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2020 年度 実施状況報告書

Analyses of the Synergy of Sub/Supercritical H2O-CO2 System for Synthesis of Green Platform Chemicals

研究課題

研究課題/領域番号 17KK0118
研究機関熊本大学

研究代表者

キタイン アルマンド  熊本大学, 大学教育統括管理運営機構, 教授 (50504693)

研究期間 (年度) 2018 – 2021
キーワードhydrolysis / supercritical CO2 / subcritical water / Raman spectroscopy / functionalization / reduction / 5-HMF / glycosidic bond
研究実績の概要

Due to coronavirus-related pandemic, mobility of researchers and students was not possible this academic year. However, the following research-related and academic activities were carried out with Valladolid University. ① Mobility of an alumnus from Kumamoto University, under the Marie-Curie Individual Fellowship Program (Research Title: "Cascade Hydrolytic Recovery and Conversion of Suberin in High Pressure Media."). She was a doctoral student under the supervision of Prof. T Kida and Prof. AT Quitain. She will carry out research related to biomass utilization using microwave and supercritical fluid technologies in Valladolid University for 2 years starting October 2020.②Online lecture by Prof. MJ Cocero on“Perspectives on Biomass Utilization”, being offered at the Center for International Education and participated by a total of about 180 undergraduate students from Kumamoto University and Sepuluh Nopember Institute of Technology (ITS, Indonesia). ③Publication of a joint article in reputable journal in this field: “Supercritical CO2-subcritical H2O system: A green reactive separation medium for selective conversion of glucose to 5-hydroxymethylfurfural” that consolidates previous research outcomes of Prof. AT Quitain and his students in Valladolid University.

Experiments on nanodiamond provided by Prof. Anke Krueger of Wuerzburg University on CO2 reduction and sugar conversion to useful chemicals and fuels were also carried out here in Kumamoto University.

現在までの達成度 (区分)
現在までの達成度 (区分)

3: やや遅れている

理由

Due to corona virus-related pandemic, mobility of researcher and students was not possible this year.

今後の研究の推進方策

The application of nanodiamond on catalytic hydrothermal conversion of CO2 into useful chemicals or fuels will be further investigated utilizing the synergy of supercritical CO2 and subcritical H2O. Catalytic reduction of CO2 under hydrothermal conditions into useful compounds such as formic acid and methanol will be further elucidated by simply adding the carbon-based catalysts into the
system. Nanodiamond will be compared with our graphene oxide-based catalysts. If the pandemic situation gets better, the principal investigator will visit Wuerzburg University to functionalize carbon-based catalysts to improved yields of target materials - low molecular weight carboxylic acids and alcohols. The work on sugar conversion into useful chemicals will also be further investigated.

  • 研究成果

    (18件)

すべて 2021 2020

すべて 雑誌論文 (12件) (うち国際共著 12件、 査読あり 12件、 オープンアクセス 1件) 学会発表 (6件) (うち国際学会 5件、 招待講演 2件)

  • [雑誌論文] Supercritical CO2-subcritical H2O system: A green reactive separation medium for selective conversion of glucose to 5-hydroxymethylfurfural2021

    • 著者名/発表者名
      Inoue Ryuto、Agutaya Jonas Karl Christopher N.、Quitain Armando T.、Sasaki Mitsuru、Cocero Maria Jose、Kida Tetsuya
    • 雑誌名

      The Journal of Supercritical Fluids

      巻: 168 ページ: 105079~105079

    • DOI

      10.1016/j.supflu.2020.105079

    • 査読あり / 国際共著
  • [雑誌論文] Electrochemical hydrogen production from humid air using cation-modified graphene oxide membranes2021

    • 著者名/発表者名
      Hamidah Nur Laila、Shintani Masataka、Ahmad Fauzi Aynul Sakinah、Kitamura Shota、Mission Elaine G.、Hatakeyama Kazuto、Sasaki Mitsuru、Quitain Armando T.、Kida Tetsuya
    • 雑誌名

      Pure and Applied Chemistry

      巻: 93 ページ: 1~11

    • DOI

      10.1515/pac-2019-0807

    • 査読あり / 国際共著
  • [雑誌論文] A non-catalytic process to produce levulinic acid from the flesh fruits of trembesi (Samanea saman) using a subcritical water2021

    • 著者名/発表者名
      Pujiastuti Y A、Zullaikah S、Setiawan D、Fahrurozy I、Syafril A R、Prawira Y、Quitain A T
    • 雑誌名

      IOP Conference Series: Earth and Environmental Science

      巻: 649 ページ: 012028~012028

    • DOI

      10.1088/1755-1315/649/1/012028

    • 査読あり / 国際共著
  • [雑誌論文] Metal-Free Synthesis of HMF from Glucose Using the Supercritical CO2-Subcritical H2O Isopropanol System2020

    • 著者名/発表者名
      Agutaya Jonas Karl Christopher N.、Inoue Ryuto、Vin Tsie Samantha Siew、Quitain Armando T.、de la Pena-Garcia Jorge、Perez-Sanchez Horacio、Sasaki Mitsuru、Kida Tetsuya
    • 雑誌名

      Industrial & Engineering Chemistry Research

      巻: 59 ページ: 16527~16538

    • DOI

      10.1021/acs.iecr.0c03551

    • 査読あり / 国際共著
  • [雑誌論文] Graphene Oxide Membranes with Cerium-Enhanced Proton Conductivity for Water Vapor Electrolysis2020

    • 著者名/発表者名
      Hamidah Nur Laila、Shintani Masataka、Ahmad Fauzi Aynul Sakinah、Putri Ghina Kifayah、Kitamura Shota、Hatakeyama Kazuto、Sasaki Mitsuru、Quitain Armando T.、Kida Tetsuya
    • 雑誌名

      ACS Applied Nano Materials

      巻: 3 ページ: 4292~4304

    • DOI

      10.1021/acsanm.0c00439

    • 査読あり / 国際共著
  • [雑誌論文] Carbon-based potentiometric hydrogen sensor using a proton conducting graphene oxide membrane coupled with a WO3 sensing electrode2020

    • 著者名/発表者名
      Ahmad Fauzi Aynul Sakinah、Hamidah Nur Laila、Sato Shinya、Shintani Masataka、Putri Ghina Kifayah、Kitamura Shota、Hatakeyama Kazuto、Quitain Armando T.、Kida Tetsuya
    • 雑誌名

      Sensors and Actuators B: Chemical

      巻: 323 ページ: 128678~128678

    • DOI

      10.1016/j.snb.2020.128678

    • 査読あり / 国際共著
  • [雑誌論文] Green synthesis of sulfonated organosilane functionalized multiwalled carbon nanotubes and its catalytic activity for one-pot conversion of high free fatty acid seed oil to biodiesel2020

    • 著者名/発表者名
      Macawile Maria Cristina、Quitain Armando T.、Kida Tetsuya、Tan Raymond、Auresenia Joseph
    • 雑誌名

      Journal of Cleaner Production

      巻: 275 ページ: 123146~123146

    • DOI

      10.1016/j.jclepro.2020.123146

    • 査読あり / 国際共著
  • [雑誌論文] Synergizing Sulfonated Hydrothermal Carbon and Microwave Irradiation for Intensified Esterification Reaction2020

    • 著者名/発表者名
      Tumkot Laddawan、Quitain Armando T.、Boonnoun Panatpong、Laosiripojana Navadol、Kida Tetsuya、Shotipruk Artiwan
    • 雑誌名

      ACS Omega

      巻: 5 ページ: 23542~23548

    • DOI

      10.1021/acsomega.0c01660

    • 査読あり / オープンアクセス / 国際共著
  • [雑誌論文] Nitrogen, Sulfur Co-Doped Reduced Graphene Oxide: Synthesis and Characterization2020

    • 著者名/発表者名
      Abdul Mannan Md.、Hirano Yudai、Quitain Armando T.、Koinuma Michio、Kida Tetsuya
    • 雑誌名

      Micro and Nanosystems

      巻: 12 ページ: 129~134

    • DOI

      10.2174/1876402911666190722111138

    • 査読あり / 国際共著
  • [雑誌論文] Sulfonated Hydrothermal Carbon-Based Catalyzed Esterification under Microwave Irradiation: Optimization and Kinetic Study2020

    • 著者名/発表者名
      Tumkot Laddawan、Quitain Armando T.、Kida Tetsuya、Laosiripojana Navadol、Shotipruk Artiwan、Boonnoun Panatpong
    • 雑誌名

      Bulletin of Chemical Reaction Engineering & Catalysis

      巻: 15 ページ: 514~524

    • DOI

      10.9767/bcrec.15.2.7040.514-524

    • 査読あり / 国際共著
  • [雑誌論文] Application of a solid electrolyte CO2 sensor to the performance evaluation of CO2 capture materials2020

    • 著者名/発表者名
      Yamamoto Ayaka、Shinkai Takeshi、Loy Adrian Chun Minh、Mohamed Mustakimah、Baldovino Fritzie Hannah B.、Yusup Suzana、Quitain Armando T.、Kida Tetsuya
    • 雑誌名

      Sensors and Actuators B: Chemical

      巻: 315 ページ: 128105~128105

    • DOI

      10.1016/j.snb.2020.128105

    • 査読あり / 国際共著
  • [雑誌論文] Biogasoline production from linoleic acid via catalytic cracking over nickel and copper-doped ZSM-5 catalysts2020

    • 著者名/発表者名
      Gurdeep Singh Haswin Kaur、Yusup Suzana、Quitain Armando T.、Abdullah Bawadi、Ameen Mariam、Sasaki Mitsuru、Kida Tetsuya、Cheah Kin Wai
    • 雑誌名

      Environmental Research

      巻: 186 ページ: 109616~109616

    • DOI

      10.1016/j.envres.2020.109616

    • 査読あり / 国際共著
  • [学会発表] Mechanistic insights into the acid-catalyzed depolymerization of cellulose and fucoidan over graphene oxide under microwave irradiation2021

    • 著者名/発表者名
      Jonas Karl Christopher N. Agutaya et al.
    • 学会等名
      Workshop on ASEAN Biomass Conversion Technologies
    • 国際学会
  • [学会発表] Biodiesel Production from Microalgal Biomass via In-situ Transesterification using Carbon-Based Catalyst under Microwave Irradiation2021

    • 著者名/発表者名
      Yik Lam Kam et al.
    • 学会等名
      Workshop on ASEAN Biomass Conversion Technologies
    • 国際学会
  • [学会発表] Conversion of fructose into 5-HMF, FA and LA by Graphite Oxide Activated by Microwave2021

    • 著者名/発表者名
      Miyu Nakamura et al.
    • 学会等名
      International Symposium on Green Chemistry and Engineering : Multidisciplinary and Multicultural Exchanges towards the Attainment of the UN Sustainable Development Goals
    • 国際学会
  • [学会発表] Deamination of aspartic acid using supercritical carbon dioxide and graphene oxide2021

    • 著者名/発表者名
      Shunsuke Kimura et al.
    • 学会等名
      International Symposium on Green Chemistry and Engineering : Multidisciplinary and Multicultural Exchanges towards the Attainment of the UN Sustainable Development Goals
    • 国際学会
  • [学会発表] Globalizing Kumamoto University’s Advanced Green Technologies for Biomass Utilization2020

    • 著者名/発表者名
      Armando T. Quitain
    • 学会等名
      International Conference on Engineering and Industrial Technology
    • 国際学会 / 招待講演
  • [学会発表] Development of algal bioenergy systems for green and sustainable ASEAN region2020

    • 著者名/発表者名
      Armando T. Quitain, Suttichai Assubumrungrat, Siti Zullaikah, Raymond Tan, Joseph Auresenia, Tetsuya Kida
    • 学会等名
      Japan Petroleum Institute Annual Conference(
    • 招待講演

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公開日: 2021-12-27  

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