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2017 年度 実績報告書

粘土鉱物-色素複合体を用いた強発光材料の開発

研究課題

研究課題/領域番号 15K13291
研究機関首都大学東京

研究代表者

高木 慎介  首都大学東京, 都市環境科学研究科, 教授 (40281240)

研究期間 (年度) 2015-04-01 – 2018-03-31
キーワード蛍光 / 発光 / AIE / S-FIE / 光機能材料 / 粘土鉱物 / ナノシート
研究実績の概要

Organic fluorescent dyes have received a great notice as luminescent materials for organic ELs, sensors, probes, dye lasers and so on. In recent years, Aggregation Induced Emission (AIE) has been reported as a unique phenomenon that enhances the luminescence intensity due to aggregation of dyes. In this study, we examined the fluorescence behavior of AIE molecules such as cyanine derivatives (DASMs) on the clay surface (S-FIE) in addition to the observation of AIE behavior in the poor solvents. The substituent effect on fluorescence behavior for AIE and S-FIE was also investigated. The absorption spectra were observed for sample where dye loadings are 2~150% vs cation exchange capacity (CEC) of the clay. DASMs adsorbed as a monomer state on clay up to ca. 25% vs. CEC. One of the 3 states (component 1) showed a strong emission enhancement compared to it without clay, as shown in Fig. 3 (S-FIE). As a result, Fluorescence increased not only for unsubstituted DASM but also for Me-DASM and Et-DASM (DASM: 29 times, Me-DASM: 160 times and Et-DASM: 110 times). These indicate that S-FIE phenomenon is not restrained by molecular structures if the molecule adsorbs on the clay surface in a monomer state. While the effect of AIE on the fluorescence enhancement strongly depends on the molecule’s structure, that of S-FIE sample is not restricted by the molecule’s structure. Furthermore, because the mechanism of S-FIE is relatively clear, S-FIE is easy to be predicted.

  • 研究成果

    (11件)

すべて 2018 2017

すべて 雑誌論文 (5件) (うち査読あり 5件) 学会発表 (5件) (うち国際学会 2件、 招待講演 5件) 図書 (1件)

  • [雑誌論文] Characterization of dispersed titania nanosheet under aqueous conditions and its complex formation behavior with cationic porphyrin2018

    • 著者名/発表者名
      Sano Keito、Sonotani Amane、Tatsumi Daichi、Ohtani Yuta、Shimada Tetsuya、Takagi Shinsuke
    • 雑誌名

      J. Photochem. Photobiol. A

      巻: 353 ページ: 597~601

    • DOI

      10.1016/j.jphotochem.2017.08.003

    • 査読あり
  • [雑誌論文] Elucidation of the Adsorption Distribution of Cationic Porphyrin on the Inorganic Surface by Energy Transfer as a Molecular Ruler2018

    • 著者名/発表者名
      Nakayama Ayumi、Mizuno Junya、Ohtani Yuta、Shimada Tetsuya、Takagi Shinsuke
    • 雑誌名

      J. Phys. Chem. C

      巻: 122 ページ: 4365~4371

    • DOI

      10.1021/acs.jpcc.7b12104

    • 査読あり
  • [雑誌論文] Fluorescence Enhancement Behavior of Hemicyanine Derivatives on the Clay Nanosheets: Aggregation Induced Emission (AIE) vs. Surface - Fixation Induced Emission (S-FIE)2018

    • 著者名/発表者名
      Kudo Nana、Tsukamoto Takamasa、Tokieda Daiki、Shimada Tetsuya、Takagi Shinsuke
    • 雑誌名

      Chem. Lett.

      巻: 未定 ページ: 未定

    • DOI

      10.1246/cl.180043

    • 査読あり
  • [雑誌論文] Highly Selective Photochemical Epoxidation of Cyclohexene Sensitized by Ru(II) Porphyrin?Clay Hybrid Catalyst2017

    • 著者名/発表者名
      Tatsumi Daichi、Tsukamoto Takamasa、Honna Ryou、Hoshino Shota、Shimada Tetsuya、Takagi Shinsuke
    • 雑誌名

      Chem. Lett.

      巻: 46 ページ: 1311~1314

    • DOI

      10.1246/cl.170521

    • 査読あり
  • [雑誌論文] Photoluminescence by Intercalation of a Fluorescent β-Diketone Dye into a Layered Silicate2017

    • 著者名/発表者名
      Hirose Mutsumi、Ito Fuyuki、Shimada Tetsuya、Takagi Shinsuke、Sasai Ryo、Okada Tomohiko
    • 雑誌名

      Langmuir

      巻: 33 ページ: 13515~13521

    • DOI

      10.1021/acs.langmuir.7b03460

    • 査読あり
  • [学会発表] Unique absorption and emission behavior of layered materials - dyes complexes2018

    • 著者名/発表者名
      高木慎介
    • 学会等名
      日本化学会第98春季年会
    • 招待講演
  • [学会発表] 二次元性材料が提供する興味深い光化学反応場2018

    • 著者名/発表者名
      高木慎介
    • 学会等名
      日本化学会第98春季年会
    • 招待講演
  • [学会発表] 人工光合成研究の夢2018

    • 著者名/発表者名
      高木慎介
    • 学会等名
      第3回 FoS Club Meeting
    • 招待講演
  • [学会発表] PHOTOCHEMICAL EPOXIDATION WITH LIGHT HARVESTING FUNCTIONALITY ON THE INORGANIC SURFACES2017

    • 著者名/発表者名
      S. Takagi
    • 学会等名
      2017 International Conference on Artificial Photosynthesis (ICARP2017)
    • 国際学会 / 招待講演
  • [学会発表] Environment-responsive materials composed by dyes and layered compounds2017

    • 著者名/発表者名
      S. Takagi
    • 学会等名
      The 1st International Workshop on Chromogenic Materials and Devices
    • 国際学会 / 招待講演
  • [図書] 1.Inorganic Nanosheets and Nanosheet-Based Materials (Chapter 1.&14. ),2018

    • 著者名/発表者名
      S. Takagi
    • 総ページ数
      60
    • 出版者
      Springer

URL: 

公開日: 2019-12-27  

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