ＭＯＦを出発原料として用いたキャパシタ用多孔質電極の合成

2017 年度 実績報告書

• 研究課題/領域番号: 16F16722
• 研究機関: 国立研究開発法人物質・材料研究機構
• 研究代表者: 山内 悠輔 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA主任研究者 (10455272)
• 研究分担者: KANETI YUSUF VALENTINO 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 外国人特別研究員
• 研究期間 (年度): 2016-10-07 – 2019-03-31
• キーワード: Mesoporous materials

研究実績の概要

Recently, we found out that nanoporous cobalt oxide nanosheets can be prepared using Cu-based MOFs as sacrificial templates for energy storage application. This is a new approach and very useful for designing various nanoporous materials with different shapes.

In addition, we demonstrated a general template-free strategy for generating hierarchical mixed oxide nanosheets from monodispersed cobalt glycerate spheres for supercapacitor/gas sensing application. Although we did not use the MOFs as sacrificial templates, this method can be reported as the alternative approach.

現在までの達成度 (区分)

1: 当初の計画以上に進展している

理由

We carried out additional experiments to extend our synthetic concept.

今後の研究の推進方策

We have 6 months until this JSPS project finishes. We will complete all the projects, and we will publish the papers somewhere.

研究成果

• [雑誌論文] General template-free strategy for fabricating mesoporous two-dimensional mixed oxide nanosheets via self-deconstruction/reconstruction of monodispersed metal glycerate nanospheres (2018)
  • 著者名/発表者名: Kaneti Yusuf Valentino, Salunkhe Rahul R., Wulan Septiani Ni Luh, Young Christine, Jiang Xuchuan, He Yan-Bing, Kang Yong-Mook, Sugahara Yoshiyuki, Yamauchi Yusuke
  • 雑誌名: J Mater Chem A 巻: 6 ページ: 5971～5983
  • DOI: 10.1039/C8TA00008E
  • 査読あり / 国際共著
• [雑誌論文] Spontaneous Weaving of Graphitic Carbon Networks Synthesized by Pyrolysis of ZIF-67 Crystals (2017)
  • 著者名/発表者名: Zhang Wei, Jiang Xiangfen, Wang Xuebin, Kaneti Yusuf Valentino, Chen Yinxiang, Liu Jian, Jiang Ji-Sen, Yamauchi Yusuke, Hu Ming
  • 雑誌名: Angewandte Chemie International Edition 巻: 56 ページ: 8435～8440
  • DOI: 10.1002/anie.201701252
  • 査読あり / 国際共著
• [雑誌論文] Strategies for Improving the Functionality of Zeolitic Imidazolate Frameworks: Tailoring Nanoarchitectures for Functional Applications (2017)
  • 著者名/発表者名: Kaneti Yusuf Valentino, Dutta Saikat, Hossain Md. S. A., Shiddiky Muhammad J. A., Tung Kuo-Lun, Shieh Fa-Kuen, Tsung Chia-Kuang, Wu Kevin C.-W., Yamauchi Yusuke
  • 雑誌名: Advanced Materials 巻: 29 ページ: 1700213～1700213
  • DOI: 10.1002/adma.201700213
  • 査読あり / 国際共著
• [雑誌論文] Fabrication of an MOF-derived heteroatom-doped Co/CoO/carbon hybrid with superior sodium storage performance for sodium-ion batteries (2017)
  • 著者名/発表者名: Kaneti Yusuf Valentino, Zhang Jun, He Yan-Bing, Wang Zhijie, Tanaka Shunsuke, Hossain Md Shahriar A., Pan Zheng-Ze, Xiang Bin, Yang Quan-Hong, Yamauchi Yusuke
  • 雑誌名: J Mater Chem A 巻: 5 ページ: 15356～15366
  • DOI: 10.1039/C7TA03939E
  • 査読あり / 国際共著
• [雑誌論文] Mesoporous Alumina as an Effective Adsorbent for Molybdenum (Mo) toward Instant Production of Radioisotope for Medical Use (2017)
  • 著者名/発表者名: Saptiama Indra, Kaneti Yusuf Valentino, Suzuki Yumi, Suzuki Yoshitaka, Tsuchiya Kunihiko, Sakae Takeji, Takai Kimiko, Fukumitsu Nobuyoshi, Alothman Zeid Abdullah, Hossain Md. Shahriar A., Ariga Katsuhiko, Yamauchi Yusuke
  • 雑誌名: Bulletin of the Chemical Society of Japan 巻: 90 ページ: 1174～1179
  • DOI: 10.1246/bcsj.20170184
  • 査読あり / 国際共著
• [雑誌論文] A mesoporous tin phosphate-graphene oxide hybrid toward the oxygen reduction reaction (2017)
  • 著者名/発表者名: Pramanik Malay, Li Cuiling, Kaneti Yusuf Valentino, Yamauchi Yusuke
  • 雑誌名: Chem Commun 巻: 53 ページ: 5721～5724
  • DOI: 10.1039/C7CC01311F
  • 査読あり
• [雑誌論文] Prussian blue derived iron oxide nanoparticles wrapped in graphene oxide sheets for electrochemical supercapacitors (2017)
  • 著者名/発表者名: Tanaka Shunsuke, Salunkhe Rahul R., Kaneti Yusuf Valentino, Malgras Victor, Alshehri Saad M., Ahamad Tansir, Zakaria Mohamed B., Dou Shi Xue, Yamauchi Yusuke, Hossain Md. Shahriar A.
  • 雑誌名: RSC Advances 巻: 7 ページ: 33994～33999
  • DOI: 10.1039/C7RA03179C
  • 査読あり / 国際共著
• [雑誌論文] Tailored Design of Bicontinuous Gyroid Mesoporous Carbon and Nitrogen-Doped Carbon from Poly(ethylene oxide-b-caprolactone) Diblock Copolymers (2017)
  • 著者名/発表者名: Chu Wei-Cheng, Bastakoti Bishnu Prasad, Kaneti Yusuf Valentino, Li Jheng-Guang, Alamri Hatem R., Alothman Zeid A., Yamauchi Yusuke, Kuo Shiao-Wei
  • 雑誌名: Chemistry - A European Journal 巻: 23 ページ: 13734～13741
  • DOI: 10.1002/chem.201702360
  • 査読あり / 国際共著