フラーレン誘導体による多彩なナノ・メゾスコピック構造の作製と機能開拓

2008 年度 研究成果報告書

• 研究課題/領域番号: 18310081
• 研究種目: 基盤研究(B)
• 配分区分: 補助金
• 応募区分: 一般
• 研究分野: ナノ材料・ナノバイオサイエンス
• 研究機関: 独立行政法人物質・材料研究機構
• 研究代表者: 有賀 克彦 独立行政法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA主任研究者 (50193082)
• 研究期間 (年度): 2006 – 2008
• キーワード: ナノチューブ・フラーレン / 自己組織化 / 超分子化学 / ナノ材料 / マイクロ・ナノデバイス

研究概要

機能炭素ユニットであるフラーレンを材料として有効利用するため、ごく微細レベルで自由に成型加工しうる技術の開発を行った。フラーレンに炭化水素鎖を導入した化合物を各種有機溶媒中で、ワイア、球状、フラワー状等の構造へと組み上げることに成功した。フラワー状構造体を基板上に塗布することにより、超撥水性の表面を得た。また、純粋フラーレン物質を様々な液体間の界面でひし形や六角形のナノシートに成型できること、それらの一部は水を加えることによってナノロッドに変形できることも見出した。

研究成果

• [雑誌論文] Nanorod Driven Orientational Control of Liquid Crystal for Polarization-Tailored Electro-optic Devices, Acharya (2009)
  • 著者名/発表者名: Somobrata Kundu, Sudarshan; Hill, Jonathan P.; Richards, Gary J.; Ariga, Katsuhiko
  • 雑誌名: Adv. Mater. 21(9) ページ: 989-993
• [雑誌論文] Toward Volatile and Nonvolatile Molecular Memories: Fluorescence Switching Based on Fluoride-Triggered Interconversion of Simple Porphyrin Derivatives (2009)
  • 著者名/発表者名: Shundo, Atsuomi; Hill, Jonathan P.; Ariga, Katsuhiko
  • 雑誌名: Chem. Eur. J. 15(11) ページ: 2486-2490
• [雑誌論文] Supramolecular Templates for Nanoflake-Metal Surfaces (2009)
  • 著者名/発表者名: Shen, Yanfei; Wang, Jiaobing; Kuhlmann, Uwe; Hildebrandt, Peter; Ariga, Katsuhiko; Mohwald, Helmuth; Kurth, Dirk G.; Nakanishi, Takashi
  • 雑誌名: Chem. Eur. J. 15(12) ページ: 2763-2767
• [雑誌論文] Superconducting Nanocrystalline Tin Protected by Carbon (2009)
  • 著者名/発表者名: Pol, Vilas; Thiyagarajan, Pappannan; Acharya, Somobratra; Ariga, Katsuhiko; Felner, Israel
  • 雑誌名: Langmuir 25(5) ページ: 2582-2584
• [雑誌論文] Layer-by-Layer Films of Dual-Pore Carbon Capsules with Designable Selectivity of Gas Adsorption (2009)
  • 著者名/発表者名: Ji, Qingmin; Yoon, Suk Bon; Hill, Jonathan P.; Vinu, Ajayan; Yu, Jong-Sung; Ariga, Katsuhiko
  • 雑誌名: J. Am. Chem. Soc. 131(12) ページ: 4220-4221
• [雑誌論文] Solvent-Engineering for Shape-Shifter Pure Fullerene (C60) (2009)
  • 著者名/発表者名: Sathish, Marappan; Miyazawa, Kun'ichi; Hill, Jonathan; Ariga, Katsuhiko
  • 雑誌名: J. Am. Chem. Soc. 131(18) ページ: 6372-6373
• [雑誌論文] The Effect of Surface Free Energy on PDMS Transfer in Microcontact Printing, and its Application to ToF-SIMS to Probe Surface Energies (2009)
  • 著者名/発表者名: Yang, Li; Shirahata, Naoto; Saini, Gaurav; Zhang, Feng; Pei, Lei; Asplund, Matthew; Kurth, Dirk; Ariga, Katsuhiko; Sautter, Ken; Nakanishi, Takashi; Smentkowski, Vincent; Linford, Matthew
  • 雑誌名: Langmuir 25(10) ページ: 5674-5683
• [雑誌論文] Chiral Recognition at the Air-Water Interface (2008)
  • 著者名/発表者名: Ariga, Katsuhiko; Michinobu, Tsuyoshi; Nakanishi, Takashi; Hill, Jonathan P.
  • 雑誌名: Curr. Opin. Colloid Interface Sci. 13(1-2) ページ: 23-30
• [雑誌論文] Nanostructured Microspheres of MnO2 formed by Room Temperature Solution Processing (2008)
  • 著者名/発表者名: Hill, Jonathan P.; Alam, Sher; Ariga, Katsuhiko; Anson, Christopher E.; Powell, Annie K.
  • 雑誌名: Chem. Commun. (3) ページ: 383-385
• [雑誌論文] Nano-Carbon Superhydrophobic Surfaces Created from Fullerene Based Hierarchical Supramolecular Assemblies (2008)
  • 著者名/発表者名: Nakanishi, Takashi; Michinobu, Tsuyoshi; Yoshida, Kaname; Shirahata, Naoto; Ariga, Katsuhiko; Mohwald, Helmuth; Kurth, Dirk G.
  • 雑誌名: Adv. Mater. 20(3) ページ: 20(3)
• [雑誌論文] Stimuli-Free Auto-Modulated Material Release from Mesoporous Nano-Compartment Films (2008)
  • 著者名/発表者名: Ji, Qingmin; Miyahara, Masahiko; Hill, Jonathan P.; Acharya, Somobrata; Vinu, Ajayan; Yoon, Suk Bon; Yu, Jong-Sung; Sakamoto, Kazutami; Ariga, Katsuhiko
  • 雑誌名: J. Am. Chem. Soc. 130(8) ページ: 2376-2377
• [雑誌論文] Formation of Nano-Domains Confined in Two-Dimensional Molecular Plane (2008)
  • 著者名/発表者名: Oishi, Yushi; Kato, Takayuki; Narita, Takayuki; Ariga, Katsuhiko; Kunitake, Toyoki
  • 雑誌名: Langmuir 24(5) ページ: 1682-1685
• [雑誌論文] Novel Three Dimensional Cubic Fm3m Mesoporous Aluminosilicates with Tailored Cage Type Pore Structure and High Aluminum Content (2008)
  • 著者名/発表者名: Srinivasu, Pavuluri; Alam, Sher; Balasubramanian, Veerappan V.; Velmathi, Sivan; Sawant, Dhanashri P.; Bohlmann, Winfred; Mirajkar, Subhash P.; Ariga, Katsuhiko; Halligudi, Shivappa B.; Vinu, Ajayan
  • 雑誌名: Adv. Funct. Mater. 18(4) ページ: 640-651
• [雑誌論文] Heteropoly Acid Encapsulated SBA-15/TiO2 Nanocomposites and Their Unusual Performance in Acid-Catalyzed Organic Transformations, Sawant (2008)
  • 著者名/発表者名: Dhanashri P.; Justus, Josena; Balasubramanian, Veerappan V.; Ariga, Katsuhiko; Srinivasu, Pavuluri; Velmathi, Sivan; Halligudi, Shivappa B.; Vinu, Ajayan
  • 雑誌名: Chem. Eur. J. 14(10) ページ: 3200-3212
• [雑誌論文] Ultra Narrow PbS Nanorods with Intense Fluorescence (2008)
  • 著者名/発表者名: Acharya, Somobrata; Gautam, Ujjal K.; Sasaki, Toshio; Bando, Yoshio; Golan, Yuval; Ariga, Katsuhiko
  • 雑誌名: J. Am. Chem. Soc. 130(14) ページ: 4594-4595
• [雑誌論文] Growth and electrical properties of N,N'-bis(n-pentyl)terrylene-3,4:11,12- tetracarboximide thin films (2008)
  • 著者名/発表者名: Petit, Matthieu; Hayakawa, Ryoma; Shirai, Yasuhiro; Wakayama, Yutaka Wakayama; Hill, Jonathan P.; Ariga, Katsuhiko; Chikow, Toyohiro
  • 雑誌名: Appl. Phys. Lett. 92(16) ページ: 163301
• [雑誌論文] Direct Synthesis and the Morphological Control of Highly Ordered Two-Dimensional p6mm Mesoporous Niobium Silicates with High Niobium Content (2008)
  • 著者名/発表者名: Srinivasu, Pavuluri; Anand, Chokkalingam; Alam, Sher; Ariga, Katsuhiko; Halligudi, Shiva B.; Balasubramanian, Veerappan V.; Vinu, Ajayan
  • 雑誌名: J. Phys. Chem. C 112(27) ページ: 10130-10140
• [雑誌論文] Twisted, Two-faced Porphyrins as Hosts for Bispyridyl Fullerenes: Construction and Photophysical Properties (2008)
  • 著者名/発表者名: Xie, Yongshu; Hill, Jonathan P.; Schumacher, Amy Lea; Sandanayaka, Atula, S. D.; Araki, Yasuyuki; Karr, Paul A.; Labuta, Jan; D'Souza, Francis; Ito, Osamu; Anson, Christopher, E.; Powell, Annie, K.; Ariga, Katsuhiko
  • 雑誌名: J. Phys. Chem. C 112(28) ページ: 10559-10572
• [雑誌論文] A Layered Mesoporous Carbon Sensor Based on Nanopore-Filling Cooperative Adsorption in the Liquid Phase (2008)
  • 著者名/発表者名: Ariga, Katsuhiko; Vinu, Ajayan; Ji, Qingmin; Ohmori, Osamu; Hill, Jonathan P.; Acharya, Somobrata; Koike, Jun; Shiratori, Seimei, Angew
  • 雑誌名: Chem. Int. Ed. 47(38) ページ: 7254-7257
• [雑誌論文] Decomposition of Dinuclear Manganese Complexes for Preparation of Nanostructured Oxide Materials (2008)
  • 著者名/発表者名: ill, Jonathan P.; Palza, Humberto; Alam, Sher; Ariga, Katsuhiko; Schumacher, Amy; D'Souza, Francis; Anson, Christopher; Powell, Annie
  • 雑誌名: Inorg. Chem. 47(18) ページ: 8306-8314
• [雑誌論文] Multi-dimensional Control of Surfactant Guided Assemblies of Quantum Gold Particle (2008)
  • 著者名/発表者名: Ji, Qingmin; Acharya, Somobrata; Hill, Jonathan P.; Richards, Gary J.; Ariga, Katsuhiko
  • 雑誌名: Adv. Mater. 20(21) ページ: 4027-4032
• [雑誌論文] Three-Dimensional Ultralarge-Pore Ia3d Mesoporous Silica with Various Pore Diameters and Their Application in Biomolecule Immobilization (2008)
  • 著者名/発表者名: Vinu, Ajayan; Gokulakrishnan, Narasimhan; Balasubramanian, Veerappan V.; Alam, Sher; Kapoor, Mahendra P.; Ariga, Katsuhiko; Mori, Toshiyuki
  • 雑誌名: Chem. Eur. J. 14(36) ページ: 11529-11538
• [雑誌論文] Catalysis of a Peptidic Micellar Assembly Covalently Immobilized within Mesoporous Silica Channels: Importance of Amphiphilic Spatial Design (2007)
  • 著者名/発表者名: Otani, Wataru; Kinbara, Kazushi; Zhang, Qingmin; Ariga, Katsuhiko; Aida, Takuzo
  • 雑誌名: Chem. Eur. J. 13(6) ページ: 1731-1736
• [雑誌論文] Carboxy-Mesoporous Carbon and Its Excellent Adsorption Capability for Proteins (2007)
  • 著者名/発表者名: Vinu, Ajayan; Hossian, Kazi Zakir; Srinivasu, Pavuluri; Miyahara, Masahiko; Anandan, Srinivasan; Gokulakrishnan, Narasimhan; Mori, Toshiyuki; Ariga, Katsuhiko; Balasubramanian, Veerappan Vaithilingam
  • 雑誌名: J. Mater. Chem. 17(18) ページ: 1819-1825
• [雑誌論文] Layer-by-Layer Assembly as a Versatile Bottom-Up Nanofabrication Technique for Exploratory Research and Realistic Application (2007)
  • 著者名/発表者名: Ariga, Katsuhiko; Hill, Jonathan P.; Ji, Qingmin
  • 雑誌名: Phys. Chem. Chem. Phys. 9(19) ページ: 2319-2340
• [雑誌論文] Supramolecular Triad and Pentad Composed of Zinc Porphyrin(s), Oxoporphyrinogen, and Fullerene(s): Design and Electron Transfer Studies, Schumacher (2007)
  • 著者名/発表者名: Amy Lea; Sandanayaka, Atula, S. D.; Hill, Jonathan, P.; Ariga, Katsuhiko; Karr, Paul, A.; Araki, Yasuyuki; Ito, Osamu; D'Souza, Francis
  • 雑誌名: Chem. Eur. J. 13(16) ページ: 4628-4635
• [雑誌論文] Preparation and Characterization of a Novel Organic-Inorganic Nanohybrid "Cerasome" Formed with Liposomal Membrane and Silicate Surface (2007)
  • 著者名/発表者名: Katagiri, Kiyofumi; Hashizume, Mineo; Ariga, Katsuhiko; Terashima, Takashi; Kikuch, Jun-ichi
  • 雑誌名: Chem. Eur. J. 13(18) ページ: 5272-5281
• [雑誌論文] Structural Study of the Thermally Induced and Photoinduced Phase Transitions of the 1,3,5-Trithia-2,4,6-Triazapentalenyl (TTTA) Radical (2007)
  • 著者名/発表者名: Naumov, Pance; Hill, Jonathan P.; Sakurai, Kenji; Tanaka, Masahiko; Ariga, Katsuhiko
  • 雑誌名: J. Phys. Chem. A 111(28) ページ: 6449-6455
• [雑誌論文] Three Dimensional Cage Type Mesoporous CN-Based Hybrid Material with Very High Surface Area and Pore Volume (2007)
  • 著者名/発表者名: Vinu, Ajayan; Srinivasu, Pavuluri; Sawant, Dhanashri P.; Mori, Toshiyuki; Ariga, Katsuhiko; Chang, Jong-San; Jhung, Sung-Hwa; Balasubramanian, Veerappan Vaithilingam; Hwang, Young Kyu
  • 雑誌名: Chem. Mater. 19(17) ページ: 4367-4372
• [雑誌論文] Self-Assembled Microstructures of Functional Molecules (2007)
  • 著者名/発表者名: Ariga, Katsuhiko; Nakanishi, Takashi; Hill, Jonathan P.
  • 雑誌名: Curr. Opin. Colloid Interface Sci. 12(3) ページ: 106-120
• [雑誌論文] One-Pot Separation of Tea Components through Selective Adsorption on Pore-Engineered Nanocarbon, Carbon Nanocage (2007)
  • 著者名/発表者名: Ariga, Katsuhiko; Vinu, Ajayan; Miyahara, Masahiko; Hill, Jonathan P.; Mori, Toshiyuki
  • 雑誌名: J. Am. Chem. Soc 129(36) ページ: 11022-11023
• [雑誌論文] Coordination Chemistry and Supramolecular Chemistry in Mesoporous Nanospace (2007)
  • 著者名/発表者名: Ariga, Katsuhiko; Vinu, Ajayan; Hill, Jonathan P.; Mori, Toshiyuki
  • 雑誌名: Coord. Chem. Rev. 251(21-24) ページ: 2562-2591
• [雑誌論文] elf-Assembly Structures of a Phenol-Substituted Porphyrin in the Solid State: Hydrogen Bonding (2007)
  • 著者名/発表者名: Kagome Lattice, and Defect Tolerance, Hill, Jonathan P.; Wakayama, Yutaka; Akada, Misaho; Ariga, Katsuhiko
  • 雑誌名: J. Phys. Chem. C 111(44) ページ: 16174-16180
• [雑誌論文] Tautomerism in Novel Oxocorrologens (2007)
  • 著者名/発表者名: Xie, Yongshu; Hill, Jonathan P.; Schumacher, Amy Lea; Karr, Paul A.; D'Souza, Francis; Anson, Christopher E.; Powell, Annie K.; Ariga, Katsuhiko
  • 雑誌名: Chem. Eur. J. 13(35) ページ: 9824-9833
• [雑誌論文] Flower-Shaped Supramolecular Assemblies: Hierarchical Organization of a Fullerene Bearing Long Aliphatic Chains (2007)
  • 著者名/発表者名: Nakanishi, Takashi; Ariga, Katsuhiko; Michinobu, Tsuyoshi; Yoshida, Kaname; Takahashi, Hirokazu; Teranishi, Toshiharu; Mohwald, Helmuth; Kurth, Dirk G.
  • 雑誌名: Small 3(12) ページ: 2019-2023
• [雑誌論文] Preparation and Catalytic Performances of Ultra Large Pore TiSBA-15 Mesoporous Molecular Sieves with Very High Ti Content (2006)
  • 著者名/発表者名: Vinu, A.; Srinivasu, P.; Miyahara, M.; Ariga, K.
  • 雑誌名: J. Phys. Chem. B 110(2) ページ: 801-806
• [雑誌論文] Control of Morphology and Helicity of Chiral Mesoporous Silica (2006)
  • 著者名/発表者名: Jin, Haiying; Liu, Zheng; Ohsuna, Tetsu; Terasaki, Osamu; Inoue, Yoshihisa; Sakamoto, Kazutami; Nakanishi, Takashi; Ariga, Katsuhiko; Che, Shunai
  • 雑誌名: Adv. Mater. 18(5) ページ: 593-596
• [雑誌論文] Perfectly Straight Nanowires of Fullerenes Bearing Long Alkyl-Chains on Graphite (2006)
  • 著者名/発表者名: Nakanishi, Takashi; Miyashita, Naoko; Michinobu, Tsuyoshi; Wakayama, Yutaka; Tsuruoka, Tohru; Ariga, Katsuhiko; Kurth, Dirk G.
  • 雑誌名: J. Am. Chem. Soc. J. Am. Chem. Soc. ページ: 6328-6329
• [雑誌論文] A Paradigm Shift in the Field of Molecular Recognition at the Air-Water Interface: from Static to Dynamic (2006)
  • 著者名/発表者名: Ariga, Katsuhiko; Nakanishi, Takashi; Hill, Jonathan P.
  • 雑誌名: Soft Matter 2(6) ページ: 465-477
• [雑誌論文] Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation (2006)
  • 著者名/発表者名: Hill, Jonathan P.; Wakayama, Yutaka; Schmitt, Wolfgang; Tsuruoka, Tohru; Nakanishi, Takashi; Zandler, Melvin L.; McCarty, Amy L.; D'Souza, Francis; Milgrom, Lionel R.; Ariga, Katsuhiko
  • 雑誌名: Chem. Commun. (22) ページ: 2320-2322
• [雑誌論文] Characterization and Catalytic Performances of Three Dimensional Mesoporous FeSBA-1 Catalysts, Vinu, Ajayan; Krithiga, Thangavelu; Balasubramanian (2006)
  • 著者名/発表者名: Veerappan V.; Asthana, Anjana; Srinivasu, Pavuluri; Mori, Toshiyuki; Ariga, Katsuhiko; Ramanath, Ganapathiraman; Ganesan, Pethuraja G.
  • 雑誌名: J. Phys. Chem. B 110(24) ページ: 11924-11931
• [雑誌論文] Room Temperature Liquid Fullerenes: An Uncommon Morphology of C60 Derivatives (2006)
  • 著者名/発表者名: Michinobu, Tsuyoshi; Nakanishi, Takashi; Hill, Jonathan P; Funabashi, Masahiro; Ariga, Katsuhiko
  • 雑誌名: J. Am. Chem. Soc. 128 (32) ページ: 10384-10385
• [雑誌論文] Mechanical Control of Enantioselectivity of Amino Acid Recognition by Cholesterol-Armed Cyclen Monolayer at the Air-Water Interface (2006)
  • 著者名/発表者名: Michinobu, Tsuyoshi; Shinoda, Satoshi; Nakanishi, Takashi; Hill, Jonathan P.; Fujii, Kazuko; Player, Tomoko N.; Tsukube, Hiroshi; Ariga, Katsuhiko
  • 雑誌名: J. Am. Chem. Soc. 128(45) ページ: 14478-14479
• [雑誌論文] Soft Langmuir-Blodgett Technique for Hard Nanomaterials
  • 著者名/発表者名: Acharya, Somobrata; Hill, Jonathan P.; Ariga, Katsuhiko
  • 雑誌名: Adv. Mater. (in press) ページ: DOI: 10.1002/adma.200802648
• [雑誌論文] Hierarchic Nanostructure for Auto-Modulation of Material Release: Mesoporous Nanocompartment Films
  • 著者名/発表者名: Ji, Qingmin; Acharya, Somobrata; Hill, Jonathan P.: Vinu, Ajayan; Yoon, Suk Bon; Yu, Jong-Sung; Sakamoto, Kazutami; Ariga, Katsuhiko
  • 雑誌名: Adv. Funct. Mater. (in press) ページ: DOI: 10.1002/adfm.200801762
• [雑誌論文] Diverse Self-assembly in Soluble Oligoazaacenes: A Microscopy Study
  • 著者名/発表者名: Richards, Gary J.; Hill, Jonathan P.; Okamoto, Ken; Shundo, Atsuomi; Akada, Misaho; Elsegood, Mark R. J.; Mori, Toshiyuki; Ariga, Katsuhiko
  • 雑誌名: Langmuir (in press) ページ: DOI: 10.1021/la8041633
• [雑誌論文] Synthesis of New Red Emitting Single-phase Europium Oxycarbonate
  • 著者名/発表者名: Pol, Vilas G.; Calderon-Moreno, Jose M.; Popa, Monica; Acharya, Somobratra; Ariga, Katsuhiko
  • 雑誌名: Thiyagarajan, P., Inorg. Chem. (in press)
• [雑誌論文] Evidence for a ball-shaped cyclen cyclophane: an experimental and first principles study
  • 著者名/発表者名: Hill, Jonathan P.; Scipioni, Roberto; Boero, Mauro; Wakayama, Yutaka; Akada, Misaho; Miyazaki, Tsuyoshi; Ariga, Katsuhiko
  • 雑誌名: Phys. Chem. Chem. Phys. (in press) ページ: DOI:10.1039/b822802g
• [雑誌論文] Advances in Biomimetic and Nanostructured Biohybrid Materials
  • 著者名/発表者名: Ruiz-Hitzky, Eduardo; Darder, Margarita; Aranda, Pilar; Ariga, Katsuhiko
  • 雑誌名: Adv. Mater. (in press)