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2014 年度 実績報告書

ナノ薄膜の創製と熱電的性質の解明および閉じ込め効果の検証

研究課題

研究課題/領域番号 14F04736
研究機関独立行政法人物質・材料研究機構

研究代表者

森 孝雄  独立行政法人物質・材料研究機構, 無機ナノ構造ユニット, グループリーダー (90354430)

研究分担者 TYNELL Tommi  独立行政法人物質・材料研究機構, 無機ナノ構造ユニット, 外国人特別研究員
研究期間 (年度) 2014-04-25 – 2016-03-31
キーワード薄膜 / 熱電
研究実績の概要

Research on the JSPS postdoctoral fellowship with the theme “Thermoelectric properties of nanostructured thin films fabricated with molecular beam epitaxy” was commenced in the beginning of May 2014 with a focus on fabricating thin films of alkaline earth hexaborides using the molecular beam epitaxy (MBE) technique. Initial difficulties with achieving crystalline films were overcome during the summer, and strontium boride thin films of relatively high crystallinity have now been successfully fabricated. While this already enables the evaluation and potential improvement of the films’ thermoelectric performance, the focus of the research effort for the latter half of the fiscal year has been the realization of epitaxially grown films, as this would open further possibilities for nanostructuring. The results of this research have also been presented at two different scientific conferences during fiscal year 2014.
In addition to the progress described above, an effort has been made during the latter half of the fiscal year 2014 to prepare a chemical vapor deposition (CVD) system for the deposition of various boride thin films. The intent is to use the system as a different approach to the challenge of fabricating nanostructured boride films, and the expectation is to compare results obtained from both techniques (MBE and CVD) to build a more robust picture of the different ways to optimize boride thin films for thermoelectric applications. The CVD system has now been brought online, and initial tests on boron growth have been successful.

現在までの達成度 (区分)
現在までの達成度 (区分)

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理由

Regarding the progress, we think it has been satisfactory, since we have been successful at the very challenging topic of fabricating thin films of thermoelectric borides using the molecular beam epitaxy (MBE) technique. Borides are very high temperature materials and MBE usually cannot be used but we overcame experimental difficulties, and strontium boride thin films of relatively high crystallinity have now been successfully fabricated. And as a very pro-active research approach we have even successfully prepared a CVD system to become able to access the deposition of various boride thin films, and where initial tests on boron growth have been successful.

今後の研究の推進方策

Regarding the future plan, it is two-fold. First, the thermoelectric properties evaluation and potential improvement of the films’ thermoelectric performance will be carried out on the alkaline earth hexaborides MBE thin films. Secondly, the chemical vapor deposition (CVD) system will be utilized as a different approach to the challenge of fabricating nanostructured boride films, and the expectation is to compare results obtained from both techniques (MBE and CVD) to build a more robust picture of the different ways to optimize boride thin films for thermoelectric applications.

  • 研究成果

    (2件)

すべて 2015 2014

すべて 学会発表 (2件)

  • [学会発表] Growth of strontium hexaboride thin films with MBE2015

    • 著者名/発表者名
      Tommi Tynell, Takashi Aizawa, Isao Ohkubo, Takao Mori
    • 学会等名
      Annual Meeting of the Ceramic Society of Japan
    • 発表場所
      Okayama University
    • 年月日
      2015-03-18 – 2015-03-20
  • [学会発表] Growth of hexaboride thin films with MBE2014

    • 著者名/発表者名
      Tommi Tynell, Takashi Aizawa, Isao Ohkubo, Takao Mori
    • 学会等名
      9th Conference of the Flux Growth Society of Japan
    • 発表場所
      Kochi University
    • 年月日
      2014-12-11 – 2014-12-12

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公開日: 2016-06-01  

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