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2019 年度 実績報告書

High-throughput approach for establishing structure-performance relationship in Ziegler-Natta catalyzed olefin polymerization

研究課題

研究課題/領域番号 17K14492
研究機関北陸先端科学技術大学院大学

研究代表者

CHAMMINGKWAN P  北陸先端科学技術大学院大学, 先端科学技術研究科, 講師 (60752376)

研究期間 (年度) 2017-04-01 – 2020-03-31
キーワードHigh-throughput / Ziegler-Natta / Olefin polymerization / Structure-performance
研究実績の概要

The target in the final was set at evaluating the catalyst performance in olefin polymerization and constructing the structure-performance relationship. In this final year, a catalyst library containing 17 catalyst samples having different physical and chemical features has been generated and the performances were evaluated in homopolymerization of propylene and copolymerization of propylene and ethylene for making impact propylene copolymer. Combined with the results throughout the project, it was found that the correspondence between important structural features of the catalysts and their performances was hardly acquired on the basis of one-to-one relation. However, the performance can be reasonably ascribed as the multivariate functions of descriptors using a linear regression model.

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公開日: 2021-01-27  

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