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2023 年度 実績報告書

Analyses of the Synergy of Sub/Supercritical H2O-CO2 System for Synthesis of Green Platform Chemicals

研究課題

研究課題/領域番号 17KK0118
研究機関熊本大学

研究代表者

キタイン アルマンド  熊本大学, 大学教育統括管理運営機構, 教授 (50504693)

研究期間 (年度) 2018 – 2023
キーワードhydrolysis / deamination / etherification / supercritical CO2 / sugars / bioflavonoids / 5-HMF / reduction
研究実績の概要

This academic year 2023, the following research activities and outcomes were achieved:

1. Further analysis of the CO2-H2O synergy on the degradation of various kinds of amino acids were performed, showing unique properties of the mixture around 250 oC. The application to removal of sugar moieties from flavonoid glycosides at relatively milder conditions below 150 oC, and glycerol conversion to fuel additives were also investigated. The CO2-H2O mixture showed unique synergistic effect on hydrolysis and etherification reactions, respectively.
2. Detailed investigation of the integration of this CO2-H2O synergy on carbon-based catalyst surface and a microwave susceptor showed the system to have promising effect on reactions even at a relatively milder bulk conditions of less than 150 oC.

European host professors also visited Kumamoto to give lectures to young researchers and students of Kumamoto University on biomass valorization and application of functionalized carbon-based catalysis.

  • 研究成果

    (16件)

すべて 2024 2023 2018

すべて 国際共同研究 (2件) 雑誌論文 (5件) (うち国際共著 5件、 査読あり 5件) 学会発表 (9件) (うち国際学会 7件、 招待講演 2件)

  • [国際共同研究] Wuerzburg University(Germany)2018

    • 年月日
      2018-09-12 – 2018-09-25 | 2019-08-112019-09-26 | 2021-02-102021-03-11
    • 国名
      ドイツ
    • 外国機関名
      Wuerzburg University
    • 主な海外共同研究者名
      Prof. Anke Krueger
    • 部局
      Institute of Organic Chemistry
    • 職名
      Professor
  • [国際共同研究] Valladolid University(Spain)2018

    • 年月日
      2018-04-26 – 2018-05-06 | 2018-08-112018-09-11 | 2019-02-092019-03-09 | 2020-02-092020-03-15 | 2020-08-122020-09-11 | 2022-08-222022-09-11 | 2023-03-192023-04-03 | 2023-09-082023-09-25 | 2024-03-162024-03-31
    • 国名
      スペイン
    • 外国機関名
      Valladolid University
    • 主な海外共同研究者名
      Prof. Maria Jose Cocero
    • 部局
      Dept of Chem Eng and Env Tech
    • 職名
      Professor
  • [雑誌論文] Oxidation of sulfide mineral and metal extraction analysis in the microwave-assisted roasting pretreatment of refractory gold ore2024

    • 著者名/発表者名
      Hapid Abdul、Zullaikah Siti、Mahfud、Kawigraha Adji、Sudiyanto Yanto、Benita Nareswari Ratika、Quitain Armando T.
    • 雑誌名

      Arabian Journal of Chemistry

      巻: 17 ページ: 105447~105447

    • DOI

      10.1016/j.arabjc.2023.105447

    • 査読あり / 国際共著
  • [雑誌論文] Ethanol sensing mechanism of ZnO nanorods revealed by DRIFT spectroscopy and DFT calculations2024

    • 著者名/発表者名
      Shinkai Takeshi、Agutaya Jonas Karl Christopher N.、Manna Biplab、Boepple Matthias、Iwai Masaru、Masumoto Keigo、Koga Kanako、Kawanami Koki、Nakamura Yusui、Quitain Armando T.、Suematsu Koichi、Inomata Yusuke、Barsan Nicolae、Kida Tetsuya
    • 雑誌名

      Journal of Materials Chemistry A

      巻: 12 ページ: 7564~7576

    • DOI

      10.1039/D3TA06486G

    • 査読あり / 国際共著
  • [雑誌論文] Application of Phosphonium- and Choline Chloride Based Deep Eutectic Solvents as Catalyst for Emulsifier Production from Low Quality Oil Assisted by Microwave Irradiation2024

    • 著者名/発表者名
      Sulaiman Miranda Amiroh、Zullaikah Siti、Yong Hoo Peng、Quitain Armando T.
    • 雑誌名

      Materials Science Forum

      巻: 1113 ページ: 139~154

    • DOI

      10.4028/p-o1Zllv

    • 査読あり / 国際共著
  • [雑誌論文] Manganese doped graphene oxide: Selective hydrogenation catalyst for converting 5-hydroxymethyl furfural to 5-methyl furfural2024

    • 著者名/発表者名
      Ahmad Muhammad Sohail、Nagata Yu、Masumoto Keigo、Inomata Yusuke、Hatakeyama Kazuto、Quitain Armando T.、Shotipruk Artiwan、Kida Tetsuya
    • 雑誌名

      Molecular Catalysis

      巻: 553 ページ: 113787~113787

    • DOI

      10.1016/j.mcat.2023.113787

    • 査読あり / 国際共著
  • [雑誌論文] Investigation of Calcium Oxide?Impregnated Zeolite Catalyst Toward Catalytic Pyrolysis of Oil Palm Empty Fruit Bunch: Bio-oil Yields, Characterizations, and Kinetic Study2023

    • 著者名/発表者名
      Lim Huei Yeong、Yusup Suzana、Acda Menandro N.、Chin Bridgid Lai Fui、Rianawati Elisabeth、Unrean Pornkamol、Yiin Chung Loong、Quitain Armando T.、Assabumrungrat Suttichai
    • 雑誌名

      BioEnergy Research

      巻: 17 ページ: 419~433

    • DOI

      10.1007/s12155-023-10618-2

    • 査読あり / 国際共著
  • [学会発表] Hydrothermal-Based Processing of Algal Biomass to Fuels and Chemicals2024

    • 著者名/発表者名
      Armando T. Quitain, Yuri Ogasawara, Shinnosuke Uchikado, Jonas Karl N. Agutaya, Yusuke Inomata, Suttichai Assabumrungrat, Tetsuya Kida
    • 学会等名
      1st Inter Symposium for Sustainable Algal Cultivation and Applications
    • 招待講演
  • [学会発表] Degradation of Heperidin Into High-Value Chemicals by CO2-H2O Synergy Under Microwave Irradiation,2024

    • 著者名/発表者名
      Kota Nishimure, Armando T. Quitain, Tetsuya Kida
    • 学会等名
      49th International Congress on Science, Technology and Technology-based Innovation, 2024
  • [学会発表] Progress on CO2-H2O Based Green Approaches for Biomass Valorization, , 20232023

    • 著者名/発表者名
      A. T. Quitain, T. Nagamine, S. Ichimaru, J.K.C.N. Agutaya, Y. Inomata, T. Kida
    • 学会等名
      19th European Meeting on Supercritical Fluids
    • 国際学会 / 招待講演
  • [学会発表] CO2-H2O Based Green Engineering for Algal Biomass Valorization2023

    • 著者名/発表者名
      Armando T. Quitain
    • 学会等名
      International Conference on Algal Biomass, Biofuels and Bioproducts
    • 国際学会
  • [学会発表] CO2-Intensified Hydrothermal Cleavage of Glycosidic Bond in Citrus Bioflavonoids,2023

    • 著者名/発表者名
      Quitain, A T, JKN Agutaya, M Sasaki, MJ Cocero, T Kida
    • 学会等名
      International Sovothermal and Hydrothermal Association (ISHA) Conference 2023
    • 国際学会
  • [学会発表] Deamination of Bio-oil Using Hydrothermal Liquefaction Intensified with Supercritical Carbon Dioxide2023

    • 著者名/発表者名
      Nagamine T., A. T. Quitain, Y. Inomata, T. Kida
    • 学会等名
      International Sovothermal and Hydrothermal Association (ISHA) Conference 2023
    • 国際学会
  • [学会発表] Mechanistic study of the deamination of algal biomass in the supercritical carbon dioxide-subcritical water system using aspartic acid as a model compound2023

    • 著者名/発表者名
      Nagamine Taisei, Armando T. Quitain, Yusuke Inomata and Tetsuya Kida
    • 学会等名
      International Conference on Algal Biomass, Biofuels and Bioproducts, 2023
    • 国際学会
  • [学会発表] Conversion of algal carbohydrates to 5-HMF using the microwave-irradiated graphene oxide under supercritical CO2 conditions2023

    • 著者名/発表者名
      Sumire Ichimaru, Armando T. Quitain, Yusuke Inomata and Tetsuya Kida
    • 学会等名
      International Conference on Algal Biomass, Biofuels and Bioproducts, 2023
    • 国際学会
  • [学会発表] Conversion of Carbohydrates to 5-HMF Using the Microwave-Irradiated Reduced Graphene Oxide Under Supercritical CO2 Conditions2023

    • 著者名/発表者名
      Sumire Ichimaru, Jonas Karl Christopher N. Agutaya, Armando T. Quitain, Yusuke Inomata, Tetsuya Kida,
    • 学会等名
      20th APCChE Congress/84th PIChE Annual Convention, 2023
    • 国際学会

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公開日: 2024-12-25  

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