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2018 年度 実施状況報告書

Analyses of the Synergy of Sub/Supercritical H2O-CO2 System for Synthesis of Green Platform Chemicals

研究課題

研究課題/領域番号 17KK0118
研究機関熊本大学

研究代表者

キタイン アルマンド  熊本大学, グローバル教育カレッジ, 教授 (50504693)

研究期間 (年度) 2018 – 2020
キーワードhydrolysis / supercritical CO2 / subcritical H2O / Raman spectroscopy / functionalization / CO2 reduction / 5-HMF / glycosidic bond
研究実績の概要

In-situ monitoring of the reaction taking place during hydrolysis of hesperidin under supercritical CO2-subcritical H2O system was carried out by Raman spectroscopy using the high temperature and high pressure sapphire view cell at Valladolid University. Two graduate students was also attached to this university to help monitor the reaction mechanisms involving the hydrolysis of the glycosidic bond linking the sugar moieties and aglycone, and the conversion of the obtained sugar into 5-HMF.Results of Raman spectroscopy indicated the presence of superacidic interfacial layer between the supercritical CO2 phase and subcritical H2O phase, which could explain the reason for the relatively higher yield of hesperetin compared to the conventional method.The analysis of molecular orientation of hesperidin between the two phases is currently on going.

I also visited Prof. Anke Krueger Group of Wurzburg University with two graduate students - one worked on various analyses of functionalized nanodiamond using various approaches such as supercritical H2O, CO2 and NH3 carried out at Kumamoto University. The other student learned P and B functionalization of carbon materials, which will be used in succeeding experiments including carbon dioxide reduction into useful chemicals.

現在までの達成度 (区分)
現在までの達成度 (区分)

1: 当初の計画以上に進展している

理由

A new research collaboration with the Bioinformatics and High Performance Computing Research Group of Prof. Horacio Sanchez of Universidad Catolica San Antonio de Murcia (Spain) has been established to elucidate the mechanism of the hydrolysis by molecular dynamic simulation to support the data obtained by Raman spectroscopy.To encourage student mobility and development of young researchers, 4 graduate students have also been dispatched to work on the project. Two students were supported by the TOBITATE Ryugaku JAPAN Program.Also, another PhD student from the Philippines joined Kumamoto University to work on the application of the proposed supercritical CO2-H2O synergy to extraction of natural compounds, and the results have been submitted for publication in the Journal of Supercritical Fluids.
Also, a memorandum of understanding (MOU) for research collaboration and student exchanges between Kumamoto University and Valladolid University (Spain) and Wurzburg University (Germany) has been signed. This MOU will foster active research collaboration and students exchanges with the two top European universities. Prof. Maria Jose Cocero has also been invited as an International Research Organization for Advanced Science and Technology (IROAST) Visiting Professor to further enhance research collaboration between the 2 universities.

今後の研究の推進方策

The conversion of the obtained sugar (glucose) from hesperidin into bioenergy platform chemicals such as 5-HMF will be further elucidated and analyzed in collaboration with Prof. MJ Cocero (Valladolid University). Furthermore,the functionalized carbon materials (nanodiamond and reduced graphene oxide) will be used for the reduction of CO2 using the novel hydrothermal CO2 reduction process.The application will be extended to catalytic hydrothermal conversion of CO2 into useful chemicals or fuels by our novel reactive separation approach. Catalytic reduction of CO2 under hydrothermal conditions into useful compounds such as carboxylic acids and alcohol will be elucidated using the developed catalysts.

  • 研究成果

    (7件)

すべて 2019 2018

すべて 雑誌論文 (5件) (うち国際共著 5件、 査読あり 5件) 学会発表 (1件) (うち国際学会 1件) 図書 (1件)

  • [雑誌論文] Enhanced Levulinic Acid Production from Cellulose by Combined Bronsted Hydrothermal Carbon and Lewis Acid Catalysts2019

    • 著者名/発表者名
      Tat Boonyakarn, Piyaporn Wataniyakul, Panatpong Boonnoun, Armando T Quitain, Tetsuya Kida, Mitsuru Sasaki, Navadol Laosiripojana, Bunjerd Jongsomjit, Artiwan Shotipruk
    • 雑誌名

      Industrial & Engineering Chemistry Research

      巻: 58 ページ: 2697-2703

    • DOI

      10.1021/acs.iecr.8b05332

    • 査読あり / 国際共著
  • [雑誌論文] Supercritical carbon dioxide-mediated esterification in a microfluidic reactor2018

    • 著者名/発表者名
      Armando T Quitain, Elaine G Mission, Yoshifumi Sumigawa, Mitsuru Sasaki
    • 雑誌名

      Chemical Engineering and Processing-Process Intensification

      巻: 123 ページ: 168-173

    • DOI

      10.1016/j.cep.2017.11.002

    • 査読あり / 国際共著
  • [雑誌論文] Integrating reduced graphene oxide with microwave-subcritical water for cellulose depolymerization2018

    • 著者名/発表者名
      Elaine G Mission, Armando T Quitain, Yudai Hirano, Mitsuru Sasaki, Maria Jose Cocero, Tetsuya Kida
    • 雑誌名

      Catalysis Science & Technology

      巻: 8 ページ: 5434-5444

    • DOI

      10.1039/C8CY00953H

    • 査読あり / 国際共著
  • [雑誌論文] Preparation of hydrothermal carbon as catalyst support for conversion of biomass to 5-hydroxymethylfurfural2018

    • 著者名/発表者名
      Piyaporn Wataniyakul, Panatpong Boonnoun, Armando T Quitain, Mitsuru Sasaki, Tetsuya Kida, Navadol Laosiripojana, Artiwan Shotipruk
    • 雑誌名

      Catalysis Communications

      巻: 104 ページ: 41-47

    • DOI

      10.1016/j.catcom.2017.10.014

    • 査読あり / 国際共著
  • [雑誌論文] Optimization of hydrothermal liquefaction of palm kernel shell and consideration of supercritical carbon dioxide mediation effect2018

    • 著者名/発表者名
      Yi Herng Chan, Armando T Quitain, Suzana Yusup, Yoshimitsu Uemura, Mitsuru Sasaki, Tetsuya Kida
    • 雑誌名

      The Journal of Supercritical Fluids

      巻: 133 ページ: 640-646

    • DOI

      10.1016/j.supflu.2017.06.007

    • 査読あり / 国際共著
  • [学会発表] Analyses of the Synergy of Sub/Supercritical H2O-CO2 System for Synthesis of Green Platform Chemicals2018

    • 著者名/発表者名
      A. Quitain*, J. K. Agutaya, R. Inoue, M. Sasaki, M. J. Cocero and T. Kida
    • 学会等名
      Regional Symposium on Chemical Engineering (RSCE) 2018
    • 国際学会
  • [図書] Advances in Feedstock Conversion Technologies for Alternative Fuels and Bioproducts2019

    • 著者名/発表者名
      See Cheng Yim, Yi Herng Chan, Suzana Yusup, Khairiraihanna Johari, Armando T Quitain, Daniel Joe Dailin
    • 総ページ数
      18
    • 出版者
      Woodhead Publishing
    • ISBN
      978-0-12-817937-6

URL: 

公開日: 2019-12-27  

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