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2015 年度 実績報告書

バイオマス改質と水素生成をともなう低温廃熱回収

研究課題

研究課題/領域番号 15J07587
研究機関東北大学

研究代表者

朱 遠征  東北大学, 大学院工学研究科, 特別研究員(DC2)

研究期間 (年度) 2015-04-24 – 2017-03-31
キーワードcerium oxide / nanoparticles / catalyst / oxygen storage capacity
研究実績の概要

In order to improve catalytic activity of CeO2 nanoparticle for hydrogenation from biomass conversion, Cr doping was investigated. 5 mol% Cr-doped cubic CeO2 nanoparticles was synthesized using batch reactor. The high-resolution transmission electron microscopy (HRTEM) showed that cubic Cr-doped CeO2 exposed with {100} facet. The kinetic study was carried out at 150 ℃, 200 ℃, 300 ℃, 350 ℃, 400 ℃ respectively.During the temperature increase process, from XRD patterns Cr compound will be formed even at 150 ℃ and 200 ℃.
The oxygen-storage capacity (OSC) is defined as the amount of oxygen stored in and released from the solid. The OSC of5 mol% Cr-doped CeO2 and cubic CeO2 was measured using thermogravimetric differential thermal analysis (BELCAT) which shows that Cr-doped CeO2 is 1.5 times as large as cubic CeO2 at 250 ℃ and 2.5 times as large as cubic CeO2 at 300 ℃.
Biomass-derived methanol have been used as the model compound for hydrogen generation at 300 ℃ for 1 hour in batch reactor. When 5 mol% Cr-doped CeO2 used as catalyst, H2 amount is 25.6 times as large as no catalyst, and is 3.0 times as large as CeO2 used as catalyst. This result suggests that Cr doping can effectively improve the catalytic activity of CeO2 and also increase hydrogen generation amount.
Because of the high speed temperature increase process and fast reaction rate,a lab-scale plug-flow reactor was used to increase Cr doping amount.Cr doping amount can reach 21 mol%.XRD patterns showed that the diffraction peak shifted toward a higher angle as the Cr was doped into the CeO2.

現在までの達成度 (区分)
現在までの達成度 (区分)

1: 当初の計画以上に進展している

理由

Based on the research results, Cr doping can improve the oxygen storage capacity (OSC) of CeO2 nanoparticles. We can obtained the 21 mol% Cr-doped CeO2 nanoparticles using flow type reactor. From methonal decomposition experiment, we can know that Cr doping can effectively improve the catalytic activity of CeO2 and also increase hydrogen generation amount. These results are almost consistent with expectations.

今後の研究の推進方策

The synthesized Cr-doped CeO2 nanoparticles will be used for hydrogenation from organic waste materials such as bitumen,black liquor and so on.The catalytic reaction will be carried out in a batch reactor. Different kinds of catalysts will be used and the liquid products can be analyzed using chromatography (GC)-mass spectrometry (MS) and flame ionization detector (FID). Hydrogen product can be analyzed using GC-thermal conductivity detector(TCD). The optimize catalyst will be investigated.

  • 研究成果

    (4件)

すべて 2015

すべて 雑誌論文 (1件) (うち査読あり 1件、 謝辞記載あり 1件) 学会発表 (3件) (うち国際学会 2件)

  • [雑誌論文] Green solvent for green materials: a supercritical hydrothermal method and shape-controlled synthesis of Cr-doped CeO2 nanoparticles2015

    • 著者名/発表者名
      Yuanzheng Zhu, Seiichi Takami, Gimyeong Seong, Mehdi Dejhosseini, Muhammad Zamir Hossain, Takio Noguchi, Daisuke Hojo, Nobuaki Aoki, Tsutomu Aida, Tadafumi Adschiri
    • 雑誌名

      Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences

      巻: 373 ページ: 1-14

    • DOI

      10.1098/rsta.2015.0012

    • 査読あり / 謝辞記載あり
  • [学会発表] Supercritical hydrothermal synthesis of crystal-face and shape controlled Cr-doped CeO2 nanoparticles with high catalytic activity2015

    • 著者名/発表者名
      Yuanzheng Zhu, Seiichi Takami, Gimyeong Seong, Daisuke Hojo, Nobuaki Aoki, Tadafumi Adschiri
    • 学会等名
      第15回東北大学多元物質科学研究所研究発表会2015
    • 発表場所
      東北大学さくらホール、仙台
    • 年月日
      2015-12-22 – 2015-12-22
  • [学会発表] Supercritical Hydrothermal Synthesis of Facet-Controlled Cr-doped CeO2 Nanoparticles2015

    • 著者名/発表者名
      Yuanzheng Zhu, Seiichi Takami, Gimyeong Seong, Daisuke Hojo, Nobuaki Aoki, Tadafumi Adschiri
    • 学会等名
      11th International Symposium on Supercritical Fluids Incorporating with Supergreen 2015
    • 発表場所
      Global Education Center for Engineers (GECE), Seoul national university, Seoul, Korea
    • 年月日
      2015-10-13 – 2015-10-13
    • 国際学会
  • [学会発表] Shape-Controlled Synthesis of Cr Doped CeO2 Nanoparticles in Sub- and Supercritical Water2015

    • 著者名/発表者名
      Yuanzheng Zhu, Seiichi Takami, Daisuke Hojo, Nobuaki Aoki, Tsutomu Aida, Tadafumi Adschiri
    • 学会等名
      7th International Conference on Green and Sustainable Chemistry (GSC-7) and 4th JACI/GSC Symposium
    • 発表場所
      Hitotsubashi Hall, Hitotsubashi University, Tokyo
    • 年月日
      2015-07-08 – 2015-07-08
    • 国際学会

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公開日: 2016-12-27  

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