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2018 年度 実績報告書

分子認識界面に立脚した選択部-センサ一体型システムによる肺がんマーカー分子の識別

研究課題

研究課題/領域番号 18J12622
研究機関九州大学

研究代表者

ZHU Zetao  九州大学, 総合理工学府, 特別研究員(DC2)

研究期間 (年度) 2018-04-25 – 2020-03-31
キーワードMetal oxide nanowires / Vapor liquid solid / Impurity doping / Carrier density control / Doping homogeneity
研究実績の概要

Wide range control of a carrier density has played an essential role on developments of semiconductor devices. However, such control of carrier density via an impurity doping has been impossible for semiconducting oxide nanowires due to the occurrence of unintentional carrier doping. Here we demonstrate 6 orders of magnitude control of conductivity of Sb-doped SnO2 nanowires grown via true vapor-liquid-solid (VLS) process. Strictly tailoring two crystal growth interfaces (liquid-solid: LS and vapor-solid: VS) is required to suppress an unintentional carrier doping in presence of impurity dopants. This wide range electrical controllability of single crystalline oxide nanowires will be a foundation to design various electronic device applications utilizing their semiconducting properties.

現在までの達成度 (区分)
現在までの達成度 (区分)

1: 当初の計画以上に進展している

理由

In this year, I conduct the research about the crystal growth and impurity doping behavior of single crystal metal oxide nanowires fabricated via vapor-liquid-solid (VLS) process. In details, the impact of interfacial (LS and VS) selective growth on the electrical transport property of impurity doped nanowires is clarified. Here 6 orders of magnitude control of electrical conductivity of single crystalline Sb-doped SnO2 nanowires is demonstrated. This electrical conductivity range via an intentional impurity doping is the widest of the ones in metal oxide semiconducting nanowires reported so far. This wide range electrical conductivity controllability of single crystalline metal oxide nanowires will be a foundation for the various electronic device applications.

今後の研究の推進方策

VOCs (volatile organic compounds) detection/discrimination in human’s exhaled breath by electronic devices is a crucially important issue in terms of the disease-related biomarkers. In this work, I propose an original selector/sensor device system to distinguish a lung cancer marker of nonanal (C9 aldehyde) among the similar molecules of octanal and decanal (C8 and C10 aldehyde).
In this year, the details of research plan is as follows. 1) Adsorption mechanism of nonanal on Sb-SnO2 nanowire array will be studied by combining the p-MAIRS, photoluminescence characterization, and molecular simulation. 2) The electrical discrimination of nonanal among mixtures of C8, C9, C10 aldehyde will be demonstrated using the on-chip selector-sensor devices based on the results obtained so far.

  • 研究成果

    (3件)

すべて 2019 2018

すべて 雑誌論文 (1件) (うち国際共著 1件、 査読あり 1件) 学会発表 (2件) (うち国際学会 1件)

  • [雑誌論文] Engineering Nanowire-Mediated Cell Lysis for Microbial Cell Identification2019

    • 著者名/発表者名
      Yasui Takao、Yanagida Takeshi、Shimada Taisuke、Otsuka Kohei、Takeuchi Masaki、Nagashima Kazuki、Rahong Sakon、Naito Toyohiro、Takeshita Daiki、Yonese Akihiro、Magofuku Ryo、Zhu Zetao、Kaji Noritada、Kanai Masaki、Kawai Tomoji、Baba Yoshinobu
    • 雑誌名

      ACS Nano

      巻: 13 ページ: 2262-2273

    • DOI

      10.1021/acsnano.8b08959

    • 査読あり / 国際共著
  • [学会発表] Dual Impact of Impurity on Crystal Growth Interface and Electrical Homogeneity of Metal Oxide Nanowires in Vapor-Liquid-Solid Process2018

    • 著者名/発表者名
      Z. Zhu, T. Takahashi, K. Nagashima, M. Suzuki, M. Kanai, G. Zhang, H. Anzai and T. Yanagida
    • 学会等名
      2018 International Conference on Solid State Device and Materials
    • 国際学会
  • [学会発表] Dual Impact of Impurity on Crystal Growth Interface and Electrical Homogeneity of Metal Oxide Nanowires in Vapor-Liquid-Solid Process2018

    • 著者名/発表者名
      Z. Zhu, K. Nagashima, T. Takahashi, M. Suzuki, M. Kanai, G. Zhang, T. Hosomi, H. Anzai and T. Yanagida
    • 学会等名
      平成30年度応用物理学会九州支部学術講演会

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公開日: 2019-12-27  

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