクロおよびマクロ細孔の触媒反応活性におよぽす影響,の以上5件を調査研究した.
新物質の合成に関して,(1)酸性条件におけるメソポーラス物質の合成,(2)あたらしいメソポーラス物質の合成,(3)最近のゼオライト合成における進歩,(4)電子顕微鏡による構造決定,(5)リン酸ジルコニア層状化合物め化学,の以上5件を調査研究した.
有機化学反応への応用に関して,(1)ナノ空間化学の新展開,Asの除去,不整有機反応など,(2)モンモリロナイトとMS4Aの共用による有機反応,(3)金属ナノ細線の生成と触媒活性,(4)メソポーラス物質による重合触媒MAOの精製,の以上4件を調査研究した.
光触媒反応への応用に関して,(1)Taメソポーラス物質の合成と水の光分解,(2)メソポーラス物質塩基サイトの精製とプロペン分解触媒反応,(3)Crメソポーラス物質の光触媒活性,の以上3件を調査研究した.
さらに,ミクロおよびメソポーラス物質における計算機化学の進歩も調査した.
これらを総合して,今後のこの分野の研究遂行における指針とした.なお,まとめた冊子を印刷し,全国の研究者に配布した.

研究成果

• [文献書誌] H.A.Begum, N.Katada, M.Niwa: "Chemical Vapor Deposition of Silica on Silicalite Crystals and Shape Selective Adsorption of Paraffins"Microporous Materials. 46巻. 13-21 (2001)
• [文献書誌] A.Kohara, N.Katada, M.Niwa: "Very strong acid site in HZSM-5 formed during the template removal step, its control structure and catalytic activity"Studies in Surface Science and Catalysis. 135巻. 341-341 (2001)
• [文献書誌] K.Okumura, K.Nishigaki, M.Niwa: "Prominent catalytic activity of Ga-containing MCM-41 in the Friedel-Crafts alkylation"Microporous and Mesoporous Materials. 44-45巻. 509-516 (2001)
• [文献書誌] K.Okumura, M.Hashimoto, T.Mimura, M.Niwa: "Acid properties and catalysis of MCM-22 with different Al concentration"Journal of Catalysis. (印刷中).
• [文献書誌] 片田直伸, 丹羽 幹: "本当のY型ゼオライトの酸性質"ペトロテック. 24巻11号. 927-930 (2001)
• [文献書誌] N.Katada, H.Fujinaga, Y.Nakamura, K.Okumura, K.Nishigaki, M.Niwa: "Catalytic Activity of Mesopotous Silica for Synthesis of Methyl N-Phenyl Carbamate from Dimethyl Carbonate and Aniline"Catalysis Letters. (印刷中).
• [文献書誌] Y.Takahara, J.N.Kondo, T.Takata, D.Lu, K.Domen: "Mesoporous Ta oxide:(1) characterization and photocatalytic activity for overall water decomposition"Chem. Mater.. 13巻4号. 1194-1199 (2001)
• [文献書誌] J.N.Kondo, Y.Takahara, T.Takata, D.Lu, K.Domen: "Mesoporous Ta oxide:(2) improvement of synthetic method and observation of mesostructure formation"Chem. Mater.. 13巻4号. 1200-1206 (2001)
• [文献書誌] B.Lee, J.N.Kondo, D.Lu, K.Domen: "Synthesis and characterization of mesoporous material of single crystal particles"Stud. Surf. Sci. Catal.. 135巻. 07P15 (2001)
• [文献書誌] B.Lee, D.Lu, J.N.Kondo, K.Domen: "Single crystal particles of a mesoporous mixed transition metal oxide with a wormhole structure"Chem. Commun.. 2001巻. 2118-2119 (2001)
• [文献書誌] J.N.Kondo, Y.Takahara, B.Lee, D.Lu, H.Domen: "Synthesis and Property of Mesoporous Tantalum Oxides"Topics in Catal.. (印刷中).
• [文献書誌] B.Lee, T.Yamashita, J.N.Kondo, D.Lu, K.Domen: "Single-crystal particles of mesoporous niobium-tantalum mixed oxide"Chem. Mater.. 14巻2号. 867-875 (2002)
• [文献書誌] J.N.Kondo, T.Yamashita, T.Katou, B.Lee, D.Lu, M.Hara, K.Domen: "Single crystal particles of mesoporous (Nb, Ta)205"Stud. Surf. Sci. Catal.. (印刷中).
• [文献書誌] Y.Takahara, D.Lu, J.N.Kondo, K.Domen: "Synthesis and application for overall water splitting of transition metal-mixed mesoporous Ta oxide"Solid State lonics. (印刷中).
• [文献書誌] S.Yang, J.N.Kondo, K.Domen: "Infrared observation of the stable carbenium ions formed by adsorption of olefins on zeolite Y at low temperatures"Stud. Surf. Sci. Catal.. 135巻. 12P06 (2001)
• [文献書誌] S.Yang, J.N.Kondo, K.Domen: "Simultaneous observation of alkenyl carbenium ions and alkoxy species on HZSM-5 zeolite by adsorption of 1-methylcyclopentene and 1-methylcyclopentanol"J. Phys. Chem. B. 105巻33号. 7878-7881 (2001)
• [文献書誌] S.Yang, J.N.Kondo, K.Domen: "Formation of stable alkenyl carbenium ions on high yield by adsorption of 1-methylcyclopentene on zeolite Y at low temperatures"Chem. Commun.. 2001巻. 2008-2009 (2001)
• [文献書誌] S.Yang, J.N.Kondo, K.Domen: "Formation of alkenyl carbenium ions by adsorption of cyclic precursors on zeolites"Catal. Today. 26/27巻. 1-13 (2002)
• [文献書誌] S.Yang, J.N.Kondo, K Domen: "Adsorption, migration and reactions of hydrocarbons on zeolites observed by IR"Catal. Survey Jpn.. 5巻2号. 139-143 (2002)
• [文献書誌] M.W.Anderson, J.R.Agger, N.Hanif, O.Terasaki, T.Ohsuna: "Crystal growth in framework materials"Solid State Science. 3巻. 809-819 (2001)
• [文献書誌] F Gao, G.Zhu, S.Qui, B.Wei, C.Shao, 0.Terasaki: "The synthesis of offretite single crystals in the system containing pyrocated or F-"Materials Letters. 48巻. 1-7 (2001)
• [文献書誌] K Li, C.Shao, S.Qiu, F.S.Xiao, W Zheng, Z.Liu, 0.Terasaki: "Blue photoluminescence from SiC nanoparticles encapsulated in ZSM-5"Materials Letters. 48巻. 242-246 (2001)
• [文献書誌] G.Zhu, S.Qiu, F.Gao, D.Li, Y.Li, R.Wang, B.Gao, B.Li, Y.Gao, R.Xu, Z.Liu, 0.Terasaki: "Template-assisted self-assembly of macro-micro bifunctional porous materials"J. Materials Chem.. 11巻. 1687-1693 (2001)
• [文献書誌] H.J.Shin, R.Ryoo, Z.Liu, 0.Terasaki: "Template Synthesis of Assymmetrically Mesostructured Platinum Networks"J. Am. Chem. Soc.. 123巻. 1246-1247 (2001)
• [文献書誌] G.Zhu, S.Qiu, 0.Terasaki, Y.Wei: "Polystyrene Bead-Assisted Self-Assembly of Microstruclured Silica Hollow Sheres in Highly Alkaline Media"J. Am. Chem. Soc.. 123巻. 7723-7724 (2001)
• [文献書誌] N.Togashi, Y.Sakamoto, T.Ohsuna, 0.Terasaki: "Arrayed Pbl2 Clusters in the Spaces of Zeolite LTA"Materials Science and Engineering. A312巻. 267-273 (2001)
• [文献書誌] J.M.Thomas, 0.Terasaki, P.L.Gai, W.Zhou, J.Gonzalez-calbet: "Structural Elucidation of Microporous and Mesoporous Catalysts and Molecular Sieve"Account of Chemical Research. 34巻. 583-594 (2001)
• [文献書誌] M.Jaroniec, M.Kruk, H.J.Shin, R.Ryoo, Y.Sakamoto, O.Terasaki: "Comprehensive characterization of highly ordered MCM-41 silicas using nitrogen adsorption, thermogravimetry X-ray diffraction and transmission electron microscopy"Microporous and Mesoporous Materials. 48巻. 127-134 (2001)
• [文献書誌] M.W.Anderson, J.R.Agger, N.Hanif, 0.Terasaki: "Growth models in microporous materials"Microporous and Mesoporous Materials. 48巻. 1-9 (2001)
• [文献書誌] Z.Liu, 0.Terasaki, T.Ohsuna, K.Hiraga.H.J.Shin, R.Ryoo: "HREM study of channel structure of silica mesoporous SBA-15 and structure of Pt-wires produced in the channels"Chem. Phys. Chem.. 2001巻. 229-231 (2001)
• [文献書誌] Z.Liu, T.Ohsuna, 0.Terasaki, M.A.Camblor, MJ Diaz-Cabanas, K.Hiraga: "The First Zeolite with Three-Dimensional Intersecting Straight-Channel System of 12-Membered Rings"J. Am. Chem. Soc.. 123巻. 5370-5371 (2001)
• [文献書誌] S.H.Joo, S.J.Choi, I.Oh, J.Kwak, Z.Liu, 0.Terasaki, R.Ryoo: "Ordered Carbon Nanopipes with Tunable Diameter Exhibiting Extraordinary High Dispersion of Pt Nanoparticles"Nature. 412巻. 169-172 (2001)
• [文献書誌] 0.Terasaki, T.Ohsuna: "Is electron microscope an efficient magnifying glass for micro-and mesoporous materals?"Stud. Surf. Sci. and Cat.. 135巻. 61-71 (2001)
• [文献書誌] R.Ryoo, S.H.Joo, S.Jun.T.Tubakiyama, 0.Terasaki: "Ordered mesoporous carbon molecular sieves by templated synthesis the structural varieties"Stud. Surf. Sci. and Cat.. 135巻. 150-157 (2001)
• [文献書誌] S.Che, Y.Sakamoto, 0.Terasaki, T.Tatsumi: "Control of Crystal Morphology of SBA-1 Mesoporous Silica"Chem. Mater.. 13巻. 2237-2239 (2001)
• [文献書誌] J.R.Matos, L.P.Mercuri.M.Jaroniec, M.Kruk, Y.Sakamoto, 0.Terasaki: "Synthesis and characterization of europium-doped ordered mesoporous silicas"J. Mater. Chem.. 11巻. 2580-2586 (2001)
• [文献書誌] J.Fan, C.Yu, L.Wang, D.Zhao, Y.Sakamoto, 0.Terasaki: "Mesotunnels on the silica wall of ordered SBA-15 to generate three-dimensional large-pore Mesoporous Networks"J. Am. Chem. Soc.. 123巻. 12113-12114 (2001)
• [文献書誌] Y.Tsunoda, M.Shirata, W.Sugimoto, Z.Liu, 0.Terasaki, K.Kuroda, Y.Sugahara: "Preparation of a Protonated Form of a Layered Perovskite Tantalale from an Aurivillius Phase Bi2SrTa2O9 via Acid Treatment and Its HREM Characterization"Inorg. Chem.. 40巻. 5768-5771 (2001)
• [文献書誌] S.Che, Y.Sakamoto, H.Yoshitake, 0.Terasaki, T.Tatsumi: "Synthesis and Characterization of Mo-SBA-1 Cubic Mesoporous Molecular Sieves"J. Phys. Chem. B. 105巻. 10565-10572 (2001)
• [文献書誌] X.Ma, T.Kyotani, Z.Liu, 0.Terasaki, A.Tomita: "Very High Surface Area Microporous Carbon with Three-Dimensional Nano-Array Structure Synthesis and Its Molecular Structure"Chem. Mater.. 50巻. 129-135 (2001)
• [文献書誌] S.Che, S.Kamiya, 0.Terasaki, T.Tatsumi: "The formation of cubic Pm3n Mesostructure by an Epitaxial Phase Transformation from Hexagonal p6mm Mesophase"J. Am. Chem. Soc.. 123巻. 12089-12090 (2001)
• [文献書誌] F.Gao, G.Zhu, X.Li, B.Li, 0.Terasaki, S.Qiu: "Synthesis of a High-Quality Host Material Zeolite MFI Giant Single Crystal from Monocrystalline Silicon Slice"J. Phys. Chem., B. 105巻. 12704-12708 (2001)
• [文献書誌] M.J.Diaz-Cabanas, M.A.Camblor, Z.Liu, T.Ohsuna, 0.Terasaki: "Zeolite syntheses using linear diquats of varying length in fluoride media. The synthesis of ITQ-8, ITQ-1O, ITQ-14 and high silica Nu-87"J. Mater. Chem.. 12巻. 249-257 (2002)
• [文献書誌] M.Kaneda, T.Tsubakiyama, A.Carisson, Y.Sakamoto, T.Ohsuna, 0.Terasaki, S.H.Joo.R.Ryoo: "Structural Study of Mesoporous MCM-48 and Carbon Networks Synthesized in the Spaces of MCM-48 by Electron Crystallography"J. Phys. Chem. B. 106巻. 1256-1266 (2002)
• [文献書誌] 0.Terasaki, Z.Liu, T.Ohsuna, H.J Shin.R.Ryoo: "EM study of novel Pt-nanowires synthesized in the spaces of silica mesoporous materials"Microsc. and Microanal.. 8巻. 35-39 (2002)
• [文献書誌] J.M.Kim, Y.Sakamoto, Y.K.Hwang, Y.U.Kwon, 0.Terasaki, S.E.Park, G.D.Stucky: "Structural Design of Mesoporous Silica by Micelle-Packing Control Using Mixture of Amphiphilic Block Copolymers"J. Phys. Chem. B. 106巻(印刷中). (2002)
• [文献書誌] I.Diaz, 0.Terasaki, D.Zhao, J.Perez-Pariente, J.M.Kim, G.D.Stucky: "Three-Dimensional Cubic Mesoporous Structures of S8A-12 and Related Materials by Electron Crystallography"J. Phys. Chem. B. (印刷中).
• [文献書誌] S.Inagaki, S.Guan, T.Ohsuna.0.Terasaki: "An ordered mesoporous organic-silica hybrid material with a crystal-like wall structure"Nature. (印刷中).
• [文献書誌] K.Ebitani, A.Nishi, Y.Hirano, H.Yoshida.T.Tanaka, T.Mizugaki, K.Kaneda, A.Morikawa: "XAFS study on active Pr sites in zeolite as a photocatalyst for decomposition of nitrous oxide"J. Synchrotron Radiation. 8巻. 481-483 (2001)
• [文献書誌] Y.Kato, K.Shimizu, N.Matsushita, T.Yoshida, H.Yoshida, A.Satsuma, T.Hattori: "Quantification of Aluminium Coordinations in Alumina and Silica-alumina by Al K-edge XANES"Phys. Chem. Chem. Phys.. 3巻. 1925-1929 (2001)
• [文献書誌] A.Satsuma, T.Ebigase, Y.Inaki, H.Yoshida, S.Kobayashi, Md.A.Uddin, Y.Sakata, T.Hattori: "Catalytic Sites of Mesoporous Silica in Degradation of Polyethylene"Stud. Surf. Sci. Catal.. 135巻. 277-277 (2001)
• [文献書誌] G.Martra, H.Yoshida, V.Dellarocca, C.Murata, T.Yoshida, I.Hattori, S.Coluccia, L.Marchese: "Spectroscopic characterisation and photocatalytic properties of Mg2^+-modified MCM-41"Stud. Surf. Sci. Catal.. 140巻. 331-340 (2001)
• [文献書誌] K.Shimizu, T.Kaneko, T.Fujishima, T.Kodama, H.Yoshida, Y.Kitayama: "Selective oxidation of liquid hydrocarbons over photoirradiated TiO2 pillared clays"Chem. Commun.. 2001巻. 2358-2359 (2001)
• [文献書誌] Y.Kato, H.Yoshida, T.Hattori: "Photo-induced non-oxidative coupling of methane over H-zeolite around room temperature"Microporous and Mesoporous Materials. 51巻. 223-231 (2002)
• [文献書誌] S.Sumiya, Y.Oumi, T.Uozumi, T.Sano: "Characterization of AISBA-15 prepared by post-synthesis alumination with trimethylaluminium"J. Mater. Chem.. 11巻. 1111-1115 (2001)
• [文献書誌] T.Sano.T.Niimi, T.Miyazaki, S.Shingo, Y.Oumi, Y.Uozumi: "Effective activation of metallocene catalyst with AIMCM-41 in propylene polymerization"Catat. Lett.. 71巻. 105-110 (2001)
• [文献書誌] Y.Oumi, H.Takagi, S.Sumiya, R.Mizuno, T.Uozumi, T.Sano: "Novel post-synthesis of alumination method for MCM-41 using trimethylaluminum"Microporous Mesoporous Mater.. 44-45巻. 267-274 (2001)
• [文献書誌] T.Sano, H.Hagimoto, S.Sumiya, Y.Naito, Y.Oumi, T.Uozumi, K.Soga: "Application of porous inorganic materials to adsorptive separation of methylalumoxane used as co-catalyst in olefin polymerization"Microporous Mesoporous Mater.. 44-15巻. 557-564 (2001)
• [文献書誌] T.Sano, S.Wakabayashi, Y.Oumi, T.Uozumi: "Synthesis of large mordenite crystals in the presence of aliphatic alcohol"Microporous Mesoporous Mater.. 46巻. 67-74 (2001)
• [文献書誌] T.Sano, T.Niimi, T.Miyazaki, S.Tsubaki, Y.Oumi, T.Uozumi: "Potential use of AIMCM-41 for activation of metallocene catalyst"Stud. Surf. Sci. Catal. 135巻. 271-271 (2001)
• [文献書誌] Y.Oumi, R.Mizuno, K.Azuma, S.Sumiya, S.Nawata, T.Fukushima, T.Uozumi, T.Sano: "Influence of pH of the solution on realumination of BEA zeolite"Stud. Surf. Sci. Catal.. 135巻. 271-271 (2001)
• [文献書誌] P.Kumar, Y.Oumi, T.Sano, K.Yamana: "Characterization and catalytic activities of faujasites synthesized by using coal fly ash"J. Cerm. Soc. Japan. 109巻. 968-973 (2001)
• [文献書誌] P.Kumar, N.K.Mal, Y.Oumi, K.Yamana, T.Sano: "Mesoporous materials prepared using coal fly ash as the silicon and aluminium source"J. Mater. Chem.. 11巻. 3285-3290 (2001)
• [文献書誌] Y.Oumi, R.Mizuno, K.Azuma, S.Nawata, T.Fukushima, T.Uozumi, T.Sano: "Reversibility of dealumination-realumination process of BEA zeolite"Microporous Mesoporous Mater.. 49巻. 103-109 (2001)
• [文献書誌] P.Kumar, Y.Oumi, T.Sano, K.Yamana: "Syntheszied and characterization of porous materials by using coal fly ash"MRS Proc.. 2巻. 21-28 (2001)
• [文献書誌] H.Matsuda, H.Yanagishita.D.Kitamoto, K.Haraya, T.Nakane, T.Takada, Y.Idemoto, N.Koura.T.Sano: "Preparation of silicalite pervaporation membrane with ethanol permselectivsty by 2 step hydrothermal synthesis"Sep. Sci. Technol.. 36巻. 3305-3310 (2001)
• [文献書誌] 近江靖則, 宮本明, 佐野庸治: "計算化学手法によるゼオライトの熱劣化過程の検討"マテリアルライフ. 14巻. 47-53 (2002)
• [文献書誌] H.Matsuda, H.Yanagishita, D.Kitamoto, T.Ikegami, K.Haraya, T.Nakane, Y.Idemoto, N.Koura, T.Sano: "Improvement of ethanol premselectivity of silicalite membrane in pervaporation by silicon rubber coating"J. Membrane Sci.. (印刷中).
• [文献書誌] P.Kumar, Y.Oumi, T.Sano, K.Yamana: "Masoporous aluminosilicates from coal fly ash"Stud. Surf. Sci. Catal.. (印刷中).
• [文献書誌] Y.Oumi, K.Azuma, T.Ikeda, S.Sasaki, T.Sano: "The modeling of wall structure of siliceous MCM-41 based on the formation process"Stud. Surf. Sci. Catal.. (印刷中).
• [文献書誌] P.Kumar, Y.Oumi, K.Yamana, T.Sano: "Synthesis and characterization of inorganic porous materials using coal fly ash"Materials Life. (印刷中).
• [文献書誌] H.Yamashita, K.Yoshizawa, M.Ariyuki, S.Higashimoto, M.Che, M.Anpo: "Photocalalytic Reactions on chromium containing Mesoporous Silica Molecular Sieves (Cr-HMS) under Visible Light Irradiation : Decomposition of NO and Partial Oxidation of Propane"Chem. Commun.. 2001巻. 435-436 (2001)
• [文献書誌] H.Yamashita, M.Nishimura, T.Nakajima, M.Hada, H.Nakatsuii, M.Anpo: "Effect of Ion-exchanged Alkali Metal Cations on the Photolysis of 2-pentanone Included within ZSM-5 Zeolite Cavities : A Study of Ab Initio Molecular orbital Calculations"Res. Chem. Intermed.. 27巻. 89-102 (2001)
• [文献書誌] K.Ikeue, H.Yamashita, T.Takewaki, M.Anpo: "Photocatalytic Reactions of CO2 with H2O on Ti-Beta Zeolite Photocatalysts : Effect of the Hydrophobic and Hydrophilic Properties"J. Phys. Chem. B. 105巻. 8350-8355 (2001)
• [文献書誌] J.Zhang, Y.Hu, M.Matsuoka, H.Yamashita, M.Minagawa, H.Hidaka, M.Anpo: "Relationship between the Local Structures of Titanium Oxide Photocatalysts and Their Reactivities in the Dcomrosition of NO"J. Phys. Chem.. 105巻. 8395-8398 (2001)
• [文献書誌] J.Zhang, T.Ayusawa, K.Kinugawa, H.Yamashita, M.Matsuoka, M.Anpo: "Investigations of TiO2 Photocatalysts for the Decomposition of NO in the Flow System -The Role of Pretreatment and Reaction Conditions in the Photocatalytic Efficiency-"J. Catal.. 198巻. 1-8 (2001)
• [文献書誌] J.Zhnag, M.Matsuoka, H.Yamashita, M.Anpo: "XAFS Studies on the Local Structures of Ti-HMS Mesoporous Molecular Sieves and Their Photocatalytic Properties"J. Synchrotron Rad.. 8巻. 637-639 (2001)
• [文献書誌] K.Ikeue, H.Mukai, H.Yamashita, S.Inagaki, M.Matsuoka, M.Anpo: "Characterization and Photocatalytic Reduction of CO2 with H2O on Ti/FSM-16 Synthesized by Various Preparation Methods"J. Synchrotron Rad.. 8巻. 640-642 (2001)
• [文献書誌] M.Matsuoka, W.S.Ju, H.Yamashita, M.Anpo: "Investigations on the Local Structure of Ag+/ZSM-5 Catalysts and their Photocatalvtic Reactivities for the Decomoosition of N2O at 298 K"J. Synchrotron Rad.. 8巻. 613-615 (2001)
• [文献書誌] W.S.Ju, M.Matsuoka, H.Yamashita, M.Anpo: "Local Structures of Pb(II) ion Catalyst Anchored within Zeolite Cavities and their Photocatalytic Reactivities for the Elimination of N2O"J. Synchrotron Rad.. 8巻. 608-609 (2001)
• [文献書誌] S.Higashimoto, M.Matsuoka, H.Yamashita, M.Anpo, 0.Kitao: "characterization of the VS-1 catalyst Using Various Spectroscopic Techniques and Its Unique Photocatalytic Reactivity for the Decomposition of NO in the Absence and Presence of C3H8"Microporous and Mesoporous Materials. 48巻. 329-335 (2001)
• [文献書誌] H.Yamashita, K.Yoshizawa, M.Ariyuki, S.Higashimoto, M.Anpo: "Photocatalytic Reactions on Chromium Containing Mesoporous Molecular Sieves under Visible Light Irradiation"Stud. Surf. Sci. Catal.. 135巻. 9-9 (2001)
• [文献書誌] H.Yamashita, S.Takada, M.Nishimura, H.Bessho, M.Anpo: "Effects or Ion-exchanged Alkali Metal Catioris on the Photolysis of Alkyl Ketones Included Within ZSM-5 Zeolite Cavities A Study of Ab lnitio Molecular Orbital Calculations"Stud. Surf Sci. Catal.. 135巻. 8-8 (2001)
• [文献書誌] 山下弘巳: "ゼオライト細孔内での不斉光化学反応"化学. 56巻. 56-57 (2001)
• [文献書誌] H.Yamashita, K.Ikeue, T.Takewaki, M.Anpo: "In situ XAFS Studies on the Effects of the Hydrophobic-hydrophilic Properties of Ti-Beta Zeolites in the Photocatalytic Reduction of CO2 with H2O"Topics in Catal.. (印刷中).
• [文献書誌] H.Yamashita, K.Yoshizawa, M.Ariyuki, S.Higashimoto, M.Anpo: "Photocatalytic Echylene Polymerization on Chromium Containing Mesoporous Molecular Sieves"Stud. Surf. Sci. Catal.. (印刷中).
• [文献書誌] 山下弘巳, 安保正一: "イオンビームを利用する新規光触媒の創製と光触媒"炭素原料と材料設計. 3巻. 101-112 (2001)
• [文献書誌] H.Yamashita, K.Ikeue, M.Anpo: "Photocatalytic Reduction of CO2 with H2O on Various Titanium Oxide Catalysts"ACS Book on CO2 Conversion and Utilization. (印刷中).
• [文献書誌] H.Yamashita: "XAFS Analysis and Application to Carbon Related Materials and Catalysts"Carbon Alloys. (印刷中).
• [文献書誌] 山下弘巳, 安保正一: "光触媒担持多孔質体の開発と応用"光触媒(酸化チタン)商品の開発. (印刷中).
• [文献書誌] T.Kugita, M.Ezawa, T.Owada, Y.Tomita, S.Namba, N.Hashimoto, M.Onaka: "MCM-41 as a Highly Active Catalyst for Diets-Alder Reaction of Anthracene with p-Benzoquinone"Microporous Mesoporous Mater.. 44-45巻. 531-536 (2001)
• [文献書誌] M.Onaka N.Hashimoto, R.Yamasaki, Y.Kitabata: "Nanoporous Solid Acid Catalyst for the Diels-Alder Reaction of 1, 3-Dienes with Acrylates"Chem. Lett.. 2002巻. 166-167 (2002)
• [文献書誌] 尾中 篤: "グリーンケミストリーと固体酸触媒の探索"ペトロテック. 24巻. 837-841 (2001)
• [文献書誌] K.Fujishima, A.Fukuoka, A.Yamagishi, S.Inagaki, Y.Fukushima, M.Ichikawa: "Photooxidalion or benzene to phenol by ruthenium bipyridine complexes grafted on mesoporous silica FSM-16"J. Mol. Catal. A : Chemical. 166巻. 211-218 (2001)
• [文献書誌] P.Knops-Gerrits, P.A.Jacobs, A.Fukuoka, M.Ichikawa, F.Faglioni, W.A.Goddard: "Reactivity of methane mono-oxygenase. insights from quantum mechanic studies on synthetic iron model complexes"J. Mol. Catal. A : Chemical. 166巻. 3-13 (2001)
• [文献書誌] A.Fukuoka, Y.Sakamoto, S.Guan.S.Inagaki, N.Sugimoto, Y.Fukushima, K.Hirahara, S.Iijima, M.Ichikawa: "Novel Templaling Synthesis of Necklace-shaped Mono-and Bimetallic Nanowires In Hybrid Organic-Inorganic Mesoporous Material"J. Am. Chem. Soc.. 123巻. 3373-3374 (2001)
• [文献書誌] A.Fukuoka, N.Higashimoto, Y.Sakamoto, M.Sasaki, N.Sugimoto, S.Inagaki, Y.Fukushima, M.Ichikawa: "Ship-in-bottle synthesis and catalytic performances of platinum carbonyl clusters, nanowires, and nanoparticles in micro-and mesoporous materials"Catal. Today. 66巻. 23-31 (2001)
• [文献書誌] A.Fukuoka, N.Higashimoto, Y.Sakamoto, S.Inagaki, Y.Fukushima, M.Ichikawa: "Preparation and catalysis of mono-and bimetallic nanowire and -particle in FSM-16"Microporous Mesoporous Mater.. 48巻. 171-179 (2001)
• [文献書誌] A.Fukuoka, N.Higashimoto, Y.Sakamoto, S.Inagaki, Y.Fukushima, M.Ichikawa: "Preparation, XAFS characterization, and Catalysis of Platinum Nanowires and Nanoparticles in Mesoporous Silica FSM-16"Topics in Catalysis. 18巻. 73-78 (2002)
• [文献書誌] 尾中篤, 瀬川幸一: "グリーン触媒-固体酸触媒"講談社. 210 (2001)
• [文献書誌] A.Fukuoka, M.Ichikawa: "Morphology-Controlled Materials -Advanced Materials Processing and Characterization"Springer-Verlag(印刷中).