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2019 年度 実績報告書

金属酸化物,及びリン酸塩を骨格に有する新規メソ多孔体の合成と応用

研究課題

研究課題/領域番号 19F19070
研究機関国立研究開発法人物質・材料研究機構

研究代表者

山内 悠輔  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA主任研究者 (10455272)

研究分担者 BHANJA PIYALI  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 外国人特別研究員
研究期間 (年度) 2019-04-25 – 2021-03-31
キーワード多孔体
研究実績の概要

Porous nanomaterials have attracted immense attention due to their distinctive features such as tunable pore architectures, large pore volumes, and high specific surface areas. In particular, metal oxides and metal phosphates are highly stable, and their nanostructures can be tuned by using different templates. The major purpose of this research is to design novel porous nanomaterials which can be applied to several applications in a wide range of research areas such as energy generation and storage. Furthermore, carbon dioxide fixation and its conversion to highly valued fine chemicals and fuels can largely mitigate this greenhouse gas. Thus, the purpose of this research is to develop sustainable catalysts.
In this year, we synthesized several mesoporous metal phosphates and metal oxides using aqueous sol-gel routes at different synthetic conditions. We also applied water-alcohol mixture in these sol-gel synthesis processes to obtain stable and highly ordered mesophases. Apart from utilizing self-assembly of surfactants in aqueous and mixed solvent phases, evaporation induced self-assembly route was also utilized for designing mesoporous metal phosphates and metal oxides. Some of results were published already in international journals.

現在までの達成度 (区分)
現在までの達成度 (区分)

1: 当初の計画以上に進展している

理由

すべての記載事項を着実に達成している.

今後の研究の推進方策

Mesoporous metallophosphates containing different transition and non-transition reactive metal component will be designed using surfactant templating routes. Apart from utilizing the supramolecular assembly of the surfactants in aqueous and mixed solvent phases, evaporation induced self-assembly route will also be utilized for designing periodic mesoporous metal oxide and metallophosphate materials. Non-aqueous solvents will be used under acidic pH conditions to hydrolyze the metal and phosphate precursors in the presence of different non-ionic triblock copolymers as template. This will be followed by the polycondensation of these inorganic nuclei under slow evaporation process. Further, calcination of the dried gel at elevated temperature will resulted in the formation of metal oxide and metallophosphate mesophases.

  • 研究成果

    (4件)

すべて 2020 2019

すべて 雑誌論文 (4件) (うち国際共著 4件、 査読あり 4件)

  • [雑誌論文] Facile Synthesis of Nanoporous Transition Metal‐Based Phosphates for Oxygen Evolution Reaction2020

    • 著者名/発表者名
      Bhanja Piyali、Kim Yena、Paul Bappi、Lin Jianjian、Alshehri Saad M.、Ahamad Tansir、Kaneti Yusuf Valentino、Bhaumik Asim、Yamauchi Yusuke
    • 雑誌名

      ChemCatChem

      巻: --- ページ: ---

    • DOI

      10.1002/cctc.201901803

    • 査読あり / 国際共著
  • [雑誌論文] Crystalline Porous Organic Polymer Bearing -SO3H Functionality for High Proton Conductivity2020

    • 著者名/発表者名
      Bhanja Piyali、Palui Arnab、Chatterjee Sauvik、Kaneti Yusuf Valentino、Na Jongbeom、Sugahara Yoshiyuki、Bhaumik Asim、Yamauchi Yusuke
    • 雑誌名

      ACS Sustainable Chemistry & Engineering

      巻: 8 ページ: 2423~2432

    • DOI

      10.1021/acssuschemeng.9b06234

    • 査読あり / 国際共著
  • [雑誌論文] Iron phosphide anchored nanoporous carbon as an efficient electrode for supercapacitors and the oxygen reduction reaction2019

    • 著者名/発表者名
      Yousef Ahmed K.、Kim Yena、Bhanja Piyali、Mei Peng、Pramanik Malay、Sanad M. M. S.、Rashad M. M.、El-Sayed A. Y.、Alshehri Abdulmohsen Ali、Alghamdi Yousef Gamaan、Alzahrani Khalid Ahmed、Ide Yusuke、Lin Jianjian、Yamauchi Yusuke
    • 雑誌名

      RSC Advances

      巻: 9 ページ: 25240~25247

    • DOI

      10.1039/C9RA04326H

    • 査読あり / 国際共著
  • [雑誌論文] Nanoarchitectured Metal Phosphates and Phosphonates: A New Material Horizon toward Emerging Applications2019

    • 著者名/発表者名
      Bhanja Piyali、Na Jongbeom、Jing Tang、Lin Jianjian、Wakihara Toru、Bhaumik Asim、Yamauchi Yusuke
    • 雑誌名

      Chemistry of Materials

      巻: 31 ページ: 5343~5362

    • DOI

      10.1021/acs.chemmater.9b01742

    • 査読あり / 国際共著

URL: 

公開日: 2021-01-27  

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