研究実績の概要 |
By performing electrochemical anodization on Ti29Nb13Ta4.6Zr alloys, quaternary Ti-Nb-Ta-Zr-O (TNTZO) mixed-oxide nanotube arrays with controllable geometric features were prepared. Compared with pristine TiO2, the TNTZO photoanodes exhibited noticeably enhanced photoactivity toward solar water splitting. The analytic results of time-resolved PL, EIS, and Voc decay measurements manifest that the superior photoactivity of TNTZO originated from the introduction of Nd, Ta, and Zr elements, which enhanced the amount of accessible charge carriers, modified the electronic structure, and improved the hole-transfer kinetics for expediting water splitting. A paper entitled "Mechanistic Insights into Photodegradation of Organic Dyes Using Heterostructure Photocatalysts" was published in Catalyst in 2019, and this paper is selected as best paper award in 2021. 3 Papers were published in 2020. A paper entitled "Reduced graphene oxides-wrapped ZnO with notable photocatalytic property" was published in Journal of the Taiwan Institute of Chemical Engineers. Another paper entitled“Incorporating graphene quantum dots to enhance the photoactivity of CdSe-sensitized TiO2 nanorods for solar hydrogen production”was published in Journal of Materials Chemistry in 2020, and was selected as the back cover story. A invited review paper entitled "Near infrared-driven photoelectrochemical water splitting: Review and future prospects" was published in Arabian Journal of Chemistry in 2020.
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