• 研究課題をさがす
  • 研究者をさがす
  • KAKENの使い方
  1. 課題ページに戻る

2018 年度 実績報告書

鉱物触媒水熱反応を用いた二酸化炭素の地中資源化システム

研究課題

研究課題/領域番号 18J12695
研究機関東北大学

研究代表者

WANG JIAJIE  東北大学, 環境科学研究科, 特別研究員(DC2)

研究期間 (年度) 2018-04-25 – 2020-03-31
キーワードOlivine / serpentinization / carbonation / Hydrogen production / CO2 storage / Hydrocarbon
研究実績の概要

In this research year, the strategies of H2 production and CO2 mineralization by olivine serpentinization and carbonation have been successfully combined in the CO2-rich hydrothermal system. The effects of various reaction conditions have been investigated and published in 2 Journal papers and 6 conferences.
Higher NaHCO3 concentration significantly promoted H2 generation, the results were summarized in the paper published in "Journal of CO2 utilization(IF:6.141)" and international conference of "ISOPE-2018". The effects of temperature were summarized in the paper accepted by "International Journal of Hydrogen Energy (IF: 4.229)".
The high H2 production we realized now can support further CO2 hydrogenation with addition of mineral catalyst.

現在までの達成度 (区分)
現在までの達成度 (区分)

2: おおむね順調に進展している

理由

The research we proposed before was the CO2 hydrogenation with the utilization of mineral catalysts in a hydrothermal georeactor. The topic is still included in our research; however, the research contents have expanded now. To facilitate hydrocarbon generation, H2 production is very important, which is also one kind of clean energy.
One year has been taken to elevate the H2 production from olivine alteration, and significant achievements have been made. The results has been summarized in 2 journal papers and 3 conference papers.
Also, the effect of mineral catalysts (e.g., magnetite and chromite) we proposed before have been experimentally studied and will be summarized in the next research year.
So I think the research was conducted well, although not all of the contents are in the plan.

今後の研究の推進方策

1) The catalytic abilities of magnetite and chromite were not good according to the present data, so the effect of other mineral catalysts will be further studied, include the operation conditions, such as dosage, loading position.
2) H2 can be produced during olivine alteration under CO2-rich conditions. However, olivine in the natural geological setting is commonly associated with pyroxene, the influence is still poorly understood and will be studies in the next research year.
3) Simulation. After getting the experimental data, we plan to build models to simulate the reaction process, such as how the heat accumulated and how the minerals be formed, which can explained the feasibility of field application.
4) Doctor thesis writing and final presentation preparation.

  • 研究成果

    (9件)

すべて 2019 2018 その他

すべて 雑誌論文 (2件) (うち査読あり 2件) 学会発表 (6件) (うち国際学会 4件) 備考 (1件)

  • [雑誌論文] Acceleration of hydrogen production during water-olivine-CO2 reactions via high-temperature-facilitated Fe(II) release2019

    • 著者名/発表者名
      Wang Jiajie、Watanabe Noriaki、Okamoto Atsushi、Nakamura Kengo、Komai Takeshi
    • 雑誌名

      International Journal of Hydrogen Energy

      巻: 44 ページ: 11514~11524

    • DOI

      10.1016/j.ijhydene.2019.03.119

    • 査読あり
  • [雑誌論文] Enhanced hydrogen production with carbon storage by olivine alteration in CO2-rich hydrothermal environments2019

    • 著者名/発表者名
      Wang Jiajie、Watanabe Noriaki、Okamoto Atsushi、Nakamura Kengo、Komai Takeshi
    • 雑誌名

      Journal of CO2 Utilization

      巻: 30 ページ: 205~213

    • DOI

      10.1016/j.jcou.2019.02.008

    • 査読あり
  • [学会発表] NaHCO3-promoted olivine weathering with H2 generation and CO2 sequestration in alkaline hydrothermal system2019

    • 著者名/発表者名
      Wang Jiajie、Watanabe Noriaki、Okamoto Atsushi、Nakamura Kengo、Komai Takeshi
    • 学会等名
      9th International Conference on Future Environment and Energy
    • 国際学会
  • [学会発表] Simultaneous olivine alteration and carbonation in CO2-rich geological condition: Mineral change and products investigation2018

    • 著者名/発表者名
      Wang Jiajie 、Nakamura Kengo、Watanabe Noriaki、Komai Takeshi
    • 学会等名
      15th International workshop on water dynamics
    • 国際学会
  • [学会発表] CO2の貯蔵を利用したエネルギー生産:地殻リアクターの自然加熱中におけるカンラン石の結晶構造の変化2018

    • 著者名/発表者名
      Wang Jiajie 、Nakamura Kengo、Watanabe Noriaki、Komai Takeshi
    • 学会等名
      平成30年度 資源・素材学会東北支部春季大会
  • [学会発表] Simultaneous Olivine Alteration and Carbonation in CO2-Rich Geological Condition2018

    • 著者名/発表者名
      Wang Jiajie 、Nakamura Kengo、Watanabe Noriaki、Komai Takeshi
    • 学会等名
      International Society of Offshore and Polar Engineers
    • 国際学会
  • [学会発表] CO2リッチ水熱環境における橄欖石の加速風化を用いた水素生成と炭素固定2018

    • 著者名/発表者名
      Wang Jiajie、Watanabe Noriaki、Okamoto Atsushi、Nakamura Kengo、Komai Takeshi
    • 学会等名
      日本地熱学会 平成30年学術講演会(東京大会)
  • [学会発表] Simultaneous H2 production with carbon storage by enhanced olivine weathering in laboratory-scale: An investigation of CO2 effect2018

    • 著者名/発表者名
      Wang Jiajie、Watanabe Noriaki、Okamoto Atsushi、Nakamura Kengo、Komai Takeshi
    • 学会等名
      The Second International Conference on Materials Chemistry and Environmental Protection
    • 国際学会
  • [備考] 駒井-渡邉研究室ホームページ

    • URL

      http://www.kankyo.tohoku.ac.jp/teacher/senshin008.html

URL: 

公開日: 2019-12-27  

サービス概要 検索マニュアル よくある質問 お知らせ 利用規程 科研費による研究の帰属

Powered by NII kakenhi